Articles | Volume 11, issue 20
Biogeosciences, 11, 5687–5706, 2014
Biogeosciences, 11, 5687–5706, 2014

Research article 16 Oct 2014

Research article | 16 Oct 2014

Fluid chemistry of the low temperature hyperalkaline hydrothermal system of Prony Bay (New Caledonia)

C. Monnin1, V. Chavagnac1, C. Boulart1,*, B. Ménez2, M. Gérard3, E. Gérard2, C. Pisapia2, M. Quéméneur4, G. Erauso4, A. Postec4, L. Guentas-Dombrowski6,5, C. Payri5, and B. Pelletier7 C. Monnin et al.
  • 1Géosciences Environnement Toulouse, Université de Toulouse/CNRS/IRD, 14, Avenue Edouard Belin, 31400 Toulouse, France
  • 2Institut de Physique du Globe de Paris, Sorbonne Paris Cité, Université Paris Diderot, CNRS UMR7154, 1 rue Jussieu, 75238 Paris CEDEX 5, France
  • 3Institut de minéralogie et de physique des milieux condensés, Université Pierre et Marie Curie – 4 place Jussieu, 75005 Paris, France
  • 4Aix Marseille Université, CNRS/INSU, IRD, Mediterranean Institute of Oceanography (MIO), UM110, 13288 Marseille, France
  • 5UR227 COREUS Ecosystèmes des communautés récifales et leurs usages dans le Pacifique, Centre IRD de Nouméa, BP A5, 98848 Nouméa, New Caledonia
  • 6Toulon Université, Laboratoire des Matériaux Polymères Interfaces Environnement Marin (MAPIEM), ISITV – Avenue Georges Pompidou BP56 – 83162 La Valette-du-Var CEDEX, France
  • 7Grand Observatoire de l'environnement et de la biodiversité terrestre et marine du Pacifique Sud (GIS GOPS), Centre IRD de Nouméa, BP A5, 98848 Nouméa, New Caledonia
  • *now at: Centre IFREMER Brest, Géosciences Marines, Laboratoire Géochimie Métallogénie, B.P. 70, 29280 Plouzané France

Abstract. The terrestrial hyperalkaline springs of Prony Bay (southern lagoon, New Caledonia) have been known since the nineteenth century, but a recent high-resolution bathymetric survey of the seafloor has revealed the existence of numerous submarine structures similar to the well-known Aiguille de Prony, which are also the location of high-pH fluid discharge into the lagoon. During the HYDROPRONY cruise (28 October to 13 November 2011), samples of waters, gases and concretions were collected by scuba divers at underwater vents. Four of these sampling sites are located in Prony Bay at depths up to 50 m. One (Bain des Japonais spring) is also in Prony Bay but uncovered at low tide and another (Rivière des Kaoris spring) is on land slightly above the seawater level at high tide. We report the chemical composition (Na, K, Ca, Mg, Cl, SO4, dissolved inorganic carbon, SiO2(aq)) of 45 water samples collected at six sites of high-pH water discharge, as well as the composition of gases. Temperatures reach 37 °C at the Bain des Japonais and 32 °C at the spring of the Kaoris. Gas bubbling was observed only at these two springs. The emitted gases contain between 12 and 30% of hydrogen in volume of dry gas, 6 to 14% of methane, and 56 to 72% of nitrogen, with trace amounts of carbon dioxide, ethane and propane.

pH values and salinities of all the 45 collected water samples range from the seawater values (8.2 and 35 g L−1) to hyperalkaline freshwaters of the Ca-OH type (pH 11 and salinities as low as 0.3 g L−1) showing that the collected samples are always a mixture of a hyperalkaline fluid of meteoric origin and ambient seawater. Cl-normalized concentrations of dissolved major elements first show that the Bain des Japonais is distinct from the other sites. Water collected at this site are three component mixtures involving the high-pH fluid, the lagoon seawater and the river water from the nearby Rivière du Carénage. The chemical compositions of the hyperalkaline endmembers (at pH 11) are not significantly different from one site to the other although the sites are several kilometres away from each other and are located on different ultramafic substrata. The very low salinity of the hyperalkaline endmembers shows that seawater does not percolate through the ultramafic formation.

Mixing of the hyperalkaline hydrothermal endmember with local seawater produces large ranges and very sharp gradients of pH, salinity and dissolved element concentrations. There is a major change in the composition of the water samples at a pH around 10, which delimitates the marine environment from the hyperalkaline environment. The redox potential evolves toward negative values at high pH indicative of the reducing conditions due to bubbling of the H2-rich gas. The calculation of the mineral saturation states carried out for the Na-K-Ca-Mg-Cl-SO4-DIC-SiO2-H2O system shows that this change is due to the onset of brucite formation. While the saturation state of the Ca carbonates over the whole pH range is typical of that found in a normal marine environment, Mg- and Mg-Ca carbonates (magnesite, hydromagnesite, huntite, dolomite) exhibit very large supersaturations with maximum values at a pH of around 10, very well marked for the Bain des Japonais, emphasizing the role of water mixing in mineral formation.

The discharge of high-pH waters of meteoric origin into the lagoon marine environment makes the hydrothermal system of Prony Bay unique compared to other low temperature serpentinizing environments such as Oman (fully continental) or Lost City (fully marine).

Final-revised paper