Articles | Volume 12, issue 1
https://doi.org/10.5194/bg-12-67-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/bg-12-67-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Technical Note: Large overestimation of pCO2 calculated from pH and alkalinity in acidic, organic-rich freshwaters
G. Abril
CORRESPONDING AUTHOR
Laboratoire EPOC, Environnements et Paléoenvironnements Océaniques et Continentaux, CNRS, Université de Bordeaux, France
Programa de Geoquímica, Universidade Federal Fluminense, Niterói, Rio de Janeiro, Brazil
S. Bouillon
Katholieke Universiteit Leuven, Department of Earth & Environmental Sciences, Leuven, Belgium
F. Darchambeau
Unité d'Océanographie Chimique, Université de Liège, Belgium
C. R. Teodoru
Katholieke Universiteit Leuven, Department of Earth & Environmental Sciences, Leuven, Belgium
T. R. Marwick
Katholieke Universiteit Leuven, Department of Earth & Environmental Sciences, Leuven, Belgium
F. Tamooh
Katholieke Universiteit Leuven, Department of Earth & Environmental Sciences, Leuven, Belgium
F. Ochieng Omengo
Katholieke Universiteit Leuven, Department of Earth & Environmental Sciences, Leuven, Belgium
N. Geeraert
Katholieke Universiteit Leuven, Department of Earth & Environmental Sciences, Leuven, Belgium
L. Deirmendjian
Laboratoire EPOC, Environnements et Paléoenvironnements Océaniques et Continentaux, CNRS, Université de Bordeaux, France
P. Polsenaere
Laboratoire EPOC, Environnements et Paléoenvironnements Océaniques et Continentaux, CNRS, Université de Bordeaux, France
A. V. Borges
Unité d'Océanographie Chimique, Université de Liège, Belgium
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Short summary
We compared pCO2 data calculated from pH and alkalinity from those measured directly in a large array of temperate and tropical freshwaters. This revealed a large overestimation (up to 300%) of calculated pCO2 in the case of acidic and organic-rich waters, due to a contribution of organic acids anions to alkalinity and a lower buffering capacity of the carbonate system at acidic pH. Given the widespread distribution of acidic freshwaters, direct measurements of water pCO2 are encouraged.
We compared pCO2 data calculated from pH and alkalinity from those measured directly in a large...
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