Articles | Volume 23, issue 15
https://doi.org/10.5194/bg-23-5377-2026
https://doi.org/10.5194/bg-23-5377-2026
Research article
 | 
04 Aug 2026
Research article |  | 04 Aug 2026

Selective accumulation of dissolved organic matter in the sea surface microlayer: integrated multi-spectral CDOM and FDOM characterization and a novel FDOM/CDOM index at a Mediterranean coastal site

Elli Pitta, Eleni Tzempelikou, and Christina Zeri

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Cited articles

Astrahan, P., Herut, B., Paytan, A., and Rahav, E.: The Impact of Dry Atmospheric Deposition on the Sea-Surface Microlayer in the SE Mediterranean Sea: An Experimental Approach, Front. Mar. Sci., 3, 222, https://doi.org/10.3389/fmars.2016.00222, 2016. 
Azimi, S., Ludwig, A., Thévenot, D. R., and Colin, J.-L.: Trace metal determination in total atmospheric deposition in rural and urban areas, Sci. Total Environ., 308, 247–256, https://doi.org/10.1016/S0048-9697(02)00678-2, 2003. 
Barthelmeß, T. and Engel, A.: How biogenic polymers control surfactant dynamics in the surface microlayer: insights from a coastal Baltic Sea study, Biogeosciences, 19, 4965–4992, https://doi.org/10.5194/bg-19-4965-2022, 2022. 
Blough, N. L. and Del Vecchio, R.: Chromophoric DOM in coastal environment, in: Biogeochemistry of marine dissolved organic matter, edited by: Hansell, D. A. and Carlson, C. A., Academic, 509–546, https://doi.org/10.1016/B978-012323841-2/50012-9, 2002. 
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Chromophoric dissolved organic matter dynamics (CDOM) in the sea surface microlayer (SML) and underlying water were examined at a coastal site. The SML was enriched in dissolved organic carbon (DOC), CDOM and fluorescent dissolved organic matter (FDOM). Optical indices and FDOM/CDOM index showed wavelength-dependent enrichment and decoupling of CDOM-FDOM, suggesting that photodegradation, biological processes and atmospheric inputs shape DOC pool beyond simple upward flux from underlying waters.
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