Articles | Volume 12, issue 7
https://doi.org/10.5194/bg-12-2131-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/bg-12-2131-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Reconstruction of secular variation in seawater sulfate concentrations
T. J. Algeo
CORRESPONDING AUTHOR
Department of Geology, University of Cincinnati, Cincinnati, Ohio 45221-0013, USA
State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan, 430074, China
State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan, 430074, China
G. M. Luo
State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan, 430074, China
H. Y. Song
State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan, 430074, China
T. W. Lyons
Department of Earth Sciences, University of California, Riverside, California 92521-0423, USA
D. E. Canfield
Nordic Center for Earth Evolution (NordCEE) and Institute of Biology, University of Southern Denmark, Campusvej 55, 5230 Odense M, Denmark
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Short summary
Seawater sulfate concentrations are closely related to the oxygenation history of Earth's surface environment. We develop two approaches for quantification of ancient seawater sulfate concentrations based on the sulfur isotopic composition of pyrite and carbonate-associated sulfur (CAS). Our analysis indicates low seawater sulfate (<5mM) at 635 million years ago, rising in a stepwise manner to near-modern levels (~20-30mM) by about 250 million years ago.
Seawater sulfate concentrations are closely related to the oxygenation history of Earth's...
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