Articles | Volume 12, issue 6
https://doi.org/10.5194/bg-12-2047-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/bg-12-2047-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
31 Mar 2015
Research article |
| 31 Mar 2015
Inorganic carbon dynamics of melt-pond-covered first-year sea ice in the Canadian Arctic
N.-X. Geilfus
CORRESPONDING AUTHOR
Centre for Earth Observation Science, Department of Environment and Geography, University of Manitoba, Winnipeg, Canada
Arctic Research Centre, Aarhus University, Aarhus, Denmark
R. J. Galley
Centre for Earth Observation Science, Department of Environment and Geography, University of Manitoba, Winnipeg, Canada
O. Crabeck
Centre for Earth Observation Science, Department of Environment and Geography, University of Manitoba, Winnipeg, Canada
T. Papakyriakou
Centre for Earth Observation Science, Department of Environment and Geography, University of Manitoba, Winnipeg, Canada
Centre for Earth Observation Science, Department of Environment and Geography, University of Manitoba, Winnipeg, Canada
J.-L. Tison
Laboratoire de Glaciologie, DSTE, Université Libre de Bruxelles, Brussels, Belgium
S. Rysgaard
Centre for Earth Observation Science, Department of Environment and Geography, University of Manitoba, Winnipeg, Canada
Arctic Research Centre, Aarhus University, Aarhus, Denmark
Greenland Climate Research Centre, Greenland Institute of Natural Resources, Nuuk, Greenland
Related authors
Zhiyuan Gao, Nicolas-Xavier Geilfus, Alfonso Saiz-Lopez, and Feiyue Wang
Atmos. Chem. Phys., 22, 1811–1824, https://doi.org/10.5194/acp-22-1811-2022, https://doi.org/10.5194/acp-22-1811-2022, 2022
Short summary
Short summary
Every spring in the Arctic, a series of photochemical events occur over the ice-covered ocean, known as bromine explosion events, ozone depletion events, and mercury depletion events. Here we report the re-creation of these events at an outdoor sea ice facility in Winnipeg, Canada, far away from the Arctic. The success provides a new platform with new opportunities to uncover fundamental mechanisms of these Arctic springtime phenomena and how they may change in a changing climate.
Nicolas-Xavier Geilfus, Ryan J. Galley, Brent G. T. Else, Karley Campbell, Tim Papakyriakou, Odile Crabeck, Marcos Lemes, Bruno Delille, and Søren Rysgaard
The Cryosphere, 10, 2173–2189, https://doi.org/10.5194/tc-10-2173-2016, https://doi.org/10.5194/tc-10-2173-2016, 2016
Short summary
Short summary
The fate of ikaite precipitation within sea ice is poorly understood. In this study, we estimated ikaite precipitation of up to 167 µmol kg-1 within sea ice, while its export and dissolution into the underlying seawater was responsible for a TA increase of 64–66 μmol kg-1. We estimated that more than half of the total ikaite precipitated was still contained in the ice when sea ice began to melt. The dissolution of the ikaite crystals in the water column kept the seawater pCO2 undersaturated.
N.-X. Geilfus, J.-L. Tison, S. F. Ackley, R. J. Galley, S. Rysgaard, L. A. Miller, and B. Delille
The Cryosphere, 8, 2395–2407, https://doi.org/10.5194/tc-8-2395-2014, https://doi.org/10.5194/tc-8-2395-2014, 2014
Short summary
Short summary
Temporal evolution of pCO2 profiles in sea ice in the Bellingshausen Sea, Antarctica (Oct. 2007), shows that physical and thermodynamic processes control the CO2 system in the ice. We show that each cooling/warming event was associated with an increase/decrease in the brine salinity, TA, TCO2, and in situ brine and bulk ice pCO2. Thicker snow covers reduced the amplitude of these changes. Both brine and bulk ice pCO2 were undersaturated, causing the sea ice to act as a sink for atmospheric CO2.
O. Crabeck, B. Delille, D. Thomas, N.-X. Geilfus, S. Rysgaard, and J.-L. Tison
Biogeosciences, 11, 6525–6538, https://doi.org/10.5194/bg-11-6525-2014, https://doi.org/10.5194/bg-11-6525-2014, 2014
S. Rysgaard, F. Wang, R. J. Galley, R. Grimm, D. Notz, M. Lemes, N.-X. Geilfus, A. Chaulk, A. A. Hare, O. Crabeck, B. G. T. Else, K. Campbell, L. L. Sørensen, J. Sievers, and T. Papakyriakou
The Cryosphere, 8, 1469–1478, https://doi.org/10.5194/tc-8-1469-2014, https://doi.org/10.5194/tc-8-1469-2014, 2014
J. Zhou, J.-L. Tison, G. Carnat, N.-X. Geilfus, and B. Delille
The Cryosphere, 8, 1019–1029, https://doi.org/10.5194/tc-8-1019-2014, https://doi.org/10.5194/tc-8-1019-2014, 2014
Jack C. Landy, Claude de Rijke-Thomas, Carmen Nab, Isobel Lawrence, Isolde A. Glissenaar, Robbie D. C. Mallett, Renée M. Fredensborg Hansen, Alek Petty, Michel Tsamados, Amy R. Macfarlane, and Anne Braakmann-Folgmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-2904, https://doi.org/10.5194/egusphere-2024-2904, 2024
Short summary
Short summary
In this study we use three satellites to test the planned remote sensing approach of the upcoming mission CRISTAL over sea ice: that its dual radars will accurately measure the heights of the top and base of snow sitting atop floating sea ice floes. Our results suggest that CRISTAL's dual radars won’t necessarily measure the snow top and base under all conditions. We find that accurate height measurements depend much more on surface roughness than on snow properties, as is commonly assumed.
Evgenii Salganik, Odile Crabeck, Niels Fuchs, Nils Hutter, Philipp Anhaus, and Jack Christopher Landy
EGUsphere, https://doi.org/10.5194/egusphere-2024-2398, https://doi.org/10.5194/egusphere-2024-2398, 2024
Short summary
Short summary
To measure Arctic ice thickness, we often check how much ice sticks out of the water. This method depends on knowing the ice's density, which drops significantly in summer. Our study, validated with sonar and laser data, shows that these seasonal changes in density can complicate melt measurements. We stress the importance of considering these density changes for more accurate ice thickness readings.
Paul R. Bierman, Andrew J. Christ, Catherine M. Collins, Halley M. Mastro, Juliana Souza, Pierre-Henri Blard, Stefanie Brachfeld, Zoe R. Courville, Tammy M. Rittenour, Elizabeth K. Thomas, Jean-Louis Tison, and François Fripiat
The Cryosphere, 18, 4029–4052, https://doi.org/10.5194/tc-18-4029-2024, https://doi.org/10.5194/tc-18-4029-2024, 2024
Short summary
Short summary
In 1966, the U.S. Army drilled through the Greenland Ice Sheet at Camp Century, Greenland; they recovered 3.44 m of frozen material. Here, we decipher the material’s history. Water, flowing during a warm interglacial when the ice sheet melted from northwest Greenland, deposited the upper material which contains fossil plant and insect parts. The lower material, separated by more than a meter of ice with some sediment, is till, deposited by the ice sheet during a prior cold period.
Stephen E. L. Howell, David G. Babb, Jack C. Landy, Isolde A. Glissenaar, Kaitlin McNeil, Benoit Montpetit, and Mike Brady
The Cryosphere, 18, 2321–2333, https://doi.org/10.5194/tc-18-2321-2024, https://doi.org/10.5194/tc-18-2321-2024, 2024
Short summary
Short summary
The CAA serves as both a source and a sink for sea ice from the Arctic Ocean, while also exporting sea ice into Baffin Bay. It is also an important region with respect to navigating the Northwest Passage. Here, we quantify sea ice transport and replenishment across and within the CAA from 2016 to 2022. We also provide the first estimates of the ice area and volume flux within the CAA from the Queen Elizabeth Islands to Parry Channel, which spans the central region of the Northwest Passage.
Sarah Wauthy, Jean-Louis Tison, Mana Inoue, Saïda El Amri, Sainan Sun, François Fripiat, Philippe Claeys, and Frank Pattyn
Earth Syst. Sci. Data, 16, 35–58, https://doi.org/10.5194/essd-16-35-2024, https://doi.org/10.5194/essd-16-35-2024, 2024
Short summary
Short summary
The datasets presented are the density, water isotopes, ions, and conductivity measurements, as well as age models and surface mass balance (SMB) from the top 120 m of two ice cores drilled on adjacent ice rises in Dronning Maud Land, dating from the late 18th century. They offer many development possibilities for the interpretation of paleo-profiles and for addressing the mechanisms behind the spatial and temporal variability of SMB and proxies observed at the regional scale in East Antarctica.
Monojit Saha, Julienne Stroeve, Dustin Isleifson, John Yackel, Vishnu Nandan, Jack Christopher Landy, and Hoi Ming Lam
EGUsphere, https://doi.org/10.5194/egusphere-2023-2509, https://doi.org/10.5194/egusphere-2023-2509, 2023
Short summary
Short summary
Snow on sea ice is vital for near-shore sea ice geophysical and biological processes. Past studies have measured snow depths using satellite altimeters Cryosat-2 and ICESat-2 (Cryo2Ice) but estimating sea surface height from lead-less land-fast sea ice remains challenging. Snow depths from Cryo2Ice are compared to in-situ after adjusting for tides. Realistic snow depths are retrieved but difference in roughness, satellite footprints and snow geophysical properties are identified as challenges.
Marie G. P. Cavitte, Hugues Goosse, Kenichi Matsuoka, Sarah Wauthy, Vikram Goel, Rahul Dey, Bhanu Pratap, Brice Van Liefferinge, Thamban Meloth, and Jean-Louis Tison
The Cryosphere, 17, 4779–4795, https://doi.org/10.5194/tc-17-4779-2023, https://doi.org/10.5194/tc-17-4779-2023, 2023
Short summary
Short summary
The net accumulation of snow over Antarctica is key for assessing current and future sea-level rise. Ice cores record a noisy snowfall signal to verify model simulations. We find that ice core net snowfall is biased to lower values for ice rises and the Dome Fuji site (Antarctica), while the relative uncertainty in measuring snowfall increases rapidly with distance away from the ice core sites at the ice rises but not at Dome Fuji. Spatial variation in snowfall must therefore be considered.
Geoffrey J. Dawson and Jack C. Landy
The Cryosphere, 17, 4165–4178, https://doi.org/10.5194/tc-17-4165-2023, https://doi.org/10.5194/tc-17-4165-2023, 2023
Short summary
Short summary
In this study, we compared measurements from CryoSat-2 and ICESat-2 over Arctic summer sea ice to understand any possible biases between the two satellites. We found that there is a difference when we measure elevation over summer sea ice using CryoSat-2 and ICESat-2, and this is likely due to surface melt ponds. The differences we found were in good agreement with theoretical predictions, and this work will be valuable for summer sea ice thickness measurements from both altimeters.
Isolde A. Glissenaar, Jack C. Landy, David G. Babb, Geoffrey J. Dawson, and Stephen E. L. Howell
The Cryosphere, 17, 3269–3289, https://doi.org/10.5194/tc-17-3269-2023, https://doi.org/10.5194/tc-17-3269-2023, 2023
Short summary
Short summary
Observations of large-scale ice thickness have unfortunately only been available since 2003, a short record for researching trends and variability. We generated a proxy for sea ice thickness in the Canadian Arctic for 1996–2020. This is the longest available record for large-scale sea ice thickness available to date and the first record reliably covering the channels between the islands in northern Canada. The product shows that sea ice has thinned by 21 cm over the 25-year record in April.
Vishnu Nandan, Rosemary Willatt, Robbie Mallett, Julienne Stroeve, Torsten Geldsetzer, Randall Scharien, Rasmus Tonboe, John Yackel, Jack Landy, David Clemens-Sewall, Arttu Jutila, David N. Wagner, Daniela Krampe, Marcus Huntemann, Mallik Mahmud, David Jensen, Thomas Newman, Stefan Hendricks, Gunnar Spreen, Amy Macfarlane, Martin Schneebeli, James Mead, Robert Ricker, Michael Gallagher, Claude Duguay, Ian Raphael, Chris Polashenski, Michel Tsamados, Ilkka Matero, and Mario Hoppmann
The Cryosphere, 17, 2211–2229, https://doi.org/10.5194/tc-17-2211-2023, https://doi.org/10.5194/tc-17-2211-2023, 2023
Short summary
Short summary
We show that wind redistributes snow on Arctic sea ice, and Ka- and Ku-band radar measurements detect both newly deposited snow and buried snow layers that can affect the accuracy of snow depth estimates on sea ice. Radar, laser, meteorological, and snow data were collected during the MOSAiC expedition. With frequent occurrence of storms in the Arctic, our results show that
wind-redistributed snow needs to be accounted for to improve snow depth estimates on sea ice from satellite radars.
Zhiyuan Gao, Nicolas-Xavier Geilfus, Alfonso Saiz-Lopez, and Feiyue Wang
Atmos. Chem. Phys., 22, 1811–1824, https://doi.org/10.5194/acp-22-1811-2022, https://doi.org/10.5194/acp-22-1811-2022, 2022
Short summary
Short summary
Every spring in the Arctic, a series of photochemical events occur over the ice-covered ocean, known as bromine explosion events, ozone depletion events, and mercury depletion events. Here we report the re-creation of these events at an outdoor sea ice facility in Winnipeg, Canada, far away from the Arctic. The success provides a new platform with new opportunities to uncover fundamental mechanisms of these Arctic springtime phenomena and how they may change in a changing climate.
Isolde A. Glissenaar, Jack C. Landy, Alek A. Petty, Nathan T. Kurtz, and Julienne C. Stroeve
The Cryosphere, 15, 4909–4927, https://doi.org/10.5194/tc-15-4909-2021, https://doi.org/10.5194/tc-15-4909-2021, 2021
Short summary
Short summary
Scientists can estimate sea ice thickness using satellites that measure surface height. To determine the sea ice thickness, we also need to know the snow depth and density. This paper shows that the chosen snow depth product has a considerable impact on the findings of sea ice thickness state and trends in Baffin Bay, showing mean thinning with some snow depth products and mean thickening with others. This shows that it is important to better understand and monitor snow depth on sea ice.
Robbie D. C. Mallett, Julienne C. Stroeve, Michel Tsamados, Jack C. Landy, Rosemary Willatt, Vishnu Nandan, and Glen E. Liston
The Cryosphere, 15, 2429–2450, https://doi.org/10.5194/tc-15-2429-2021, https://doi.org/10.5194/tc-15-2429-2021, 2021
Short summary
Short summary
We re-estimate pan-Arctic sea ice thickness (SIT) values by combining data from the Envisat and CryoSat-2 missions with data from a new, reanalysis-driven snow model. Because a decreasing amount of ice is being hidden below the waterline by the weight of overlying snow, we argue that SIT may be declining faster than previously calculated in some regions. Because the snow product varies from year to year, our new SIT calculations also display much more year-to-year variability.
Stephen E. L. Howell, Randall K. Scharien, Jack Landy, and Mike Brady
The Cryosphere, 14, 4675–4686, https://doi.org/10.5194/tc-14-4675-2020, https://doi.org/10.5194/tc-14-4675-2020, 2020
Short summary
Short summary
Melt ponds form on the surface of Arctic sea ice during spring and have been shown to exert a strong influence on summer sea ice area. Here, we use RADARSAT-2 satellite imagery to estimate the predicted peak spring melt pond fraction in the Canadian Arctic Archipelago from 2009–2018. Our results show that RADARSAT-2 estimates of peak melt pond fraction can be used to provide predictive information about summer sea ice area within certain regions of the Canadian Arctic Archipelago.
Thore Kausch, Stef Lhermitte, Jan T. M. Lenaerts, Nander Wever, Mana Inoue, Frank Pattyn, Sainan Sun, Sarah Wauthy, Jean-Louis Tison, and Willem Jan van de Berg
The Cryosphere, 14, 3367–3380, https://doi.org/10.5194/tc-14-3367-2020, https://doi.org/10.5194/tc-14-3367-2020, 2020
Short summary
Short summary
Ice rises are elevated parts of the otherwise flat ice shelf. Here we study the impact of an Antarctic ice rise on the surrounding snow accumulation by combining field data and modeling. Our results show a clear difference in average yearly snow accumulation between the windward side, the leeward side and the peak of the ice rise due to differences in snowfall and wind erosion. This is relevant for the interpretation of ice core records, which are often drilled on the peak of an ice rise.
Robbie D. C. Mallett, Isobel R. Lawrence, Julienne C. Stroeve, Jack C. Landy, and Michel Tsamados
The Cryosphere, 14, 251–260, https://doi.org/10.5194/tc-14-251-2020, https://doi.org/10.5194/tc-14-251-2020, 2020
Short summary
Short summary
Soils store large carbon and are important for global warming. We do not know what factors are important for soil carbon storage in the alpine Andes and how they work. We studied how rainfall affects soil carbon storage related to soil structure. We found soil structure is not important, but soil carbon storage and stability controlled by rainfall are dependent on rocks under the soils. The results indicate that we should pay attention to the rocks when studying soil carbon storage in the Andes.
Goulven G. Laruelle, Peter Landschützer, Nicolas Gruber, Jean-Louis Tison, Bruno Delille, and Pierre Regnier
Biogeosciences, 14, 4545–4561, https://doi.org/10.5194/bg-14-4545-2017, https://doi.org/10.5194/bg-14-4545-2017, 2017
Célia J. Sapart, Natalia Shakhova, Igor Semiletov, Joachim Jansen, Sönke Szidat, Denis Kosmach, Oleg Dudarev, Carina van der Veen, Matthias Egger, Valentine Sergienko, Anatoly Salyuk, Vladimir Tumskoy, Jean-Louis Tison, and Thomas Röckmann
Biogeosciences, 14, 2283–2292, https://doi.org/10.5194/bg-14-2283-2017, https://doi.org/10.5194/bg-14-2283-2017, 2017
Short summary
Short summary
The Arctic Ocean, especially the Siberian shelves, overlays large areas of subsea permafrost that is degrading. We show that methane with a biogenic origin is emitted from this permafrost. At locations where bubble plumes have been observed, methane can escape oxidation in the surface sediment and rapidly migrate through the very shallow water column of this region to escape to the atmosphere, generating a positive radiative feedback.
Morgane Philippe, Jean-Louis Tison, Karen Fjøsne, Bryn Hubbard, Helle A. Kjær, Jan T. M. Lenaerts, Reinhard Drews, Simon G. Sheldon, Kevin De Bondt, Philippe Claeys, and Frank Pattyn
The Cryosphere, 10, 2501–2516, https://doi.org/10.5194/tc-10-2501-2016, https://doi.org/10.5194/tc-10-2501-2016, 2016
Short summary
Short summary
The reconstruction of past snow accumulation rates is crucial in the context of recent climate change and sea level rise. We measured ~ 250 years of snow accumulation using a 120 m ice core drilled in coastal East Antarctica, where such long records are very scarce. This study is the first to show an increase in snow accumulation, beginning in the 20th and particularly marked in the last 50 years, thereby confirming model predictions of increased snowfall associated with climate change.
Nicolas-Xavier Geilfus, Ryan J. Galley, Brent G. T. Else, Karley Campbell, Tim Papakyriakou, Odile Crabeck, Marcos Lemes, Bruno Delille, and Søren Rysgaard
The Cryosphere, 10, 2173–2189, https://doi.org/10.5194/tc-10-2173-2016, https://doi.org/10.5194/tc-10-2173-2016, 2016
Short summary
Short summary
The fate of ikaite precipitation within sea ice is poorly understood. In this study, we estimated ikaite precipitation of up to 167 µmol kg-1 within sea ice, while its export and dissolution into the underlying seawater was responsible for a TA increase of 64–66 μmol kg-1. We estimated that more than half of the total ikaite precipitated was still contained in the ice when sea ice began to melt. The dissolution of the ikaite crystals in the water column kept the seawater pCO2 undersaturated.
William J. Burt, Helmuth Thomas, Lisa A. Miller, Mats A. Granskog, Tim N. Papakyriakou, and Leah Pengelly
Biogeosciences, 13, 4659–4671, https://doi.org/10.5194/bg-13-4659-2016, https://doi.org/10.5194/bg-13-4659-2016, 2016
Short summary
Short summary
This study assesses the state of the carbon cycle in Hudson Bay, an ecologically important region of the Canadian Arctic. Results show that river input, sea-ice melt, biological activity, and general circulation patterns all have significant, and regionally dependent, impacts on the carbon cycle. The study also highlights the importance of detailed sampling procedures in highly stratified waters, and reveals that the deep Hudson Bay is primarily filled with waters of Pacific origin.
Odile Crabeck, Ryan Galley, Bruno Delille, Brent Else, Nicolas-Xavier Geilfus, Marcos Lemes, Mathieu Des Roches, Pierre Francus, Jean-Louis Tison, and Søren Rysgaard
The Cryosphere, 10, 1125–1145, https://doi.org/10.5194/tc-10-1125-2016, https://doi.org/10.5194/tc-10-1125-2016, 2016
Short summary
Short summary
We present a new non-destructive X-ray-computed tomography technique to quantify the air volume fraction and produce separate 3-D images of air-volume inclusions in sea ice. While the internal layers showed air-volume fractions < 2 %, the ice–air interface (top 2 cm) showed values up to 5 %. As a result of the presence of large bubbles and higher air volume fraction measurements in sea ice, we introduce new perspectives on processes regulating gas exchange at the ice–atmosphere interface.
Thomas Goossens, Célia J. Sapart, Dorthe Dahl-Jensen, Trevor Popp, Saïda El Amri, and Jean-Louis Tison
The Cryosphere, 10, 553–567, https://doi.org/10.5194/tc-10-553-2016, https://doi.org/10.5194/tc-10-553-2016, 2016
Short summary
Short summary
This first multi-parametric analysis of the basal ice layer of the NEEM ice core reveals that its formation does not result from a mixing process between local relict ice and the deepest ice layers of the advancing ice sheet during its growth phase. Instead, it is shown that the basal sequence partly originates from melting and refreezing processes acting at the ice/bedrock interface under a well-developed ice sheet. These have partially destroyed the paleoclimatic records of the ice.
J.-L. Tison, M. de Angelis, G. Littot, E. Wolff, H. Fischer, M. Hansson, M. Bigler, R. Udisti, A. Wegner, J. Jouzel, B. Stenni, S. Johnsen, V. Masson-Delmotte, A. Landais, V. Lipenkov, L. Loulergue, J.-M. Barnola, J.-R. Petit, B. Delmonte, G. Dreyfus, D. Dahl-Jensen, G. Durand, B. Bereiter, A. Schilt, R. Spahni, K. Pol, R. Lorrain, R. Souchez, and D. Samyn
The Cryosphere, 9, 1633–1648, https://doi.org/10.5194/tc-9-1633-2015, https://doi.org/10.5194/tc-9-1633-2015, 2015
Short summary
Short summary
The oldest paleoclimatic information is buried within the lowermost layers of deep ice cores. It is therefore essential to judge how deep these records remain unaltered. We study the bottom 60 meters of the EPICA Dome C ice core from central Antarctica to show that the paleoclimatic signal is only affected at the small scale (decimeters) in terms of some of the global ice properties. However our data suggest that the time scale has been considerably distorted by mechanical stretching.
N.-X. Geilfus, J.-L. Tison, S. F. Ackley, R. J. Galley, S. Rysgaard, L. A. Miller, and B. Delille
The Cryosphere, 8, 2395–2407, https://doi.org/10.5194/tc-8-2395-2014, https://doi.org/10.5194/tc-8-2395-2014, 2014
Short summary
Short summary
Temporal evolution of pCO2 profiles in sea ice in the Bellingshausen Sea, Antarctica (Oct. 2007), shows that physical and thermodynamic processes control the CO2 system in the ice. We show that each cooling/warming event was associated with an increase/decrease in the brine salinity, TA, TCO2, and in situ brine and bulk ice pCO2. Thicker snow covers reduced the amplitude of these changes. Both brine and bulk ice pCO2 were undersaturated, causing the sea ice to act as a sink for atmospheric CO2.
O. Crabeck, B. Delille, D. Thomas, N.-X. Geilfus, S. Rysgaard, and J.-L. Tison
Biogeosciences, 11, 6525–6538, https://doi.org/10.5194/bg-11-6525-2014, https://doi.org/10.5194/bg-11-6525-2014, 2014
J. Zhou, B. Delille, F. Brabant, and J.-L. Tison
Biogeosciences, 11, 5007–5020, https://doi.org/10.5194/bg-11-5007-2014, https://doi.org/10.5194/bg-11-5007-2014, 2014
S. Rysgaard, F. Wang, R. J. Galley, R. Grimm, D. Notz, M. Lemes, N.-X. Geilfus, A. Chaulk, A. A. Hare, O. Crabeck, B. G. T. Else, K. Campbell, L. L. Sørensen, J. Sievers, and T. Papakyriakou
The Cryosphere, 8, 1469–1478, https://doi.org/10.5194/tc-8-1469-2014, https://doi.org/10.5194/tc-8-1469-2014, 2014
J. Zhou, J.-L. Tison, G. Carnat, N.-X. Geilfus, and B. Delille
The Cryosphere, 8, 1019–1029, https://doi.org/10.5194/tc-8-1019-2014, https://doi.org/10.5194/tc-8-1019-2014, 2014
L. L. Sørensen, B. Jensen, R. N. Glud, D. F. McGinnis, M. K. Sejr, J. Sievers, D. H. Søgaard, J.-L. Tison, and S. Rysgaard
The Cryosphere, 8, 853–866, https://doi.org/10.5194/tc-8-853-2014, https://doi.org/10.5194/tc-8-853-2014, 2014
R. J. Galley, B. G. T. Else, N.-X. Geilfus, A. A. Hare, D. Isleifson, L. Ryner, D. G. Barber, and S. Rysgaard
The Cryosphere Discuss., https://doi.org/10.5194/tcd-7-4977-2013, https://doi.org/10.5194/tcd-7-4977-2013, 2013
Revised manuscript not accepted
M. Vancoppenolle, D. Notz, F. Vivier, J. Tison, B. Delille, G. Carnat, J. Zhou, F. Jardon, P. Griewank, A. Lourenço, and T. Haskell
The Cryosphere Discuss., https://doi.org/10.5194/tcd-7-3209-2013, https://doi.org/10.5194/tcd-7-3209-2013, 2013
Revised manuscript not accepted
Related subject area
Biogeochemistry: Air - Sea Exchange
Dimethyl sulfide (DMS) climatologies, fluxes, and trends – Part 1: Differences between seawater DMS estimations
Dimethyl sulfide (DMS) climatologies, fluxes, and trends – Part 2: Sea–air fluxes
Aerosol trace element solubility and deposition fluxes over the polluted, dusty Mediterranean and Black Sea basins
High-frequency continuous measurements reveal strong diel and seasonal cycling of pCO2 and CO2 flux in a mesohaline reach of the Chesapeake Bay
Significant role of physical transport in the marine carbon monoxide (CO) cycle: observations in the East Sea (Sea of Japan), the western North Pacific, and the Bering Sea in summer
Central Arctic Ocean surface–atmosphere exchange of CO2 and CH4 constrained by direct measurements
Spatial and seasonal variability in volatile organic sulfur compounds in seawater and the overlying atmosphere of the Bohai and Yellow seas
Estimating marine carbon uptake in the northeast Pacific using a neural network approach
Sea–air methane flux estimates derived from marine surface observations and instantaneous atmospheric measurements in the northern Labrador Sea and Baffin Bay
Global analysis of the controls on seawater dimethylsulfide spatial variability
Air–sea gas exchange in a seagrass ecosystem – results from a 3He ∕ SF6 tracer release experiment
Concentrations of dissolved dimethyl sulfide (DMS), methanethiol and other trace gases in context of microbial communities from the temperate Atlantic to the Arctic Ocean
Marine nitrogen fixation as a possible source of atmospheric water-soluble organic nitrogen aerosols in the subtropical North Pacific
Ice nucleating properties of the sea ice diatom Fragilariopsis cylindrus and its exudates
On physical mechanisms enhancing air–sea CO2 exchange
Winter season Southern Ocean distributions of climate-relevant trace gases
How biogenic polymers control surfactant dynamics in the surface microlayer: insights from a coastal Baltic Sea study
Identifying the biological control of the annual and multi-year variations in South Atlantic air–sea CO2 flux
The sensitivity of pCO2 reconstructions to sampling scales across a Southern Ocean sub-domain: a semi-idealized ocean sampling simulation approach
Physical mechanisms for biological carbon uptake during the onset of the spring phytoplankton bloom in the northwestern Mediterranean Sea (BOUSSOLE site)
Wintertime process study of the North Brazil Current rings reveals the region as a larger sink for CO2 than expected
New constraints on biological production and mixing processes in the South China Sea from triple isotope composition of dissolved oxygen
Tidal mixing of estuarine and coastal waters in the western English Channel is a control on spatial and temporal variability in seawater CO2
A seamless ensemble-based reconstruction of surface ocean pCO2 and air–sea CO2 fluxes over the global coastal and open oceans
Sea ice concentration impacts dissolved organic gases in the Canadian Arctic
Evaluating the Arabian Sea as a regional source of atmospheric CO2: seasonal variability and drivers
An empirical MLR for estimating surface layer DIC and a comparative assessment to other gap-filling techniques for ocean carbon time series
Derivation of seawater pCO2 from net community production identifies the South Atlantic Ocean as a CO2 source
Eukaryotic community composition in the sea surface microlayer across an east–west transect in the Mediterranean Sea
Enhancement of the North Atlantic CO2 sink by Arctic Waters
Global ocean dimethyl sulfide climatology estimated from observations and an artificial neural network
Atmospheric deposition of organic matter at a remote site in the central Mediterranean Sea: implications for the marine ecosystem
Underway seawater and atmospheric measurements of volatile organic compounds in the Southern Ocean
Dimethylsulfide (DMS), marine biogenic aerosols and the ecophysiology of coral reefs
Spatial variations in CO2 fluxes in the Saguenay Fjord (Quebec, Canada) and results of a water mixing model
Gas exchange estimates in the Peruvian upwelling regime biased by multi-day near-surface stratification
Insights from year-long measurements of air–water CH4 and CO2 exchange in a coastal environment
On the role of climate modes in modulating the air–sea CO2 fluxes in eastern boundary upwelling systems
Reviews and syntheses: the GESAMP atmospheric iron deposition model intercomparison study
Increase of dissolved inorganic carbon and decrease in pH in near-surface waters in the Mediterranean Sea during the past two decades
Utilizing the Drake Passage Time-series to understand variability and change in subpolar Southern Ocean pCO2
Effect of wind speed on the size distribution of gel particles in the sea surface microlayer: insights from a wind–wave channel experiment
The seasonal cycle of pCO2 and CO2 fluxes in the Southern Ocean: diagnosing anomalies in CMIP5 Earth system models
Marine phytoplankton stoichiometry mediates nonlinear interactions between nutrient supply, temperature, and atmospheric CO2
Interannual drivers of the seasonal cycle of CO2 in the Southern Ocean
Constraints on global oceanic emissions of N2O from observations and models
Arctic Ocean CO2 uptake: an improved multiyear estimate of the air–sea CO2 flux incorporating chlorophyll a concentrations
Uncertainty in the global oceanic CO2 uptake induced by wind forcing: quantification and spatial analysis
Phytoplankton growth response to Asian dust addition in the northwest Pacific Ocean versus the Yellow Sea
Global high-resolution monthly pCO2 climatology for the coastal ocean derived from neural network interpolation
Sankirna D. Joge, Anoop S. Mahajan, Shrivardhan Hulswar, Christa A. Marandino, Martí Galí, Thomas G. Bell, and Rafel Simó
Biogeosciences, 21, 4439–4452, https://doi.org/10.5194/bg-21-4439-2024, https://doi.org/10.5194/bg-21-4439-2024, 2024
Short summary
Short summary
Dimethyl sulfide (DMS) is the largest natural source of sulfur in the atmosphere and leads to the formation of cloud condensation nuclei. DMS emission and quantification of its impacts have large uncertainties, but a detailed study on the emissions and drivers of their uncertainty is missing to date. The emissions are usually calculated from the seawater DMS concentrations and a flux parameterization. Here we quantify the differences in DMS seawater products, which can affect DMS fluxes.
Sankirna D. Joge, Anoop S. Mahajan, Shrivardhan Hulswar, Christa A. Marandino, Martí Galí, Thomas G. Bell, Mingxi Yang, and Rafel Simó
Biogeosciences, 21, 4453–4467, https://doi.org/10.5194/bg-21-4453-2024, https://doi.org/10.5194/bg-21-4453-2024, 2024
Short summary
Short summary
Dimethyl sulfide (DMS) is the largest natural source of sulfur in the atmosphere and leads to the formation of cloud condensation nuclei. DMS emissions and quantification of their impacts have large uncertainties, but a detailed study on the range of emissions and drivers of their uncertainty is missing to date. The emissions are calculated from the seawater DMS concentrations and a flux parameterization. Here we quantify the differences in the effect of flux parameterizations used in models.
Rachel Ursula Shelley, Alexander Roberts Baker, Max Thomas, and Sam Murphy
EGUsphere, https://doi.org/10.5194/egusphere-2024-2667, https://doi.org/10.5194/egusphere-2024-2667, 2024
Short summary
Short summary
The fractions of trace elements in atmospheric particles over the Mediterranean and Black seas that are soluble have been measured. These soluble fractions can affect the growth of microorganisms in the ocean and our results show that they are affected by mixing with pollutants from the surrounding land and shipping emissions. Atmospheric particles contribute to the soluble element loads found in the Mediterranean surface waters and influence the balance between nitrogen and phosphorus there.
A. Whitman Miller, Jim R. Muirhead, Amanda C. Reynolds, Mark S. Minton, and Karl J. Klug
Biogeosciences, 21, 3717–3734, https://doi.org/10.5194/bg-21-3717-2024, https://doi.org/10.5194/bg-21-3717-2024, 2024
Short summary
Short summary
High frequency pCO2 measurements reveal net neutral CO2 flux in a mesohaline reach of the Chesapeake Bay. Net off-gassing to the atmosphere begins in June when water temperatures rise above ~26ºC, continuing through November when temperatures fall below ~10ºC. Dissolved CO2 concentrations follow day–night cycles and are especially pronounced in warm waters. From December through May, the river is largely an uninterrupted sink for CO2 (i.e. CO2 is drawn out of the atmosphere into the river).
Young Shin Kwon, Tae Siek Rhee, Hyun-Cheol Kim, and Hyoun-Woo Kang
Biogeosciences, 21, 1847–1865, https://doi.org/10.5194/bg-21-1847-2024, https://doi.org/10.5194/bg-21-1847-2024, 2024
Short summary
Short summary
Delving into CO dynamics from the East Sea to the Bering Sea, our study unveils the influence of physical transport on CO budgets. By measuring CO concentrations and parameters, we elucidate the interplay between biological and physical processes, highlighting the role of lateral transport in shaping CO distributions. Our findings underscore the importance of considering both biogeochemical and physical drivers in understanding marine carbon fluxes.
John Prytherch, Sonja Murto, Ian Brown, Adam Ulfsbo, Brett F. Thornton, Volker Brüchert, Michael Tjernström, Anna Lunde Hermansson, Amanda T. Nylund, and Lina A. Holthusen
Biogeosciences, 21, 671–688, https://doi.org/10.5194/bg-21-671-2024, https://doi.org/10.5194/bg-21-671-2024, 2024
Short summary
Short summary
We directly measured methane and carbon dioxide exchange between ocean or sea ice and the atmosphere during an icebreaker-based expedition to the central Arctic Ocean (CAO) in summer 2021. These measurements can help constrain climate models and carbon budgets. The methane measurements, the first such made in the CAO, are lower than previous estimates and imply that the CAO is an insignificant contributor to Arctic methane emission. Gas exchange rates are slower than previous estimates.
Juan Yu, Lei Yu, Zhen He, Gui-Peng Yang, Jing-Guang Lai, and Qian Liu
Biogeosciences, 21, 161–176, https://doi.org/10.5194/bg-21-161-2024, https://doi.org/10.5194/bg-21-161-2024, 2024
Short summary
Short summary
The distributions of volatile organic sulfur compounds (VSCs) (DMS, COS, and CS2) in the seawater and atmosphere of the Bohai and Yellow Seas were evaluated. Seasonal variations in VSCs were found and showed summer > spring. The COS concentrations exhibited positive correlation with DOC concentrations in seawater during summer. VSCs concentrations in seawater decreased with the depth. Sea-to-air fluxes of COS, DMS, and CS2 indicated that these marginal seas are sources of atmospheric VSCs.
Patrick J. Duke, Roberta C. Hamme, Debby Ianson, Peter Landschützer, Mohamed M. M. Ahmed, Neil C. Swart, and Paul A. Covert
Biogeosciences, 20, 3919–3941, https://doi.org/10.5194/bg-20-3919-2023, https://doi.org/10.5194/bg-20-3919-2023, 2023
Short summary
Short summary
The ocean is both impacted by climate change and helps mitigate its effects through taking up carbon from the atmosphere. We used a machine learning approach to investigate what controls open-ocean carbon uptake in the northeast Pacific open ocean. Marine heatwaves that lasted 2–3 years increased uptake, while the upwelling strength of the Alaskan Gyre controlled uptake over 10-year time periods. The trend from 1998–2019 suggests carbon uptake in the northeast Pacific open ocean is increasing.
Judith Vogt, David Risk, Evelise Bourlon, Kumiko Azetsu-Scott, Evan N. Edinger, and Owen A. Sherwood
Biogeosciences, 20, 1773–1787, https://doi.org/10.5194/bg-20-1773-2023, https://doi.org/10.5194/bg-20-1773-2023, 2023
Short summary
Short summary
The release of the greenhouse gas methane from Arctic submarine sources could exacerbate climate change in a positive feedback. Continuous monitoring of atmospheric methane levels over a 5100 km voyage in the western margin of the Labrador Sea and Baffin Bay revealed above-global averages likely affected by both onshore and offshore methane sources. Instantaneous sea–air methane fluxes were near zero at all measured stations, including a persistent cold-seep location.
George Manville, Thomas G. Bell, Jane P. Mulcahy, Rafel Simó, Martí Galí, Anoop S. Mahajan, Shrivardhan Hulswar, and Paul R. Halloran
Biogeosciences, 20, 1813–1828, https://doi.org/10.5194/bg-20-1813-2023, https://doi.org/10.5194/bg-20-1813-2023, 2023
Short summary
Short summary
We present the first global investigation of controls on seawater dimethylsulfide (DMS) spatial variability over scales of up to 100 km. Sea surface height anomalies, density, and chlorophyll a help explain almost 80 % of DMS variability. The results suggest that physical and biogeochemical processes play an equally important role in controlling DMS variability. These data provide independent confirmation that existing parameterisations of seawater DMS concentration use appropriate variables.
Ryo Dobashi and David T. Ho
Biogeosciences, 20, 1075–1087, https://doi.org/10.5194/bg-20-1075-2023, https://doi.org/10.5194/bg-20-1075-2023, 2023
Short summary
Short summary
Seagrass meadows are productive ecosystems and bury much carbon. Understanding their role in the global carbon cycle requires knowledge of air–sea CO2 fluxes and hence the knowledge of gas transfer velocity (k). In this study, k was determined from the dual tracer technique in Florida Bay. The observed gas transfer velocity was lower than previous studies in the coastal and open oceans at the same wind speeds, most likely due to wave attenuation by seagrass and limited wind fetch in this area.
Valérie Gros, Bernard Bonsang, Roland Sarda-Estève, Anna Nikolopoulos, Katja Metfies, Matthias Wietz, and Ilka Peeken
Biogeosciences, 20, 851–867, https://doi.org/10.5194/bg-20-851-2023, https://doi.org/10.5194/bg-20-851-2023, 2023
Short summary
Short summary
The oceans are both sources and sinks for trace gases important for atmospheric chemistry and marine ecology. Here, we quantified selected trace gases (including the biological metabolites dissolved dimethyl sulfide, methanethiol and isoprene) along a 2500 km transect from the North Atlantic to the Arctic Ocean. In the context of phytoplankton and bacterial communities, our study suggests that methanethiol (rarely measured before) might substantially influence ocean–atmosphere cycling.
Tsukasa Dobashi, Yuzo Miyazaki, Eri Tachibana, Kazutaka Takahashi, Sachiko Horii, Fuminori Hashihama, Saori Yasui-Tamura, Yoko Iwamoto, Shu-Kuan Wong, and Koji Hamasaki
Biogeosciences, 20, 439–449, https://doi.org/10.5194/bg-20-439-2023, https://doi.org/10.5194/bg-20-439-2023, 2023
Short summary
Short summary
Water-soluble organic nitrogen (WSON) in marine aerosols is important for biogeochemical cycling of bioelements. Our shipboard measurements suggested that reactive nitrogen produced and exuded by nitrogen-fixing microorganisms in surface seawater likely contributed to the formation of WSON aerosols in the subtropical North Pacific. This study provides new implications for the role of marine microbial activity in the formation of WSON aerosols in the ocean surface.
Lukas Eickhoff, Maddalena Bayer-Giraldi, Naama Reicher, Yinon Rudich, and Thomas Koop
Biogeosciences, 20, 1–14, https://doi.org/10.5194/bg-20-1-2023, https://doi.org/10.5194/bg-20-1-2023, 2023
Short summary
Short summary
The formation of ice is an important process in Earth’s atmosphere, biosphere, and cryosphere, in particular in polar regions. Our research focuses on the influence of the sea ice diatom Fragilariopsis cylindrus and of molecules produced by it upon heterogenous ice nucleation. For that purpose, we studied the freezing of tiny droplets containing the diatoms in a microfluidic device. Together with previous studies, our results suggest a common freezing behaviour of various sea ice diatoms.
Lucía Gutiérrez-Loza, Erik Nilsson, Marcus B. Wallin, Erik Sahlée, and Anna Rutgersson
Biogeosciences, 19, 5645–5665, https://doi.org/10.5194/bg-19-5645-2022, https://doi.org/10.5194/bg-19-5645-2022, 2022
Short summary
Short summary
The exchange of CO2 between the ocean and the atmosphere is an essential aspect of the global carbon cycle and is highly relevant for the Earth's climate. In this study, we used 9 years of in situ measurements to evaluate the temporal variability in the air–sea CO2 fluxes in the Baltic Sea. Furthermore, using this long record, we assessed the effect of atmospheric and water-side mechanisms controlling the efficiency of the air–sea CO2 exchange under different wind-speed conditions.
Li Zhou, Dennis Booge, Miming Zhang, and Christa A. Marandino
Biogeosciences, 19, 5021–5040, https://doi.org/10.5194/bg-19-5021-2022, https://doi.org/10.5194/bg-19-5021-2022, 2022
Short summary
Short summary
Trace gas air–sea exchange exerts an important control on air quality and climate, especially in the Southern Ocean (SO). Almost all of the measurements there are skewed to summer, but it is essential to expand our measurement database over greater temporal and spatial scales. Therefore, we report measured concentrations of dimethylsulfide (DMS, as well as related sulfur compounds) and isoprene in the Atlantic sector of the SO. The observations of isoprene are the first in the winter in the SO.
Theresa Barthelmeß and Anja Engel
Biogeosciences, 19, 4965–4992, https://doi.org/10.5194/bg-19-4965-2022, https://doi.org/10.5194/bg-19-4965-2022, 2022
Short summary
Short summary
Greenhouse gases released by human activity cause a global rise in mean temperatures. While scientists can predict how much of these gases accumulate in the atmosphere based on not only human-derived sources but also oceanic sinks, it is rather difficult to predict the major influence of coastal ecosystems. We provide a detailed study on the occurrence, composition, and controls of substances that suppress gas exchange. We thus help to determine what controls coastal greenhouse gas fluxes.
Daniel J. Ford, Gavin H. Tilstone, Jamie D. Shutler, and Vassilis Kitidis
Biogeosciences, 19, 4287–4304, https://doi.org/10.5194/bg-19-4287-2022, https://doi.org/10.5194/bg-19-4287-2022, 2022
Short summary
Short summary
This study explores the seasonal, inter-annual, and multi-year drivers of the South Atlantic air–sea CO2 flux. Our analysis showed seasonal sea surface temperatures dominate in the subtropics, and the subpolar regions correlated with biological processes. Inter-annually, the El Niño–Southern Oscillation correlated with the CO2 flux by modifying sea surface temperatures and biological activity. Long-term trends indicated an important biological contribution to changes in the air–sea CO2 flux.
Laique M. Djeutchouang, Nicolette Chang, Luke Gregor, Marcello Vichi, and Pedro M. S. Monteiro
Biogeosciences, 19, 4171–4195, https://doi.org/10.5194/bg-19-4171-2022, https://doi.org/10.5194/bg-19-4171-2022, 2022
Short summary
Short summary
Based on observing system simulation experiments using a mesoscale-resolving model, we found that to significantly improve uncertainties and biases in carbon dioxide (CO2) mapping in the Southern Ocean, it is essential to resolve the seasonal cycle (SC) of the meridional gradient of CO2 through high frequency (at least daily) observations that also span the region's meridional axis. We also showed that the estimated SC anomaly and mean annual CO2 are highly sensitive to seasonal sampling biases.
Liliane Merlivat, Michael Hemming, Jacqueline Boutin, David Antoine, Vincenzo Vellucci, Melek Golbol, Gareth A. Lee, and Laurence Beaumont
Biogeosciences, 19, 3911–3920, https://doi.org/10.5194/bg-19-3911-2022, https://doi.org/10.5194/bg-19-3911-2022, 2022
Short summary
Short summary
We use in situ high-temporal-resolution measurements of dissolved inorganic carbon and atmospheric parameters at the air–sea interface to analyse phytoplankton bloom initiation identified as the net rate of biological carbon uptake in the Mediterranean Sea. The shift from wind-driven to buoyancy-driven mixing creates conditions for blooms to begin. Active mixing at the air–sea interface leads to the onset of the surface phytoplankton bloom due to the relaxation of wind speed following storms.
Léa Olivier, Jacqueline Boutin, Gilles Reverdin, Nathalie Lefèvre, Peter Landschützer, Sabrina Speich, Johannes Karstensen, Matthieu Labaste, Christophe Noisel, Markus Ritschel, Tobias Steinhoff, and Rik Wanninkhof
Biogeosciences, 19, 2969–2988, https://doi.org/10.5194/bg-19-2969-2022, https://doi.org/10.5194/bg-19-2969-2022, 2022
Short summary
Short summary
We investigate the impact of the interactions between eddies and the Amazon River plume on the CO2 air–sea fluxes to better characterize the ocean carbon sink in winter 2020. The region is a strong CO2 sink, previously underestimated by a factor of 10 due to a lack of data and understanding of the processes responsible for the variability in ocean carbon parameters. The CO2 absorption is mainly driven by freshwater from the Amazon entrained by eddies and by the winter seasonal cooling.
Hana Jurikova, Osamu Abe, Fuh-Kwo Shiah, and Mao-Chang Liang
Biogeosciences, 19, 2043–2058, https://doi.org/10.5194/bg-19-2043-2022, https://doi.org/10.5194/bg-19-2043-2022, 2022
Short summary
Short summary
We studied the isotopic composition of oxygen dissolved in seawater in the South China Sea. This tells us about the origin of oxygen in the water column, distinguishing between biological oxygen produced by phytoplankton communities and atmospheric oxygen entering seawater through gas exchange. We found that the East Asian Monsoon plays an important role in determining the amount of oxygen produced vs. consumed by the phytoplankton, as well as in inducing vertical water mass mixing.
Richard P. Sims, Michael Bedington, Ute Schuster, Andrew J. Watson, Vassilis Kitidis, Ricardo Torres, Helen S. Findlay, James R. Fishwick, Ian Brown, and Thomas G. Bell
Biogeosciences, 19, 1657–1674, https://doi.org/10.5194/bg-19-1657-2022, https://doi.org/10.5194/bg-19-1657-2022, 2022
Short summary
Short summary
The amount of carbon dioxide (CO2) being absorbed by the ocean is relevant to the earth's climate. CO2 values in the coastal ocean and estuaries are not well known because of the instrumentation used. We used a new approach to measure CO2 across the coastal and estuarine zone. We found that CO2 and salinity were linked to the state of the tide. We used our CO2 measurements and model salinity to predict CO2. Previous studies overestimate how much CO2 the coastal ocean draws down at our site.
Thi Tuyet Trang Chau, Marion Gehlen, and Frédéric Chevallier
Biogeosciences, 19, 1087–1109, https://doi.org/10.5194/bg-19-1087-2022, https://doi.org/10.5194/bg-19-1087-2022, 2022
Short summary
Short summary
Air–sea CO2 fluxes and associated uncertainty over the open ocean to coastal shelves are estimated with a new ensemble-based reconstruction of pCO2 trained on observation-based data. The regional distribution and seasonality of CO2 sources and sinks are consistent with those suggested in previous studies as well as mechanisms discussed therein. The ensemble-based uncertainty field allows identifying critical regions where improvements in pCO2 and air–sea CO2 flux estimates should be a priority.
Charel Wohl, Anna E. Jones, William T. Sturges, Philip D. Nightingale, Brent Else, Brian J. Butterworth, and Mingxi Yang
Biogeosciences, 19, 1021–1045, https://doi.org/10.5194/bg-19-1021-2022, https://doi.org/10.5194/bg-19-1021-2022, 2022
Short summary
Short summary
We measured concentrations of five different organic gases in seawater in the high Arctic during summer. We found higher concentrations near the surface of the water column (top 5–10 m) and in areas of partial ice cover. This suggests that sea ice influences the concentrations of these gases. These gases indirectly exert a slight cooling effect on the climate, and it is therefore important to measure the levels accurately for future climate predictions.
Alain de Verneil, Zouhair Lachkar, Shafer Smith, and Marina Lévy
Biogeosciences, 19, 907–929, https://doi.org/10.5194/bg-19-907-2022, https://doi.org/10.5194/bg-19-907-2022, 2022
Short summary
Short summary
The Arabian Sea is a natural CO2 source to the atmosphere, but previous work highlights discrepancies between data and models in estimating air–sea CO2 flux. In this study, we use a regional ocean model, achieve a flux closer to available data, and break down the seasonal cycles that impact it, with one result being the great importance of monsoon winds. As demonstrated in a meta-analysis, differences from data still remain, highlighting the great need for further regional data collection.
Jesse M. Vance, Kim Currie, John Zeldis, Peter W. Dillingham, and Cliff S. Law
Biogeosciences, 19, 241–269, https://doi.org/10.5194/bg-19-241-2022, https://doi.org/10.5194/bg-19-241-2022, 2022
Short summary
Short summary
Long-term monitoring is needed to detect changes in our environment. Time series of ocean carbon have aided our understanding of seasonal cycles and provided evidence for ocean acidification. Data gaps are inevitable, yet no standard method for filling gaps exists. We present a regression approach here and compare it to seven other common methods to understand the impact of different approaches when assessing seasonal to climatic variability in ocean carbon.
Daniel J. Ford, Gavin H. Tilstone, Jamie D. Shutler, and Vassilis Kitidis
Biogeosciences, 19, 93–115, https://doi.org/10.5194/bg-19-93-2022, https://doi.org/10.5194/bg-19-93-2022, 2022
Short summary
Short summary
This study identifies the most accurate biological proxy for the estimation of seawater pCO2 fields, which are key to assessing the ocean carbon sink. Our analysis shows that the net community production (NCP), the balance between photosynthesis and respiration, was more accurate than chlorophyll a within a neural network scheme. The improved pCO2 estimates, based on NCP, identified the South Atlantic Ocean as a net CO2 source, compared to a CO2 sink using chlorophyll a.
Birthe Zäncker, Michael Cunliffe, and Anja Engel
Biogeosciences, 18, 2107–2118, https://doi.org/10.5194/bg-18-2107-2021, https://doi.org/10.5194/bg-18-2107-2021, 2021
Short summary
Short summary
Fungi are found in numerous marine environments. Our study found an increased importance of fungi in the Ionian Sea, where bacterial and phytoplankton counts were reduced, but organic matter was still available, suggesting fungi might benefit from the reduced competition from bacteria in low-nutrient, low-chlorophyll (LNLC) regions.
Jon Olafsson, Solveig R. Olafsdottir, Taro Takahashi, Magnus Danielsen, and Thorarinn S. Arnarson
Biogeosciences, 18, 1689–1701, https://doi.org/10.5194/bg-18-1689-2021, https://doi.org/10.5194/bg-18-1689-2021, 2021
Short summary
Short summary
The Atlantic north of 50° N is an intense ocean sink area for atmospheric CO2. Observations in the vicinity of Iceland reveal a previously unrecognized Arctic contribution to the North Atlantic CO2 sink. Sustained CO2 influx to waters flowing from the Arctic Ocean is linked to their excess alkalinity derived from sources in the changing Arctic. The results relate to the following question: will the North Atlantic continue to absorb CO2 in the future as it has in the past?
Wei-Lei Wang, Guisheng Song, François Primeau, Eric S. Saltzman, Thomas G. Bell, and J. Keith Moore
Biogeosciences, 17, 5335–5354, https://doi.org/10.5194/bg-17-5335-2020, https://doi.org/10.5194/bg-17-5335-2020, 2020
Short summary
Short summary
Dimethyl sulfide, a volatile compound produced as a byproduct of marine phytoplankton activity, can be emitted to the atmosphere via gas exchange. In the atmosphere, DMS is oxidized to cloud condensation nuclei, thus contributing to cloud formation. Therefore, oceanic DMS plays an important role in regulating the planet's climate by influencing the radiation budget. In this study, we use an artificial neural network model to update the global DMS climatology and estimate the sea-to-air flux.
Yuri Galletti, Silvia Becagli, Alcide di Sarra, Margherita Gonnelli, Elvira Pulido-Villena, Damiano M. Sferlazzo, Rita Traversi, Stefano Vestri, and Chiara Santinelli
Biogeosciences, 17, 3669–3684, https://doi.org/10.5194/bg-17-3669-2020, https://doi.org/10.5194/bg-17-3669-2020, 2020
Short summary
Short summary
This paper reports the first data about atmospheric deposition of dissolved organic matter (DOM) on the island of Lampedusa. It also shows the implications for the surface marine layer by studying the impact of atmospheric organic carbon deposition in the marine ecosystem. It is a preliminary study, but it is pioneering and important for having new data that can be crucial in order to understand the impact of atmospheric deposition on the marine carbon cycle in a global climate change scenario.
Charel Wohl, Ian Brown, Vassilis Kitidis, Anna E. Jones, William T. Sturges, Philip D. Nightingale, and Mingxi Yang
Biogeosciences, 17, 2593–2619, https://doi.org/10.5194/bg-17-2593-2020, https://doi.org/10.5194/bg-17-2593-2020, 2020
Short summary
Short summary
The oceans represent a poorly understood source of organic carbon to the atmosphere. In this paper, we present ship-based measurements of specific compounds in ambient air and seawater of the Southern Ocean. We present fluxes of these gases between air and sea at very high resolution. The data also contain evidence for day and night variations in some of these compounds. These measurements can be used to better understand the role of the Southern Ocean in the cycling of these compounds.
Rebecca L. Jackson, Albert J. Gabric, Roger Cropp, and Matthew T. Woodhouse
Biogeosciences, 17, 2181–2204, https://doi.org/10.5194/bg-17-2181-2020, https://doi.org/10.5194/bg-17-2181-2020, 2020
Short summary
Short summary
Coral reefs are a strong source of atmospheric sulfur through stress-induced emissions of dimethylsulfide (DMS). This biogenic sulfur can influence aerosol and cloud properties and, consequently, the radiative balance over the ocean. DMS emissions may therefore help to mitigate coral physiological stress via increased low-level cloud cover and reduced sea surface temperature. The importance of DMS in coral physiology and climate is reviewed and the implications for coral bleaching are discussed.
Louise Delaigue, Helmuth Thomas, and Alfonso Mucci
Biogeosciences, 17, 547–566, https://doi.org/10.5194/bg-17-547-2020, https://doi.org/10.5194/bg-17-547-2020, 2020
Short summary
Short summary
This paper reports on the first compilation and analysis of the surface water pCO2 distribution in the Saguenay Fjord, the southernmost subarctic fjord in the Northern Hemisphere, and thus fills a significant knowledge gap in current regional estimates of estuarine CO2 emissions.
Tim Fischer, Annette Kock, Damian L. Arévalo-Martínez, Marcus Dengler, Peter Brandt, and Hermann W. Bange
Biogeosciences, 16, 2307–2328, https://doi.org/10.5194/bg-16-2307-2019, https://doi.org/10.5194/bg-16-2307-2019, 2019
Short summary
Short summary
We investigated air–sea gas exchange in oceanic upwelling regions for the case of nitrous oxide off Peru. In this region, routine concentration measurements from ships at 5 m or 10 m depth prove to overestimate surface (bulk) concentration. Thus, standard estimates of gas exchange will show systematic error. This is due to very shallow stratified layers that inhibit exchange between surface water and waters below and can exist for several days. Maximum bias occurs in moderate wind conditions.
Mingxi Yang, Thomas G. Bell, Ian J. Brown, James R. Fishwick, Vassilis Kitidis, Philip D. Nightingale, Andrew P. Rees, and Timothy J. Smyth
Biogeosciences, 16, 961–978, https://doi.org/10.5194/bg-16-961-2019, https://doi.org/10.5194/bg-16-961-2019, 2019
Short summary
Short summary
We quantify the emissions and uptake of the greenhouse gases carbon dioxide and methane from the coastal seas of the UK over 1 year using the state-of-the-art eddy covariance technique. Our measurements show how these air–sea fluxes vary twice a day (tidal), diurnally (circadian) and seasonally. We also estimate the air–sea gas transfer velocity, which is essential for modelling and predicting coastal air-sea exchange.
Riley X. Brady, Nicole S. Lovenduski, Michael A. Alexander, Michael Jacox, and Nicolas Gruber
Biogeosciences, 16, 329–346, https://doi.org/10.5194/bg-16-329-2019, https://doi.org/10.5194/bg-16-329-2019, 2019
Stelios Myriokefalitakis, Akinori Ito, Maria Kanakidou, Athanasios Nenes, Maarten C. Krol, Natalie M. Mahowald, Rachel A. Scanza, Douglas S. Hamilton, Matthew S. Johnson, Nicholas Meskhidze, Jasper F. Kok, Cecile Guieu, Alex R. Baker, Timothy D. Jickells, Manmohan M. Sarin, Srinivas Bikkina, Rachel Shelley, Andrew Bowie, Morgane M. G. Perron, and Robert A. Duce
Biogeosciences, 15, 6659–6684, https://doi.org/10.5194/bg-15-6659-2018, https://doi.org/10.5194/bg-15-6659-2018, 2018
Short summary
Short summary
The first atmospheric iron (Fe) deposition model intercomparison is presented in this study, as a result of the deliberations of the United Nations Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection (GESAMP; http://www.gesamp.org/) Working Group 38. We conclude that model diversity over remote oceans reflects uncertainty in the Fe content parameterizations of dust aerosols, combustion aerosol emissions and the size distribution of transported aerosol Fe.
Liliane Merlivat, Jacqueline Boutin, David Antoine, Laurence Beaumont, Melek Golbol, and Vincenzo Vellucci
Biogeosciences, 15, 5653–5662, https://doi.org/10.5194/bg-15-5653-2018, https://doi.org/10.5194/bg-15-5653-2018, 2018
Short summary
Short summary
The fugacity of carbon dioxide in seawater (fCO2) was measured hourly in the surface waters of the NW Mediterranean Sea during two 3-year sequences separated by 18 years. A decrease of pH of 0.0022 yr−1 was computed. About 85 % of the accumulation of dissolved inorganic carbon (DIC) comes from chemical equilibration with increasing atmospheric CO2; the remaining 15 % accumulation is consistent with estimates of transfer of Atlantic waters through the Gibraltar Strait.
Amanda R. Fay, Nicole S. Lovenduski, Galen A. McKinley, David R. Munro, Colm Sweeney, Alison R. Gray, Peter Landschützer, Britton B. Stephens, Taro Takahashi, and Nancy Williams
Biogeosciences, 15, 3841–3855, https://doi.org/10.5194/bg-15-3841-2018, https://doi.org/10.5194/bg-15-3841-2018, 2018
Short summary
Short summary
The Southern Ocean is highly under-sampled and since this region dominates the ocean sink for CO2, understanding change is critical. Here we utilize available observations to evaluate how the seasonal cycle, variability, and trends in surface ocean carbon in the well-sampled Drake Passage region compare to that of the broader subpolar Southern Ocean. Results indicate that the Drake Passage is representative of the broader region; however, additional winter observations would improve comparisons.
Cui-Ci Sun, Martin Sperling, and Anja Engel
Biogeosciences, 15, 3577–3589, https://doi.org/10.5194/bg-15-3577-2018, https://doi.org/10.5194/bg-15-3577-2018, 2018
Short summary
Short summary
Biogenic gel particles such as transparent exopolymer particles (TEP) and Coomassie stainable particles (CSP) are important components in the sea-surface microlayer (SML). Their potential role in air–sea gas exchange and in primary organic aerosol emission has generated considerable research interest. Our wind wave channel experiment revealed how wind speed controls the accumulation and size distribution of biogenic gel particles in the SML.
N. Precious Mongwe, Marcello Vichi, and Pedro M. S. Monteiro
Biogeosciences, 15, 2851–2872, https://doi.org/10.5194/bg-15-2851-2018, https://doi.org/10.5194/bg-15-2851-2018, 2018
Short summary
Short summary
Here we analyze seasonal cycle of CO2 biases in 10 CMIP5 models in the SO. We find two main model biases; exaggeration of primary production such that biologically driven DIC changes mainly regulates FCO2 variability, and an overestimation of the role of solubility, such that changes in temperature dominantly drive FCO2 seasonal changes to an extent of opposing biological CO2 uptake in spring. CMIP5 models show greater zonal homogeneity in the seasonal cycle of FCO2 than observational products.
Allison R. Moreno, George I. Hagstrom, Francois W. Primeau, Simon A. Levin, and Adam C. Martiny
Biogeosciences, 15, 2761–2779, https://doi.org/10.5194/bg-15-2761-2018, https://doi.org/10.5194/bg-15-2761-2018, 2018
Short summary
Short summary
To bridge the missing links between variable marine elemental stoichiometry, phytoplankton physiology and carbon cycling, we embed four environmentally controlled stoichiometric models into a five-box ocean model. As predicted each model varied in its influence on the biological pump. Surprisingly, we found that variation can lead to nonlinear controls on atmospheric CO2 and carbon export, suggesting the need for further studies of ocean C : P and the impact on ocean carbon cycling.
Luke Gregor, Schalk Kok, and Pedro M. S. Monteiro
Biogeosciences, 15, 2361–2378, https://doi.org/10.5194/bg-15-2361-2018, https://doi.org/10.5194/bg-15-2361-2018, 2018
Short summary
Short summary
The Southern Ocean accounts for a large portion of the variability in oceanic CO2 uptake. However, the drivers of these changes are not understood due to a lack of observations. In this study, we used an ensemble of gap-filling methods to estimate surface CO2. We found that winter was a more important driver of longer-term variability driven by changes in wind stress. Summer variability of CO2 was driven primarily by increases in primary production.
Erik T. Buitenhuis, Parvadha Suntharalingam, and Corinne Le Quéré
Biogeosciences, 15, 2161–2175, https://doi.org/10.5194/bg-15-2161-2018, https://doi.org/10.5194/bg-15-2161-2018, 2018
Short summary
Short summary
Thanks to decreases in CFC concentrations, N2O is now the third-most important greenhouse gas, and the dominant contributor to stratospheric ozone depletion. Here we estimate the ocean–atmosphere N2O flux. We find that an estimate based on observations alone has a large uncertainty. By combining observations and a range of model simulations we find that the uncertainty is much reduced to 2.45 ± 0.8 Tg N yr−1, and better constrained and at the lower end of the estimate in the latest IPCC report.
Sayaka Yasunaka, Eko Siswanto, Are Olsen, Mario Hoppema, Eiji Watanabe, Agneta Fransson, Melissa Chierici, Akihiko Murata, Siv K. Lauvset, Rik Wanninkhof, Taro Takahashi, Naohiro Kosugi, Abdirahman M. Omar, Steven van Heuven, and Jeremy T. Mathis
Biogeosciences, 15, 1643–1661, https://doi.org/10.5194/bg-15-1643-2018, https://doi.org/10.5194/bg-15-1643-2018, 2018
Short summary
Short summary
We estimated monthly air–sea CO2 fluxes in the Arctic Ocean and its adjacent seas north of 60° N from 1997 to 2014, after mapping pCO2 in the surface water using a self-organizing map technique. The addition of Chl a as a parameter enabled us to improve the estimate of pCO2 via better representation of its decline in spring. The uncertainty in the CO2 flux estimate was reduced, and a net annual Arctic Ocean CO2 uptake of 180 ± 130 Tg C y−1 was determined to be significant.
Alizée Roobaert, Goulven G. Laruelle, Peter Landschützer, and Pierre Regnier
Biogeosciences, 15, 1701–1720, https://doi.org/10.5194/bg-15-1701-2018, https://doi.org/10.5194/bg-15-1701-2018, 2018
Chao Zhang, Huiwang Gao, Xiaohong Yao, Zongbo Shi, Jinhui Shi, Yang Yu, Ling Meng, and Xinyu Guo
Biogeosciences, 15, 749–765, https://doi.org/10.5194/bg-15-749-2018, https://doi.org/10.5194/bg-15-749-2018, 2018
Short summary
Short summary
This study compares the response of phytoplankton growth in the northwest Pacific to those in the Yellow Sea. In general, larger positive responses of phytoplankton induced by combined nutrients (in the subtropical gyre of the northwest Pacific) than those induced by a single nutrient (in the Kuroshio Extension and the Yellow Sea) from the dust are observed. We also emphasize the importance of an increase in bioavailable P stock for phytoplankton growth following dust addition.
Goulven G. Laruelle, Peter Landschützer, Nicolas Gruber, Jean-Louis Tison, Bruno Delille, and Pierre Regnier
Biogeosciences, 14, 4545–4561, https://doi.org/10.5194/bg-14-4545-2017, https://doi.org/10.5194/bg-14-4545-2017, 2017
Cited articles
Bates, N. R. and Mathis, J. T.: The Arctic Ocean marine carbon cycle: evaluation of air-sea CO2 exchanges, ocean acidification impacts and potential feedbacks, Biogeosciences, 6, 2433–2459, https://doi.org/10.5194/bg-6-2433-2009, 2009.
Copin Montégut, C.: A new formula for the effect of temperature on the partial pressure of carbon dioxide in seawater, Mar. Chem., 25, 29–37, 1988.
Cox, G. F. N. and Weeks, W. F.: Salinity variations in sea ice, J. Glaciol., 13, 109–120, 1974.
Cox, G. F. N. and Weeks, W. F.: Equations for determining the gas and brine volumes in sea-ice samples, J. Glaciol., 29, 306–316, 1983.
Crabeck, O., Delille, B., Thomas, D., Geilfus, N.-X., Rysgaard, S., and Tison, J.-L.: CO2 and CH4 in sea ice from a subarctic fjord under influence of riverine input, Biogeosciences, 11, 6525–6538, https://doi.org/10.5194/bg-11-6525-2014, 2014.
Dickson, A. G. and Millero, F. J.: A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media, Deep-Sea Res. Pt. I, 34, 1733–1743, 1987.
Dieckmann, G. S. and Hellmer, H. H.: The importance of Sea Ice: An Overview, in: Sea Ice, second edition, edited by: Thomas, D. N. and Dieckmann, G. S., Wiley-Blackwell, Oxford, UK, 1–22, 2010.
Dieckmann, G. S., Nehrke, G., Uhlig, C., Göttlicher, J., Gerland, S., Granskog, M. A., and Thomas, D. N.: Brief Communication: Ikaite (CaCO3 × 6H2O) discovered in Arctic sea ice, The Cryosphere, 4, 227–230, https://doi.org/10.5194/tc-4-227-2010, 2010.
Eicken, H., Krouse, H. R., Kadko, D., and Perovich, D. K.: Tracer studies of pathways and rates of meltwater transport through Arctic summer sea ice, J. Geophys. Res., 107, 8046, https://doi.org/10.1029/2000JC000583, 2002.
Eicken, H., Grenfell, T. C., Perovich, D. K., Richter-Menge, J. A., and Frey, K.: Hydraulic controls of summer Arctic pack ice albedo, J. Geophys. Res., 109, C08007, https://doi.org/10.1029/2003JC001989, 2004.
Fetterer, F. and Untersteiner, N.: Observations of melt ponds on Arctic sea ice, J. Geophys. Res., 103, 24821–24835, 1998.
Frankignoulle, M.: Field-measurements of air sea CO2 exchange, Limnol. Oceanogr., 33, 313–322, 1988.
Freitag, J. and Eicken, H.: Meltwater circulation and permeability of Arctic summer sea ice derived from hydrological field experiments, J. Glaciol., 49, 349–358, 2003.
Galindo, V., Levasseur, M., Mundy, C. J., Gosselin, M., Tremblay, J.-É., Scarratt, M., Gratton, Y., Papakiriakou, T., Poulin, M., and Lizotte, M.: Biological and physical processes influencing sea ice, under-ice algae, and dimethylsulfoniopropionate during spring in the Canadian Arctic Archipelago, J. Geophys. Res.-Oceans, 119, 3746–3766, 2014.
Galley, R. J., Else, B. G. T., Howell, S. E. L., Lukovich, J. V., and Barber, D. G.: Landfast sea ice conditions in the Canadian Arctic: 1983–2009, ARCTIC, 65, 133–144, 2012.
Geilfus, N. X., Delille, B., Verbeke, V., and Tison, J. L.: Towards a method for high vertical resolution measurements of the partial pressure of CO2 within bulk sea ice, J. Glaciol., 58, 287–300, 2012a.
Geilfus, N. X., Carnat, G., Papakyriakou, T., Tison, J. L., Else, B., Thomas, H., Shadwick, E., and Delille, B.: Dynamics of pCO2 and related air–ice CO2 fluxes in the Arctic coastal zone (Amundsen Gulf, Beaufort Sea), J. Geophys. Res., 117, C00G10, https://doi.org/10.1029/2011JC007118, 2012b.
Geilfus, N. X., Carnat, G., Dieckmann, G. S., Halden, N., Nehrke, G., Papakyriakou, T., Tison, J. L., and Delille, B.: First estimates of the contribution of CaCO3 precipitation to the release of CO2 to the atmosphere during young sea ice growth, J. Geophys. Res., 118, 244–255, https://doi.org/10.1029/2012JC007980, 2013a.
Geilfus, N. X., Galley, R. J., Cooper, M., Halden, N., Hare, A., Wang, F., Søgaard, D. H., and Rysgaard, S.: Gypsum crystals observed in experimental and natural sea ice, Geophys. Res. Lett., 40, 6362–6367, https://doi.org/10.1002/2013GL058479, 2013b.
Geilfus, N.-X., Tison, J.-L., Ackley, S. F., Galley, R. J., Rysgaard, S., Miller, L. A., and Delille, B.: Sea ice pCO2 dynamics and air–ice CO2 fluxes during the Sea Ice Mass Balance in the Antarctic (SIMBA) experiment – Bellingshausen Sea, Antarctica, The Cryosphere, 8, 2395–2407, https://doi.org/10.5194/tc-8-2395-2014, 2014.
Gleitz, M., Rutgers van der Loeff, M., Thomas, D. N., Dieckmann, G. S., and Millero, F. J.: Comparison of summer and winter inorganic carbon, oxygen and nutrient concentrations in Antarctic sea ice brine, Mar. Chem., 51, 81–91, 1995.
Glud, R. N., Rysgaard, S., Turner, G., McGinnis, D. F., and Leakey, R. J. G.: Biological- and physical-induced oxygen dynamics in melting sea ice of the Fram Strait, Limnol. Oceanogr., 59, 1097–1111, 2014.
Hansen, J. W., Thamdrup, B., and Jørgensen, B. B.: Anoxic incubation of sediment in gas-tight plastic bags: a method for biogeochemical processes studies, Mar. Ecol.-Prog. Ser., 208, 273–282, 2000.
Hanson, A. M.: Studies of the mass budget of arctic pack-ice floes, J. Glaciol., 5, 701–709, 1965.
Haraldsson, C., Anderson, L. G., Hassellov, M., Hulth, S., and Olsson, K.: Rapid, high-precision potentiometric titration of alkalinity in ocean and sediment pore waters, Deep-Sea Res. Pt. I, 44, 2031–2044, 1997.
Landy, J. C., Ehn, J. K., Shields, M., and Barber, D. G.: Surface melt pond evolution on landfast first-year sea ice in the Canadian Arctic Archipelago, J. Geophys. Res.-Oceans, 119, 3054–3075, https://doi.org/10.1002/2013JC009617, 2014.
Lazar, B. and Loya, Y.: Bioerosion of coral reefs – a chemical approach, Limnol. Oceanogr., 36, 377–383, 1991.
Leppäranta, M. and Manninen, T.: The brine and gas content of sea ice with attention to low salinities and high temperatures, Finnish Institute of Marine Research, Helsinki, Finland, Internal Report, 1988, 15 pp., 1988.
Mehrbach, C., Culberson, C. H., Hawley, J. E., and Pytkowicz, R. M.: Measurements of the apparent dissociation constants of carbonic acid in seawater at atmospheric pressure, Limnol. Oceanogr., 18, 897–907, 1973.
Miller, L. A., Carnat, G., Else, B. G. T., Sutherland, N., and Papakyriakou, T. N.: Carbonate system evolution at the Arctic Ocean surface during autumn freeze-up, J. Geophys. Res., 111, C00G04, https://doi.org/10.1029/2011JC007143, 2011.
Mundy, C. J., Gosselin, M., Ehn, J. K., Belzile, C., Poulin, M., Alou, E., Roy, S., Hop, H., Lessard, S., Papakyriakou, T. N., Barber, D. G., and Stewart, J.: Characteristics of two distinct high-light acclimated algal communities during advanced stages of sea ice melt, Polar Biol., 34, 1869–1886, 2011.
Nomura, D., Eicken, H., Gradinger, R., and Shirasawa, K.: Rapid physically driven inversion of the air–sea ice CO2 flux in the seasonal landfast ice off Barrow, Alaska after onset surface melt, Cont. Shelf. Res., 30, 1998–2004, 2010a.
Nomura, D., Yoshikawa-Inoue, H., Toyota, T., and Shirasawa, K.: Effects of snow, snow-melting and re-freezing processes on air–sea ice CO2 flux, J. Glaciol., 56, 262–270, 2010b.
Nomura, D., Granskog, M. A., Assmy, P., Simizu, D., and Hashida, G.: Arctic and Antarctic sea ice acts as a sink for atmospheric CO2 during periods of snowmelt and surface flooding, J. Geophys. Res.-Oceans, 118, 6511–6524, https://doi.org/10.1002/2013JC009048, 2013.
Papadimitriou, S., Kennedy, H., Norman, L., Kennedy, D. P., Dieckmann, G. S., and Thomas, D. N.: The effect of biological activity, CaCO3 mineral dynamics, and CO2 degassing in the inorganic carbon cycle in sea ice and late winter-early spring in the Weddell Sea, Antarctica, J. Geophys. Res., 117, C08011, https://doi.org/10.1029/2012JC008058, 2012.
Papakyriakou, T. and Miller, L.: Springtime CO2 exchange over seasonal sea ice in the Canadian Arctic Archipelago, Ann. Glaciol., 52, 215–224, https://doi.org/10.3189/172756411795931534, 2011.
Parmentier, F.-J. W., Christensen, T. R., Sørensen, L. L., Rysgaard, S., McGuire, A. D., Miller, P. A., and Walker, D. A.: The impact of lower sea-ice extent on Arctic greenhouse-gas exchange, Nature Climate Change, 3, 195–202, https://doi.org/10.1038/NCLIMATE1784, 2013.
Perovich, D. K., Tucker, W. B., and Ligett, K. A.: Aerial observations of the evolution of ice surface conditions during summer, J. Geophys. Res., 107, 8048, https://doi.org/10.1029/2000JC000449, 2002.
Perovich, D. K., Jones, K. F., Light, B., Eicken, H., Markus, T., Stroeve, J., and Lindsay, R.: Solar partitioning in a changing Arctic sea-ice cover, Ann. Glaciol., 52, 192–196, 2011.
Polashenski, C., Perovich, D., and Courville, Z.: The mechanisms of sea ice melt pond formation and evolution, J. Geophys. Res., 117, C01001, https://doi.org/10.1029/2011JC007231, 2012.
Rösel, A. and Kaleschke, L.: Exceptional melt pond occurrence in the years 2007 and 2011 on the Arctic sea ice revealed from MODIS satellite data, J. Geophys. Res., 117, C05018, https://doi.org/10.1029/2011JC007869, 2012.
Rysgaard, S., Glud, R. N., Sejr, M. K., Bendtsen, J., and Christensen, P. B.: Inorganic carbon transport during sea ice growth and decay: a carbon pump in polar seas, J. Geophys. Res., 112, C03016, https://doi.org/10.1029/2006JC003572, 2007.
Rysgaard, S., Bendtsen, J., Delille, B., Dieckmann, G. S., Glud, R. N., Kennedy, H., Mortensen, J., Papadimitriou, S., Thomas, D. N., and Tison, J. L.: Sea ice contribution to the air–sea CO2 exchange in the Arctic and Southern Oceans, Tellus B, 63, 823–830, 2011.
Rysgaard, S., Glud, R. N., Lennert, K., Cooper, M., Halden, N., Leakey, R. J. G., Hawthorne, F. C., and Barber, D.: Ikaite crystals in melting sea ice – implications for pCO2 and pH levels in Arctic surface waters, The Cryosphere, 6, 901–908, https://doi.org/10.5194/tc-6-901-2012, 2012a.
Rysgaard, S., Mortensen, J., Juul-Pedersen, T., Sørensen, L. L., Lennert, K., Søgaard, D. H., Arendt, K. E., Blicher, M. E., Sejr, M. K., and Bendtsen, J.: High air–sea CO2 uptake rates in nearshore and shelf areas of Southern Greenland: temporal and spatial variability, Mar. Chem., 128–129, 26–33, 2012b.
Rysgaard, S., Søgaard, D. H., Cooper, M., Pućko, M., Lennert, K., Papakyriakou, T. N., Wang, F., Geilfus, N. X., Glud, R. N., Ehn, J., McGinnis, D. F., Attard, K., Sievers, J., Deming, J. W., and Barber, D.: Ikaite crystal distribution in winter sea ice and implications for CO2 system dynamics, The Cryosphere, 7, 707–718, https://doi.org/10.5194/tc-7-707-2013, 2013.
Rysgaard, S., Wang, F., Galley, R. J., Grimm, R., Notz, D., Lemes, M., Geilfus, N.-X., Chaulk, A., Hare, A. A., Crabeck, O., Else, B. G. T., Campbell, K., Sørensen, L. L., Sievers, J., and Papakyriakou, T.: Temporal dynamics of ikaite in experimental sea ice, The Cryosphere, 8, 1469–1478, https://doi.org/10.5194/tc-8-1469-2014, 2014.
Semiletov, I. P., Makshtas, A., Akasofu, S. I., and Andreas, E. L.: Atmospheric CO2 balance: the role of Arctic sea ice, Geophys. Res. Lett., 31, L05121, https://doi.org/10.1029/2003GL017996, 2004.
Søgaard, D. H., Thomas, D. N., Rysgaard, S., Norman, L., Kaartokallio, H., Juul-Pedersen, T., Glud, R. N., and Geilfus, N. X.: The relative contributions of biological and abiotic processes to the carbon dynamics in subarctic sea ice, Polar Biol., 36, 1761–1777, https://doi.org/10.1007/s00300-013-1396-3, 2013.
Takahashi, T., Sutherland, S. C., Wanninkhof, R., Sweeney, C., Feely, R. A., Chipman, D. W., Hales, B., Friederich, G., Chavez, F., Sabine, C., Watson, A., Bakker, D. C. E., Schuster, U., Metzl, N., Inoue, H. Y., Ishii, M., Midorikawa, T., Nojiri, Y., Kortzinger, A., Steinhoff, T., Hoppenma, M., Olafsson, J., Arnarson, T. S., Tilbrook, B., Johannessen, T., Olsen, A., Bellerby, R., Wong, C. S., Delille, B., Bates, N. R., and de Baar, H. J. W.: Climatological mean and decadal change in surface ocean pCO2, and net sea–air CO2 flux over the global oceans, Deep-Sea Res. Pt. II, 56, 554–577, 2009.
Taylor, P. D. and Feltham, D. L.: A model of melt pond evolution on sea ice, J. Geophys. Res., 109, C12007, https://doi.org/10.1029/2004JC002361, 2004.
Untersteiner, N.: Natural desalination and equilibrium salinity profile of perennial sea ice, J. Geophys. Res., 73, 1251–1257, 1968.
Weeks, W. F. (Ed.): On Sea Ice, Fairbanks, Alaska, 664 pp., 2010.
Zeebe, R. E. and Wolf-Gladrow, D.: CO2 in Seawater: Equilibrium, Kinetics, Isotopes, Elsevier, 2001.
Zeebe, R. E., Eicken, H., Robinson, D. H., WolfGladrow, D., and Dieckmann, G. S.: Modeling the heating and melting of sea ice through light absorption by microalgae, J. Geophys. Res., 101, 1163–1181, 1996.
Zhou, J. Y., Delille, B., Eicken, H., Vancoppenolle, M., Brabant, F., Carnat, G., Geilfus, N. X., Papakyriakou, T., Heinesch, B., and Tison, J. L.: Physical and biogeochemical properties in landfast sea ice (Barrow, Alaska): insights on brine and gas dynamics across seasons, J. Geophys. Res.-Oceans, 118, 3172–3189, 2013.
Short summary
We investigated the evolution of inorganic carbon within landfast sea ice in Resolute Passage during the spring and summer melt period.
Low TA and TCO2 concentrations observed in sea ice and brine were associated with the percolation of meltwater from melt ponds. Meltwater was continuously supplied to the ponds which prevented melt ponds from fully equilibrating with the atmospheric CO2 concentration, promoting a continuous uptake of CO2 from the atmosphere.
We investigated the evolution of inorganic carbon within landfast sea ice in Resolute Passage...
Altmetrics
Final-revised paper
Preprint