On surface fluxes at night – the virtual chamber approach

Abstract. Quantification of the emission rates of various gases from soils at night remains a challenge, confronting climate science (in the case of CO₂ and CH₄) and agriculture science (for NH₃ and N₂O, among others). In the stable conditions prevailing at night, concentrations of such emitted gases build up at the surface during the night, with intermittent interruptions commonly attributed to the passage of packets of turbulence. The utility of conventional micrometeorological experimental methods in such circumstances is questionable, and chamber methods have been developed to meet the challenge. Here, a statistical approach is proposed, in which micrometeorological field data are used to replicate the likely characteristics of a chamber experiment, yielding estimates of surface fluxes at the surface itself and not at some height above it. The methodology proposed is developmental at this time, with details intended to correspond to the use of both closed and vented chambers. Its application to three recent field studies is explored: (1) a study of nocturnal CO₂ emission from two test areas (one previously tilled and the other not) in Ohio in 2015; (2) a similar experiment conducted in Zimbabwe in 2013 (one area previously tilled and a second left fallow), and (3) an investigation of NH₃ effluxes from a crop previously treated with urea ammonium nitrate (UAN), in Illinois in 2014. There are few measurements with which to compare the results presented here, however the values obtained are within the range of available field data.