Articles | Volume 23, issue 1
https://doi.org/10.5194/bg-23-77-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/bg-23-77-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
05 Jan 2026
Research article |
| 05 Jan 2026
| 05 Jan 2026
Biogenically driven marine organic aerosol production over the West Pacific Ocean
Yujue Wang
CORRESPONDING AUTHOR
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
Laboratory for Marine Ecology and Environmental Science, Qingdao Marine Science and Technology Center, Qingdao, China
Yizhe Yi
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, China
Yiwen Zhang
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
Shubin Li
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
Hong-Hai Zhang
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China
Mingliang Gu
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
Shibo Yan
Third Institute of Oceanography, Ministry of Natural Resources, Siming District, Xiamen, Fujian 361005, China
Jialei Zhu
Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin, China
Chao Zhang
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
Laboratory for Marine Ecology and Environmental Science, Qingdao Marine Science and Technology Center, Qingdao, China
Jinhui Shi
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
Laboratory for Marine Ecology and Environmental Science, Qingdao Marine Science and Technology Center, Qingdao, China
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
Laboratory for Marine Ecology and Environmental Science, Qingdao Marine Science and Technology Center, Qingdao, China
Xiaohong Yao
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
Laboratory for Marine Ecology and Environmental Science, Qingdao Marine Science and Technology Center, Qingdao, China
Huiwang Gao
Frontiers Science Center for Deep Ocean Multispheres and Earth System, Key Laboratory of Marine Environment and Ecology, Ministry of Education of China, Ocean University of China, Qingdao, China
Laboratory for Marine Ecology and Environmental Science, Qingdao Marine Science and Technology Center, Qingdao, China
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Earth Syst. Sci. Data, 15, 5403–5425, https://doi.org/10.5194/essd-15-5403-2023, https://doi.org/10.5194/essd-15-5403-2023, 2023
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Qi Yuan, Yuanyuan Wang, Yixin Chen, Siyao Yue, Jian Zhang, Yinxiao Zhang, Liang Xu, Wei Hu, Dantong Liu, Pingqing Fu, Huiwang Gao, and Weijun Li
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This study for the first time found large amounts of liquid–liquid phase separation particles with soot redistributing in organic coatings instead of sulfate cores in the eastern Tibetan Plateau atmosphere. The particle size and the ratio of the organic matter coating thickness to soot size are two of the major possible factors that likely affect the soot redistribution process. The soot redistribution process promoted the morphological compaction of soot particles.
Yuyang Li, Jiewen Shen, Bin Zhao, Runlong Cai, Shuxiao Wang, Yang Gao, Manish Shrivastava, Da Gao, Jun Zheng, Markku Kulmala, and Jingkun Jiang
Atmos. Chem. Phys., 23, 8789–8804, https://doi.org/10.5194/acp-23-8789-2023, https://doi.org/10.5194/acp-23-8789-2023, 2023
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We set up a new parameterization for 1.4 nm particle formation rates from sulfuric acid–dimethylamine (SA–DMA) nucleation, fully including the effects of coagulation scavenging and cluster stability. Incorporating the new parameterization into 3-D chemical transport models, we achieved better consistencies between simulation results and observation data. This new parameterization provides new insights into atmospheric nucleation simulations and its effects on atmospheric pollution or health.
Yifang Gu, Ru-Jin Huang, Jing Duan, Wei Xu, Chunshui Lin, Haobin Zhong, Ying Wang, Haiyan Ni, Quan Liu, Ruiguang Xu, Litao Wang, and Yong Jie Li
Atmos. Chem. Phys., 23, 5419–5433, https://doi.org/10.5194/acp-23-5419-2023, https://doi.org/10.5194/acp-23-5419-2023, 2023
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Secondary organic aerosol (SOA) can be produced by various pathways, but its formation mechanisms are unclear. Observations were conducted in the North China Plain during a highly oxidizing atmosphere in summer. We found that fast photochemistry dominated SOA formation during daytime. Two types of aqueous-phase chemistry (nocturnal and daytime processing) take place at high relative humidity. The potential transformation from primary organic aerosol (POA) to SOA was also an important pathway.
Chunshui Lin, Ru-Jin Huang, Haobin Zhong, Jing Duan, Zixi Wang, Wei Huang, and Wei Xu
Atmos. Chem. Phys., 23, 3595–3607, https://doi.org/10.5194/acp-23-3595-2023, https://doi.org/10.5194/acp-23-3595-2023, 2023
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The complex interaction between O3 and PM2.5, coupled with the topology of the Fenwei Plain and the evolution of the boundary layer height, highlights the challenges in further reducing particulate pollution in winter despite years of efforts to reduce emissions. Through scenario analysis in a chemical box model constrained by observation, we show the co-benefits of reducing NOx and VOCs simultaneously in reducing ozone and SOA.
Shujun Zhong, Shuang Chen, Junjun Deng, Yanbing Fan, Qiang Zhang, Qiaorong Xie, Yulin Qi, Wei Hu, Libin Wu, Xiaodong Li, Chandra Mouli Pavuluri, Jialei Zhu, Xin Wang, Di Liu, Xiaole Pan, Yele Sun, Zifa Wang, Yisheng Xu, Haijie Tong, Hang Su, Yafang Cheng, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 2061–2077, https://doi.org/10.5194/acp-23-2061-2023, https://doi.org/10.5194/acp-23-2061-2023, 2023
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This study investigated the role of the secondary organic aerosol (SOA) loading on the molecular composition of wintertime urban aerosols by ultrahigh-resolution mass spectrometry. Results demonstrate that the SOA loading is an important factor associated with the oxidation degree, nitrate group content, and chemodiversity of nitrooxy–organosulfates. Our study also found that the hydrolysis of nitrooxy–organosulfates is a possible pathway for the formation of organosulfates.
Zhenming Wang, Shaoqing Zhang, Yishuai Jin, Yinglai Jia, Yangyang Yu, Yang Gao, Xiaolin Yu, Mingkui Li, Xiaopei Lin, and Lixin Wu
Geosci. Model Dev., 16, 705–717, https://doi.org/10.5194/gmd-16-705-2023, https://doi.org/10.5194/gmd-16-705-2023, 2023
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To improve the numerical model predictability of monthly extended-range scales, we use the simplified slab ocean model (SOM) to restrict the complicated sea surface temperature (SST) bias from a 3-D dynamical ocean model. As for SST prediction, whether in space or time, the WRF-SOM is verified to have better performance than the WRF-ROMS, which has a significant impact on the atmosphere. For extreme weather events such as typhoons, the predictions of WRF-SOM are in good agreement with WRF-ROMS.
Yu Lin, Leiming Zhang, Qinchu Fan, He Meng, Yang Gao, Huiwang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 22, 16073–16090, https://doi.org/10.5194/acp-22-16073-2022, https://doi.org/10.5194/acp-22-16073-2022, 2022
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In this study, we analyzed 7-year (from May 2014 to April 2021) concentration data of six criteria air pollutants (PM2.5, PM10, O3, NO2, CO and SO2) as well as the sum of NO2 and O3 in six cities in South China. Three different analysis methods were used to identify emission-driven interannual variations and perturbations from varying weather conditions. In addition, a self-developed method was further introduced to constrain analysis uncertainties.
Meng Wang, Yusen Duan, Wei Xu, Qiyuan Wang, Zhuozhi Zhang, Qi Yuan, Xinwei Li, Shuwen Han, Haijie Tong, Juntao Huo, Jia Chen, Shan Gao, Zhongbiao Wu, Long Cui, Yu Huang, Guangli Xiu, Junji Cao, Qingyan Fu, and Shun-cheng Lee
Atmos. Chem. Phys., 22, 12789–12802, https://doi.org/10.5194/acp-22-12789-2022, https://doi.org/10.5194/acp-22-12789-2022, 2022
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In this study, we report the long-term measurement of organic carbon (OC) and elementary carbon (EC) in PM2.5 with hourly time resolution conducted at a regional site in Shanghai from 2016 to 2020. The results from this study provide critical information about the long-term trend of carbonaceous aerosol, in particular secondary OC, in one of the largest megacities in the world and are helpful for developing pollution control measures from a long-term planning perspective.
Yangyang Yu, Shaoqing Zhang, Haohuan Fu, Lixin Wu, Dexun Chen, Yang Gao, Zhiqiang Wei, Dongning Jia, and Xiaopei Lin
Geosci. Model Dev., 15, 6695–6708, https://doi.org/10.5194/gmd-15-6695-2022, https://doi.org/10.5194/gmd-15-6695-2022, 2022
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To understand the scientific consequence of perturbations caused by slave cores in heterogeneous computing environments, we examine the influence of perturbation amplitudes on the determination of the cloud bottom and cloud top and compute the probability density function (PDF) of generated clouds. A series of comparisons of the PDFs between homogeneous and heterogeneous systems show consistently acceptable error tolerances when using slave cores in heterogeneous computing environments.
Qirui Zhong, Nick Schutgens, Guido van der Werf, Twan van Noije, Kostas Tsigaridis, Susanne E. Bauer, Tero Mielonen, Alf Kirkevåg, Øyvind Seland, Harri Kokkola, Ramiro Checa-Garcia, David Neubauer, Zak Kipling, Hitoshi Matsui, Paul Ginoux, Toshihiko Takemura, Philippe Le Sager, Samuel Rémy, Huisheng Bian, Mian Chin, Kai Zhang, Jialei Zhu, Svetlana G. Tsyro, Gabriele Curci, Anna Protonotariou, Ben Johnson, Joyce E. Penner, Nicolas Bellouin, Ragnhild B. Skeie, and Gunnar Myhre
Atmos. Chem. Phys., 22, 11009–11032, https://doi.org/10.5194/acp-22-11009-2022, https://doi.org/10.5194/acp-22-11009-2022, 2022
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Aerosol optical depth (AOD) errors for biomass burning aerosol (BBA) are evaluated in 18 global models against satellite datasets. Notwithstanding biases in satellite products, they allow model evaluations. We observe large and diverse model biases due to errors in BBA. Further interpretations of AOD diversities suggest large biases exist in key processes for BBA which require better constraining. These results can contribute to further model improvement and development.
Jing Duan, Ru-Jin Huang, Yifang Gu, Chunshui Lin, Haobin Zhong, Wei Xu, Quan Liu, Yan You, Jurgita Ovadnevaite, Darius Ceburnis, Thorsten Hoffmann, and Colin O'Dowd
Atmos. Chem. Phys., 22, 10139–10153, https://doi.org/10.5194/acp-22-10139-2022, https://doi.org/10.5194/acp-22-10139-2022, 2022
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Biomass-burning-influenced oxygenated organic aerosol (OOA-BB), formed from the photochemical oxidation and aging of biomass burning OA (BBOA), was resolved in urban Xi’an. The aqueous-phase processed oxygenated OA (aq-OOA) concentration was more dependent on secondary inorganic aerosol (SIA) content and aerosol liquid water content (ALWC). The increased aq-OOA contribution during SIA-enhanced periods likely reflects OA evolution due to the addition of alcohol or peroxide groups
Haobin Zhong, Ru-Jin Huang, Chunshui Lin, Wei Xu, Jing Duan, Yifang Gu, Wei Huang, Haiyan Ni, Chongshu Zhu, Yan You, Yunfei Wu, Renjian Zhang, Jurgita Ovadnevaite, Darius Ceburnis, and Colin D. O'Dowd
Atmos. Chem. Phys., 22, 9513–9524, https://doi.org/10.5194/acp-22-9513-2022, https://doi.org/10.5194/acp-22-9513-2022, 2022
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To investigate the physico-chemical properties of aerosol transported from major pollution regions in China, observations were conducted ~200 m above the ground at the junction location of the two key pollution areas. We found that the formation efficiency, oxidation state and production rate of secondary aerosol were different in the transport sectors from different pollution regions, and they were largely enhanced by the regional long-distance transport.
Junjun Deng, Hao Ma, Xinfeng Wang, Shujun Zhong, Zhimin Zhang, Jialei Zhu, Yanbing Fan, Wei Hu, Libin Wu, Xiaodong Li, Lujie Ren, Chandra Mouli Pavuluri, Xiaole Pan, Yele Sun, Zifa Wang, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 22, 6449–6470, https://doi.org/10.5194/acp-22-6449-2022, https://doi.org/10.5194/acp-22-6449-2022, 2022
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Light-absorbing brown carbon (BrC) plays an important role in climate change and atmospheric chemistry. Here we investigated the seasonal and diurnal variations in water-soluble BrC in PM2.5 in the megacity Tianjin in coastal China. Results of the source apportionments from the combination with organic molecular compositions and optical properties of water-soluble BrC reveal a large contribution from primary bioaerosol particles to BrC in the urban atmosphere.
Xiajie Yang, Qiaoqiao Wang, Nan Ma, Weiwei Hu, Yang Gao, Zhijiong Huang, Junyu Zheng, Bin Yuan, Ning Yang, Jiangchuan Tao, Juan Hong, Yafang Cheng, and Hang Su
Atmos. Chem. Phys., 22, 3743–3762, https://doi.org/10.5194/acp-22-3743-2022, https://doi.org/10.5194/acp-22-3743-2022, 2022
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We use the GEOS-Chem model with additional anthropogenic and biomass burning chlorine emissions combined with updated parameterizations for N2O5 ＋ Cl chemistry to investigate the impacts of chlorine chemistry on air quality in China. Our study not only significantly improves the model's performance but also demonstrates the importance of non-sea-salt chlorine sources as well as an appropriate parameterization for N2O5 ＋ Cl chemistry to the impact of chlorine chemistry in China.
Yanhong Zhu, Weijun Li, Yue Wang, Jian Zhang, Lei Liu, Liang Xu, Jingsha Xu, Jinhui Shi, Longyi Shao, Pingqing Fu, Daizhou Zhang, and Zongbo Shi
Atmos. Chem. Phys., 22, 2191–2202, https://doi.org/10.5194/acp-22-2191-2022, https://doi.org/10.5194/acp-22-2191-2022, 2022
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The solubilities of iron in fine particles in a megacity in Eastern China were studied under haze, fog, dust, clear, and rain weather conditions. For the first time, a receptor model was used to quantify the sources of dissolved and total iron aerosol. Microscopic analysis further confirmed the aging of iron aerosol during haze and fog conditions that facilitated dissolution of insoluble iron.
Yating Gao, Dihui Chen, Yanjie Shen, Yang Gao, Huiwang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 22, 1515–1528, https://doi.org/10.5194/acp-22-1515-2022, https://doi.org/10.5194/acp-22-1515-2022, 2022
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This study focuses on spatiotemporal heterogeneity of observed gaseous amines, NH3, their particulate counterparts in PM2.5 over different sea zones, and the disproportional release of alkaline gases and corresponding particulate counterparts from seawater in the sea zones in terms of different extents of enrichment of TMAH+ and DMAH+ in the sea surface microlayer (SML). A novel hypothesis is delivered.
Ying Zhou, Simo Hakala, Chao Yan, Yang Gao, Xiaohong Yao, Biwu Chu, Tommy Chan, Juha Kangasluoma, Shahzad Gani, Jenni Kontkanen, Pauli Paasonen, Yongchun Liu, Tuukka Petäjä, Markku Kulmala, and Lubna Dada
Atmos. Chem. Phys., 21, 17885–17906, https://doi.org/10.5194/acp-21-17885-2021, https://doi.org/10.5194/acp-21-17885-2021, 2021
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We characterized the connection between new particle formation (NPF) events in terms of frequency, intensity and growth at a near-highway location in central Beijing and at a background mountain site 80 km away. Due to the substantial contribution of NPF to the global aerosol budget, identifying the conditions that promote the occurrence of regional NPF events could help understand their contribution on a large scale and would improve their implementation in global models.
Liang Xu, Xiaohuan Liu, Huiwang Gao, Xiaohong Yao, Daizhou Zhang, Lei Bi, Lei Liu, Jian Zhang, Yinxiao Zhang, Yuanyuan Wang, Qi Yuan, and Weijun Li
Atmos. Chem. Phys., 21, 17715–17726, https://doi.org/10.5194/acp-21-17715-2021, https://doi.org/10.5194/acp-21-17715-2021, 2021
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We quantified different types of marine aerosols and explored the Cl depletion of sea salt aerosol (SSA) in the eastern China seas and the northwestern Pacific Ocean. We found that anthropogenic acidic gases in the troposphere were transported longer distances compared to the anthropogenic aerosols and could significantly impact remote marine aerosols. Meanwhile, variations of chloride depletion in SSA can serve as a potential indicator for anthropogenic gaseous pollutants in remote marine air.
Dihui Chen, Yanjie Shen, Juntao Wang, Yang Gao, Huiwang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 21, 16413–16425, https://doi.org/10.5194/acp-21-16413-2021, https://doi.org/10.5194/acp-21-16413-2021, 2021
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The study provides solid evidence to demonstrate that atmospheric trimethylamine (TMAgas) and particulate trimethylaminium in PM2.5 (TMAH+) observed in marine atmospheres were uniquely derived from seawater emissions. As sea-derived TMAgas correlated significantly with DMAgas and NH3gas, sea-derived DMAgas and NH3gas can be estimated and can quantify the contribution to the observed species in the marine atmosphere. Similarly, the contributions of primary DMAH+ have also been estimated.
Chunshui Lin, Darius Ceburnis, Anna Trubetskaya, Wei Xu, William Smith, Stig Hellebust, John Wenger, Colin O'Dowd, and Jurgita Ovadnevaite
Atmos. Meas. Tech., 14, 6905–6916, https://doi.org/10.5194/amt-14-6905-2021, https://doi.org/10.5194/amt-14-6905-2021, 2021
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Source apportionment of solid-fuel-burning emissions can be complicated by the use of different fuels, stoves, and burning conditions. Here, the organic aerosol mass spectra produced from burning a range of solid fuels in several stoves were compared. This study accounts for the source variability and provides better constraints on the primary factor contributions to the ambient organic aerosol estimations, holding significant implications for public health and policymakers.
Wei Xu, Kirsten N. Fossum, Jurgita Ovadnevaite, Chunshui Lin, Ru-Jin Huang, Colin O'Dowd, and Darius Ceburnis
Atmos. Chem. Phys., 21, 8655–8675, https://doi.org/10.5194/acp-21-8655-2021, https://doi.org/10.5194/acp-21-8655-2021, 2021
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Cloud condensation nuclei (CCN) are an important topic in atmospheric studies, especially for evaluating the climate impact of aerosol. Here in this study, CCN closure is studied by using chemical composition based on an aerosol mass spectrometer (AMS) and hygroscopicity growth measurements based on a humidified tandem differential mobility analyzer (HTDMA) at the Mace Head atmospheric research station.
Yujiao Zhu, Likun Xue, Jian Gao, Jianmin Chen, Hongyong Li, Yong Zhao, Zhaoxin Guo, Tianshu Chen, Liang Wen, Penggang Zheng, Ye Shan, Xinfeng Wang, Tao Wang, Xiaohong Yao, and Wenxing Wang
Atmos. Chem. Phys., 21, 1305–1323, https://doi.org/10.5194/acp-21-1305-2021, https://doi.org/10.5194/acp-21-1305-2021, 2021
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This work investigates the long-term changes in new particle formation (NPF) events under reduced SO2 emissions at the summit of Mt. Tai during seven campaigns from 2007 to 2018. We found the NPF intensity increased 2- to 3-fold in 2018 compared to 2007. In contrast, the probability of new particles growing to CCN size largely decreased. Changes to biogenic VOCs and anthropogenic emissions are proposed to explain the distinct NPF characteristics.
Liya Ma, Yujiao Zhu, Mei Zheng, Yele Sun, Lei Huang, Xiaohuan Liu, Yang Gao, Yanjie Shen, Huiwang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 21, 183–200, https://doi.org/10.5194/acp-21-183-2021, https://doi.org/10.5194/acp-21-183-2021, 2021
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In this study, we investigate three patterns of new particles growing to CCN (cloud condensation nuclei) size, i.e., one-stage growth and two-stage growth-A and growth-B patterns. Combining the observations of gaseous pollutants and measured or modeled particulate chemical species, the three growth patterns were discussed regarding the spatial heterogeneity, formation of secondary aerosols, and evaporation of semivolatile particulates as was the survival probability of new particles to CCN size.
Cited articles
Albert, M. F. M. A., Schaap, M., Manders, A. M. M., Scannell, C., O'Dowd, C. D., and de Leeuw, G.: Uncertainties in the determination of global sub-micron marine organic matter emissions, Atmospheric Environment, 57, 289–300, https://doi.org/10.1016/j.atmosenv.2012.04.009, 2012.
Aller, J. Y., Radway, J. C., Kilthau, W. P., Bothe, D. W., Wilson, T. W., Vaillancourt, R. D., Quinn, P. K., Coffman, D. J., Murray, B. J., and Knopf, D. A.: Size-resolved characterization of the polysaccharidic and proteinaceous components of sea spray aerosol, Atmospheric Environment, 154, 331–347, https://doi.org/10.1016/j.atmosenv.2017.01.053, 2017.
Barnes, I., Hjorth, J., and Mihalopoulos, N.: Dimethyl sulfide and dimethyl sulfoxide and their oxidation in the atmosphere, Chem. Rev., 106, 940–975, https://doi.org/10.1021/cr020529+, 2006.
Bates, T. S., Quinn, P. K., Coffman, D. J., Johnson, J. E., Upchurch, L., Saliba, G., Lewis, S., Graff, J., Russell, L. M., and Behrenfeld, M. J.: Variability in Marine Plankton Ecosystems Are Not Observed in Freshly Emitted Sea Spray Aerosol Over the North Atlantic Ocean, Geophys. Res. Lett., 47, https://doi.org/10.1029/2019gl085938, 2020.
Boreddy, S. K. R., Haque, M. M., and Kawamura, K.: Long-term (2001–2012) trends of carbonaceous aerosols from a remote island in the western North Pacific: an outflow region of Asian pollutants, Atmos. Chem. Phys., 18, 1291–1306, https://doi.org/10.5194/acp-18-1291-2018, 2018.
Brooks, S. D. and Thornton, D. C. O.: Marine Aerosols and Clouds, Annual Review of Marine Science, 10, 289–313, https://doi.org/10.1146/annurev-marine-121916-063148, 2018a.
Brooks, S. D. and Thornton, D. C. O.: Marine Aerosols and Clouds, Ann. Rev. Mar. Sci., 10, 289–313, https://doi.org/10.1146/annurev-marine-121916-063148, 2018b.
Bruggemann, M., Hayeck, N., and George, C.: Interfacial photochemistry at the ocean surface is a global source of organic vapors and aerosols, Nat. Commun., 9, 2101, https://doi.org/10.1038/s41467-018-04528-7, 2018.
Cao, C., Yu, X., Marco Wong, W. H., Sun, N., Zhang, K., Sun, Z., Chen, L., Wu, C., Wang, G., and Yu, J. Z.: An Instrumental Method for the Simultaneous Determination of Organic Carbon, Elemental Carbon, Inorganic Nitrogen, and Organic Nitrogen in Aerosol Samples, J. Geophys. Res. Atmos., 130, https://doi.org/10.1029/2025jd043904, 2025.
Carlton, A. G., Wiedinmyer, C., and Kroll, J. H.: A review of Secondary Organic Aerosol (SOA) formation from isoprene, Atmos. Chem. Phys., 9, 4987–5005, https://doi.org/10.5194/acp-9-4987-2009, 2009.
Cavalli, F.: Advances in characterization of size-resolved organic matter in marine aerosol over the North Atlantic, J. Geophys. Res., 109, D24215, https://doi.org/10.1029/2004jd005137, 2004a.
Cavalli, F.: Advances in characterization of size-resolved organic matter in marine aerosol over the North Atlantic, Journal of Geophysical Research, 109, https://doi.org/10.1029/2004jd005137, 2004b.
Chen, Q., Ikemori, F., and Mochida, M.: Light Absorption and Excitation-Emission Fluorescence of Urban Organic Aerosol Components and Their Relationship to Chemical Structure, Environ. Sci. Technol., 50, 10859–10868, https://doi.org/10.1021/acs.est.6b02541, 2016a.
Chen, Q., Miyazaki, Y., Kawamura, K., Matsumoto, K., Coburn, S., Volkamer, R., Iwamoto, Y., Kagami, S., Deng, Y., Ogawa, S., Ramasamy, S., Kato, S., Ida, A., Kajii, Y., and Mochida, M.: Characterization of Chromophoric Water-Soluble Organic Matter in Urban, Forest, and Marine Aerosols by HR-ToF-AMS Analysis and Excitation-Emission Matrix Spectroscopy, Environmental Science & Technology, 50, 10351–10360, https://doi.org/10.1021/acs.est.6b01643, 2016b.
Chow, J. C., Watson, J. G., Chen, L. W., Arnott, W. P., Moosmuller, H., and Fung, K.: Equivalence of elemental carbon by thermal/optical reflectance and transmittance with different temperature protocols, Environ. Sci. Technol., 38, 4414–4422, https://doi.org/10.1021/es034936u, 2004.
Christiansen, S., Salter, M. E., Gorokhova, E., Nguyen, Q. T., and Bilde, M.: Sea spray aerosol formation: Laboratory results on the role of air entrainment, water temperature, and phytoplankton biomass, Environ. Sci. Technol., 53, 13107–13116, https://doi.org/10.1021/acs.est.9b04078, 2019.
Cochran, R. E., Laskina, O., Jayarathne, T., Laskin, A., Laskin, J., Lin, P., Sultana, C., Lee, C., Moore, K. A., Cappa, C. D., Bertram, T. H., Prather, K. A., Grassian, V. H., and Stone, E. A.: Analysis of Organic Anionic Surfactants in Fine and Coarse Fractions of Freshly Emitted Sea Spray Aerosol, Environmental Science & Technology, 50, 2477–2486, https://doi.org/10.1021/acs.est.5b04053, 2016.
Cochran, R. E., Laskina, O., Trueblood, J. V., Estillore, A. D., Morris, H. S., Jayarathne, T., Sultana, C. M., Lee, C., Lin, P., Laskin, J., Laskin, A., Dowling, J. A., Qin, Z., Cappa, C. D., Bertram, T. H., Tivanski, A. V., Stone, E. A., Prather, K. A., and Grassian, V. H.: Molecular Diversity of Sea Spray Aerosol Particles: Impact of Ocean Biology on Particle Composition and Hygroscopicity, Chem, 2, 655–667, https://doi.org/10.1016/j.chempr.2017.03.007, 2017.
Cravigan, L. T., Mallet, M. D., Vaattovaara, P., Harvey, M. J., Law, C. S., Modini, R. L., Russell, L. M., Stelcer, E., Cohen, D. D., Olsen, G., Safi, K., Burrell, T. J., and Ristovski, Z.: Sea spray aerosol organic enrichment, water uptake and surface tension effects, Atmos. Chem. Phys., 20, 7955–7977, https://doi.org/10.5194/acp-20-7955-2020, 2020.
Crocker, D. R., Kaluarachchi, C. P., Cao, R., Dinasquet, J., Franklin, E. B., Morris, C. K., Amiri, S., Petras, D., Nguyen, T., Torres, R. R., Martz, T. R., Malfatti, F., Goldstein, A. H., Tivanski, A. V., Prather, K. A., and Thiemens, M. H.: Isotopic Insights into Organic Composition Differences between Supermicron and Submicron Sea Spray Aerosol, Environmental Science & Technology, 56, 9947–9958, https://doi.org/10.1021/acs.est.2c02154, 2022.
Cui, L., Xiao, Y., Hu, W., Song, L., Wang, Y., Zhang, C., Fu, P., and Zhu, J.: Enhanced dataset of global marine isoprene emissions from biogenic and photochemical processes for the period 2001–2020, Earth Syst. Sci. Data, 15, 5403–5425, https://doi.org/10.5194/essd-15-5403-2023, 2023.
de Jonge, R. W., Xavier, C., Olenius, T., Elm, J., Svenhag, C., Hyttinen, N., Nieradzik, L., Sarnela, N., Kristensson, A., Petaja, T., Ehn, M., and Roldin, P.: Natural Marine Precursors Boost Continental New Particle Formation and Production of Cloud Condensation Nuclei, Environmental Science & Technology, 58, 10956-10968, https://doi.org/10.1021/acs.est.4c01891, 2024.
de Leeuw, G., Andreas, E. L., Anguelova, M. D., Fairall, C. W., Lewis, E. R., O'Dowd, C., Schulz, M., and Schwartz, S. E.: Production flux of sea spray aerosol, Rev. Geophys., 49, https://doi.org/10.1029/2010rg000349, 2011.
DeMott, P. J., Hill, T. C., McCluskey, C. S., Prather, K. A., Collins, D. B., Sullivan, R. C., Ruppel, M. J., Mason, R. H., Irish, V. E., Lee, T., Hwang, C. Y., Rhee, T. S., Snider, J. R., McMeeking, G. R., Dhaniyala, S., Lewis, E. R., Wentzell, J. J., Abbatt, J., Lee, C., Sultana, C. M., Ault, A. P., Axson, J. L., Diaz Martinez, M., Venero, I., Santos-Figueroa, G., Stokes, M. D., Deane, G. B., Mayol-Bracero, O. L., Grassian, V. H., Bertram, T. H., Bertram, A. K., Moffett, B. F., and Franc, G. D.: Sea spray aerosol as a unique source of ice nucleating particles, The Proceedings of the National Academy of Sciences, 113, 5797–5803, https://doi.org/10.1073/pnas.1514034112, 2016.
Facchini, M. C., Rinaldi, M., Decesari, S., Carbone, C., Finessi, E., Mircea, M., Fuzzi, S., Ceburnis, D., Flanagan, R., Nilsson, E. D., de Leeuw, G., Martino, M., Woeltjen, J., and O'Dowd, C. D.: Primary submicron marine aerosol dominated by insoluble organic colloids and aggregates, Geophys. Res. Lett., 35, https://doi.org/10.1029/2008gl034210, 2008.
Fu, P., Kawamura, K., and Miura, K.: Molecular characterization of marine organic aerosols collected during a round-the-world cruise, Journal of Geophysical Research, 116, https://doi.org/10.1029/2011jd015604, 2011.
Fu, P., Kawamura, K., Chen, J., Qin, M., Ren, L., Sun, Y., Wang, Z., Barrie, L. A., Tachibana, E., Ding, A., and Yamashita, Y.: Fluorescent water-soluble organic aerosols in the High Arctic atmosphere, Scientific Reports, 5, 9845, https://doi.org/10.1038/srep09845, 2015.
Gantt, B. and Meskhidze, N.: The physical and chemical characteristics of marine primary organic aerosol: a review, Atmos. Chem. Phys., 13, 3979–3996, https://doi.org/10.5194/acp-13-3979-2013, 2013.
Gantt, B., Meskhidze, N., Facchini, M. C., Rinaldi, M., Ceburnis, D., and O'Dowd, C. D.: Wind speed dependent size-resolved parameterization for the organic mass fraction of sea spray aerosol, Atmos. Chem. Phys., 11, 8777–8790, https://doi.org/10.5194/acp-11-8777-2011, 2011.
Gantt, B., Johnson, M. S., Meskhidze, N., Sciare, J., Ovadnevaite, J., Ceburnis, D., and O'Dowd, C. D.: Model evaluation of marine primary organic aerosol emission schemes, Atmos. Chem. Phys., 12, 8553–8566, https://doi.org/10.5194/acp-12-8553-2012, 2012.
Graber, E. R. and Rudich, Y.: Atmospheric HULIS: How humic-like are they? A comprehensive and critical review, Atmos. Chem. Phys., 6, 729–753, https://doi.org/10.5194/acp-6-729-2006, 2006.
Grythe, H., Ström, J., Krejci, R., Quinn, P., and Stohl, A.: A review of sea-spray aerosol source functions using a large global set of sea salt aerosol concentration measurements, Atmos. Chem. Phys., 14, 1277–1297, https://doi.org/10.5194/acp-14-1277-2014, 2014.
Gu, W., Xie, Z., Wei, Z., Chen, A., Jiang, B., Yue, F., and Yu, X.: Marine Fresh Carbon Pool Dominates Summer Carbonaceous Aerosols Over Arctic Ocean, J. Geophys. Res. Atmos., 128, https://doi.org/10.1029/2022jd037692, 2023.
Gupta, M., Sahu, L. K., Tripathi, N., Sudheer, A. K., and Singh, A.: Processes Controlling DMS Variability in Marine Boundary Layer of the Arabian Sea During Post-Monsoon Season of 2021, J. Geophys. Res. Atmos., 130, https://doi.org/10.1029/2024jd042547, 2025.
Hedges, J. I.: Global biogeochemical cycles: progress and problems, Marine Chemistry, 39, 67–93, https://doi.org/10.1016/0304-4203(92)90096-S, 1992.
Hersbach, H., Bell, B., Berrisford, P., Hirahara, S., Horányi, A., Muñoz-Sabater, J., Nicolas, J., Peubey, C., Radu, R., Schepers, D., Simmons, A., Soci, C., Abdalla, S., Abellan, X., Balsamo, G., Bechtold, P., Biavati, G., Bidlot, J., Bonavita, M., De Chiara, G., Dahlgren, P., Dee, D., Diamantakis, M., Dragani, R., Flemming, J., Forbes, R., Fuentes, M., Geer, A., Haimberger, L., Healy, S., Hogan, R. J., Hólm, E., Janisková, M., Keeley, S., Laloyaux, P., Lopez, P., Lupu, C., Radnoti, G., de Rosnay, P., Rozum, I., Vamborg, F., Villaume, S., and Thépaut, J. N.: The ERA5 global reanalysis, Quarterly Journal of the Royal Meteorological Society, 146, 1999–2049, https://doi.org/10.1002/qj.3803, 2020.
Hoque, M., Kawamura, K., Seki, O., and Hoshi, N.: Spatial distributions of dicarboxylic acids, ω-oxoacids, pyruvic acid and α-dicarbonyls in the remote marine aerosols over the North Pacific, Marine Chemistry, 172, 1–11, https://doi.org/10.1016/j.marchem.2015.03.003, 2015.
Hoque, M. M. M., Kawamura, K., and Uematsu, M.: Spatio-temporal distributions of dicarboxylic acids, ω-oxocarboxylic acids, pyruvic acid, α-dicarbonyls and fatty acids in the marine aerosols from the North and South Pacific, Atmospheric Research, 185, 158–168, https://doi.org/10.1016/j.atmosres.2016.10.022, 2017.
Hsu, S.-C., Wong, G. T. F., Gong, G.-C., Shiah, F.-K., Huang, Y.-T., Kao, S.-J., Tsai, F., Candice Lung, S.-C., Lin, F.-J., Lin, I. I., Hung, C.-C., and Tseng, C.-M.: Sources, solubility, and dry deposition of aerosol trace elements over the East China Sea, Mar. Chem., 120, 116–127, https://doi.org/10.1016/j.marchem.2008.10.003, 2010.
Hu, J., Li, J., Tsona Tchinda, N., Song, Y., Xu, M., Li, K., and Du, L.: Underestimated role of sea surface temperature in sea spray aerosol formation and climate effects, npj Climate and Atmospheric Science, 7, https://doi.org/10.1038/s41612-024-00823-x, 2024.
Huang, S., Wu, Z., Poulain, L., van Pinxteren, M., Merkel, M., Assmann, D., Herrmann, H., and Wiedensohler, A.: Source apportionment of the organic aerosol over the Atlantic Ocean from 53° N to 53° S: significant contributions from marine emissions and long-range transport, Atmos. Chem. Phys., 18, 18043–18062, https://doi.org/10.5194/acp-18-18043-2018, 2018.
Huang, S., Wu, Z., Wang, Y., Poulain, L., Hopner, F., Merkel, M., Herrmann, H., and Wiedensohler, A.: Aerosol Hygroscopicity and its Link to Chemical Composition in a Remote Marine Environment Based on Three Transatlantic Measurements, Environmental Science & Technology, 56, 9613–9622, https://doi.org/10.1021/acs.est.2c00785, 2022.
Huebert, B. J. and Charlson, R. J.: Uncertainties in data on organic aerosols, Tellus B: Chemical and Physical Meteorology, 52, https://doi.org/10.3402/tellusb.v52i5.17099, 2000.
Kunwar, B. and Kawamura, K.: One-year observations of carbonaceous and nitrogenous components and major ions in the aerosols from subtropical Okinawa Island, an outflow region of Asian dusts, Atmos. Chem. Phys., 14, 1819–1836, https://doi.org/10.5194/acp-14-1819-2014, 2014.
Laskin, A., Laskin, J., and Nizkorodov, S. A.: Chemistry of atmospheric brown carbon, Chem. Rev., 115, 4335–4382, https://doi.org/10.1021/cr5006167, 2015.
Lawler, M. J., Lewis, S. L., Russell, L. M., Quinn, P. K., Bates, T. S., Coffman, D. J., Upchurch, L. M., and Saltzman, E. S.: North Atlantic marine organic aerosol characterized by novel offline thermal desorption mass spectrometry: polysaccharides, recalcitrant material, and secondary organics, Atmos. Chem. Phys., 20, 16007–16022, https://doi.org/10.5194/acp-20-16007-2020, 2020.
Lewis, E. and Schwartz, S.: Sea Salt Aerosol Production: Mechanisms, Methods, Measurements and Models – A Critical Review, Washington DC American Geophysical Union Geophysical Monograph Series, 152, 37–43, 2004.
Li, J., Han, Z., Fu, P., Yao, X., and Liang, M.: Seasonal characteristics of emission, distribution, and radiative effect of marine organic aerosols over the western Pacific Ocean: an investigation with a coupled regional climate aerosol model, Atmos. Chem. Phys., 24, 3129–3161, https://doi.org/10.5194/acp-24-3129-2024, 2024.
Lim, H. J. and Turpin, B. J.: Origins of primary and secondary organic aerosol in Atlanta: results of time-resolved measurements during the Atlanta Supersite Experiment, Environ. Sci. Technol., 36, 4489–4496, https://doi.org/10.1021/es0206487, 2002.
Ma, X., Li, K., Zhang, S., Tchinda, N. T., Li, J., Herrmann, H., and Du, L.: Molecular characteristics of sea spray aerosols during aging with the participation of marine volatile organic compounds, Science of the Total Environment, 954, 176380, https://doi.org/10.1016/j.scitotenv.2024.176380, 2024.
Miyazaki, Y., Kawamura, K., and Sawano, M.: Size distributions and chemical characterization of water-soluble organic aerosols over the western North Pacific in summer, Journal of Geophysical Research: Atmospheres, 115, https://doi.org/10.1029/2010jd014439, 2010.
Miyazaki, Y., Yamashita, Y., Kawana, K., Tachibana, E., Kagami, S., Mochida, M., Suzuki, K., and Nishioka, J.: Chemical transfer of dissolved organic matter from surface seawater to sea spray water-soluble organic aerosol in the marine atmosphere, Scientific Reports, 8, 14861, https://doi.org/10.1038/s41598-018-32864-7, 2018a.
Miyazaki, Y., Yamashita, Y., Kawana, K., Tachibana, E., Kagami, S., Mochida, M., Suzuki, K., and Nishioka, J.: Chemical transfer of dissolved organic matter from surface seawater to sea spray water-soluble organic aerosol in the marine atmosphere, Sci. Rep., 8, 14861, https://doi.org/10.1038/s41598-018-32864-7, 2018b.
Miyazaki, Y., Suzuki, K., Tachibana, E., Yamashita, Y., Muller, A., Kawana, K., and Nishioka, J.: New index of organic mass enrichment in sea spray aerosols linked with senescent status in marine phytoplankton, Scientific Reports, 10, 17042, https://doi.org/10.1038/s41598-020-73718-5, 2020.
Murphy, K. R., Stedmon, C. A., Graeber, D., and Bro, R.: Fluorescence spectroscopy and multi-way techniques. PARAFAC, Analytical Methods, 5, https://doi.org/10.1039/c3ay41160e, 2013.
O'Dowd, C. D., Facchini, M. C., Cavalli, F., Ceburnis, D., Mircea, M., Decesari, S., Fuzzi, S., Yoon, Y. J., and Putaud, J. P.: Biogenically driven organic contribution to marine aerosol, Nature, 431, 676–680, https://doi.org/10.1038/nature02959, 2004.
O'Dowd, C. D., Langmann, B., Varghese, S., Scannell, C., Ceburnis, D., and Facchini, M. C.: A combined organic-inorganic sea-spray source function, Geophysical Research Letters, 35, https://doi.org/10.1029/2007gl030331, 2008.
Pöhlker, C., Huffman, J. A., and Pöschl, U.: Autofluorescence of atmospheric bioaerosols – fluorescent biomolecules and potential interferences, Atmos. Meas. Tech., 5, 37–71, https://doi.org/10.5194/amt-5-37-2012, 2012.
Prather, K. A., Bertram, T. H., Grassian, V. H., Deane, G. B., Stokes, M. D., DeMott, P. J., Aluwihare, L. I., Palenik, B. P., Azam, F., Seinfeld, J. H., Moffet, R. C., Molina, M. J., Cappa, C. D., Geiger, F. M., Roberts, G. C., Russell, L. M., Ault, A. P., Baltrusaitis, J., Collins, D. B., Corrigan, C. E., Cuadra-Rodriguez, L. A., Ebben, C. J., Forestieri, S. D., Guasco, T. L., Hersey, S. P., Kim, M. J., Lambert, W. F., Modini, R. L., Mui, W., Pedler, B. E., Ruppel, M. J., Ryder, O. S., Schoepp, N. G., Sullivan, R. C., and Zhao, D.: Bringing the ocean into the laboratory to probe the chemical complexity of sea spray aerosol, Proc. Natl. Acad. Sci. USA, 110, 7550–7555, https://doi.org/10.1073/pnas.1300262110, 2013.
Quinn, P. K. and Bates, T. S.: The case against climate regulation via oceanic phytoplankton sulphur emissions, Nature, 480, 51–56, https://doi.org/10.1038/nature10580, 2011.
Quinn, P. K., Bates, T. S., Schulz, K. S., Coffman, D. J., Frossard, A. A., Russell, L. M., Keene, W. C., and Kieber, D. J.: Contribution of sea surface carbon pool to organic matter enrichment in sea spray aerosol, Nat. Geosci., 7, 228–232, https://doi.org/10.1038/ngeo2092, 2014.
Quinn, P. K., Collins, D. B., Grassian, V. H., Prather, K. A., and Bates, T. S.: Chemistry and related properties of freshly emitted sea spray aerosol, Chem. Rev., 115, 4383–4399, https://doi.org/10.1021/cr500713g, 2015.
Quinn, P. K., Coffman, D. J., Johnson, J. E., Upchurch, L. M., and Bates, T. S.: Small fraction of marine cloud condensation nuclei made up of sea spray aerosol, Nat. Geosci., 10, 674–679, https://doi.org/10.1038/ngeo3003, 2017.
Rinaldi, M., Fuzzi, S., Decesari, S., Marullo, S., Santoleri, R., Provenzale, A., von Hardenberg, J., Ceburnis, D., Vaishya, A., O'Dowd, C. D., and Facchini, M. C.: Is chlorophyll-athe best surrogate for organic matter enrichment in submicron primary marine aerosol?, Journal of Geophysical Research: Atmospheres, 118, 4964–4973, https://doi.org/10.1002/jgrd.50417, 2013.
Russell, L. M., Hawkins, L. N., Frossard, A. A., Quinn, P. K., and Bates, T. S.: Carbohydrate-like composition of submicron atmospheric particles and their production from ocean bubble bursting, The Proceedings of the National Academy of Sciences 107, 6652–6657, https://doi.org/10.1073/pnas.0908905107, 2010.
Sahu, L. K., Kondo, Y., Miyazaki, Y., Kuwata, M., Koike, M., Takegawa, N., Tanimoto, H., Matsueda, H., Yoon, S. C., and Kim, Y. J.: Anthropogenic aerosols observed in Asian continental outflow at Jeju Island, Korea, in spring 2005, J. Geophys. Res. Atmos., 114, https://doi.org/10.1029/2008jd010306, 2009.
Salter, M. E., Nilsson, E. D., Butcher, A., and Bilde, M.: On the seawater temperature dependence of the sea spray aerosol generated by a continuous plunging jet, Journal of Geophysical Research: Atmospheres, 119, 9052–9072, https://doi.org/10.1002/2013jd021376, 2014.
Santander, M. V., Mitts, B. A., Pendergraft, M. A., Dinasquet, J., Lee, C., Moore, A. N., Cancelada, L. B., Kimble, K. A., Malfatti, F., and Prather, K. A.: Tandem Fluorescence Measurements of Organic Matter and Bacteria Released in Sea Spray Aerosols, Environmental Science & Technology, 55, 5171–5179, https://doi.org/10.1021/acs.est.0c05493, 2021.
Santander, M. V., Schiffer, J. M., Lee, C., Axson, J. L., Tauber, M. J., and Prather, K. A.: Factors controlling the transfer of biogenic organic species from seawater to sea spray aerosol, Scientific Reports, 12, 3580, https://doi.org/10.1038/s41598-022-07335-9, 2022.
Schmitt-Kopplin, P., Liger-Belair, G., Koch, B. P., Flerus, R., Kattner, G., Harir, M., Kanawati, B., Lucio, M., Tziotis, D., Hertkorn, N., and Gebefügi, I.: Dissolved organic matter in sea spray: a transfer study from marine surface water to aerosols, Biogeosciences, 9, 1571–1582, https://doi.org/10.5194/bg-9-1571-2012, 2012.
Shank, L. M., Howell, S., Clarke, A. D., Freitag, S., Brekhovskikh, V., Kapustin, V., McNaughton, C., Campos, T., and Wood, R.: Organic matter and non-refractory aerosol over the remote Southeast Pacific: oceanic and combustion sources, Atmos. Chem. Phys., 12, 557–576, https://doi.org/10.5194/acp-12-557-2012, 2012.
Siemer, J. P., Machín, F., González-Vega, A., Arrieta, J. M., Gutiérrez-Guerra, M. A., Pérez-Hernández, M. D., Vélez-Belchí, P., Hernández-Guerra, A., and Fraile-Nuez, E.: Recent Trends in SST, Chl-a, Productivity and Wind Stress in Upwelling and Open Ocean Areas in the Upper Eastern North Atlantic Subtropical Gyre, J. Geophys. Res. Oceans, 126, https://doi.org/10.1029/2021jc017268, 2021.
Sinclair, K., van Diedenhoven, B., Cairns, B., Alexandrov, M., Moore, R., Ziemba, L. D., and Crosbie, E.: Observations of Aerosol-Cloud Interactions During the North Atlantic Aerosol and Marine Ecosystem Study, Geophysical Research Letters, 47, https://doi.org/10.1029/2019gl085851, 2020.
Spracklen, D. V., Arnold, S. R., Sciare, J., Carslaw, K. S., and Pio, C.: Globally significant oceanic source of organic carbon aerosol, Geophys. Res. Lett., 35, https://doi.org/10.1029/2008gl033359, 2008.
Stedmon, C. A. and Bro, R.: Characterizing dissolved organic matter fluorescence with parallel factor analysis: a tutorial, Limnology and Oceanography: Methods, 6, 572–579, https://doi.org/10.4319/lom.2008.6.572, 2008.
Tang, J., Xu, B., Zhao, S., Li, J., Tian, L., Geng, X., Jiang, H., Mo, Y., Zhong, G., Jiang, B., Chen, Y., Tang, J., and Zhang, G.: Long-Emission-Wavelength Humic-Like Component (L-HULIS) as a Secondary Source Tracer of Brown Carbon in the Atmosphere, Journal of Geophysical Research: Atmospheres, 129, https://doi.org/10.1029/2023jd040144, 2024.
Tripathi, N., Sahu, L. K., Singh, A., Yadav, R., Patel, A., Patel, K., and Meenu, P.: Elevated Levels of Biogenic Nonmethane Hydrocarbons in the Marine Boundary Layer of the Arabian Sea During the Intermonsoon, J. Geophys. Res. Atmos., 125, https://doi.org/10.1029/2020jd032869, 2020.
Tripathi, N., Girach, I. A., Kompalli, S. K., Murari, V., Nair, P. R., Babu, S. S., and Sahu, L. K.: Sources and Distribution of Light NMHCs in the Marine Boundary Layer of the Northern Indian Ocean During Winter: Implications to Aerosol Formation, J. Geophys. Res. Atmos., 129, https://doi.org/10.1029/2023jd039433, 2024.
Trueblood, J. V., Wang, X., Or, V. W., Alves, M. R., Santander, M. V., Prather, K. A., and Grassian, V. H.: The Old and the New: Aging of Sea Spray Aerosol and Formation of Secondary Marine Aerosol through OH Oxidation Reactions, ACS Earth and Space Chemistry, 3, 2307–2314, https://doi.org/10.1021/acsearthspacechem.9b00087, 2019.
Tuchen, F. P., Perez, R. C., Foltz, G. R., Brandt, P., Subramaniam, A., Lee, S. K., Lumpkin, R., and Hummels, R.: Modulation of Equatorial Currents and Tropical Instability Waves During the 2021 Atlantic Niño, J. Geophys. Res. Oceans, 129, https://doi.org/10.1029/2023jc020431, 2023.
Turpin, B. J. and Huntzicker, J. J.: Identification of Secondary Organic Aerosol Episodes and Quantitation of Primary and Secondary Organic Aerosol Concentrations During SCAQS, Atmospheric Environment, 29, 3527–3544, https://doi.org/10.1016/1352-2310(94)00276-Q, 1995.
Vergara-Temprado, J., Murray, B. J., Wilson, T. W., O'Sullivan, D., Browse, J., Pringle, K. J., Ardon-Dryer, K., Bertram, A. K., Burrows, S. M., Ceburnis, D., DeMott, P. J., Mason, R. H., O'Dowd, C. D., Rinaldi, M., and Carslaw, K. S.: Contribution of feldspar and marine organic aerosols to global ice nucleating particle concentrations, Atmos. Chem. Phys., 17, 3637–3658, https://doi.org/10.5194/acp-17-3637-2017, 2017.
Vignati, E., Facchini, M. C., Rinaldi, M., Scannell, C., Ceburnis, D., Sciare, J., Kanakidou, M., Myriokefalitakis, S., Dentener, F., and O'Dowd, C. D.: Global scale emission and distribution of sea-spray aerosol: Sea-salt and organic enrichment, Atmos. Environ., 44, 670–677, https://doi.org/10.1016/j.atmosenv.2009.11.013, 2010.
Wang, J., Zhang, H. H., Booge, D., Zhang, Y. Q., Li, X. J., Wu, Y. C., Zhang, J. W., and Chen, Z. H.: Isoprene Production and Its Driving Factors in the Northwest Pacific Ocean, Global Biogeochem. Cy., 37, https://doi.org/10.1029/2023gb007841, 2023a.
Wang, X., Sultana, C. M., Trueblood, J., Hill, T. C., Malfatti, F., Lee, C., Laskina, O., Moore, K. A., Beall, C. M., McCluskey, C. S., Cornwell, G. C., Zhou, Y., Cox, J. L., Pendergraft, M. A., Santander, M. V., Bertram, T. H., Cappa, C. D., Azam, F., DeMott, P. J., Grassian, V. H., and Prather, K. A.: Microbial Control of Sea Spray Aerosol Composition: A Tale of Two Blooms, ACS Central Science, 1, 124–131, https://doi.org/10.1021/acscentsci.5b00148, 2015.
Wang, X., Deane, G. B., Moore, K. A., Ryder, O. S., Stokes, M. D., Beall, C. M., Collins, D. B., Santander, M. V., Burrows, S. M., Sultana, C. M., and Prather, K. A.: The role of jet and film drops in controlling the mixing state of submicron sea spray aerosol particles, Proc. Natl. Acad. Sci. USA, 114, 6978–6983, https://doi.org/10.1073/pnas.1702420114, 2017.
Wang, Y.: Data for “Biogenically driven marine organic aerosol production over the Northwest Pacific Ocean”, Zenodo [data set], https://doi.org/10.5281/zenodo.16831992, 2025.
Wang, Y., Zhang, P., Li, J., Liu, Y., Zhang, Y., Li, J., and Han, Z.: An updated aerosol simulation in the Community Earth System Model (v2.1.3): dust and marine aerosol emissions and secondary organic aerosol formation, Geosci. Model Dev., 17, 7995–8021, https://doi.org/10.5194/gmd-17-7995-2024, 2024.
Wang, Y., Zhang, Y., Li, W., Wu, G., Qi, Y., Li, S., Zhu, W., Yu, J. Z., Yu, X., Zhang, H. H., Sun, J., Wang, W., Sheng, L., Yao, X., Gao, H., Huang, C., Ma, Y., and Zhou, Y.: Important roles and formation of atmospheric organosulfates in marine organic aerosols: Influence of phytoplankton emissions and anthropogenic pollutants, Environ. Sci. Technol., 57, 10284–10294, https://doi.org/10.1021/acs.est.3c01422, 2023b.
Wolf, M. J., Coe, A., Dove, L. A., Zawadowicz, M. A., Dooley, K., Biller, S. J., Zhang, Y., Chisholm, S. W., and Cziczo, D. J.: Investigating the Heterogeneous Ice Nucleation of Sea Spray Aerosols Using Prochlorococcus as a Model Source of Marine Organic Matter, Environmental Science & Technology, 53, 1139–1149, https://doi.org/10.1021/acs.est.8b05150, 2019.
Xu, W., Ovadnevaite, J., Fossum, K. N., Lin, C., Huang, R.-J., Ceburnis, D., and O'Dowd, C.: Sea spray as an obscured source for marine cloud nuclei, Nature Geoscience, 15, 282–286, https://doi.org/10.1038/s41561-022-00917-2, 2022.
Yu, Y., Wang, H., Wang, T., Song, K., Tan, T., Wan, Z., Gao, Y., Dong, H., Chen, S., Zeng, L., Hu, M., Wang, H., Lou, S., Zhu, W., and Guo, S.: Elucidating the importance of semi-volatile organic compounds to secondary organic aerosol formation at a regional site during the EXPLORE-YRD campaign, Atmos. Environ., 246, https://doi.org/10.1016/j.atmosenv.2020.118043, 2021.
Yu, Z. and Li, Y.: Marine volatile organic compounds and their impacts on marine aerosol-A review, Sci. Total Environ., 768, 145054, https://doi.org/10.1016/j.scitotenv.2021.145054, 2021.
Zhang, W. and Gu, D.: Geostationary satellite reveals increasing marine isoprene emissions in the center of the equatorial Pacific Ocean, npj Climate and Atmospheric Science, 5, 1, https://doi.org/10.1038/s41612-022-00311-0, 2022.
Zhang, Y., Wang, Y., Li, S., Yi, Y., Guo, Y., Yu, C., Jiang, Y., Ni, Y., Hu, W., Zhu, J., Qi, J., Shi, J., Yao, X., and Gao, H.: Sources and Optical Properties of Marine Organic Aerosols Under the Influence of Marine Emissions, Asian Dust, and Anthropogenic Pollutants, J. Geophys. Res. Atmos., 130, https://doi.org/10.1029/2025jd043472, 2025.
Zhao, X., Liu, X., Burrows, S. M., and Shi, Y.: Effects of marine organic aerosols as sources of immersion-mode ice-nucleating particles on high-latitude mixed-phase clouds, Atmos. Chem. Phys., 21, 2305–2327, https://doi.org/10.5194/acp-21-2305-2021, 2021.
Short summary
Marine organic aerosols remain poorly quantified, which limits our understanding on the climate regulation of marine aerosols. Based on shipboard cruises over the Pacific Ocean, we proposed an observation-based parameterization approach to estimate the primary and secondary marine organic aerosols using sea surface chlorophyll a and sea salts in marine aerosols. The results highlight that the spatial distribution of marine organic aerosols was driven by the marine biological activities.
Marine organic aerosols remain poorly quantified, which limits our understanding on the climate...
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