Articles | Volume 21, issue 20
https://doi.org/10.5194/bg-21-4665-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/bg-21-4665-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Reviews and syntheses
| 
29 Oct 2024
Reviews and syntheses |
| 29 Oct 2024
| 29 Oct 2024
Reviews and syntheses: Opportunities for robust use of peak intensities from high-resolution mass spectrometry in organic matter studies
William Kew
Environmental Molecular Sciences Laboratory, Richland, WA 99352, USA
Allison Myers-Pigg
Pacific Northwest National Laboratory, Richland, WA 99352, USA
Christine H. Chang
Pacific Northwest National Laboratory, Richland, WA 99352, USA
Sean M. Colby
Pacific Northwest National Laboratory, Richland, WA 99352, USA
Josie Eder
Environmental Molecular Sciences Laboratory, Richland, WA 99352, USA
Malak M. Tfaily
Department of Environmental Science, University of Arizona, Tucson, AZ 85719, USA
Jeffrey Hawkes
Department of Chemistry, University of Uppsala, Uppsala, 75124, Sweden
Rosalie K. Chu
Environmental Molecular Sciences Laboratory, Richland, WA 99352, USA
Pacific Northwest National Laboratory, Richland, WA 99352, USA
School of the Environment, Washington State University, Pullman, WA 99164, USA
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Cited
10 citations as recorded by crossref.
- Logging disrupts the ecology of molecules in headwater streams E. Freeman et al. 10.1073/pnas.2409104122
- Harmonization of FT-ICR-MS Instruments for Interoperable Multi-Laboratory Comprehensive Compositional Profiling S. Pieczonka et al. 10.1021/acs.analchem.5c00488
- Rethinking Aerobic Respiration in the Hyporheic Zone under Variation in Carbon and Nitrogen Stoichiometry A. Tureţcaia et al. 10.1021/acs.est.3c04765
- Reaction of Organic Matter with Nitronium Ion as a Source of Organic Nitrate Esters in Proxies for Organic Aerosols R. Hansen et al. 10.1021/acsearthspacechem.3c00111
- Case study evaluation of size-resolved molecular composition and phase state of carbonaceous particles in wildfire influenced smoke from the Pacific Northwest G. Vandergrift et al. 10.1039/D3EA00058C
- Organic molecules are deterministically assembled in variably inundated river sediments, but drivers remain unclear J. Stegen et al. 10.1038/s41598-024-76675-5
- Investigating the impacts of solid phase extraction on dissolved organic matter optical signatures and the pairing with high‐resolution mass spectrometry data across a freshwater stream network J. Roebuck Jr et al. 10.1002/lom3.10603
- Tethered balloon system and High-Resolution Mass Spectrometry Reveal Increased Organonitrates Aloft Compared to the Ground Level G. Vandergrift et al. 10.1021/acs.est.4c02090
- Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol Y. Chen et al. 10.1021/acs.est.3c03532
- Improvement of Electrospray Ionization Response Linearity and Quantification in Dissolved Organic Matter Using Synthetic Deuterated Internal Standards A. Craig et al. 10.1021/acs.analchem.5c02463
1 citations as recorded by crossref.
9 citations as recorded by crossref.
- Harmonization of FT-ICR-MS Instruments for Interoperable Multi-Laboratory Comprehensive Compositional Profiling S. Pieczonka et al. 10.1021/acs.analchem.5c00488
- Rethinking Aerobic Respiration in the Hyporheic Zone under Variation in Carbon and Nitrogen Stoichiometry A. Tureţcaia et al. 10.1021/acs.est.3c04765
- Reaction of Organic Matter with Nitronium Ion as a Source of Organic Nitrate Esters in Proxies for Organic Aerosols R. Hansen et al. 10.1021/acsearthspacechem.3c00111
- Case study evaluation of size-resolved molecular composition and phase state of carbonaceous particles in wildfire influenced smoke from the Pacific Northwest G. Vandergrift et al. 10.1039/D3EA00058C
- Organic molecules are deterministically assembled in variably inundated river sediments, but drivers remain unclear J. Stegen et al. 10.1038/s41598-024-76675-5
- Investigating the impacts of solid phase extraction on dissolved organic matter optical signatures and the pairing with high‐resolution mass spectrometry data across a freshwater stream network J. Roebuck Jr et al. 10.1002/lom3.10603
- Tethered balloon system and High-Resolution Mass Spectrometry Reveal Increased Organonitrates Aloft Compared to the Ground Level G. Vandergrift et al. 10.1021/acs.est.4c02090
- Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol Y. Chen et al. 10.1021/acs.est.3c03532
- Improvement of Electrospray Ionization Response Linearity and Quantification in Dissolved Organic Matter Using Synthetic Deuterated Internal Standards A. Craig et al. 10.1021/acs.analchem.5c02463
Latest update: 26 Sep 2025
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Short summary
Natural organic matter (NOM) is often studied via Fourier transform mass spectrometry (FTMS), which identifies organic molecules as mass spectra peaks. The intensity of peaks is data that is often discarded due to technical concerns. We review the theory behind these concerns and show they are supported empirically. However, simulations show that ecological analyses of NOM data that include FTMS peak intensities are often valid. This opens a path for robust use of FTMS peak intensities for NOM.
Natural organic matter (NOM) is often studied via Fourier transform mass spectrometry (FTMS),...
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