Articles | Volume 22, issue 19
https://doi.org/10.5194/bg-22-5511-2025
https://doi.org/10.5194/bg-22-5511-2025
Research article
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10 Oct 2025
Research article | Highlight paper |  | 10 Oct 2025

A tracer study for the development of in-water monitoring, reporting, and verification (MRV) of ship-based ocean alkalinity enhancement

Adam V. Subhas, Jennie E. Rheuban, Zhaohui Aleck Wang, Daniel C. McCorkle, Anna P. M. Michel, Lukas Marx, Chloe L. Dean, Kate Morkeski, Matthew G. Hayden, Mary Burkitt-Gray, Francis Elder, Yiming Guo, Heather H. Kim, and Ke Chen

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Cited articles

Bach, L. T.: The additionality problem of ocean alkalinity enhancement, Biogeosciences, 21, 261–277, https://doi.org/10.5194/bg-21-261-2024, 2024. 
Bednarsek, N., Van de Mortel, H., Pelletier, G., García-Reyes, M., Feely, R. A., and Dickson, A.: Assessment framework to predict sensitivity of marine calcifiers to ocean alkalinity enhancement: identification of biological thresholds and importance of precautionary principle, One Ocean Science Congress 2025, Nice, France, 3–6 Jun 2025, OOS2025-809, https://doi.org/10.5194/oos2025-809, 2025. 
Busch, J. A., Engel, J., Zielinski, O., and Friedrichs, A.: Citizens' observatory for coast and ocean optical monitoring, Citclops Report D2.2: Review of state of the art in affordable fluorescence sensors (308469), https://doi.org/10.3390/rs8110879, 2013. 
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Co-editor-in-chief
This study represents a pioneering step in the development of in situ monitoring, reporting, and verification (MRV) frameworks for ocean alkalinity enhancement (OAE), a leading marine carbon dioxide removal strategy. The authors conducted one of the first open-ocean rhodamine tracer release experiments explicitly designed to simulate alkalinity enhancement, demonstrating a scalable and practical approach for tracking the fate of alkalinity additions in dynamic marine environments. By moving beyond theoretical modeling and implementing real world testing, this work establishes a critical methodological foundation for future field trials and offers a replicable strategy for validating carbon removal through OAE.
Short summary
Ocean alkalinity enhancement (OAE) is a carbon removal approach in which alkaline materials are added to the marine environment, increasing the ocean's ability to store carbon dioxide. We conducted an open-water experiment releasing and tracking a fluorescent water tracer. Under the right conditions, in-water monitoring of OAE does appear to be possible. We conclude with a series of practical recommendations for open-water OAE monitoring.
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