Articles | Volume 22, issue 22
https://doi.org/10.5194/bg-22-7187-2025
© Author(s) 2025. This work is distributed under the Creative Commons Attribution 4.0 License.
New observations confirm the progressive acidification in the Mozambique Channel
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- Final revised paper (published on 25 Nov 2025)
- Supplement to the final revised paper
- Preprint (discussion started on 29 Jul 2025)
- Supplement to the preprint
Interactive discussion
Status: closed
Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor
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RC1: 'Comment on egusphere-2025-3469', Anonymous Referee #1, 01 Sep 2025
- AC1: 'Reply on RC1', Nicolas METZL, 25 Sep 2025
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RC2: 'Comment on egusphere-2025-3469', Anonymous Referee #2, 05 Sep 2025
- AC2: 'Reply on RC2', Nicolas METZL, 25 Sep 2025
Peer review completion
AR – Author's response | RR – Referee report | ED – Editor decision | EF – Editorial file upload
ED: Reconsider after major revisions (26 Sep 2025) by Hermann Bange
AR by Nicolas METZL on behalf of the Authors (07 Oct 2025)
Author's response
Author's tracked changes
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ED: Referee Nomination & Report Request started (07 Oct 2025) by Hermann Bange
RR by Anonymous Referee #1 (03 Nov 2025)
ED: Publish subject to technical corrections (03 Nov 2025) by Hermann Bange
AR by Nicolas METZL on behalf of the Authors (03 Nov 2025)
Author's response
Manuscript
General comments
This study provides novel results on OA in the Mozambique Channel, addressing relevant scientific questions and contributing to the understanding of Global Change impacts in the Indian Ocean. The authors present recent observations from this region, contrasted with existing datasets and supported by climatologies and neural network approaches. The study design, concepts, methods, and data employed give the manuscript appropriate scientific significance.
However, several aspects require major revision to improve the quality of the research and the presentation of the results and conclusions. In particular, the manuscript would benefit from a clearer description of the study area and its main oceanographic features, a more detailed and structured explanation of the applied methodology, and a careful revision of the trend calculations. Addressing this last point is crucial to strengthen the main conclusions of the study.
Below, I provide my major and minor concerns.
Major comments
The introduction is concise and well-structured. However, it would be convenient to make explicit reference to the study area and include a description of the most characteristic processes that may act as sources of variability for the CO2 system. Alternatively, a short description could be included in the introduction, with further details provided in a Study Area subsection within the methodology.
The color code in Figure 1 does not allow interpretation. It is difficult to distinguish the tracks of each cruise, particularly the red ones (from 2010 onwards, when most cruises took place). Please consider using a unique color for each cruise to improve readability.
Line 128: How was SST measured? And salinity? What were the instrumental uncertainties? How was the equilibrator temperature corrected relative to in situ values? Even if this information has been described in previous works, it would be helpful to include it in Section 2.2 so that readers can fully understand the methodology.
Lines 299–300: “…the climatology (Fay et al., 2024) or the FFNN model (Chau et al., 2024) is coherent compared to the data.” Was any intercomparison test performed? It would be appropriate to include results of such an intercomparison, for instance, the mean difference between climatology/NN outputs and observations, and/or provide an additional figure in the Supplementary Material (e.g. time in months on the X-axis and difference on the Y-axis).
Figure 3: The criteria for selecting these specific periods are not clear, and this choice may introduce bias. The averaging of the 2003, 2004, and 2014 cruises seems to give greater influence to the earlier years . It would be more informative to present the direct observations of each cruise with distinct markers. This approach would facilitate interpretation and enable clearer comparison with FFNN and climatology results. Including error bars would also strengthen the figure.
Section 3.3 does not appear to align well with the overall structure of the paper. Although the main result derived from this section is interesting for the broader discussion, it does not directly fit within the objectives. I therefore suggest moving this section to an Appendix and including the figure as Supplementary Material.
Section 3.3.2: How were the trends calculated? Were they derived from observational data or from climatology/NN outputs? This is a critical point that needs clarification. For example, between 1963 and 1995 (line 498) a trend is reported, but only two data points exist. In this case, it would be more appropriate to report the change between 1963 and 1995 (-0.040 units) rather than describing it as an interannual trend, which would be biased without intermediate data. The same concern applies to trends reported for 1995–2019 (lines 507–509) and 1995–2022 (lines 514–515). Similarly, in Table 4 the limited number of observations in the second half of the 20th century (only in 1963 and 1995) introduces biases in trend estimation. In addition, the high variability observed since 2018 could influence the calculated trends. Under these circumstances, no interannual or decadal trends can be identified with any statistical significance; instead, it would be more reliable to compare recent values with those from 1995 to estimate the magnitude of change. These changes will require a revision of the main conclusions of the paper, as well as the abstract
Section 3.4 (line 622): The calculation applied in this section may be difficult for readers to follow. The reconstruction of past and future values and the data sources used are not entirely clear. It might be beneficial to expand on the methodological details, either in the methodology section or in a dedicated Appendix, and limit the current section to the discussion of results. Additionally, please clarify the estimation error associated with Eq. 2.
Minor comments
Lines 41–42: Is this referring to surface measurements? Please clarify.
Line 47: Replace “fugacity of CO2” with “CO2 fugacity”.
Lines 47–50: The inclusion of these trends may appear arbitrary and potentially confuse the reader, since the study region has not yet been specified in the introduction. While the Indian Ocean reference is understandable, the criteria for also including the North Pacific is unclear. As a suggestion, it may be more relevant to mention the decrease in pH using trends from time-series stations (Bates et al., 2014), noting that most are located in the Northern Hemisphere and that knowledge of OA in the Southern Hemisphere remains limited. This could help emphasize the importance of the paper and engage the reader.
Line 49: What does “TS.decade-1” mean? Please use “units decade-1” or simply “decade-1” instead, and apply this consistently throughout.
Line 58: Acceleration with respect to …?
Line 135: Were only three gases used? Was a 0 ppm gas not included to zero and span the system (Pierrot et al., 2009)? If not, how were the xCO2 measurements corrected?
Lines 160–162: Please include statistical information (e.g., RMSE and r2).
Lines 193–194: “For pH, the decrease of -0.005 over three years, i.e., -0.0017 yr-1, is surprisingly close to what is generally observed at global scale and over several decades (-0.017 ± 0.004 per decade).” Please use consistent units when reporting both trends.
Table 2: Why do the mean SST and SSS values for CLIM-EPARSES fCO2 and CLIM-EPARSES AT-CT not match? They should be identical if only the computation of the carbon system variables differs. The same issue appears in Table 3 with OISO-11 and OISO-31. Please clarify.
Line 316: Please specify the salinity to which CT is normalized.
Line 323: Is there a reference supporting the reported trend?
Lines 365–366: This statement would be more appropriate in the Results section.
Line 387: Consider replacing “increased” with “reinforced”.
Lines 424–425: How were eddies identified? Were satellite images used, or is there a reference?
Line 428: ΔfCO2 should be defined as the difference between oceanic and atmospheric fCO2 before it is mentioned for the first time.
Line 496: What does “difference of ΔfCO2” mean? Please clarify.
Line 500: Please specify the units.
Line 639: Instead of simply stating “compared well”, it would be helpful to report the mean differences between this method and the observations, as well as between this method and the FFNN estimates/climatology data.
Lines 679–680: Please provide a reference.
Figure 9: Is it possible to add error bars?