Articles | Volume 10, issue 12
Biogeosciences, 10, 8013–8038, 2013
https://doi.org/10.5194/bg-10-8013-2013
Biogeosciences, 10, 8013–8038, 2013
https://doi.org/10.5194/bg-10-8013-2013

Research article 09 Dec 2013

Research article | 09 Dec 2013

Upland streamwater nitrate dynamics across decadal to sub-daily timescales: a case study of Plynlimon, Wales

S. J. Halliday1, R. A. Skeffington1, A. J. Wade1, C. Neal2, B. Reynolds3, D. Norris3, and J. W. Kirchner4,5 S. J. Halliday et al.
  • 1Department of Geography and Environmental Science, University of Reading, Reading, RG6 6AB, UK
  • 2Centre for Ecology and Hydrology, Maclean Building, Crowmarsh Gifford, Wallingford, Oxon, OX11 8BB, UK
  • 3Centre for Ecology and Hydrology, Environment Centre Wales, Deiniol Road, Bangor, Gwynedd, LL57 2UW, UK
  • 4Swiss Federal Research Institute WSL, Zürcherstrasse 111, 8903 Birmensdorf, Switzerland
  • 5Department of Environmental Systems Science, ETH Zürich, Universitätsstrasse 16, 8092 Zürich, Switzerland

Abstract. Streamwater nitrate dynamics in the River Hafren, Plynlimon, mid-Wales were investigated over decadal to sub-daily timescales using a range of statistical techniques. Long-term data were derived from weekly grab samples (1984–2010) and high-frequency data from 7-hourly samples (2007–2009) both measured at two sites: a headwater stream draining moorland and a downstream site below plantation forest. This study is one of the first to analyse upland streamwater nitrate dynamics across such a wide range of timescales and report on the principal mechanisms identified. The data analysis provided no clear evidence that the long-term decline in streamwater nitrate concentrations was related to a decline in atmospheric deposition alone, because nitrogen deposition first increased and then decreased during the study period. Increased streamwater temperature and denitrification may also have contributed to the decline in stream nitrate concentrations, the former through increased N uptake rates and the latter resultant from increased dissolved organic carbon concentrations. Strong seasonal cycles, with concentration minimums in the summer, were driven by seasonal flow minimums and seasonal biological activity enhancing nitrate uptake. Complex diurnal dynamics were observed, with seasonal changes in phase and amplitude of the cycling, and the diurnal dynamics were variable along the river. At the moorland site, a regular daily cycle, with minimum concentrations in the early afternoon, corresponding with peak air temperatures, indicated the importance of instream biological processing. At the downstream site, the diurnal dynamics were a composite signal, resultant from advection, dispersion and nitrate processing in the soils of the lower catchment. The diurnal streamwater nitrate dynamics were also affected by drought conditions. Enhanced diurnal cycling in Spring 2007 was attributed to increased nitrate availability in the post-drought period as well as low flow rates and high temperatures over this period. The combination of high-frequency short-term measurements and long-term monitoring provides a powerful tool for increasing understanding of the controls of element fluxes and concentrations in surface waters.

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