the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Understanding the impacts of peatland catchment management on DOM concentration and treatability
Chris Evans
Bryan Spears
Amy Pickard
Pippa J. Chapman
Heidrun Feuchtmayr
Fraser Leith
Susan Waldron
Don Monteith
Abstract. In the UK most large reservoirs constructed for public water supply are in upland areas and situated in catchments that contain at least some organic-rich soils. Dissolved organic matter (DOM) leaching from these soils imparts a brownish colour to water and raises treatment challenges for the water industry since excessive post-treatment concentrations result in the generation of potentially harmful disinfection by-products in drinking water. The primary method for maintaining sufficiently low pre-disinfection DOM concentrations is chemical coagulation, but in the past 15 years water companies have increasingly considered the capacity for catchment interventions to improve raw water quality at source, reducing the need for costly and complex engineering solutions in treatment works. There remains considerable uncertainty around the effectiveness of these catchment engineering-based measures and a comprehensive overview of the research in this area remains lacking. Here we review the peer-reviewed evidence for the effectiveness of four management options for upland organic soil-dominated catchments that are being considered by the water industry as options for controlling DOM releases. These are ditch blocking, revegetation, reducing forest cover, and cessation of managed burning. Results of plot scale investigations into effects of ditch blocking on ditch-blocking are available but largely equivocal, while there is a paucity of information regarding impacts at spatial scales of more direct relevance to water managers. The presence of plantation forestry on peat soils is generally associated with increasing DOM concentrations, although canopy removal has little short-term benefit and can even further increase concentrations. Although not widely studied, the available evidence suggests that Sphagnum mosses produce DOM that is more easily removed via conventional treatment processes compared to vascular plants such as heather and grass species. We found surprisingly little published research around the extent to which manipulation of in-reservoir processes might be used to mitigate or exacerbate changes in inflowing DOM as part of a catchment management approach.
This review concluded that catchment management measures have rarely been monitored with downstream water quality as the focus, and that restoration impacts vary across sites. To mitigate the uncertainty surrounding restoration effects on DOM, measures should be undertaken on a site-specific basis, where the scale, effect size and duration of the intervention are considered in relation to subsequent biogeochemical processing that occurs in the reservoir, the treatment capacity of the water treatment works and future projected DOM trends.
Jennifer Williamson et al.
Status: final response (author comments only)
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RC1: 'Comment on bg-2022-209', Anonymous Referee #1, 16 Jan 2023
General comments
This review paper pulls together studies on the effect of peatland restauration measures on DOM quantity and quality on receiving waters. It states a very diverse response to these measures and calls for more experimental studies. The paper matches the scope of Biogeosciences.
While I very much appreciate the overview on this body of literature I have major concerns regarding the resulting manuscript. For me parts of the abstract and the introduction are too long and detailed while other aspects are underrepresented. The study seems to have a UK focus but sometimes takes in international papers. It remains unclear to what extent the results and conclusions can be transferred to other places. I major shortcoming is the lack of discussion on the timescale of the reviewed studies and on the role of time in water quality response to the measures. Finally, references in the text are sometimes sparse and not all statements are underpinned with literature.
I hope my specific comments below will help to improve this manuscript.
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Specific comments
Abstract
For me the abstract is too long and too detailed. e.g. L16-23 can be greatly condensed to introduce the problem to be solved.
L29-28: It would be easier to read the result part if the names of the four management options listed above would show up here explicitly. Rather details (e.g. sentence with Sphagnum) blur the picture.
Chapter 1: Introduction
L48f: This first statement would profit from a reference to the Net Zero strategy.
L53f: Wording - "tend to be relatively high". Relative to what? Why "tend"?
L61f: It would be helpful to state that there are diverging views on the cause of DOM concentration increases and surely more than two references are needed.
L67f: Is there a reference for this last statement or are you the first one systematically asking the question on the impact of restoration on water quality?
Figure 1: I would expect a statement of the number of sites being part of that plot.
L79: No need to define an abbreviation for DWI when this term is not used in the manuscript a second time.
L78-89: This is way too long and detailed for a paper with a focus on management options and not on the chemistry behind disinfection byproducts.
L90-103: Is DOM composition a point later on in the result section? If not, try to boil this down to the information necessary to understand the rest of the manuscript.
L108f: What is the time reference of costs? Overall, per year? For this and the following statement a reference is needed!
L112ff: Here "peatland restauration" kicks in a bit surprisingly. Why only looking at peatland restauration? Yes, mentioned in the first sentence of the introduction. However, the definition of peatland as the dominant source of DOM in headwaters was not that clearly done so far. This needs a better connection. It is totally fine to limit the review to peatland restauration but it needs to be justified and clearly narrowed down in the introduction section.
L116f: Why stating "qualitative" here? Because literature does not allow a quantitative view? The latter would be much more helpful for the water industry, right? Wouldn't it be rather a result and conclusion than an objective that only qualitative but not quantitative assessment is possible with the given literature? I miss the statement on the four management options that are presented in the abstract.
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Chapter 2: Evidence for the efficacy...
L124: You jump in directly with ditch blocking without introducing earlier why this specific measure may help DOM reduction
Fig. 2: Homogenize style of the different text elements. E.g. capitalized letters or not, colon or not... Right part of the figure on the water treatment is too small to be really helpful and may need a reference for the figures source. Strange to see, again, the catchment and reservoir in this part of the figure. Figure 2 seems not to be referenced in the manuscript text and also does not clearly follow the structure of chapter 2. Where, e.g., is ditch blocking in the figure?
L128-130: This statement needs a reference.
L133: It would make sense to state the temporal scale of this reduction quantity. There can be initial effects and a longer-term evolution of concentrations. This is also true for the section L138-143. This information is in Tab. 1 but not in the text!
Tab. 1: In this style I suggest to move the table to the supplement. Maybe rather condensed and/ or visual information could be shown? e.g. as a bars with % increase/ decrease on y and time since blocking on x? I do not insist here, acknowledging the point that studies are hard to compare. However, the table is hard to grasp for the reader as information is hidden in text sections within the table.
L179-181: You mention "suitable timescales" of observation but do not define them nor introduce them earlier on in the introduction section. However, this is obviously a relevant point that needs more scientific background earlier on.
L188-192: These statements needs references.
L193f: If research is limited on what basis was the decision made that re-vegetation needs an own chapter? I am not in doubt here but the manuscript does not explain that to the reader.
L206: Check consistent spelling of re-vegetation.
L235f: Given the large body on literature on forestry-water quantity and -quality issues I suggest to cite rather review-style papers here than this very narrow selection.
Table 2: This table is not embedded in the text of the matching chapter 2.3 (between lines 233 and 258). Which information is given in the text and which in the table? Compared to Table 1 there is no temporal reverence on the before-after comparison. Is there a reason why this table focus on UK only but Table 1 have a more international width? Other than that I suggest to consider, similar to Table 1 alternative forms to display information.
 Chapter 2.3 as a whole: I have problems following the logic of this chapter and the switch of topics from section to section. This makes it hard to see the bigger picture of knowledge on forestry and DOM.
Table 3: I like the idea of the color scheme here. The type of catchment intervention does only parly match the structure of the manuscript so far. This needs improvement.
Chapter 3: Catchment management impacts
The first part of this chapter seems to be a discussion and interpretation on missing knowledge. However, it seamlessly propagates into another result section on DOM processing in the catchment. Some parts of the studies reviewed before already contains instream processes as they have been observed in stream. This drawing of a line between upstream and downstream processes is totally unclear for the readers. After this part the text comes back to a recommendation on future research... All this needs a clearer structure.
Chapter 4: Conclusions
L425-429: In this concluding section no new knowledge should be introduced. This is rather part of the introduction.
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Citation: https://doi.org/10.5194/bg-2022-209-RC1 -
RC2: 'Comment on bg-2022-209', Anonymous Referee #2, 22 Jan 2023
I enjoyed reading this docuement, and most of my comments are easily dealt with. I have included some detailed comments on an attached version of the manuscript.
 My major comments is that the paper needs a Methodology. Literature review is not just an essay on a subject, it has a an aim, a question and a method. The lack of a method means:
 - there a inconsistencies in what is or is not included in the review - see the abstract where some things are listed but not then commented on.
 - there are inconsistencies in the scope of the literature reviewed - I have already assumed that only literature from peer-reviewed literature is included although that is never stated - for example in some sections UK data is used; in others it is from outside the UK and in still others it is only British Isles data.
 - how was data combined? In some sections there are median effects and in others there are mean difference. Some sections talk of signiticant effects and others seem to be mean important by significant.Â
 - lack of clearly defined method and aim means that snippets of method and discussion appear in the results
The conclusion is not a conclusion, there seems to be a better conclusion in the discussion. Whole new ideas appear in the conclusion that were never mentionned in the rest of the text.
There are other reviews on related subjects that do use an appropriate meta-analysis for their review and so I do think the authors should have a look at some other reviews and meta-analyses to see how to structure their paper.
At the moment the paper reads like a small report given to industry partners and not a literature review for an international journal.
More specific comments:
 - remember to include the subject of the sentence.
 - there are plenty of pregnant sentences where a reference is expected but not given.
Citation: https://doi.org/10.5194/bg-2022-209-RC2 - RC3: 'Comment on bg-2022-209', Anonymous Referee #2, 22 Jan 2023
Jennifer Williamson et al.
Jennifer Williamson et al.
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