Articles | Volume 17, issue 7 
            
                
                    
            
            
            https://doi.org/10.5194/bg-17-1731-2020
                    © Author(s) 2020. This work is distributed under 
the Creative Commons Attribution 4.0 License.
                the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/bg-17-1731-2020
                    © Author(s) 2020. This work is distributed under 
the Creative Commons Attribution 4.0 License.
                the Creative Commons Attribution 4.0 License.
Oxygen isotope composition of waters recorded in carbonates in strong clumped and oxygen isotopic disequilibrium
Caroline Thaler
CORRESPONDING AUTHOR
                                            
                                    
                                            Université de Paris, Institut de physique du globe de Paris,
CNRS, 75005 Paris, France
                                        
                                    Amandine Katz
                                            Université de Paris, Institut de physique du globe de Paris,
CNRS, 75005 Paris, France
                                        
                                    Magali Bonifacie
                                            Université de Paris, Institut de physique du globe de Paris,
CNRS, 75005 Paris, France
                                        
                                    Bénédicte Ménez
                                            Université de Paris, Institut de physique du globe de Paris,
CNRS, 75005 Paris, France
                                        
                                    Magali Ader
                                            Université de Paris, Institut de physique du globe de Paris,
CNRS, 75005 Paris, France
                                        
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                            Cited
12 citations as recorded by crossref.
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 - Technical Note: Developments and Applications in Triple Oxygen Isotope Analysis of Carbonates B. Fosu et al. 10.1021/acsearthspacechem.9b00330
 - Resolving and correcting for kinetic biases on methane seep paleotemperature using carbonate ∆ 47 /∆ 48 analysis P. Staudigel et al. 10.1126/sciadv.adn0155
 - Trajectory and timescale of oxygen and clumped isotope equilibration in the dissolved carbonate system under normal and enzymatically-catalyzed conditions at 25 °C J. Uchikawa et al. 10.1016/j.gca.2021.08.014
 - Bacterial and abiogenic carbonates formed in caves–no vital effect on clumped isotope compositions A. Demény et al. 10.1371/journal.pone.0245621
 - Oxygen isotopic composition of Paleoproterozoic seawater revealed by clumped isotope analysis of dolomite, Vempalle Formation, Cuddapah, India S. Banerjee et al. 10.1016/j.chemgeo.2023.121356
 - InterCarb: A Community Effort to Improve Interlaboratory Standardization of the Carbonate Clumped Isotope Thermometer Using Carbonate Standards S. Bernasconi et al. 10.1029/2020GC009588
 - Radish concretions grown in mud during compaction A. Wetzel et al. 10.1111/sed.12924
 - Extensive non-marine depositional setting evidenced by carbonate minerals in the Ediacaran clastic series of the western East European Craton M. Bojanowski et al. 10.1016/j.precamres.2021.106379
 - Kinetic Oxygen Isotope Fractionation between Water and Aqueous OH– during Hydroxylation of CO2 D. Bajnai & D. Herwartz 10.1021/acsearthspacechem.1c00194
 - Oxygen isotope fractionation between water and the aqueous hydroxide ion R. Zeebe 10.1016/j.gca.2020.08.025
 - Reconstructing the temperature and origin of CO2 mineralisation in CarbFix calcite using clumped, carbon and oxygen isotopes C. Holdsworth et al. 10.1016/j.apgeochem.2024.105925
 
12 citations as recorded by crossref.
- Trace fossils in seep-impacted sediments as a tool to decipher the origin of fine-grained intervals of the Marnoso-arenacea turbidite succession (Miocene, northern Apennines, Italy) S. Conti et al. 10.1016/j.sedgeo.2021.105965
 - Technical Note: Developments and Applications in Triple Oxygen Isotope Analysis of Carbonates B. Fosu et al. 10.1021/acsearthspacechem.9b00330
 - Resolving and correcting for kinetic biases on methane seep paleotemperature using carbonate ∆ 47 /∆ 48 analysis P. Staudigel et al. 10.1126/sciadv.adn0155
 - Trajectory and timescale of oxygen and clumped isotope equilibration in the dissolved carbonate system under normal and enzymatically-catalyzed conditions at 25 °C J. Uchikawa et al. 10.1016/j.gca.2021.08.014
 - Bacterial and abiogenic carbonates formed in caves–no vital effect on clumped isotope compositions A. Demény et al. 10.1371/journal.pone.0245621
 - Oxygen isotopic composition of Paleoproterozoic seawater revealed by clumped isotope analysis of dolomite, Vempalle Formation, Cuddapah, India S. Banerjee et al. 10.1016/j.chemgeo.2023.121356
 - InterCarb: A Community Effort to Improve Interlaboratory Standardization of the Carbonate Clumped Isotope Thermometer Using Carbonate Standards S. Bernasconi et al. 10.1029/2020GC009588
 - Radish concretions grown in mud during compaction A. Wetzel et al. 10.1111/sed.12924
 - Extensive non-marine depositional setting evidenced by carbonate minerals in the Ediacaran clastic series of the western East European Craton M. Bojanowski et al. 10.1016/j.precamres.2021.106379
 - Kinetic Oxygen Isotope Fractionation between Water and Aqueous OH– during Hydroxylation of CO2 D. Bajnai & D. Herwartz 10.1021/acsearthspacechem.1c00194
 - Oxygen isotope fractionation between water and the aqueous hydroxide ion R. Zeebe 10.1016/j.gca.2020.08.025
 - Reconstructing the temperature and origin of CO2 mineralisation in CarbFix calcite using clumped, carbon and oxygen isotopes C. Holdsworth et al. 10.1016/j.apgeochem.2024.105925
 
Latest update: 03 Nov 2025
Short summary
                    Paleoenvironment reconstructions, retrieved from δ18O and Δ47 values measured in carbonate, are compromised when crystallization occurs in isotopic disequilibrium. We show that some paleoenvironmental information can still be retrieved from these paired disequilibrium Δ47 and δ18O values. The possibility of retrieving information on paleowaters, sediments' interstitial waters, or organisms' body water at the carbonate precipitation loci will help understand past Earth and life evolution.
                    Paleoenvironment reconstructions, retrieved from δ18O and Δ47 values measured in carbonate,...
                    
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