Articles | Volume 17, issue 7
https://doi.org/10.5194/bg-17-1955-2020
https://doi.org/10.5194/bg-17-1955-2020
Research article
 | 
14 Apr 2020
Research article |  | 14 Apr 2020

Vivianite formation in ferruginous sediments from Lake Towuti, Indonesia

Aurèle Vuillemin, André Friese, Richard Wirth, Jan A. Schuessler, Anja M. Schleicher, Helga Kemnitz, Andreas Lücke, Kohen W. Bauer, Sulung Nomosatryo, Friedhelm von Blanckenburg, Rachel Simister, Luis G. Ordoñez, Daniel Ariztegui, Cynthia Henny, James M. Russell, Satria Bijaksana, Hendrik Vogel, Sean A. Crowe, Jens Kallmeyer, and the Towuti Drilling Project Science team

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Pore water geochemistry and bulk sediment measurements of downcore profiles from site TDP-1A of the ICDP Towuti Drilling Project, Lake Towuti, Indonesia. Vuillemin A., Friese A., Lücke A., Bauer K.W., Nomosatryo S., Simister R., Ordonez L.G., Ariztegui D., Russell J.M., Bijaksana S., Vogel H., Crowe S.A., Kallmeyer J., and the Towuti Drilling Project Science Team https://doi.pangaea.de/10.1594/PANGAEA.908080

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Short summary
Ferruginous lakes experience restricted primary production due to phosphorus trapping by ferric iron oxides under oxic conditions. We report the presence of large crystals of vivianite, a ferrous iron phosphate, in sediments from Lake Towuti, Indonesia. We address processes of P retention linked to diagenesis of iron phases. Vivianite crystals had light Fe2+ isotope signatures and contained mineral inclusions consistent with antecedent processes of microbial sulfate and iron reduction.
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