Articles | Volume 22, issue 20
https://doi.org/10.5194/bg-22-6067-2025
https://doi.org/10.5194/bg-22-6067-2025
Research article
 | 
24 Oct 2025
Research article |  | 24 Oct 2025

Quantifying the agricultural footprint on the silicon cycle: insights from silicon isotopes and Ge∕Si ratios

Sofía López-Urzúa, Louis Derry, and Julien Bouchez

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Cited articles

Aguirre, A. A., Derry, L. A., Mills, T. J., and Anderson, S. P.: Colloidal transport in the Gordon Gulch catchment of the Boulder C reek CZO and its effect on C-Q relationships for silicon, Water Resour. Res., 53, 2368–2383, https://doi.org/10.1002/2016WR019730, 2017. 
Akkal-Corfini, N., Menasseri-Aubry, S., Rieux, C., Le Naour, E., and Viaud, V.: Caractérisation des systèmes de culture du bassin versant du Coetdan (ORE AgrHys, site de Naizin), Editions INRA UMR 1069 SAS, 2014. 
Ameijeiras-Mariño, Y., Opfergelt, S., Derry, L. A., Robinet, J., Govers, G., Minella, J. P. G., and Delmelle, P.: Ge/Si ratios point to increased contribution from deeper mineral weathering to streams after forest conversion to cropland, Appl. Geochem., 96, 24–34, https://doi.org/10.1016/j.apgeochem.2018.06.002, 2018. 
Anders, A. M., Sletten, R. S., Derry, L. A., and Hallet, B.: Germanium/silicon ratios in the Copper River Basin, Alaska: Weathering and partitioning in periglacial versus glacial environments: Ge/Si IN GLACIAL/PERIGLACIAL ENVIRONMENTS, J. Geophys. Res.-Earth Surf., 108, https://doi.org/10.1029/2003JF000026, 2003. 
Baronas, J. J., Torres, M. A., West, A. J., Rouxel, O., Georg, B., Bouchez, J., Gaillardet, J., and Hammond, D. E.: Ge and Si isotope signatures in rivers: A quantitative multi-proxy approach, Earth Planet. Sci. Lett., 503, 194–215, https://doi.org/10.1016/j.epsl.2018.09.022, 2018. 
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Short summary
Silicon (Si) is essential for ecosystem health and Earth's climate, yet human activities such as agriculture have significantly disrupted its natural cycle. In a French agricultural catchment, we found that crop harvesting removes most of the Si released from rocks – 1 to 4 times more than the dissolved Si transport downstream by rivers. Using geochemical tools, including Si isotopes and germanium-silicon ratio, we traced Si cycling and highlighted the impact of agriculture on Si exports.
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