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<front>
<journal-meta>
<journal-id journal-id-type="publisher">BGD</journal-id>
<journal-title-group>
<journal-title>Biogeosciences Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">BGD</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Biogeosciences Discuss.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1810-6285</issn>
<publisher><publisher-name></publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/bg-2018-438</article-id>
<title-group>
<article-title>Assessment of paleo-ocean pH records from boron isotope ratio in the Pacific 
and Atlantic ocean corals: Role of anthropogenic CO&lt;sub&gt;2&lt;/sub&gt; forcing and oceanographic factors to pH variability</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Tarique</surname>
<given-names>Mohd</given-names>
<ext-link>https://orcid.org/0000-0002-3203-2694</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rahaman</surname>
<given-names>Waliur</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>National Centre for  Polar &amp; Ocean Research, Goa</addr-line>
</aff>
<pub-date pub-type="epub">
<day>15</day>
<month>10</month>
<year>2018</year>
</pub-date>
<volume>2018</volume>
<fpage>1</fpage>
<lpage>37</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2018 Mohd Tarique</copyright-statement>
<copyright-year>2018</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://bg.copernicus.org/preprints/bg-2018-438/">This article is available from https://bg.copernicus.org/preprints/bg-2018-438/</self-uri>
<self-uri xlink:href="https://bg.copernicus.org/preprints/bg-2018-438/bg-2018-438.pdf">The full text article is available as a PDF file from https://bg.copernicus.org/preprints/bg-2018-438/bg-2018-438.pdf</self-uri>
<abstract>
<p>&lt;p&gt;Boron isotopes (&amp;delta;&lt;sup&gt;11&lt;/sup&gt;B) records from tropical ocean corals have been used to reconstruct paleo-pH of ocean for the past several decades to few centuries which are comparable to the resolution of instrumental records. In most of the studies, attempts have been made to decipher the role of anthropogenic CO&lt;sub&gt;2&lt;/sub&gt; forcing to recent trend of ocean acidification based on &amp;delta;&lt;sup&gt;11&lt;/sup&gt;B derived paleo-pH records. However, such attempts in past were often hindered by limited knowledge of oceanographic factors that contributed to past pH variability and changes. In this study, we have evaluated pH records reconstructed using &amp;delta;&lt;sup&gt;11&lt;/sup&gt;B records from the Pacific and the Atlantic Oceans corals and investigated major forcing factors that contributed to sub annual-decadal scale pH variability and changes since the industrial era ~&amp;thinsp;1850&amp;thinsp;AD.&lt;/p&gt;

&lt;p&gt;To the best of our knowledge, total eight &amp;delta;&lt;sup&gt;11&lt;/sup&gt;B records from the Pacific and two from the Atlantic Oceans are available in published literatures. The compilations of these records show large variability; range between 26.27&amp;ndash;20.82&amp;thinsp;‰ which corresponds to pH range 8.40&amp;ndash;7.63 respectively. Our investigation of pH records from the Pacific ocean based on principal component analysis (PCA) reveals that atmospheric CO&lt;sub&gt;2&lt;/sub&gt; can explains maximum up to ~&amp;thinsp;26&amp;thinsp;% of the total pH variability  during 1950&amp;ndash;2004&amp;thinsp;AD, followed by the ocean-climate oscillations (i.e. ENSO and PDO) driven oceanographic factors up to ~&amp;thinsp;17&amp;thinsp;%. The remaining large variability (~&amp;thinsp;57&amp;thinsp;%) could not be explained by above forcing factors and hence we invoke possible influence of metabolic processes of corals and/or changes in micro-environments within the reefs which are often neglected in interpreting paleo-pH records. Therefore, we highlight the need for detailed investigation in future studies to understand about the exact mechanism, processes/factors that controlled boron isotope fractionations in coral reef environments. Further, our investigation reveals that amplitude of the ENSO driven pH variability shows fivefold increase during 1980&amp;ndash;2000&amp;thinsp;AD compared to the previous three decades (1950&amp;ndash;1980&amp;thinsp;AD). This observation is consistent with the historical records of global coral bleaching events and therefore underscores role of ENSO driven environmental stress responsible for coral bleaching events. Considering model based projections of increasing frequency and amplitude of extreme ENSO events in the backdrop of recent global warming, bleaching events are likely to increase in the next decades/centuries.&lt;/p&gt;</p>
</abstract>
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