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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" dtd-version="3.0"><?xmltex \makeatother\@nolinetrue\makeatletter?>
  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">BG</journal-id>
<journal-title-group>
<journal-title>Biogeosciences</journal-title>
<abbrev-journal-title abbrev-type="publisher">BG</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Biogeosciences</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1726-4189</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/bg-12-7453-2015</article-id><title-group><article-title>Age–depth model of the past 630 kyr for Lake Ohrid (FYROM/Albania) based on
cyclostratigraphic <?xmltex \hack{\newline}?>analysis of downhole gamma ray data</article-title>
      </title-group><?xmltex \runningtitle{Age--depth model of the past 630\,kyr for Lake Ohrid}?><?xmltex \runningauthor{H.~Baumgarten et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Baumgarten</surname><given-names>H.</given-names></name>
          <email>henrike.baumgarten@liag-hannover.de</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Wonik</surname><given-names>T.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Tanner</surname><given-names>D. C.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-9488-8631</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Francke</surname><given-names>A.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-0370-5802</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Wagner</surname><given-names>B.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Zanchetta</surname><given-names>G.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-7080-9599</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Sulpizio</surname><given-names>R.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-3930-5421</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Giaccio</surname><given-names>B.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Nomade</surname><given-names>S.</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Leibniz Institute for Applied Geophysics, Section Rock Physics &amp;
Borehole Geophysics, Hanover, Germany</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>University of Cologne,
Institute for Geology and Mineralogy, Cologne, Germany</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>University
of Pisa, Dipartimento di Scienze della Terra, Pisa, Italy</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>University of Bari Aldo Moro, Dipartimento di Scienze della Terra e
Geoambientali, Bari, Italy</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Instituto di Geologia Ambientale e
Geoingegneria – CNR, Rome, Italy</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Laboratoire des Sciences du Climat et de
l'Environnement, IPSL, laboratoire CEA/CNRS/UVSQ, Gif-Sur-Yvette, France</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">H. Baumgarten (henrike.baumgarten@liag-hannover.de)</corresp></author-notes><pub-date><day>17</day><month>December</month><year>2015</year></pub-date>
      
      <volume>12</volume>
      <issue>24</issue>
      <fpage>7453</fpage><lpage>7465</lpage>
      <history>
        <date date-type="received"><day>18</day><month>February</month><year>2015</year></date>
           <date date-type="rev-request"><day>22</day><month>May</month><year>2015</year></date>
           <date date-type="rev-recd"><day>2</day><month>December</month><year>2015</year></date>
           <date date-type="accepted"><day>3</day><month>December</month><year>2015</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/3.0/">http://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015.html">This article is available from https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015.html</self-uri>
<self-uri xlink:href="https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015.pdf">The full text article is available as a PDF file from https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015.pdf</self-uri>


      <abstract>
    <p>Gamma ray (GR) fluctuations and potassium (K) values from downhole logging
data obtained in the sediments of Lake Ohrid from 0 to 240 m below lake
floor (b.l.f). correlate with fluctuations in <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values from the
global benthic isotope stack LR04 (Lisiecki and Raymo, 2005). GR and K values
are considered a reliable proxy to depict glacial–interglacial cycles, with
high clastic input during cold and/or drier periods and high carbonate
precipitation during warm and/or humid periods at Lake Ohrid. Spectral
analysis was applied to investigate the climate signal and evolution over the length of
the borehole. Linking downhole logging data with orbital cycles was used to
estimate sedimentation rates and the effect of compaction was compensated
for. Sedimentation rates increase on average by 14 % after decompaction
of the sediment layers and the mean sedimentation rates shift from
45 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> between 0 and 110 m to 30 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> from 110 to
240 m b.l.f. Tuning of minima and maxima of gamma ray and potassium values
versus LR04 extrema, in combination with eight independent
tephrostratigraphical tie points, allows establishing of a robust age model
for the downhole logging data over the past 630 kyr.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p>Lake Ohrid is located at the border between the former Yugoslav Republic of
Macedonia (FYROM) and Albania (40<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>70<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> N, 20<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>42<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> E) in
the central Mediterranean region (Fig. 1a). It is
considered as one of the oldest, continuously existing lakes worldwide. Its
sediments are assumed to contain the climate history over more than
1 million years and numerous endemic species have evolved in Lake Ohrid.
Several pre-site studies between 2004 and 2012, such as multichannel seismic
and shallow coring, demonstrated the potential of Lake Ohrid to yield a
complete and continuous palaeoclimatic record (e.g. Wagner et al., 2008;
Lindhorst et al., 2015). Hydroacoustic data obtained by multichannel airgun
and sediment echosounder seismics revealed undisturbed sediments as well as
certain high-amplitude reflectors, which were interpreted as tephra layers
(Lindhorst et al., 2015). A successful deep drilling campaign by the
International Continental Scientific Drilling Program (ICDP) was performed
in 2013. At the main drill site, the “DEEP site” in the central deep basin
of Lake Ohrid (Fig. 1b), multiple coring and downhole logging tools were
applied.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1"><caption><p><bold>(a)</bold> Regional map of Lake Ohrid in the Mediterranean region
and <bold>(b)</bold> bathymetric map of the lake. The city of Ohrid and the DEEP
drill site from the ICDP campaign are shown (modified after Wagner et al.,
2014).</p></caption>
        <?xmltex \igopts{width=227.622047pt}?><graphic xlink:href="https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015-f01.png"/>

      </fig>

      <p>The reconstruction of Lake Ohrid's climatic, tectonic, and
evolutionary biological history is one of the key objectives of the project
Scientific Collaboration on Past Speciation Conditions in Lake Ohrid
(SCOPSCO). This requires a reliable temporal framework of the biotic and
abiotic events and thus the establishment of a robust age–depth model. This
can be achieved by tephrostratigraphy (Sulpizio et al., 2010; Vogel et al.,
2010c), the use of radiometric ages (e.g. from dating of volcanic material
in the cores), or by tuning proxy data, such as <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O or TOC, to
reference records (Lang and Wolff, 2011; Stockhecke et al., 2014). Suitable
material for independent dating, e.g. well-preserved and coarse-grained
tephra layers, is often rare or hard to detect in sediments. Even if age
control points are available, changes in the sedimentation rate between
these points remain an uncertain interpolation. Amongst proxy data, the
effect of global climate signals (Milanković cycles; Milanković,
1920) can be used to construct the temporal framework of a sedimentary
record (Batenburg et al., 2012; Prokopenko et al., 2006; Wu et al., 2012).
These cycles have periodicities of 100 kyr (eccentricity; <inline-formula><mml:math display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula>), 41 kyr
(obliquity; O), and 23 and 19 kyr (precession; <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and determine
the intensity of the solar insolation on Earth, whereas their effect is
non-uniform and depends on the location of a certain site (e.g. the effect
of O is strongest at polar regions) (Pälike, 2005). The 100 kyr cycle
dominates the past ca. 900 kyr (Berger and Loutre, 2010), which is evident in
sedimentary records and strongly imprinted in the widely used global climate
reference record (LR04 stack from benthic foraminifera <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O)
(Lisiecki and Raymo, 2005, 2007). To apply cyclostratigraphic methods
successfully, generation and preservation of cycles is required, as well as
their continuous recording. Such conditions are favoured in marine
environments and ice cores, which are commonly used to analyse cyclicities
(Barthes et al., 1999; Golovchenko et al., 1990; Jarrard and Arthur, 1989;
Jouzel et al., 2007; Molinie and Ogg, 1990a). However, several lacustrine
sequences have also recorded global climate signals and have been used for
cyclostratigraphic studies (Baumgarten and Wonik, 2015; Bogota-A et al.,
2011; Nowaczyk et al., 2013; Prokopenko et al., 2006). Whereas the majority
of studies were performed on proxies from sediment cores (e.g. <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, organic matter, or pollen), analysis of physical properties from
downhole logging have also been successful (Barthes et al., 1999;
Golovchenko et al., 1990; Jarrard and Arthur, 1989; Molinie and Ogg, 1990b;
Wonik, 2001).</p>
      <p>Physical in situ properties can be only achieved by downhole logging methods
and provide a first data set that is available within hours after the tools
are run in hole. Contrasting physical properties and therefore changes in the
sediment characteristics (e.g. sedimentological composition, grain size) can
trigger cyclic changes in the logging data (Baumgarten and Wonik, 2015;
Kashiwaya et al., 1999; Paulissen and Luthi, 2011; Scholz et al., 2011). Such
cyclic changes can potentially be revealed by applying cyclostratigraphic
methods. The aim of this study is the generation of a robust age–depth model
down to 240 m below lake floor (m b.l.f.) by an integrated study of
downhole data with tephrostratigraphic age control from the sediment cores.
Special emphasis is given to the effect of compaction and its subsequent
impact on estimates of sedimentation rates. Furthermore, the response of the
physical in situ properties from spectral gamma ray (contents of potassium,
thorium, and uranium) and their application as proxy for changing
environmental conditions in the catchment area is investigated.</p>
</sec>
<sec id="Ch1.S2">
  <title>Setting and sediment dynamics of Lake Ohrid</title>
      <p>Lake Ohrid is located on the Balkan Peninsula at an altitude of 693 m above
sea level in a northwest-trending active tectonic graben. It is considered
to have formed within a first stage in the Late Miocene as a pull-apart basin
and during a second stage in the Pliocene by E–W extension which led to the
recent geometry (Lindhorst et al., 2015). The lake is considered be the
oldest continuously existing lake in Europe, as supported by molecular clock
analysis, which estimates the onset of the lake formation to be 1.5 to 3 Ma
(Trajanovski et al., 2010; Wagner et al., 2014). It houses an extraordinary
number of endemic species (&gt; 200, e.g. ostracodes), and it is
therefore considered to be a hotspot to study the evolution of the various
species (Albrecht and Wilke, 2008).</p>
      <p>Oligotrophic Lake Ohrid has a surface area of 360 km<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> and a water depth
of up to 290 m. The water originates mainly from karst inflows (50 %),
precipitation (25 %), and surface runoff (25 %). The karst springs
are primarily fed by the “sister lake” Prespa, 150 m higher in elevation
(Wagner et al., 2014). The recent local climate is characterized by warm dry
summers (mean temperature 26 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) and cold winters
(<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C). The annual precipitation is about 750 mm and winds are
prevailing southerly or northerly, which is topographically controlled by the
shape of the lake basin (Vogel et al., 2010a).</p>
      <p>Due to its downwind location of most of the Quaternary volcanoes of
central-southern Italy, Lake Ohrid's sediments can provide a record of the
volcanic history of the northern Mediterranean region (Sulpizio et al.,
2010). The catchment area southeast and northwest of the lake mostly
consists of Triassic carbonates and clastics, whereas ophiolites (nickel-,
iron-, and chromium-bearing) are exposed on the western and southwestern shore
(Vogel et al., 2010b).</p>
      <p>The sediment dynamics for the past 150 kyr have been investigated by up to
15 m long sediment cores from different marginal parts of the lake basin
(e.g. Wagner et al., 2009, Belmecheri et al., 2009, Vogel et al., 2010a). Two
major lithofacies are distinguished: A, sediments with high
detrital clastic content with no or very low carbonate content, together with
low organic matter and few diatoms, and B, sediments with high content of
carbonates, abundant ostracodes, minor amounts of clastics, and high contents
of organic matter. Lithofacies A is associated with glacial conditions
(marine isotope stages: MIS 2, 4, 6), high clastic supply, and low lake
productivity, whereas lithofacies B formed during interglacial conditions
(mainly during MIS 1 and 5), with high lake productivity and formation of
authigenic carbonates. Age control of the last glacial cycle was obtained by
radiocarbon dating and tephrochronology.</p>
</sec>
<sec id="Ch1.S3">
  <title>Methods and background</title>
<sec id="Ch1.S3.SS1">
  <title>Downhole logging data acquisition and processing</title>
      <p>The multiple-cored DEEP site has six parallel and overlapping boreholes (A to
F), of which holes A and E only cover the uppermost few metres of the
sediment succession. Each of the deeper holes was drilled with a diameter of
149 mm and water-based mud was used to clean the holes of cuttings and to
stabilize the side walls during the coring process. Hole C was logged
immediately after drilling down to 470 m b.l.f., and amongst other probes,
such as a resistivity and borehole televiewer, a spectral gamma ray (SGR) and
sonic probe were used. To prevent the unconsolidated sediments from caving in, the
SGR probe was run through the drill pipe and a continuous record of the
sediments down to 470 m b.l.f. was achieved. The SGR data were acquired
using the SGR 70-slimhole tool of the Leibniz Institute for Applied
Geophysics (LIAG), which records the total gamma radiation (GR), as well as
the spectral components (potassium, K; thorium, Th; and uranium, U) and their
contribution to the GR. The tool was run at a logging speed of
3 m min<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and a sampling rate of 10 cm. The achievable minimum bed
resolution is controlled by the size of the bismuth germanate crystal
(5 <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 15 cm) and the characteristics of the target formation such as
the absolute value range and contrast of values between neighbouring beds
(Theys, 1991). The vertical resolution is estimated to 15–20 cm. The
sonic tool, which measures the seismic velocity (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), was applied afterwards at a speed of 4 m min<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and
a depth increment of 10 cm. To allow open-hole measurements by sonic logging, the
drill pipes were successively pulled upwards until open hole sections of
ca. 50 m were accessible. The uppermost 30 m b.l.f. could not be logged by
the sonic tool, because some drill pipes were kept in hole to allow other
probes to enter. The measuring principles are described by Rider and Kennedy
(2011) and the tools are specified in Buecker et al. (2000) and Barrett et
al. (2000). The data were acquired, preprocessed, and processed with the
software GeoBase<sup>®</sup> (Antares, Germany) and
WellCAD<sup>®</sup> (Advanced Logging Technology,
Luxembourg).</p>
</sec>
<sec id="Ch1.S3.SS2">
  <title>Sliding window method</title>
      <p>Sedimentary cycles in lake records can be studied by cyclostratigraphic
methods for a potentially orbitally driven origin (Lenz et al., 2011;
Prokopenko et al., 2001; Weedon, 2003). To investigate wavelengths and
amplitude of the contained signals, fast Fourier transform (Weedon, 2003)
can be applied. The sliding window method (windowed Fourier
transform) (Baumgarten and Wonik, 2015; Molinie and Ogg, 1990b; Torrence and
Compo, 1998; Weedon, 2003) can be applied to identify the distribution of
cycles within a series and their evolution over the data set: the spectral
analysis is calculated for a depth interval of specific length (window size)
and the resulting spectrum is allocated to the centre of the window.
Subsequently, the window is moved downwards by a certain step size and the
analysis is repeated at consecutive depth positions until the window border
reaches the end of the data set. The results are presented in a
three-dimensional spectrogram with colour coding of the relative power of
the different frequency components. Generally, a small window size is
favourable to maximize the length of the resulting plot. However, the
contained cycle needs to be covered and cannot be determined if the window
size was chosen too short, e.g. only half the signal's wavelength. The
optimal window size is determined by empirical testing. Spectral analysis
for identification of the characteristic periodicities (Jenkins and Watts,
1969; Priestley, 1981) was performed on normalized SGR data using fast
Fourier transform within MATLAB (MathWorks<sup>®</sup>).</p>
      <p>The detection of cycles by SGR logging is limited by the Nyquist frequency,
which is
twice the sampling rate (Molinie and Ogg, 1990a). The temporal resolution can
be estimated by the vertical resolution of the applied tools and the averaged
sedimentation rate. For a mean sedimentation rate of, for example, 38 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>,
cycles in the range of 0.8 to 1.1 kyr are resolvable by SGR logging.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F2" specific-use="star"><caption><p><bold>(a)</bold> Correlation of downhole GR and K data from 0 to
240 m b.l.f. with LR04 (Lisiecki and Raymo, 2005) from 0 to 630 ka. The
age–depth range was set by eight anchor points from tephrochronology. Warm
and/or humid periods correlate with periods of low GR and K values.
<bold>(b)</bold> An age scale was applied to the downhole logging data (GR and K)
based on tie points to LR04 (Lisiecki and Raymo, 2005) and from
tephrochronology. <bold>(c)</bold> A synthetic curve calculated by linear regression between
GR on timescale and LR04. Both curves are displayed as overlay and three
zones are identified. A: 630 to 430 ka (MIS 15 to 12); B: 430 to 185 ka
(MIS 11 to 7); C: 185 to 0 ka (MIS 6 to 1). <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mtext>calc</mml:mtext></mml:msub></mml:math></inline-formula>
is prevailing decreased during zones A and C (dark-green colour) and higher
in zone B (light-green colour) compared to LR04. K – potassium content from spectral gamma ray; GR – total
gamma radiation; MIS – marine isotope stage; m b.l.f. – metres below lake
floor.</p></caption>
          <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015-f02.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS3">
  <title>Depth matching of downhole logging and core data</title>
      <p>In this study, downhole logging data, in conjunction with stratigraphically
aligned tephra layers in the cores, is used to construct an age–depth model.
Therefore, matching of core and logging depth is required. To provide age
control by distinct tephra layers, the layers need to be identified in the cores
by visual description or by their physical properties, such as
susceptibility from core logging, in contrast to the background sediments.
Artifacts in the coring process, such as incorrect depth allocation of coring tools or gas extension of sediments due to pressure release, produce erroneous depth. Furthermore, depth shifts between core and
logging depth are generated because the downhole data originate from one
hole (C; down to 470 m b.l.f.) and the core composite record (see Francke et
al.; 2015) is composed of four different holes which are tens of metres
apart. The depth of a distinct sediment layer may differ up to 3 to 4 m
between these holes. The matching of borehole logging data and sediment core
is described in detail in Francke et al. (2015) and based on a correlation
of K contents from SGR with K intensities from X-ray fluorescence (XRF)
scanning, and using magnetic susceptibility from downhole logging and multi-sensor core logging (MSCL) on sediment cores. Trends and patterns were
compared and matched; the larger features were preferred over correlation of
small-scale features in the data. Cross correlation was used to prevent
systematic depth shifts of these data sets and for quality control.</p>
</sec>
<sec id="Ch1.S3.SS4">
  <title>Compaction</title>
      <p>To perform cyclostratigraphic studies and to estimate an age–depth
relationship and sedimentation rates, compaction and associated reduction of
sediment thickness due to overburden pressure must be considered. The
original (decompacted) thickness of the sediments can be calculated if the
initial (surface) porosity and the compaction coefficient (Brunet, 1998) can
be determined. The amount of porosity decrease with greater depth depends on
sediment properties, such as grain size and sorting (Serra and Serra, 2003),
and can be expressed as
            <disp-formula id="Ch1.E1" content-type="numbered"><mml:math display="block"><mml:mrow><mml:mi mathvariant="normal">Φ</mml:mi><mml:mo>(</mml:mo><mml:mi>z</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="normal">Φ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>⋅</mml:mo><mml:msup><mml:mi>e</mml:mi><mml:mrow><mml:mo>(</mml:mo><mml:mo>-</mml:mo><mml:mi>c</mml:mi><mml:mi>z</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:msup><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where the porosity (<inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">Φ</mml:mi></mml:math></inline-formula>) at a specific depth (<inline-formula><mml:math display="inline"><mml:mi>z</mml:mi></mml:math></inline-formula>) is to be
estimated; <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="normal">Φ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the initial porosity and <inline-formula><mml:math display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> is the compaction
coefficient (Athy, 1930; Brunet, 1998).</p>
      <p>Porosity can be measured directly on the sediment cores, e.g. by Archimedean
weighing. However, the physical properties, in particular from
(unconsolidated) sediment cores, are typically disturbed due to drilling,
release of pressure, and core handling. Therefore, measurements by downhole
logging are more suitable; in situ porosity can be gained by neutron porosity
logging or derived, e.g. from bulk density. These tools operate with
radioactive methods and the import procedure into foreign countries is
usually extremely complicated and seldom successful. Therefore, the
radioactive tools from the LIAG could not be used at Lake Ohrid. However,
porosity was derived by an empirical relationship from sonic data (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>)
(Erickson and Jarrard, 1998), which were recorded continuously from below
30 m b.l.f. The software 2DMove<sup>®</sup> (Midland
Valley Exploration Ltd.) was used to decompact the sediments and calculate
the original sediment thickness.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <title>Results</title>
<sec id="Ch1.S4.SS1">
  <title>Selection of SGR data</title>
      <p>The output curves from SGR were compared to estimate the contribution of the
spectral components to the total gamma ray. GR is mainly controlled by K and
Th, which develop uniformly (<inline-formula><mml:math display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> &gt; 0.9). GR and K were used for
further investigations. K was chosen over Th, because it is also available
from XRF core scanning and the interpretation can be reviewed easily.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <?xmltex \opttitle{Correlation of GR with the global climate reference $\delta^{{18}}$O
record}?><title>Correlation of GR with the global climate reference <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O
record</title>
      <p>The downhole logging data (GR and K) from 0 and 240 m b.l.f. was compared to the
global benthic isotope stack LR04 (Lisiecki and Raymo, 2005). In order to
select an appropriate temporal window, we considered the current age
estimates from stratigraphical aligned tephra layers (eight age–depth
points; Table 1). After the anchor points from tephra deposits were defined,
significant variations in the data were correlated; a very similar cyclicity
with a positive correlation between GR and K from downhole logging data and
<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O data was observed (Fig. 2a). The onset and terminations of
several marine isotope stages can be easily distinguished in the downhole logging data,
whereas warm and/or humid periods (decreased <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values)
correlate with low GR values. Thirty additional tie points (Table 1) were set
due to the strong similarities between the curves characteristics. After
matching these tie points, high correlation of both data sets (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>R</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 0.75)
was observed. The tephra ages and tie points from correlation between GR, K, and LR04 were used to assign a (preliminary) timescale to the data
(Fig. 2b). Within the data, the timescale between the tie points was
generated by linear interpolation. According to the established age model,
the 240 m long sediment succession covers a time period between 630 ka
(including MIS 15) and the present.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><caption><p>Downhole logging data correlated to LR04 (Lisiecki and Raymo, 2005).
Eight anchor points from tephrochronology (Leicher et al., 2015)  and 30 additional tie points of
significant features between the downhole data and LR04 are set. The tephra
ages were recalculated (except Y-3) according relative to ACs-2 at 1.193 Ma
(Nomade et al., 2005) and the total decay constant of Steiger and
Jäger (1977), uncertainties are 2<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>. m b.l.f. – metres below
lake floor.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Depth</oasis:entry>  
         <oasis:entry colname="col2">Age from LR04 tie points</oasis:entry>  
         <oasis:entry colname="col3">Age from   tephra tie points</oasis:entry>  
         <oasis:entry colname="col4">Correlated eruption/tephra</oasis:entry>  
         <oasis:entry colname="col5">Reference</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">m b.l.f.</oasis:entry>  
         <oasis:entry colname="col2">ka</oasis:entry>  
         <oasis:entry colname="col3">ka</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">1.46</oasis:entry>  
         <oasis:entry colname="col2">4</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">13.67</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">29</oasis:entry>  
         <oasis:entry colname="col4">Y-3</oasis:entry>  
         <oasis:entry colname="col5">Albert et al., 2014</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">19.35</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">39</oasis:entry>  
         <oasis:entry colname="col4">Y-5 (Campanian Ignimbrite)</oasis:entry>  
         <oasis:entry colname="col5">De Vivo et al. (2001)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">24.37</oasis:entry>  
         <oasis:entry colname="col2">49</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">30.17</oasis:entry>  
         <oasis:entry colname="col2">62</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">36.41</oasis:entry>  
         <oasis:entry colname="col2">78</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">40.10</oasis:entry>  
         <oasis:entry colname="col2">87</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">48.40</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">109 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2</oasis:entry>  
         <oasis:entry colname="col4">X-6</oasis:entry>  
         <oasis:entry colname="col5">Iorio et al. (2013)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">55.11</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">129 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6</oasis:entry>  
         <oasis:entry colname="col4">P11</oasis:entry>  
         <oasis:entry colname="col5">Rotolo et al. (2013)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">59.19</oasis:entry>  
         <oasis:entry colname="col2">140</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">66.73</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">162 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6</oasis:entry>  
         <oasis:entry colname="col4">Vico B</oasis:entry>  
         <oasis:entry colname="col5">Laurenzi and Villa (1987)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">74.61</oasis:entry>  
         <oasis:entry colname="col2">171</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">85.09</oasis:entry>  
         <oasis:entry colname="col2">185</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">97.00</oasis:entry>  
         <oasis:entry colname="col2">206</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">103.40</oasis:entry>  
         <oasis:entry colname="col2">223</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">106.48</oasis:entry>  
         <oasis:entry colname="col2">230</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">112.10</oasis:entry>  
         <oasis:entry colname="col2">246</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">121.75</oasis:entry>  
         <oasis:entry colname="col2">271</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">132.92</oasis:entry>  
         <oasis:entry colname="col2">294</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">144.00</oasis:entry>  
         <oasis:entry colname="col2">317</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">150.65</oasis:entry>  
         <oasis:entry colname="col2">342</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">153.76</oasis:entry>  
         <oasis:entry colname="col2">350</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">161.52</oasis:entry>  
         <oasis:entry colname="col2">374</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">167.80</oasis:entry>  
         <oasis:entry colname="col2">392</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">170.04</oasis:entry>  
         <oasis:entry colname="col2">398</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">178.29</oasis:entry>  
         <oasis:entry colname="col2">433</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">183.28</oasis:entry>  
         <oasis:entry colname="col2">456</oasis:entry>  
         <oasis:entry colname="col3">457 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2</oasis:entry>  
         <oasis:entry colname="col4">Pozzolane Rosse</oasis:entry>  
         <oasis:entry colname="col5">Giaccio et al. (2013)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">201.31</oasis:entry>  
         <oasis:entry colname="col2">508</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">203.05</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">511 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6</oasis:entry>  
         <oasis:entry colname="col4">Acerno A10-A9</oasis:entry>  
         <oasis:entry colname="col5">Petrosino et al. (2014)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">206.70</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">527 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2</oasis:entry>  
         <oasis:entry colname="col4">Tufo Bagni Albule</oasis:entry>  
         <oasis:entry colname="col5">Marra et al. (2009)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">209.09</oasis:entry>  
         <oasis:entry colname="col2">536</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">212.89</oasis:entry>  
         <oasis:entry colname="col2">549</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">215.53</oasis:entry>  
         <oasis:entry colname="col2">557</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">219.20</oasis:entry>  
         <oasis:entry colname="col2">568</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">220.99</oasis:entry>  
         <oasis:entry colname="col2">574</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">225.44</oasis:entry>  
         <oasis:entry colname="col2">585</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">240.00</oasis:entry>  
         <oasis:entry colname="col2">630</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p>The conspicuous similarity of the data sets allows calculation of a synthetic
<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O curve from GR by a regression of both data sets. Therefore,
normally distributed data are required and thus the prominent tephra layers at
20 and 68 m b.l.f. (Fig. 2c) were considered to be outliers and removed. Best
results were achieved by a linear solution (<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 0.60) as follows:
            <disp-formula id="Ch1.E2" content-type="numbered"><mml:math display="block"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup><mml:msub><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mtext>calc</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:mi mathvariant="normal">‰</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mn>3.19</mml:mn><mml:mo>+</mml:mo><mml:mn>0.03</mml:mn><mml:mo>⋅</mml:mo><mml:mtext>GR</mml:mtext><mml:mo>.</mml:mo><mml:mo>(</mml:mo><mml:mtext>gAPI</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:math></disp-formula>
          Whereas cycles and trends are similar in both data sets, the amplitudes
between the LR04 stack and the synthetic <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O (derived from GR;
<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mtext>calc</mml:mtext></mml:msub></mml:math></inline-formula>; Fig. 2c) do not completely match. The <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mtext>calc</mml:mtext></mml:msub></mml:math></inline-formula> values from 630 to 430 ka are lower than compared to
LR04. From 430 to 185 ka the amplitude of <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mtext>calc</mml:mtext></mml:msub></mml:math></inline-formula> is
higher and during the past 185 kyr, <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mtext>calc</mml:mtext></mml:msub></mml:math></inline-formula> is mostly
decreased compared to LR04. These three zones (A to C) are indicated in
Fig. 2c.</p>
</sec>
<sec id="Ch1.S4.SS3">
  <title>Spectral characteristics of GR data, temporal evolution, and
sedimentation rates</title>
      <p>After visual comparison of GR and K with LR04 documenting a strong
correlation of periods with low GR and K with warm and/or humid periods, the
application of spectral analysis by sliding window analysis objectively
identifies the possible cycles and their temporal distribution. The spectral
analysis was calculated with a window of 90 m length and a step size of
1 m. Thus, the stepwise calculation for the depth section from 0 to
240 m b.l.f. and the resulting three-dimensional spectral plot (Fig. 3a) is
composed of 150 spectra. The plot ranges from 45 to 240 m b.l.f., because
the first spectrum is allocated to the window centre (Sect. 3.2) and
therefore half of the window length is not displayed. Two prominent spectral
peaks are evident in the data set, as indicated by colour with wavelengths of
30 and 45 m. The distribution of the cycles is non-uniform along the data set
and a break in the spectral characteristics occurs at about 110 m b.l.f.
Based on the reduced relative power of the 30 m signal and the subsequent
increased power of the 45 m frequency at 110 m b.l.f., the plot can be
split into a lower interval I and an upper interval II (Fig. 3a). In
addition, two single spectra from depths of 170 and 50 m b.l.f. (Fig. 3b,
c) are displayed.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><caption><p><bold>(a)</bold> Three-dimensional spectrogram from sliding window analysis of GR
data from 0 to 240 m b.l.f. The relative power of the frequency components
is indicated by colour and two spectral peaks with wavelengths of 30 and
45 m are apparent. Based on the break in the spectral characteristics at
about 110 m b.l.f., the spectral plot was subdivided into a lower interval
I (240 to 110 m b.l.f.) and an upper interval II (110 to 0 m b.l.f.).
Single spectra of GR from interval I at 170 m b.l.f. <bold>(b)</bold> and from
interval II at 50 m b.l.f. <bold>(c)</bold> are displayed below and show that
the wavelengths of 30 and 45 m are prominent. The dashed line separates the
spectral background from the spectral peaks.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015-f03.png"/>

        </fig>

      <p>The similar cyclicity in the LR04 stack and GR (Fig. 2a, b) suggests that the
100 kyr cycle, known as dominant periodicity in sedimentary archives for the
past ca. 900 kyr and clearly documented in the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O data, has the
strongest effect on the cyclic characteristics of the GR data. The highest
amplitudes were therefore linked to the 100 kyr cycle. Averaged
sedimentation rates can be calculated using this link (45 m <inline-formula><mml:math display="inline"><mml:mo>≡</mml:mo></mml:math></inline-formula> 100 kyr cycle) for 110 to 0 m b.l.f. as follows:
            <disp-formula id="Ch1.E3" content-type="numbered"><mml:math display="block"><mml:mrow><mml:mn>45</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>m</mml:mtext><mml:mo>/</mml:mo><mml:mn>100</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mtext>kyr</mml:mtext><mml:mo>=</mml:mo><mml:mn>45</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>cm</mml:mtext><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mtext>kyr</mml:mtext><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p>Furthermore, the time of deposition can be estimated by using this
sedimentation rate and the length of the interval II (length of 110 m):
            <disp-formula id="Ch1.E4" content-type="numbered"><mml:math display="block"><mml:mrow><mml:mn>110</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mtext>m</mml:mtext><mml:mo>/</mml:mo><mml:mn>45</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mtext>cm</mml:mtext><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mtext>kyr</mml:mtext><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mo>=</mml:mo><mml:mn>244</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>ka</mml:mtext><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p>The sedimentation rate for interval I (length of 130 m) can be calculated as
30 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (30 m <inline-formula><mml:math display="inline"><mml:mo>≡</mml:mo></mml:math></inline-formula> 100 kyr cycle). Thus, for interval I the duration
of deposition of 433 ka is calculated, which gives an overall time of
deposition (sum of interval I and II) of 677 ka.</p>
      <p>The sedimentation rates from sliding window analysis show a distinct shift from 30 to
45 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> at 110 m b.l.f. (Fig. 4). However, the sedimentation
rates from visual tying to LR04 are more variable and range from 22 to
71 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. Exceptionally high sedimentation rates occurred during
MIS 6 and lowest sedimentation rates occurred during MIS 11 and 13. The
sedimentation rates from LR04 tie points were averaged over the length of the
intervals and show mean values of 35 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for interval I and
48 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for interval II (Fig. 4).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><caption><p>Estimates of sedimentation rates from 0 to 240 m b.l.f. based on
visual correlation and tying to the timescale of LR04 (blue; Lisiecki and
Raymo, 2005) and sliding window analysis with linking of high amplitudes to
the 100 kyr cycle (green). The sedimentation rates from sliding window
analysis show an increase from 30 to 45 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> at about
110 m b.l.f., whereas results from tie points are more variable and range
from 22 to 71 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. The dashed red line indicates the mean values
of the sedimentation rates from LR04 tie points for interval I and II. Marine isotope
stages (MIS) from 1 to 15 are labelled.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015-f04.png"/>

        </fig>

<?xmltex \hack{\newpage}?>
</sec>
<sec id="Ch1.S4.SS4">
  <title>Decompaction of the pelagic sediments and subsequent spectral analysis
on GR data on decompacted depth scale</title>
      <p>The effect of decreased sediment thicknesses due to compaction over time was
determined to investigate its impact on the estimates of sedimentation
rates. The <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> data from sonic logging were used to derive porosity after
Erickson and Jarrard (1998). The porosity values were averaged for layers of
100 m thickness (Fig. 5a). The initial porosity (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="normal">Φ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> was
determined at 80 % and the compaction coefficient was estimated at
0.39 km<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. These parameters were used as input data for modelling
decompaction of the sediments, and the 2-D model was calculated for layers of
50 m thickness. The modelling process starts with the removal of the top
layer and subtraction of its overburden pressure. The new thicknesses of the
lowermost layers are thereafter calculated and these steps were repeated
again downwards. The resulting thicknesses of the sediment layers after
decompaction show a quasi-linear increase with greater depth for these small
depths (Fig. 5b). Decompaction of the sediment layers ranges from 10 to
30 % downwards and the cumulative thickness of the sediment sequence
(present thickness of 250 m) is increased by 35 m (to 285 m).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><caption><p><bold>(a)</bold> Porosity values derived from sonic (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) after Erickson
and Jarrard (1998) from 30 to 250 m b.l.f. Average values for intervals of
100 m length were calculated as indicated by the black line and values for
the top 30 m of the sediments were linear interpolated (dashed black line).
An initial porosity (surface porosity) of 80 % was used for modelling of
compaction by 2DMove. <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">Φ</mml:mi></mml:math></inline-formula> – porosity; <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> – <inline-formula><mml:math display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> wave velocity from
sonic.
<bold>(b)</bold> Sediment layers of thicknesses of 50 m are modelled applying the
software 2DMove. The cumulative present layer thickness of 250 m is extended
after decompaction to 285 m (original layer thickness).
<bold>(c)</bold> The GR data from 0 to 240 m b.l.f. and the intervals from subdivision
by spectral characteristics at about 110 m b.l.f. (left). The data were
stretched to the estimates of the original layer thickness. The decompacted
depth and new interval borders are displayed (right).
<bold>(d)</bold> Result from sliding window analysis of GR data on decompacted
depth scale. Two spectral peaks with wavelengths of 36 and 48 m are
emphasized. GR – gamma ray; m b.l.f. – metres below lake floor.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015-f05.png"/>

        </fig>

      <p>The GR data were stretched (Fig. 5c) and subsequently spectrally analysed by
sliding window method (Fig. 5d) to determine the effect of decompaction on the
spectral analysis. The spectral analysis shows two spectral peaks (Fig. 5d;
wavelength of 36 m from 276 to 118 m and wavelength of 48 m from 118 to
0 m). Linking these spectral peaks to the 100 kyr cycle provided
sedimentation rates of 36 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for interval I and
48 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for interval II. Times of deposition remain constant and
are 433 ka for interval I and 244 ka for interval II.</p>
</sec>
</sec>
<sec id="Ch1.S5">
  <title>Discussion</title>
<sec id="Ch1.S5.SS1">
  <?xmltex \opttitle{Climate response of GR over the past 630\,kyr}?><title>Climate response of GR over the past 630 kyr</title>
      <p>The strong correlation of GR and K with LR04 (low GR and K during warm and/or
humid periods, high in cold and/or drier periods) suggests a response of
the sedimentary system to the temperature and hydrological changes related
to the global ice-volume fluctuations during the glacial–interglacial
cycles. The fluctuations are likely to be controlled by the input and
deposition of clastics (K and Th sources), which are suggested to have
increased during the past ca. 136 kyr, when glacial conditions prevailed
(except MIS 1 and 5e) at Lake Ohrid (Vogel et al., 2010a). In particular,
the reduced input of organic matter and calcium carbonate during cold and/or
drier periods seems to amplify the enhanced input of clastic material.
During warm and/or humid periods, carbonate production and preservation is
increased (Vogel et al., 2010a). In combination with higher organic matter
flux, the clastic content of the sediments is reduced and the GR and K data
are lower. Either the total content of clastics is lower during warm-humid
periods or the amount is decreased relative to carbonate and organic
matter (diluted). However, as discussed by Vogel et al. (2010a), less
vegetation cover during cold and drier periods is likely and also suggests
increased erosion in the catchment and subsequent higher input of clastic
material. Based on our interpretation, these cyclic changes from
carbonate-rich to clastic-rich sedimentation were constant at least for the
past 630 kyr.</p>
      <p>Three zones were observed, based on amplitude differences between the
synthetic <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O curve from GR (<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mtext>calc</mml:mtext></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and
the referenced record: A, 630 to 430 ka (MIS 15 to MIS 12); B, 430 to 185 ka
(MIS 11 to MIS 7); C, 185 to 0 ka (MIS 6 to MIS 1). Comparison of the
synthetic <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mtext>calc</mml:mtext></mml:msub></mml:math></inline-formula> to LR04 revealed systematically lower
values in zones A and C and higher values in zone B.</p>
      <p>We suggest the following reasons of the GR signature:</p>
      <p><list list-type="order">
            <list-item>
              <p>Climate-dependent supply and deposition of K-rich clastics (feldspars,
clays). They are increased during cold, dry periods (high GR) and decreased
during warm, wet periods (high carbonate deposition; low GR) in the
sediments.</p>
            </list-item>
            <list-item>
              <p>Tephra layers that are partly recognizable in the GR/K data (increased
GR). Even if the prominent layers at 20 and 68 m b.l.f. could be removed,
at least 6 additional tephra layers (see tephra tie points; Fig. 2b) were
identified in the cores down to 240 m b.l.f. These thin layers (thickness
&lt; 10 cm) are not recognizable easily in the GR data and could not
be removed but are assumed to contribute to the GR/K curve. Their occurrence
in zones A and C (Fig. 2c; zones of decreased synthetic <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O)
suggests that they have an effect on the GR signature.</p>
            </list-item>
            <list-item>
              <p>Variations in the catchment area. Outcrops of Triassic carbonates and
clastics occur in large parts in Lake Ohrid's catchment area. Furthermore,
ophiolites, magmatic, and metamorphic rocks are exposed and are potential
sources of terrestrial material. Erosion and transport of these rocks, e.g.
by means of surface runoff into the lake, and
subsequently the input of K-bearing particles, were likely variable over time.</p>
            </list-item>
          </list></p>
      <p>Therefore, the GR is most likely controlled by several factors and cannot be
described in total by linear solution. However, the main component seems to
be a linear response of K-rich sediments to the global climate trend (1).
Further, we consider the attempt useful to compare both data sets and to show
the very unusual similarity in cyclic characteristic between LR04 and GR.</p>
      <p>Matching of GR and K data with the global climate reference record (LR04)
equates the timing of the climate dynamics recorded in the oceans to Lake
Ohrid. This means that if the downhole logging data are tied to this timescale, differences between the response times of Lake Ohrid and the global
climate trend (e.g. lead or lag effects of the onset of terminations) are
lost. However, even if the comparable small system was likely to be subject
to a faster climate response compared to records from the marine realm,
correlation with the global signal and the resulting age–depth model is
verified in large parts (down to 206 m b.l.f.) by tephrochronology.</p>
</sec>
<sec id="Ch1.S5.SS2">
  <title>Sedimentation rates: major trends, small-scale fluctuations, and the
effect of compaction</title>
      <p>The relative power of the spectral peaks from sliding window analysis seems
to be higher in interval I (wavelength of 30 m) in comparison to interval II
(wavelength of 45 m). The strength of the signal depends on the number of
cycles that are detected by spectral analysis. The 45 m long cycle can be
contained up to 2.4 times in the 110 m long interval II, whereas the cycle
of wavelength of 30 m might be recorded more frequently (4.3 times) in the
130 m long interval I. This can contribute to the higher intensity of the
30 m amplitude and thus we cannot interpret a stronger cyclicity for the
lower part.</p>
      <p>Based on sliding window analysis, the sedimentation rates are constant
(30 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) for a long period of time (433 kyr), apart from a shift to
increased rates at about 110 m b.l.f. to 45 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. However, small-scale
variations cannot be resolved due to averaging and the window of 90 m
length used. More variable and realistic results are indicated by tying of GR and
K to LR04. The lowest rates (minimum of 22 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) occur during MIS 13,
11, and 9. Strongly increased sedimentation rates (up to 71 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) occur during
MIS 8 and in particular during MIS 6. Therefore, decreased sedimentation
rates during interglacials and increased rates during glacial periods can be
derived. Even if these fluctuations do not correlate with all MIS, they seem
to be largely coupled to glacial–interglacial dynamics. This trend suggests
higher accumulation of clastic-rich glacial deposits compared to calcium
carbonate-rich deposition during interglacials. The overall trend from lower
mean rates in the bottom part (&gt; 110 m b.l.f., sliding window;
&gt; 130 m b.l.f.; LR04 tie points) to increased values towards the top
is comparable.</p>
      <p>The cumulative time of deposition based on these sedimentation rates and
corresponding sediment thicknesses range from 630 ka (LR04 tie points) to
677 ka (sliding window method) and are overall in a similar range (Fig. 6).
We consider the estimated time of deposition from the tuning to LR04 to be of
higher accuracy compared to the averaged estimates from sliding window
analysis. The agreement with age estimates from cores, based on wiggle
matching of (bio)geochemistry data, such as XRF scanning data, to
LR04 and local insolation patterns (Francke et al., 2015), supports the
age–depth model. Nonetheless, the sliding window method is useful to estimate
averaged sedimentation rates and to provide complementary cyclic
characteristics of the data. Whereas age control from tephrochronology is
only available down to 206 m b.l.f., our interpretation was extended down
to 240 m b.l.f. based on the constant cyclic characteristics.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6"><caption><p>Age–depth model for the sediment depths of 0 to 240 m b.l.f. The
two sedimentation rates were generated by visual tying to LR04 (blue line;
Lisiecki and Raymo, 2005) and by linking of prominent cycles to the 100 kyr
signal (green line). Tephra tie points are indicated by red triangles.
m b.l.f. – metres below lake floor.</p></caption>
          <?xmltex \igopts{width=227.622047pt}?><graphic xlink:href="https://bg.copernicus.org/articles/12/7453/2015/bg-12-7453-2015-f06.png"/>

        </fig>

      <p>The required initial porosity for modelling of the effect of compaction was
derived from sonic logging (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="normal">Φ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 80 %) and is commonly lower
(at ca. 65 %) for sedimentary basins. Studies of physical properties of
marine sediment cores have shown comparable values for seafloor deposits
(<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Φ</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 80 %, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1540 m s<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; Kim and Kim, 2001) and even higher
porosity values (&gt; 80 %; Kominz et al., 2011) for
unconsolidated sediments. The compaction coefficient <inline-formula><mml:math display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> was estimated at
0.39 km<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and lies in the range between <inline-formula><mml:math display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> used for sands (0.20 km<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>
and carbonates (0.50 km<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and thus is considered as
reasonable. The overall trend of a quasi-linear evolution of decompaction
with increasing depth was observed, although Eq. (1) describes an
exponential curve, it can be approximated to a line over short lengths
(&lt; 500 m). This is in accordance with the average linear increase
in <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> with greater depth. The tephra layers, with thicknesses of only a few centimetres,
are considered to have little impact on the compaction of these sediments.</p>
      <p>Spectral analysis of GR data on decompacted depth scale (Fig. 5c) revealed a
very similar spectral characteristic compared to the sliding window plot of
the compacted data. However, the two spectral peaks (wavelengths of 30 and
45 m) are shifted to higher wavelengths and increased to wavelengths of
36 m for interval I and 48 m for interval II. Therefore, the sedimentation
rates are increased accordingly to 36 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and would be
underestimated by 7 to 20 %, if they are not corrected for the effect of
compaction. Underestimation of sedimentation rates from sliding window
analysis is supported by comparison of results from LR04 tie points; the latter
indicate generally higher sedimentation rates (35 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, interval I; 48 cm kyr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, interval II) and show very good agreement with the
estimates of the effect of compaction.</p>
      <p>To determine the time of deposition, two input quantities were used: (1)
sedimentation rates and (2) the thickness of the sediment layer for which
they apply. Due to the stretching of the data set, the resulting
sedimentation rates and the length of the intervals are increased
and thus the duration of deposition remains unchanged. Therefore, the effect
of compaction on this calculation is negligible.</p>
</sec>
</sec>
<sec id="Ch1.S6" sec-type="conclusions">
  <title>Conclusions</title>
      <p>Can climatic indicators be derived from downhole logging, despite its
limited vertical (and temporal) resolution and can these proxies be used to
reconstruct a robust age–depth model?</p>
      <p>The strong response to the global climate signal (LR04) suggests that the K
contents reflect a cyclic change of undisturbed, continuous sedimentation.
Conditions were constant over a long period of time and prevailing in
balance with the global climate. To investigate the response of our data to
the global climate trend, a synthetic <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O curve was generated
that reveals minor deviations compared to LR04. The deviations could
indicate either that the local climatic conditions were not fully in line
with the global climate or that local processes in the sedimentary system
changed over time.</p>
      <p>Within two independent attempts, visual tying to the global reference LR04
record as well as spectral analysis by the sliding window method and linking
of high amplitudes to orbital cycles, a similar result was achieved. To
derive sedimentation rates from spectral analysis, the effect of compaction
must be taken into account. Our results show that the use of the present
thicknesses of the sediment layers underestimates sedimentation rates by an
average of 14 %, which needs to be corrected for by decompaction. In
conjunction with tephrochronology (Leicher et al., 2015) from the same core material, a robust
age–depth model can be established.</p>
      <p>This data set will play a crucial role for other working groups and will
complement the age–depth model from core analysis (Francke et al., 2015).
The combination of both of these age–depth models will provide the temporal framework, e.g. for refining of
the seismo-stratigraphical model by Lindhorst et al. (2015) and contribute
to the reconstruction of Lake Ohrid's climatic, tectonic, and evolutionary
biological history to answer the main research questions of the SCOPSCO
project.</p>
      <p>Due to the successful construction of an age–depth model based on the GR and
K data down to 240 m b.l.f., we are optimistic that the complete lacustrine
sediment succession (down to 433 m b.l.f.) has high potential for
cyclostratigraphic analysis and will provide a key component to determine
Lake Ohrid's temporal framework.</p>
</sec>

      
      </body>
    <back><ack><title>Acknowledgements</title><p>The SCOPSCO Lake Ohrid drilling campaign was funded by ICDP, the German
Ministry of Higher Education and Research, the German Research Foundation,
the University of Cologne, the British Geological Survey, the INGV and CNR
(both Italy), and the governments of the FYROM and Albania. Logistic support
was provided by the Hydrobiological Institute in Ohrid. Drilling was carried
out by Drilling, Observation and Sampling of the Earth's Continental Crust's
(DOSECC) and using the Deep Lake Drilling System (DLDS). Special thanks are
due to Beau Marshall and the drilling team. Ali Skinner and Martin Melles
provided immense help and advice during logistic preparation and the
drilling operation.</p><p>We thank the German Research Foundation for financial support for the
downhole logging (WO 672/10-1). The acquisition of these high-quality data
was only possible due to the great commitment of our technical staff, Thomas
Grelle and Jens Kuhnisch. We thank Midland Valley Exploration Ltd for the use of 2DMove.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: F. Wagner-Cremer</p></ack><ref-list>
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    <!--<article-title-html>Age–depth model of the past 630 kyr for Lake Ohrid (FYROM/Albania) based on
cyclostratigraphic analysis of downhole gamma ray data</article-title-html>
<abstract-html><h6 xmlns="http://www.w3.org/1999/xhtml" xmlns:m="http://www.w3.org/1998/Math/MathML" xmlns:svg="http://www.w3.org/2000/svg">Abstract. </h6><p xmlns="http://www.w3.org/1999/xhtml" xmlns:m="http://www.w3.org/1998/Math/MathML" xmlns:svg="http://www.w3.org/2000/svg" class="p">Gamma ray (GR) fluctuations and potassium (K) values from downhole logging
data obtained in the sediments of Lake Ohrid from 0 to 240 m below lake
floor (b.l.f). correlate with fluctuations in <m:math display="inline"><m:mrow><m:mi mathvariant="italic">δ</m:mi><m:msup level="3"><m:mi/><m:mn>18</m:mn></m:msup></m:mrow></m:math>O values from the
global benthic isotope stack LR04 (Lisiecki and Raymo, 2005). GR and K values
are considered a reliable proxy to depict glacial–interglacial cycles, with
high clastic input during cold and/or drier periods and high carbonate
precipitation during warm and/or humid periods at Lake Ohrid. Spectral
analysis was applied to investigate the climate signal and evolution over the length of
the borehole. Linking downhole logging data with orbital cycles was used to
estimate sedimentation rates and the effect of compaction was compensated
for. Sedimentation rates increase on average by 14 % after decompaction
of the sediment layers and the mean sedimentation rates shift from
45 cm kyr<m:math display="inline"><m:msup level="3"><m:mi/><m:mrow><m:mo>-</m:mo><m:mn mathvariant="normal">1</m:mn></m:mrow></m:msup></m:math> between 0 and 110 m to 30 cm kyr<m:math display="inline"><m:msup level="3"><m:mi/><m:mrow><m:mo>-</m:mo><m:mn mathvariant="normal">1</m:mn></m:mrow></m:msup></m:math> from 110 to
240 m b.l.f. Tuning of minima and maxima of gamma ray and potassium values
versus LR04 extrema, in combination with eight independent
tephrostratigraphical tie points, allows establishing of a robust age model
for the downhole logging data over the past 630 kyr.</p></abstract-html>
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