Articles | Volume 17, issue 9
https://doi.org/10.5194/bg-17-2593-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/bg-17-2593-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 May 2020
Research article |
| 15 May 2020
| 15 May 2020
Underway seawater and atmospheric measurements of volatile organic compounds in the Southern Ocean
Charel Wohl
Plymouth Marine Laboratory, Plymouth, PL1 3DH, UK
Centre for Ocean and Atmospheric Sciences, School of Environmental
Sciences, University of East Anglia, Norwich, NR4 7TJ, UK
British Antarctic Survey, Cambridge, High Cross, Madingley Road, Cambridge, CB3
0ET, UK
Ian Brown
Plymouth Marine Laboratory, Plymouth, PL1 3DH, UK
Vassilis Kitidis
Plymouth Marine Laboratory, Plymouth, PL1 3DH, UK
Anna E. Jones
British Antarctic Survey, Cambridge, High Cross, Madingley Road, Cambridge, CB3
0ET, UK
William T. Sturges
Centre for Ocean and Atmospheric Sciences, School of Environmental
Sciences, University of East Anglia, Norwich, NR4 7TJ, UK
Philip D. Nightingale
Plymouth Marine Laboratory, Plymouth, PL1 3DH, UK
Centre for Ocean and Atmospheric Sciences, School of Environmental
Sciences, University of East Anglia, Norwich, NR4 7TJ, UK
Sustainable Agriculture Systems, Rothamsted Research, North Wyke,
Devon, EX20 2SB, UK
Plymouth Marine Laboratory, Plymouth, PL1 3DH, UK
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V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
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A winter sea ice expedition to Antarctica provided the first direct observations of sea salt aerosol (SSA) production during snow storms above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in Antarctica not explained otherwise. Defining SSA sources is important given the critical roles that aerosol plays for climate, for air quality and as a potential ice core proxy for sea ice conditions in the past.
Frances E. Hopkins, Philip D. Nightingale, John A. Stephens, C. Mark Moore, Sophie Richier, Gemma L. Cripps, and Stephen D. Archer
Biogeosciences, 17, 163–186, https://doi.org/10.5194/bg-17-163-2020, https://doi.org/10.5194/bg-17-163-2020, 2020
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We investigated the effects of ocean acidification (OA) on the production of climate active gas dimethylsulfide (DMS) in polar waters. We found that polar DMS production was unaffected by OA – in contrast to temperate waters, where large increases in DMS occurred. The regional differences in DMS response may reflect natural variability in community adaptation to ambient carbonate chemistry and should be taken into account in predicting the influence of future DMS emissions on Earth's climate.
Mingxi Yang, Sarah J. Norris, Thomas G. Bell, and Ian M. Brooks
Atmos. Chem. Phys., 19, 15271–15284, https://doi.org/10.5194/acp-19-15271-2019, https://doi.org/10.5194/acp-19-15271-2019, 2019
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This work reports direct measurements of sea spray fluxes from a coastal site in the UK, which are relevant for atmospheric chemistry as well as coastal air quality. Sea spray fluxes from this location are roughly an order of magnitude greater than over the open ocean at similar wind conditions, comparable to previous coastal measurements. Unlike previous open ocean measurements that are largely wind speed dependent, we find that sea spray fluxes near the coast depend more strongly on waves.
Thomas Holding, Ian G. Ashton, Jamie D. Shutler, Peter E. Land, Philip D. Nightingale, Andrew P. Rees, Ian Brown, Jean-Francois Piolle, Annette Kock, Hermann W. Bange, David K. Woolf, Lonneke Goddijn-Murphy, Ryan Pereira, Frederic Paul, Fanny Girard-Ardhuin, Bertrand Chapron, Gregor Rehder, Fabrice Ardhuin, and Craig J. Donlon
Ocean Sci., 15, 1707–1728, https://doi.org/10.5194/os-15-1707-2019, https://doi.org/10.5194/os-15-1707-2019, 2019
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FluxEngine is an open-source software toolbox designed to allow for the easy and accurate calculation of air–sea gas fluxes. This article describes new functionality and capabilities, which include the ability to calculate fluxes for nitrous oxide and methane, optimisation for running FluxEngine on a stand-alone desktop computer, and extensive new features to support the in situ measurement community. Four research case studies are used to demonstrate these new features.
Charel Wohl, David Capelle, Anna Jones, William T. Sturges, Philip D. Nightingale, Brent G. T. Else, and Mingxi Yang
Ocean Sci., 15, 925–940, https://doi.org/10.5194/os-15-925-2019, https://doi.org/10.5194/os-15-925-2019, 2019
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In this paper we present a gas equilibrator that can be used to equilibrate gases continuously or in discrete samples from seawater into a carrier gas. The headspace is analysed by a commercially available proton-transfer-reaction mass spectrometer. This allows for the measurement of a broad range of dissolved gases up to a very high solubility in seawater. The main advantage of this equilibrator is its unique design and ease of reproducibility.
Xin Yang, Markus M. Frey, Rachael H. Rhodes, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Anna E. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 19, 8407–8424, https://doi.org/10.5194/acp-19-8407-2019, https://doi.org/10.5194/acp-19-8407-2019, 2019
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This is a comprehensive model–data comparison aiming to evaluate the proposed mechanism of sea salt aerosol (SSA) production from blowing snow on sea ice. Some key parameters such as snow salinity and blowing-snow size distribution were constrained by data collected in the Weddell Sea. The good agreement between modelled SSA and the cruise data strongly indicates that sea ice surface is a large SSA source in polar regions, a process which has not been considered in current climate models.
Mingxi Yang, Thomas G. Bell, Ian J. Brown, James R. Fishwick, Vassilis Kitidis, Philip D. Nightingale, Andrew P. Rees, and Timothy J. Smyth
Biogeosciences, 16, 961–978, https://doi.org/10.5194/bg-16-961-2019, https://doi.org/10.5194/bg-16-961-2019, 2019
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We quantify the emissions and uptake of the greenhouse gases carbon dioxide and methane from the coastal seas of the UK over 1 year using the state-of-the-art eddy covariance technique. Our measurements show how these air–sea fluxes vary twice a day (tidal), diurnally (circadian) and seasonally. We also estimate the air–sea gas transfer velocity, which is essential for modelling and predicting coastal air-sea exchange.
Naomi J. Farren, Rachel E. Dunmore, Mohammed Iqbal Mead, Mohd Shahrul Mohd Nadzir, Azizan Abu Samah, Siew-Moi Phang, Brian J. Bandy, William T. Sturges, and Jacqueline F. Hamilton
Atmos. Chem. Phys., 19, 1537–1553, https://doi.org/10.5194/acp-19-1537-2019, https://doi.org/10.5194/acp-19-1537-2019, 2019
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During the winter monsoon, air quality on the east coast of Peninsular Malaysia is influenced by local emissions and aged emissions transported from highly polluted East Asian regions. Atmospheric particulate matter has been sampled at a rural coastal location, and ion chromatography has been used to make time-resolved measurements of the major atmospheric ions present. Analysis of aerosol composition and back trajectories has provided an insight into common sources and formation pathways.
Mingxi Yang and Zoë L. Fleming
Atmos. Chem. Phys., 19, 459–471, https://doi.org/10.5194/acp-19-459-2019, https://doi.org/10.5194/acp-19-459-2019, 2019
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The atmosphere contains thousands of different organic compounds but the quantification of their total burden has been a technical challenge. This hinders our understanding in atmospheric chemistry, air pollution, and global carbon cycling. Here we present a novel and robust method to measure total atmospheric organic carbon. By comparing the total organic carbon concentration in marine air to the sum of speciated organic measurements, we aim to estimate the pool of undetected organic species.
Stephanie L. Sargeant, J. Colin Murrell, Philip D. Nightingale, and Joanna L. Dixon
Biogeosciences, 15, 5155–5167, https://doi.org/10.5194/bg-15-5155-2018, https://doi.org/10.5194/bg-15-5155-2018, 2018
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Methanol is a climate-active gas and the most abundant oxygenated volatile organic compound in the atmosphere and seawater. This study uniquely combines methanol tracer uptake experiments with 16S rRNA pyrosequencing to show basin-wide microbial methanol uptake throughout the top 200 m of the Atlantic Ocean. These rates showed a positive correlation with the numbers of SAR11 16S rRNA gene sequences, suggesting these numerous bacteria are important sinks for methanol in seawater.
Karina E. Adcock, Claire E. Reeves, Lauren J. Gooch, Emma C. Leedham Elvidge, Matthew J. Ashfold, Carl A. M. Brenninkmeijer, Charles Chou, Paul J. Fraser, Ray L. Langenfelds, Norfazrin Mohd Hanif, Simon O'Doherty, David E. Oram, Chang-Feng Ou-Yang, Siew Moi Phang, Azizan Abu Samah, Thomas Röckmann, William T. Sturges, and Johannes C. Laube
Atmos. Chem. Phys., 18, 4737–4751, https://doi.org/10.5194/acp-18-4737-2018, https://doi.org/10.5194/acp-18-4737-2018, 2018
Kieran M. Stanley, Aoife Grant, Simon O'Doherty, Dickon Young, Alistair J. Manning, Ann R. Stavert, T. Gerard Spain, Peter K. Salameh, Christina M. Harth, Peter G. Simmonds, William T. Sturges, David E. Oram, and Richard G. Derwent
Atmos. Meas. Tech., 11, 1437–1458, https://doi.org/10.5194/amt-11-1437-2018, https://doi.org/10.5194/amt-11-1437-2018, 2018
Emma C. Leedham Elvidge, Harald Bönisch, Carl A. M. Brenninkmeijer, Andreas Engel, Paul J. Fraser, Eileen Gallacher, Ray Langenfelds, Jens Mühle, David E. Oram, Eric A. Ray, Anna R. Ridley, Thomas Röckmann, William T. Sturges, Ray F. Weiss, and Johannes C. Laube
Atmos. Chem. Phys., 18, 3369–3385, https://doi.org/10.5194/acp-18-3369-2018, https://doi.org/10.5194/acp-18-3369-2018, 2018
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Chemical species measured in stratospheric air can be used as proxies for stratospheric circulation changes which cannot be measured directly. A range of tracers is important to understand changing stratospheric dynamics. We demonstrate the suitability of PFCs and HFCs as tracers and support recent work that reduces the current stratospheric lifetime of SF6. Updates to policy-relevant parameters (e.g. stratospheric lifetime) linked to this change are provided for O3-depleting substances.
David E. Oram, Matthew J. Ashfold, Johannes C. Laube, Lauren J. Gooch, Stephen Humphrey, William T. Sturges, Emma C. Leedham Elvidge, Grant L. Forster, Neil R. P. Harris, Mohammed Iqbal Mead, Azizan Abu Samah, Siew Moi Phang, Chang-Feng Ou-Yang, Neng-Huei Lin, Jia-Lin Wang, Angela K. Baker, Carl A. M. Brenninkmeijer, and David Sherry
Atmos. Chem. Phys., 17, 11929–11941, https://doi.org/10.5194/acp-17-11929-2017, https://doi.org/10.5194/acp-17-11929-2017, 2017
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We have observed large amounts of man-made chlorine compounds in E and SE Asia and in the upper tropical troposphere. These relatively short-lived compounds are not controlled by the Montreal Protocol, but if significant quantities were able to reach the stratosphere, the long-term recovery of stratospheric ozone would be delayed. We have also identified an important atmospheric transport mechanism that can rapidly transport these chemicals from E Asia to the upper troposphere via the tropics.
Richard P. Sims, Ute Schuster, Andrew J. Watson, Ming Xi Yang, Frances E. Hopkins, John Stephens, and Thomas G. Bell
Ocean Sci., 13, 649–660, https://doi.org/10.5194/os-13-649-2017, https://doi.org/10.5194/os-13-649-2017, 2017
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This paper describes a near-surface ocean profiler (NSOP) that is deployed from a research vessel. The NSOP is used to sample the top 10 m of the ocean and pumps water back to the research ship for scientific analyses such as for trace gases. The precision in the depth of the seawater collection improves upon previous methods. The NSOP has been used to observe vertical gradients in the upper 5 m for temperature, carbon dioxide and dimethylsulfide.
Thomas G. Bell, Sebastian Landwehr, Scott D. Miller, Warren J. de Bruyn, Adrian H. Callaghan, Brian Scanlon, Brian Ward, Mingxi Yang, and Eric S. Saltzman
Atmos. Chem. Phys., 17, 9019–9033, https://doi.org/10.5194/acp-17-9019-2017, https://doi.org/10.5194/acp-17-9019-2017, 2017
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The mechanisms that determine the air–sea exchange of gases such as carbon dioxide are not well understood. During a research cruise in the North Atlantic, we simultaneously measured the air–sea transfer of two gases with contrasting solubility over a range in wind and wave conditions. We compare the transfer of these gases to improve understanding of how bubbles from breaking waves may mediate air–sea gas fluxes.
Mike J. Newland, Patricia Martinerie, Emmanuel Witrant, Detlev Helmig, David R. Worton, Chris Hogan, William T. Sturges, and Claire E. Reeves
Atmos. Chem. Phys., 17, 8269–8283, https://doi.org/10.5194/acp-17-8269-2017, https://doi.org/10.5194/acp-17-8269-2017, 2017
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We report increasing levels of alkyl nitrates in the Northern Hemisphere atmosphere between 1960 and the mid-1990s. These increases are symptomatic of large-scale changes to the chemical composition of the atmosphere, particularly with regards to the amounts of short-lived, reactive species. The observed increases are likely driven by increasing levels of nitrogen oxides. These changes have direct implications for the lifetimes of climate-relevant species in the atmosphere, such as methane.
Johannes C. Laube, Norfazrin Mohd Hanif, Patricia Martinerie, Eileen Gallacher, Paul J. Fraser, Ray Langenfelds, Carl A. M. Brenninkmeijer, Jakob Schwander, Emmanuel Witrant, Jia-Lin Wang, Chang-Feng Ou-Yang, Lauren J. Gooch, Claire E. Reeves, William T. Sturges, and David E. Oram
Atmos. Chem. Phys., 16, 15347–15358, https://doi.org/10.5194/acp-16-15347-2016, https://doi.org/10.5194/acp-16-15347-2016, 2016
Mingxi Yang, John Prytherch, Elena Kozlova, Margaret J. Yelland, Deepulal Parenkat Mony, and Thomas G. Bell
Atmos. Meas. Tech., 9, 5509–5522, https://doi.org/10.5194/amt-9-5509-2016, https://doi.org/10.5194/amt-9-5509-2016, 2016
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The exchange of the greenhouse gases carbon dioxide and methane between the ocean and the atmosphere is of critical importance for the earth's climate. Despite this, direct measurements of these fluxes are relatively scarce, especially for methane, in large part due to instrumental challenges. In this paper, we evaluate the performance of two of the latest carbon dioxide and methane flux analysers. We also compare their detection limits to predicted air–sea fluxes of these gases.
Emma C. Turner, Stafford Withington, David A. Newnham, Peter Wadhams, Anna E. Jones, and Robin Clancy
Atmos. Meas. Tech., 9, 5461–5485, https://doi.org/10.5194/amt-9-5461-2016, https://doi.org/10.5194/amt-9-5461-2016, 2016
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Observations of the submillimetre part of the electromagnetic spectrum have previously been the domain of the astronomical community. However, new technological
advances in the superconducting detectors field are offering the atmospheric sciences unexplored opportunities to perform useful spectroscopy in this region,
exploiting existing radio telescope sites. Example simulations at six sites are presented for HBr, HOBr, HO2 and N2O showing the need for broad
high-resolution measurements.
Cathy M. Trudinger, Paul J. Fraser, David M. Etheridge, William T. Sturges, Martin K. Vollmer, Matt Rigby, Patricia Martinerie, Jens Mühle, David R. Worton, Paul B. Krummel, L. Paul Steele, Benjamin R. Miller, Johannes Laube, Francis S. Mani, Peter J. Rayner, Christina M. Harth, Emmanuel Witrant, Thomas Blunier, Jakob Schwander, Simon O'Doherty, and Mark Battle
Atmos. Chem. Phys., 16, 11733–11754, https://doi.org/10.5194/acp-16-11733-2016, https://doi.org/10.5194/acp-16-11733-2016, 2016
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Perfluorocarbons (PFCs) are potent, long-lived and mostly man-made greenhouse gases released to the atmosphere mainly during aluminium production and semiconductor manufacture. Here we present the first continuous histories of three PFCs from 1800 to 2014, derived from measurements of these PFCs in the atmosphere and in air bubbles in polar ice. The records show how human actions have affected these important greenhouse gases over the past century.
Dorothee C. E. Bakker, Benjamin Pfeil, Camilla S. Landa, Nicolas Metzl, Kevin M. O'Brien, Are Olsen, Karl Smith, Cathy Cosca, Sumiko Harasawa, Stephen D. Jones, Shin-ichiro Nakaoka, Yukihiro Nojiri, Ute Schuster, Tobias Steinhoff, Colm Sweeney, Taro Takahashi, Bronte Tilbrook, Chisato Wada, Rik Wanninkhof, Simone R. Alin, Carlos F. Balestrini, Leticia Barbero, Nicholas R. Bates, Alejandro A. Bianchi, Frédéric Bonou, Jacqueline Boutin, Yann Bozec, Eugene F. Burger, Wei-Jun Cai, Robert D. Castle, Liqi Chen, Melissa Chierici, Kim Currie, Wiley Evans, Charles Featherstone, Richard A. Feely, Agneta Fransson, Catherine Goyet, Naomi Greenwood, Luke Gregor, Steven Hankin, Nick J. Hardman-Mountford, Jérôme Harlay, Judith Hauck, Mario Hoppema, Matthew P. Humphreys, Christopher W. Hunt, Betty Huss, J. Severino P. Ibánhez, Truls Johannessen, Ralph Keeling, Vassilis Kitidis, Arne Körtzinger, Alex Kozyr, Evangelia Krasakopoulou, Akira Kuwata, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Claire Lo Monaco, Ansley Manke, Jeremy T. Mathis, Liliane Merlivat, Frank J. Millero, Pedro M. S. Monteiro, David R. Munro, Akihiko Murata, Timothy Newberger, Abdirahman M. Omar, Tsuneo Ono, Kristina Paterson, David Pearce, Denis Pierrot, Lisa L. Robbins, Shu Saito, Joe Salisbury, Reiner Schlitzer, Bernd Schneider, Roland Schweitzer, Rainer Sieger, Ingunn Skjelvan, Kevin F. Sullivan, Stewart C. Sutherland, Adrienne J. Sutton, Kazuaki Tadokoro, Maciej Telszewski, Matthias Tuma, Steven M. A. C. van Heuven, Doug Vandemark, Brian Ward, Andrew J. Watson, and Suqing Xu
Earth Syst. Sci. Data, 8, 383–413, https://doi.org/10.5194/essd-8-383-2016, https://doi.org/10.5194/essd-8-383-2016, 2016
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Version 3 of the Surface Ocean CO2 Atlas (www.socat.info) has 14.5 million CO2 (carbon dioxide) values for the years 1957 to 2014 covering the global oceans and coastal seas. Version 3 is an update to version 2 with a longer record and 44 % more CO2 values. The CO2 measurements have been made on ships, fixed moorings and drifting buoys. SOCAT enables quantification of the ocean carbon sink and ocean acidification, as well as model evaluation, thus informing climate negotiations.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
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Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Mingxi Yang, Thomas G. Bell, Frances E. Hopkins, Vassilis Kitidis, Pierre W. Cazenave, Philip D. Nightingale, Margaret J. Yelland, Robin W. Pascal, John Prytherch, Ian M. Brooks, and Timothy J. Smyth
Atmos. Chem. Phys., 16, 5745–5761, https://doi.org/10.5194/acp-16-5745-2016, https://doi.org/10.5194/acp-16-5745-2016, 2016
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Coastal seas are sources of methane in the atmosphere and can fluctuate from emitting to absorbing carbon dioxide. Direct air–sea transport measurements of these two greenhouse gases in near shore regions remain scarce. From a recently established coastal atmospheric station on the south-west coast of the UK, we observed that the oceanic absorption of carbon dioxide peaked during the phytoplankton bloom, while methane emission varied with the tidal cycle, likely due to an estuary influence.
Mingxi Yang, Thomas G. Bell, Frances E. Hopkins, and Timothy J. Smyth
Atmos. Chem. Phys., 16, 4771–4783, https://doi.org/10.5194/acp-16-4771-2016, https://doi.org/10.5194/acp-16-4771-2016, 2016
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Exhausts from ships are an important source of air pollution in coastal regions. We observed a ~ 3 fold reduction in the level of sulfur dioxide (a principle pollutant) from the English Channel from 2014 to 2015 after the new International Maritime Organisation regulation on ship sulfur emission became law. Our estimated ship's fuel sulfur content shows a high degree of compliance. Dimethylsulfide from the marine biota becomes a relatively more important source of sulfur in coastal marine air.
C. Le Quéré, R. Moriarty, R. M. Andrew, J. G. Canadell, S. Sitch, J. I. Korsbakken, P. Friedlingstein, G. P. Peters, R. J. Andres, T. A. Boden, R. A. Houghton, J. I. House, R. F. Keeling, P. Tans, A. Arneth, D. C. E. Bakker, L. Barbero, L. Bopp, J. Chang, F. Chevallier, L. P. Chini, P. Ciais, M. Fader, R. A. Feely, T. Gkritzalis, I. Harris, J. Hauck, T. Ilyina, A. K. Jain, E. Kato, V. Kitidis, K. Klein Goldewijk, C. Koven, P. Landschützer, S. K. Lauvset, N. Lefèvre, A. Lenton, I. D. Lima, N. Metzl, F. Millero, D. R. Munro, A. Murata, J. E. M. S. Nabel, S. Nakaoka, Y. Nojiri, K. O'Brien, A. Olsen, T. Ono, F. F. Pérez, B. Pfeil, D. Pierrot, B. Poulter, G. Rehder, C. Rödenbeck, S. Saito, U. Schuster, J. Schwinger, R. Séférian, T. Steinhoff, B. D. Stocker, A. J. Sutton, T. Takahashi, B. Tilbrook, I. T. van der Laan-Luijkx, G. R. van der Werf, S. van Heuven, D. Vandemark, N. Viovy, A. Wiltshire, S. Zaehle, and N. Zeng
Earth Syst. Sci. Data, 7, 349–396, https://doi.org/10.5194/essd-7-349-2015, https://doi.org/10.5194/essd-7-349-2015, 2015
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Accurate assessment of anthropogenic carbon dioxide emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to understand the global carbon cycle, support the development of climate policies, and project future climate change. We describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on a range of data and models and their interpretation by a broad scientific community.
S. J. Allin, J. C. Laube, E. Witrant, J. Kaiser, E. McKenna, P. Dennis, R. Mulvaney, E. Capron, P. Martinerie, T. Röckmann, T. Blunier, J. Schwander, P. J. Fraser, R. L. Langenfelds, and W. T. Sturges
Atmos. Chem. Phys., 15, 6867–6877, https://doi.org/10.5194/acp-15-6867-2015, https://doi.org/10.5194/acp-15-6867-2015, 2015
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Stratospheric ozone protects life on Earth from harmful UV-B radiation. Chlorofluorocarbons (CFCs) are man-made compounds which act to destroy this barrier.
This paper presents (1) the first measurements of the stratospheric δ(37Cl) of CFCs -11 and -113; (2) the first quantification of long-term trends in the tropospheric δ(37Cl) of CFCs -11, -12 and -113.
This study provides a better understanding of source and sink processes associated with these destructive compounds.
A. L. Ganesan, A. J. Manning, A. Grant, D. Young, D .E. Oram, W. T. Sturges, J. B. Moncrieff, and S. O'Doherty
Atmos. Chem. Phys., 15, 6393–6406, https://doi.org/10.5194/acp-15-6393-2015, https://doi.org/10.5194/acp-15-6393-2015, 2015
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The UK is one of several countries to enact legislation to reduce its greenhouse gas emissions. We present top-down emissions of methane and nitrous oxide for the UK and Ireland over 2012-2014. We inferred average UK emissions of 2.09Tg/yr CH4 and 0.101Tg/yr N2O and used sectoral distributions to determine whether these discrepancies can be attributed to specific source sectors. We found the agricultural sector likely to be overestimated in the bottom-up emissions inventories of both gases.
C. Le Quéré, R. Moriarty, R. M. Andrew, G. P. Peters, P. Ciais, P. Friedlingstein, S. D. Jones, S. Sitch, P. Tans, A. Arneth, T. A. Boden, L. Bopp, Y. Bozec, J. G. Canadell, L. P. Chini, F. Chevallier, C. E. Cosca, I. Harris, M. Hoppema, R. A. Houghton, J. I. House, A. K. Jain, T. Johannessen, E. Kato, R. F. Keeling, V. Kitidis, K. Klein Goldewijk, C. Koven, C. S. Landa, P. Landschützer, A. Lenton, I. D. Lima, G. Marland, J. T. Mathis, N. Metzl, Y. Nojiri, A. Olsen, T. Ono, S. Peng, W. Peters, B. Pfeil, B. Poulter, M. R. Raupach, P. Regnier, C. Rödenbeck, S. Saito, J. E. Salisbury, U. Schuster, J. Schwinger, R. Séférian, J. Segschneider, T. Steinhoff, B. D. Stocker, A. J. Sutton, T. Takahashi, B. Tilbrook, G. R. van der Werf, N. Viovy, Y.-P. Wang, R. Wanninkhof, A. Wiltshire, and N. Zeng
Earth Syst. Sci. Data, 7, 47–85, https://doi.org/10.5194/essd-7-47-2015, https://doi.org/10.5194/essd-7-47-2015, 2015
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Carbon dioxide (CO2) emissions from human activities (burning fossil fuels and cement production, deforestation and other land-use change) are set to rise again in 2014.
This study (updated yearly) makes an accurate assessment of anthropogenic CO2 emissions and their redistribution between the atmosphere, ocean, and terrestrial biosphere in order to better understand the global carbon cycle, support the development of climate policies, and project future climate change.
Emma C. Leedham Elvidge, S.-M. Phang, W. T. Sturges, and G. Malin
Biogeosciences, 12, 387–398, https://doi.org/10.5194/bg-12-387-2015, https://doi.org/10.5194/bg-12-387-2015, 2015
A. E. Jones, N. Brough, P. S. Anderson, and E. W. Wolff
Atmos. Chem. Phys., 14, 11843–11851, https://doi.org/10.5194/acp-14-11843-2014, https://doi.org/10.5194/acp-14-11843-2014, 2014
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We report observations of nitric acid and peroxynitric acid, in coastal Antarctica during winter. During winter, it is dark 24h per day, so there is no influence of sunlight on atmospheric composition. We show that observed variability in concentrations is highly correlated with changes in temperature. We derive enthalpies of adsorption and show they are consistent with those derived in laboratory studies. The Antarctic, during winter, is an ideal natural laboratory to study air-snow exchange.
M. Ribas-Ribas, V. M. C. Rérolle, D. C. E. Bakker, V. Kitidis, G. A. Lee, I. Brown, E. P. Achterberg, N. J. Hardman-Mountford, and T. Tyrrell
Biogeosciences, 11, 4339–4355, https://doi.org/10.5194/bg-11-4339-2014, https://doi.org/10.5194/bg-11-4339-2014, 2014
M. S. Mohd Nadzir, S. M. Phang, M. R. Abas, N. Abdul Rahman, A. Abu Samah, W. T. Sturges, D. E. Oram, G. P. Mills, Emma C. Leedham Elvidge, J. A. Pyle, N. R. P. Harris, A. D. Robinson, M. J. Ashfold, M. I. Mead, M. T. Latif, M. F. Khan, A. M. Amiruddin, N. Banan, and M. M. Hanafiah
Atmos. Chem. Phys., 14, 8137–8148, https://doi.org/10.5194/acp-14-8137-2014, https://doi.org/10.5194/acp-14-8137-2014, 2014
M. Yang, R. Beale, P. Liss, M. Johnson, B. Blomquist, and P. Nightingale
Atmos. Chem. Phys., 14, 7499–7517, https://doi.org/10.5194/acp-14-7499-2014, https://doi.org/10.5194/acp-14-7499-2014, 2014
D. C. E. Bakker, B. Pfeil, K. Smith, S. Hankin, A. Olsen, S. R. Alin, C. Cosca, S. Harasawa, A. Kozyr, Y. Nojiri, K. M. O'Brien, U. Schuster, M. Telszewski, B. Tilbrook, C. Wada, J. Akl, L. Barbero, N. R. Bates, J. Boutin, Y. Bozec, W.-J. Cai, R. D. Castle, F. P. Chavez, L. Chen, M. Chierici, K. Currie, H. J. W. de Baar, W. Evans, R. A. Feely, A. Fransson, Z. Gao, B. Hales, N. J. Hardman-Mountford, M. Hoppema, W.-J. Huang, C. W. Hunt, B. Huss, T. Ichikawa, T. Johannessen, E. M. Jones, S. D. Jones, S. Jutterström, V. Kitidis, A. Körtzinger, P. Landschützer, S. K. Lauvset, N. Lefèvre, A. B. Manke, J. T. Mathis, L. Merlivat, N. Metzl, A. Murata, T. Newberger, A. M. Omar, T. Ono, G.-H. Park, K. Paterson, D. Pierrot, A. F. Ríos, C. L. Sabine, S. Saito, J. Salisbury, V. V. S. S. Sarma, R. Schlitzer, R. Sieger, I. Skjelvan, T. Steinhoff, K. F. Sullivan, H. Sun, A. J. Sutton, T. Suzuki, C. Sweeney, T. Takahashi, J. Tjiputra, N. Tsurushima, S. M. A. C. van Heuven, D. Vandemark, P. Vlahos, D. W. R. Wallace, R. Wanninkhof, and A. J. Watson
Earth Syst. Sci. Data, 6, 69–90, https://doi.org/10.5194/essd-6-69-2014, https://doi.org/10.5194/essd-6-69-2014, 2014
D. Helmig, V. Petrenko, P. Martinerie, E. Witrant, T. Röckmann, A. Zuiderweg, R. Holzinger, J. Hueber, C. Thompson, J. W. C. White, W. Sturges, A. Baker, T. Blunier, D. Etheridge, M. Rubino, and P. Tans
Atmos. Chem. Phys., 14, 1463–1483, https://doi.org/10.5194/acp-14-1463-2014, https://doi.org/10.5194/acp-14-1463-2014, 2014
V. M. C. Rérolle, M. Ribas-Ribas, V. Kitidis, I. Brown, D. C. E. Bakker, G. A. Lee, T. Shi, M. C. Mowlem, and E. P. Achterberg
Biogeosciences Discuss., https://doi.org/10.5194/bgd-11-943-2014, https://doi.org/10.5194/bgd-11-943-2014, 2014
Preprint retracted
V. V. Petrenko, P. Martinerie, P. Novelli, D. M. Etheridge, I. Levin, Z. Wang, T. Blunier, J. Chappellaz, J. Kaiser, P. Lang, L. P. Steele, S. Hammer, J. Mak, R. L. Langenfelds, J. Schwander, J. P. Severinghaus, E. Witrant, G. Petron, M. O. Battle, G. Forster, W. T. Sturges, J.-F. Lamarque, K. Steffen, and J. W. C. White
Atmos. Chem. Phys., 13, 7567–7585, https://doi.org/10.5194/acp-13-7567-2013, https://doi.org/10.5194/acp-13-7567-2013, 2013
M. Yang, R. Beale, T. Smyth, and B. Blomquist
Atmos. Chem. Phys., 13, 6165–6184, https://doi.org/10.5194/acp-13-6165-2013, https://doi.org/10.5194/acp-13-6165-2013, 2013
Emma C. Leedham Elvidge, C. Hughes, F. S. L. Keng, S.-M. Phang, G. Malin, and W. T. Sturges
Biogeosciences, 10, 3615–3633, https://doi.org/10.5194/bg-10-3615-2013, https://doi.org/10.5194/bg-10-3615-2013, 2013
M. M. Frey, N. Brough, J. L. France, P. S. Anderson, O. Traulle, M. D. King, A. E. Jones, E. W. Wolff, and J. Savarino
Atmos. Chem. Phys., 13, 3045–3062, https://doi.org/10.5194/acp-13-3045-2013, https://doi.org/10.5194/acp-13-3045-2013, 2013
J. C. Laube, A. Keil, H. Bönisch, A. Engel, T. Röckmann, C. M. Volk, and W. T. Sturges
Atmos. Chem. Phys., 13, 2779–2791, https://doi.org/10.5194/acp-13-2779-2013, https://doi.org/10.5194/acp-13-2779-2013, 2013
A. E. Jones, E. W. Wolff, N. Brough, S. J.-B. Bauguitte, R. Weller, M. Yela, M. Navarro-Comas, H. A. Ochoa, and N. Theys
Atmos. Chem. Phys., 13, 1457–1467, https://doi.org/10.5194/acp-13-1457-2013, https://doi.org/10.5194/acp-13-1457-2013, 2013
Related subject area
Biogeochemistry: Air - Sea Exchange
Dimethyl sulfide (DMS) climatologies, fluxes, and trends – Part 1: Differences between seawater DMS estimations
Dimethyl sulfide (DMS) climatologies, fluxes, and trends – Part 2: Sea–air fluxes
High-frequency continuous measurements reveal strong diel and seasonal cycling of pCO2 and CO2 flux in a mesohaline reach of the Chesapeake Bay
Significant role of physical transport in the marine carbon monoxide (CO) cycle: observations in the East Sea (Sea of Japan), the western North Pacific, and the Bering Sea in summer
Central Arctic Ocean surface–atmosphere exchange of CO2 and CH4 constrained by direct measurements
Spatial and seasonal variability in volatile organic sulfur compounds in seawater and the overlying atmosphere of the Bohai and Yellow seas
Estimating marine carbon uptake in the northeast Pacific using a neural network approach
Sea–air methane flux estimates derived from marine surface observations and instantaneous atmospheric measurements in the northern Labrador Sea and Baffin Bay
Global analysis of the controls on seawater dimethylsulfide spatial variability
Air–sea gas exchange in a seagrass ecosystem – results from a 3He ∕ SF6 tracer release experiment
Concentrations of dissolved dimethyl sulfide (DMS), methanethiol and other trace gases in context of microbial communities from the temperate Atlantic to the Arctic Ocean
Marine nitrogen fixation as a possible source of atmospheric water-soluble organic nitrogen aerosols in the subtropical North Pacific
Ice nucleating properties of the sea ice diatom Fragilariopsis cylindrus and its exudates
On physical mechanisms enhancing air–sea CO2 exchange
Winter season Southern Ocean distributions of climate-relevant trace gases
How biogenic polymers control surfactant dynamics in the surface microlayer: insights from a coastal Baltic Sea study
Identifying the biological control of the annual and multi-year variations in South Atlantic air–sea CO2 flux
The sensitivity of pCO2 reconstructions to sampling scales across a Southern Ocean sub-domain: a semi-idealized ocean sampling simulation approach
Physical mechanisms for biological carbon uptake during the onset of the spring phytoplankton bloom in the northwestern Mediterranean Sea (BOUSSOLE site)
Wintertime process study of the North Brazil Current rings reveals the region as a larger sink for CO2 than expected
New constraints on biological production and mixing processes in the South China Sea from triple isotope composition of dissolved oxygen
Tidal mixing of estuarine and coastal waters in the western English Channel is a control on spatial and temporal variability in seawater CO2
A seamless ensemble-based reconstruction of surface ocean pCO2 and air–sea CO2 fluxes over the global coastal and open oceans
Sea ice concentration impacts dissolved organic gases in the Canadian Arctic
Evaluating the Arabian Sea as a regional source of atmospheric CO2: seasonal variability and drivers
An empirical MLR for estimating surface layer DIC and a comparative assessment to other gap-filling techniques for ocean carbon time series
Derivation of seawater pCO2 from net community production identifies the South Atlantic Ocean as a CO2 source
Eukaryotic community composition in the sea surface microlayer across an east–west transect in the Mediterranean Sea
Enhancement of the North Atlantic CO2 sink by Arctic Waters
Global ocean dimethyl sulfide climatology estimated from observations and an artificial neural network
Atmospheric deposition of organic matter at a remote site in the central Mediterranean Sea: implications for the marine ecosystem
Dimethylsulfide (DMS), marine biogenic aerosols and the ecophysiology of coral reefs
Spatial variations in CO2 fluxes in the Saguenay Fjord (Quebec, Canada) and results of a water mixing model
Gas exchange estimates in the Peruvian upwelling regime biased by multi-day near-surface stratification
Insights from year-long measurements of air–water CH4 and CO2 exchange in a coastal environment
On the role of climate modes in modulating the air–sea CO2 fluxes in eastern boundary upwelling systems
Reviews and syntheses: the GESAMP atmospheric iron deposition model intercomparison study
Increase of dissolved inorganic carbon and decrease in pH in near-surface waters in the Mediterranean Sea during the past two decades
Utilizing the Drake Passage Time-series to understand variability and change in subpolar Southern Ocean pCO2
Effect of wind speed on the size distribution of gel particles in the sea surface microlayer: insights from a wind–wave channel experiment
The seasonal cycle of pCO2 and CO2 fluxes in the Southern Ocean: diagnosing anomalies in CMIP5 Earth system models
Marine phytoplankton stoichiometry mediates nonlinear interactions between nutrient supply, temperature, and atmospheric CO2
Interannual drivers of the seasonal cycle of CO2 in the Southern Ocean
Constraints on global oceanic emissions of N2O from observations and models
Arctic Ocean CO2 uptake: an improved multiyear estimate of the air–sea CO2 flux incorporating chlorophyll a concentrations
Uncertainty in the global oceanic CO2 uptake induced by wind forcing: quantification and spatial analysis
Phytoplankton growth response to Asian dust addition in the northwest Pacific Ocean versus the Yellow Sea
Global high-resolution monthly pCO2 climatology for the coastal ocean derived from neural network interpolation
Changes in the partial pressure of carbon dioxide in the Mauritanian–Cap Vert upwelling region between 2005 and 2012
Impact of ocean acidification on Arctic phytoplankton blooms and dimethyl sulfide concentration under simulated ice-free and under-ice conditions
Sankirna D. Joge, Anoop S. Mahajan, Shrivardhan Hulswar, Christa A. Marandino, Martí Galí, Thomas G. Bell, and Rafel Simó
Biogeosciences, 21, 4439–4452, https://doi.org/10.5194/bg-21-4439-2024, https://doi.org/10.5194/bg-21-4439-2024, 2024
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Dimethyl sulfide (DMS) is the largest natural source of sulfur in the atmosphere and leads to the formation of cloud condensation nuclei. DMS emission and quantification of its impacts have large uncertainties, but a detailed study on the emissions and drivers of their uncertainty is missing to date. The emissions are usually calculated from the seawater DMS concentrations and a flux parameterization. Here we quantify the differences in DMS seawater products, which can affect DMS fluxes.
Sankirna D. Joge, Anoop S. Mahajan, Shrivardhan Hulswar, Christa A. Marandino, Martí Galí, Thomas G. Bell, Mingxi Yang, and Rafel Simó
Biogeosciences, 21, 4453–4467, https://doi.org/10.5194/bg-21-4453-2024, https://doi.org/10.5194/bg-21-4453-2024, 2024
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Dimethyl sulfide (DMS) is the largest natural source of sulfur in the atmosphere and leads to the formation of cloud condensation nuclei. DMS emissions and quantification of their impacts have large uncertainties, but a detailed study on the range of emissions and drivers of their uncertainty is missing to date. The emissions are calculated from the seawater DMS concentrations and a flux parameterization. Here we quantify the differences in the effect of flux parameterizations used in models.
A. Whitman Miller, Jim R. Muirhead, Amanda C. Reynolds, Mark S. Minton, and Karl J. Klug
Biogeosciences, 21, 3717–3734, https://doi.org/10.5194/bg-21-3717-2024, https://doi.org/10.5194/bg-21-3717-2024, 2024
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High frequency pCO2 measurements reveal net neutral CO2 flux in a mesohaline reach of the Chesapeake Bay. Net off-gassing to the atmosphere begins in June when water temperatures rise above ~26ºC, continuing through November when temperatures fall below ~10ºC. Dissolved CO2 concentrations follow day–night cycles and are especially pronounced in warm waters. From December through May, the river is largely an uninterrupted sink for CO2 (i.e. CO2 is drawn out of the atmosphere into the river).
Young Shin Kwon, Tae Siek Rhee, Hyun-Cheol Kim, and Hyoun-Woo Kang
Biogeosciences, 21, 1847–1865, https://doi.org/10.5194/bg-21-1847-2024, https://doi.org/10.5194/bg-21-1847-2024, 2024
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Delving into CO dynamics from the East Sea to the Bering Sea, our study unveils the influence of physical transport on CO budgets. By measuring CO concentrations and parameters, we elucidate the interplay between biological and physical processes, highlighting the role of lateral transport in shaping CO distributions. Our findings underscore the importance of considering both biogeochemical and physical drivers in understanding marine carbon fluxes.
John Prytherch, Sonja Murto, Ian Brown, Adam Ulfsbo, Brett F. Thornton, Volker Brüchert, Michael Tjernström, Anna Lunde Hermansson, Amanda T. Nylund, and Lina A. Holthusen
Biogeosciences, 21, 671–688, https://doi.org/10.5194/bg-21-671-2024, https://doi.org/10.5194/bg-21-671-2024, 2024
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We directly measured methane and carbon dioxide exchange between ocean or sea ice and the atmosphere during an icebreaker-based expedition to the central Arctic Ocean (CAO) in summer 2021. These measurements can help constrain climate models and carbon budgets. The methane measurements, the first such made in the CAO, are lower than previous estimates and imply that the CAO is an insignificant contributor to Arctic methane emission. Gas exchange rates are slower than previous estimates.
Juan Yu, Lei Yu, Zhen He, Gui-Peng Yang, Jing-Guang Lai, and Qian Liu
Biogeosciences, 21, 161–176, https://doi.org/10.5194/bg-21-161-2024, https://doi.org/10.5194/bg-21-161-2024, 2024
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The distributions of volatile organic sulfur compounds (VSCs) (DMS, COS, and CS2) in the seawater and atmosphere of the Bohai and Yellow Seas were evaluated. Seasonal variations in VSCs were found and showed summer > spring. The COS concentrations exhibited positive correlation with DOC concentrations in seawater during summer. VSCs concentrations in seawater decreased with the depth. Sea-to-air fluxes of COS, DMS, and CS2 indicated that these marginal seas are sources of atmospheric VSCs.
Patrick J. Duke, Roberta C. Hamme, Debby Ianson, Peter Landschützer, Mohamed M. M. Ahmed, Neil C. Swart, and Paul A. Covert
Biogeosciences, 20, 3919–3941, https://doi.org/10.5194/bg-20-3919-2023, https://doi.org/10.5194/bg-20-3919-2023, 2023
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The ocean is both impacted by climate change and helps mitigate its effects through taking up carbon from the atmosphere. We used a machine learning approach to investigate what controls open-ocean carbon uptake in the northeast Pacific open ocean. Marine heatwaves that lasted 2–3 years increased uptake, while the upwelling strength of the Alaskan Gyre controlled uptake over 10-year time periods. The trend from 1998–2019 suggests carbon uptake in the northeast Pacific open ocean is increasing.
Judith Vogt, David Risk, Evelise Bourlon, Kumiko Azetsu-Scott, Evan N. Edinger, and Owen A. Sherwood
Biogeosciences, 20, 1773–1787, https://doi.org/10.5194/bg-20-1773-2023, https://doi.org/10.5194/bg-20-1773-2023, 2023
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The release of the greenhouse gas methane from Arctic submarine sources could exacerbate climate change in a positive feedback. Continuous monitoring of atmospheric methane levels over a 5100 km voyage in the western margin of the Labrador Sea and Baffin Bay revealed above-global averages likely affected by both onshore and offshore methane sources. Instantaneous sea–air methane fluxes were near zero at all measured stations, including a persistent cold-seep location.
George Manville, Thomas G. Bell, Jane P. Mulcahy, Rafel Simó, Martí Galí, Anoop S. Mahajan, Shrivardhan Hulswar, and Paul R. Halloran
Biogeosciences, 20, 1813–1828, https://doi.org/10.5194/bg-20-1813-2023, https://doi.org/10.5194/bg-20-1813-2023, 2023
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We present the first global investigation of controls on seawater dimethylsulfide (DMS) spatial variability over scales of up to 100 km. Sea surface height anomalies, density, and chlorophyll a help explain almost 80 % of DMS variability. The results suggest that physical and biogeochemical processes play an equally important role in controlling DMS variability. These data provide independent confirmation that existing parameterisations of seawater DMS concentration use appropriate variables.
Ryo Dobashi and David T. Ho
Biogeosciences, 20, 1075–1087, https://doi.org/10.5194/bg-20-1075-2023, https://doi.org/10.5194/bg-20-1075-2023, 2023
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Seagrass meadows are productive ecosystems and bury much carbon. Understanding their role in the global carbon cycle requires knowledge of air–sea CO2 fluxes and hence the knowledge of gas transfer velocity (k). In this study, k was determined from the dual tracer technique in Florida Bay. The observed gas transfer velocity was lower than previous studies in the coastal and open oceans at the same wind speeds, most likely due to wave attenuation by seagrass and limited wind fetch in this area.
Valérie Gros, Bernard Bonsang, Roland Sarda-Estève, Anna Nikolopoulos, Katja Metfies, Matthias Wietz, and Ilka Peeken
Biogeosciences, 20, 851–867, https://doi.org/10.5194/bg-20-851-2023, https://doi.org/10.5194/bg-20-851-2023, 2023
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The oceans are both sources and sinks for trace gases important for atmospheric chemistry and marine ecology. Here, we quantified selected trace gases (including the biological metabolites dissolved dimethyl sulfide, methanethiol and isoprene) along a 2500 km transect from the North Atlantic to the Arctic Ocean. In the context of phytoplankton and bacterial communities, our study suggests that methanethiol (rarely measured before) might substantially influence ocean–atmosphere cycling.
Tsukasa Dobashi, Yuzo Miyazaki, Eri Tachibana, Kazutaka Takahashi, Sachiko Horii, Fuminori Hashihama, Saori Yasui-Tamura, Yoko Iwamoto, Shu-Kuan Wong, and Koji Hamasaki
Biogeosciences, 20, 439–449, https://doi.org/10.5194/bg-20-439-2023, https://doi.org/10.5194/bg-20-439-2023, 2023
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Water-soluble organic nitrogen (WSON) in marine aerosols is important for biogeochemical cycling of bioelements. Our shipboard measurements suggested that reactive nitrogen produced and exuded by nitrogen-fixing microorganisms in surface seawater likely contributed to the formation of WSON aerosols in the subtropical North Pacific. This study provides new implications for the role of marine microbial activity in the formation of WSON aerosols in the ocean surface.
Lukas Eickhoff, Maddalena Bayer-Giraldi, Naama Reicher, Yinon Rudich, and Thomas Koop
Biogeosciences, 20, 1–14, https://doi.org/10.5194/bg-20-1-2023, https://doi.org/10.5194/bg-20-1-2023, 2023
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The formation of ice is an important process in Earth’s atmosphere, biosphere, and cryosphere, in particular in polar regions. Our research focuses on the influence of the sea ice diatom Fragilariopsis cylindrus and of molecules produced by it upon heterogenous ice nucleation. For that purpose, we studied the freezing of tiny droplets containing the diatoms in a microfluidic device. Together with previous studies, our results suggest a common freezing behaviour of various sea ice diatoms.
Lucía Gutiérrez-Loza, Erik Nilsson, Marcus B. Wallin, Erik Sahlée, and Anna Rutgersson
Biogeosciences, 19, 5645–5665, https://doi.org/10.5194/bg-19-5645-2022, https://doi.org/10.5194/bg-19-5645-2022, 2022
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The exchange of CO2 between the ocean and the atmosphere is an essential aspect of the global carbon cycle and is highly relevant for the Earth's climate. In this study, we used 9 years of in situ measurements to evaluate the temporal variability in the air–sea CO2 fluxes in the Baltic Sea. Furthermore, using this long record, we assessed the effect of atmospheric and water-side mechanisms controlling the efficiency of the air–sea CO2 exchange under different wind-speed conditions.
Li Zhou, Dennis Booge, Miming Zhang, and Christa A. Marandino
Biogeosciences, 19, 5021–5040, https://doi.org/10.5194/bg-19-5021-2022, https://doi.org/10.5194/bg-19-5021-2022, 2022
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Trace gas air–sea exchange exerts an important control on air quality and climate, especially in the Southern Ocean (SO). Almost all of the measurements there are skewed to summer, but it is essential to expand our measurement database over greater temporal and spatial scales. Therefore, we report measured concentrations of dimethylsulfide (DMS, as well as related sulfur compounds) and isoprene in the Atlantic sector of the SO. The observations of isoprene are the first in the winter in the SO.
Theresa Barthelmeß and Anja Engel
Biogeosciences, 19, 4965–4992, https://doi.org/10.5194/bg-19-4965-2022, https://doi.org/10.5194/bg-19-4965-2022, 2022
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Greenhouse gases released by human activity cause a global rise in mean temperatures. While scientists can predict how much of these gases accumulate in the atmosphere based on not only human-derived sources but also oceanic sinks, it is rather difficult to predict the major influence of coastal ecosystems. We provide a detailed study on the occurrence, composition, and controls of substances that suppress gas exchange. We thus help to determine what controls coastal greenhouse gas fluxes.
Daniel J. Ford, Gavin H. Tilstone, Jamie D. Shutler, and Vassilis Kitidis
Biogeosciences, 19, 4287–4304, https://doi.org/10.5194/bg-19-4287-2022, https://doi.org/10.5194/bg-19-4287-2022, 2022
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This study explores the seasonal, inter-annual, and multi-year drivers of the South Atlantic air–sea CO2 flux. Our analysis showed seasonal sea surface temperatures dominate in the subtropics, and the subpolar regions correlated with biological processes. Inter-annually, the El Niño–Southern Oscillation correlated with the CO2 flux by modifying sea surface temperatures and biological activity. Long-term trends indicated an important biological contribution to changes in the air–sea CO2 flux.
Laique M. Djeutchouang, Nicolette Chang, Luke Gregor, Marcello Vichi, and Pedro M. S. Monteiro
Biogeosciences, 19, 4171–4195, https://doi.org/10.5194/bg-19-4171-2022, https://doi.org/10.5194/bg-19-4171-2022, 2022
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Based on observing system simulation experiments using a mesoscale-resolving model, we found that to significantly improve uncertainties and biases in carbon dioxide (CO2) mapping in the Southern Ocean, it is essential to resolve the seasonal cycle (SC) of the meridional gradient of CO2 through high frequency (at least daily) observations that also span the region's meridional axis. We also showed that the estimated SC anomaly and mean annual CO2 are highly sensitive to seasonal sampling biases.
Liliane Merlivat, Michael Hemming, Jacqueline Boutin, David Antoine, Vincenzo Vellucci, Melek Golbol, Gareth A. Lee, and Laurence Beaumont
Biogeosciences, 19, 3911–3920, https://doi.org/10.5194/bg-19-3911-2022, https://doi.org/10.5194/bg-19-3911-2022, 2022
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We use in situ high-temporal-resolution measurements of dissolved inorganic carbon and atmospheric parameters at the air–sea interface to analyse phytoplankton bloom initiation identified as the net rate of biological carbon uptake in the Mediterranean Sea. The shift from wind-driven to buoyancy-driven mixing creates conditions for blooms to begin. Active mixing at the air–sea interface leads to the onset of the surface phytoplankton bloom due to the relaxation of wind speed following storms.
Léa Olivier, Jacqueline Boutin, Gilles Reverdin, Nathalie Lefèvre, Peter Landschützer, Sabrina Speich, Johannes Karstensen, Matthieu Labaste, Christophe Noisel, Markus Ritschel, Tobias Steinhoff, and Rik Wanninkhof
Biogeosciences, 19, 2969–2988, https://doi.org/10.5194/bg-19-2969-2022, https://doi.org/10.5194/bg-19-2969-2022, 2022
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We investigate the impact of the interactions between eddies and the Amazon River plume on the CO2 air–sea fluxes to better characterize the ocean carbon sink in winter 2020. The region is a strong CO2 sink, previously underestimated by a factor of 10 due to a lack of data and understanding of the processes responsible for the variability in ocean carbon parameters. The CO2 absorption is mainly driven by freshwater from the Amazon entrained by eddies and by the winter seasonal cooling.
Hana Jurikova, Osamu Abe, Fuh-Kwo Shiah, and Mao-Chang Liang
Biogeosciences, 19, 2043–2058, https://doi.org/10.5194/bg-19-2043-2022, https://doi.org/10.5194/bg-19-2043-2022, 2022
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We studied the isotopic composition of oxygen dissolved in seawater in the South China Sea. This tells us about the origin of oxygen in the water column, distinguishing between biological oxygen produced by phytoplankton communities and atmospheric oxygen entering seawater through gas exchange. We found that the East Asian Monsoon plays an important role in determining the amount of oxygen produced vs. consumed by the phytoplankton, as well as in inducing vertical water mass mixing.
Richard P. Sims, Michael Bedington, Ute Schuster, Andrew J. Watson, Vassilis Kitidis, Ricardo Torres, Helen S. Findlay, James R. Fishwick, Ian Brown, and Thomas G. Bell
Biogeosciences, 19, 1657–1674, https://doi.org/10.5194/bg-19-1657-2022, https://doi.org/10.5194/bg-19-1657-2022, 2022
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The amount of carbon dioxide (CO2) being absorbed by the ocean is relevant to the earth's climate. CO2 values in the coastal ocean and estuaries are not well known because of the instrumentation used. We used a new approach to measure CO2 across the coastal and estuarine zone. We found that CO2 and salinity were linked to the state of the tide. We used our CO2 measurements and model salinity to predict CO2. Previous studies overestimate how much CO2 the coastal ocean draws down at our site.
Thi Tuyet Trang Chau, Marion Gehlen, and Frédéric Chevallier
Biogeosciences, 19, 1087–1109, https://doi.org/10.5194/bg-19-1087-2022, https://doi.org/10.5194/bg-19-1087-2022, 2022
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Air–sea CO2 fluxes and associated uncertainty over the open ocean to coastal shelves are estimated with a new ensemble-based reconstruction of pCO2 trained on observation-based data. The regional distribution and seasonality of CO2 sources and sinks are consistent with those suggested in previous studies as well as mechanisms discussed therein. The ensemble-based uncertainty field allows identifying critical regions where improvements in pCO2 and air–sea CO2 flux estimates should be a priority.
Charel Wohl, Anna E. Jones, William T. Sturges, Philip D. Nightingale, Brent Else, Brian J. Butterworth, and Mingxi Yang
Biogeosciences, 19, 1021–1045, https://doi.org/10.5194/bg-19-1021-2022, https://doi.org/10.5194/bg-19-1021-2022, 2022
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We measured concentrations of five different organic gases in seawater in the high Arctic during summer. We found higher concentrations near the surface of the water column (top 5–10 m) and in areas of partial ice cover. This suggests that sea ice influences the concentrations of these gases. These gases indirectly exert a slight cooling effect on the climate, and it is therefore important to measure the levels accurately for future climate predictions.
Alain de Verneil, Zouhair Lachkar, Shafer Smith, and Marina Lévy
Biogeosciences, 19, 907–929, https://doi.org/10.5194/bg-19-907-2022, https://doi.org/10.5194/bg-19-907-2022, 2022
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The Arabian Sea is a natural CO2 source to the atmosphere, but previous work highlights discrepancies between data and models in estimating air–sea CO2 flux. In this study, we use a regional ocean model, achieve a flux closer to available data, and break down the seasonal cycles that impact it, with one result being the great importance of monsoon winds. As demonstrated in a meta-analysis, differences from data still remain, highlighting the great need for further regional data collection.
Jesse M. Vance, Kim Currie, John Zeldis, Peter W. Dillingham, and Cliff S. Law
Biogeosciences, 19, 241–269, https://doi.org/10.5194/bg-19-241-2022, https://doi.org/10.5194/bg-19-241-2022, 2022
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Long-term monitoring is needed to detect changes in our environment. Time series of ocean carbon have aided our understanding of seasonal cycles and provided evidence for ocean acidification. Data gaps are inevitable, yet no standard method for filling gaps exists. We present a regression approach here and compare it to seven other common methods to understand the impact of different approaches when assessing seasonal to climatic variability in ocean carbon.
Daniel J. Ford, Gavin H. Tilstone, Jamie D. Shutler, and Vassilis Kitidis
Biogeosciences, 19, 93–115, https://doi.org/10.5194/bg-19-93-2022, https://doi.org/10.5194/bg-19-93-2022, 2022
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This study identifies the most accurate biological proxy for the estimation of seawater pCO2 fields, which are key to assessing the ocean carbon sink. Our analysis shows that the net community production (NCP), the balance between photosynthesis and respiration, was more accurate than chlorophyll a within a neural network scheme. The improved pCO2 estimates, based on NCP, identified the South Atlantic Ocean as a net CO2 source, compared to a CO2 sink using chlorophyll a.
Birthe Zäncker, Michael Cunliffe, and Anja Engel
Biogeosciences, 18, 2107–2118, https://doi.org/10.5194/bg-18-2107-2021, https://doi.org/10.5194/bg-18-2107-2021, 2021
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Fungi are found in numerous marine environments. Our study found an increased importance of fungi in the Ionian Sea, where bacterial and phytoplankton counts were reduced, but organic matter was still available, suggesting fungi might benefit from the reduced competition from bacteria in low-nutrient, low-chlorophyll (LNLC) regions.
Jon Olafsson, Solveig R. Olafsdottir, Taro Takahashi, Magnus Danielsen, and Thorarinn S. Arnarson
Biogeosciences, 18, 1689–1701, https://doi.org/10.5194/bg-18-1689-2021, https://doi.org/10.5194/bg-18-1689-2021, 2021
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The Atlantic north of 50° N is an intense ocean sink area for atmospheric CO2. Observations in the vicinity of Iceland reveal a previously unrecognized Arctic contribution to the North Atlantic CO2 sink. Sustained CO2 influx to waters flowing from the Arctic Ocean is linked to their excess alkalinity derived from sources in the changing Arctic. The results relate to the following question: will the North Atlantic continue to absorb CO2 in the future as it has in the past?
Wei-Lei Wang, Guisheng Song, François Primeau, Eric S. Saltzman, Thomas G. Bell, and J. Keith Moore
Biogeosciences, 17, 5335–5354, https://doi.org/10.5194/bg-17-5335-2020, https://doi.org/10.5194/bg-17-5335-2020, 2020
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Dimethyl sulfide, a volatile compound produced as a byproduct of marine phytoplankton activity, can be emitted to the atmosphere via gas exchange. In the atmosphere, DMS is oxidized to cloud condensation nuclei, thus contributing to cloud formation. Therefore, oceanic DMS plays an important role in regulating the planet's climate by influencing the radiation budget. In this study, we use an artificial neural network model to update the global DMS climatology and estimate the sea-to-air flux.
Yuri Galletti, Silvia Becagli, Alcide di Sarra, Margherita Gonnelli, Elvira Pulido-Villena, Damiano M. Sferlazzo, Rita Traversi, Stefano Vestri, and Chiara Santinelli
Biogeosciences, 17, 3669–3684, https://doi.org/10.5194/bg-17-3669-2020, https://doi.org/10.5194/bg-17-3669-2020, 2020
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This paper reports the first data about atmospheric deposition of dissolved organic matter (DOM) on the island of Lampedusa. It also shows the implications for the surface marine layer by studying the impact of atmospheric organic carbon deposition in the marine ecosystem. It is a preliminary study, but it is pioneering and important for having new data that can be crucial in order to understand the impact of atmospheric deposition on the marine carbon cycle in a global climate change scenario.
Rebecca L. Jackson, Albert J. Gabric, Roger Cropp, and Matthew T. Woodhouse
Biogeosciences, 17, 2181–2204, https://doi.org/10.5194/bg-17-2181-2020, https://doi.org/10.5194/bg-17-2181-2020, 2020
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Coral reefs are a strong source of atmospheric sulfur through stress-induced emissions of dimethylsulfide (DMS). This biogenic sulfur can influence aerosol and cloud properties and, consequently, the radiative balance over the ocean. DMS emissions may therefore help to mitigate coral physiological stress via increased low-level cloud cover and reduced sea surface temperature. The importance of DMS in coral physiology and climate is reviewed and the implications for coral bleaching are discussed.
Louise Delaigue, Helmuth Thomas, and Alfonso Mucci
Biogeosciences, 17, 547–566, https://doi.org/10.5194/bg-17-547-2020, https://doi.org/10.5194/bg-17-547-2020, 2020
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This paper reports on the first compilation and analysis of the surface water pCO2 distribution in the Saguenay Fjord, the southernmost subarctic fjord in the Northern Hemisphere, and thus fills a significant knowledge gap in current regional estimates of estuarine CO2 emissions.
Tim Fischer, Annette Kock, Damian L. Arévalo-Martínez, Marcus Dengler, Peter Brandt, and Hermann W. Bange
Biogeosciences, 16, 2307–2328, https://doi.org/10.5194/bg-16-2307-2019, https://doi.org/10.5194/bg-16-2307-2019, 2019
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We investigated air–sea gas exchange in oceanic upwelling regions for the case of nitrous oxide off Peru. In this region, routine concentration measurements from ships at 5 m or 10 m depth prove to overestimate surface (bulk) concentration. Thus, standard estimates of gas exchange will show systematic error. This is due to very shallow stratified layers that inhibit exchange between surface water and waters below and can exist for several days. Maximum bias occurs in moderate wind conditions.
Mingxi Yang, Thomas G. Bell, Ian J. Brown, James R. Fishwick, Vassilis Kitidis, Philip D. Nightingale, Andrew P. Rees, and Timothy J. Smyth
Biogeosciences, 16, 961–978, https://doi.org/10.5194/bg-16-961-2019, https://doi.org/10.5194/bg-16-961-2019, 2019
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We quantify the emissions and uptake of the greenhouse gases carbon dioxide and methane from the coastal seas of the UK over 1 year using the state-of-the-art eddy covariance technique. Our measurements show how these air–sea fluxes vary twice a day (tidal), diurnally (circadian) and seasonally. We also estimate the air–sea gas transfer velocity, which is essential for modelling and predicting coastal air-sea exchange.
Riley X. Brady, Nicole S. Lovenduski, Michael A. Alexander, Michael Jacox, and Nicolas Gruber
Biogeosciences, 16, 329–346, https://doi.org/10.5194/bg-16-329-2019, https://doi.org/10.5194/bg-16-329-2019, 2019
Stelios Myriokefalitakis, Akinori Ito, Maria Kanakidou, Athanasios Nenes, Maarten C. Krol, Natalie M. Mahowald, Rachel A. Scanza, Douglas S. Hamilton, Matthew S. Johnson, Nicholas Meskhidze, Jasper F. Kok, Cecile Guieu, Alex R. Baker, Timothy D. Jickells, Manmohan M. Sarin, Srinivas Bikkina, Rachel Shelley, Andrew Bowie, Morgane M. G. Perron, and Robert A. Duce
Biogeosciences, 15, 6659–6684, https://doi.org/10.5194/bg-15-6659-2018, https://doi.org/10.5194/bg-15-6659-2018, 2018
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The first atmospheric iron (Fe) deposition model intercomparison is presented in this study, as a result of the deliberations of the United Nations Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection (GESAMP; http://www.gesamp.org/) Working Group 38. We conclude that model diversity over remote oceans reflects uncertainty in the Fe content parameterizations of dust aerosols, combustion aerosol emissions and the size distribution of transported aerosol Fe.
Liliane Merlivat, Jacqueline Boutin, David Antoine, Laurence Beaumont, Melek Golbol, and Vincenzo Vellucci
Biogeosciences, 15, 5653–5662, https://doi.org/10.5194/bg-15-5653-2018, https://doi.org/10.5194/bg-15-5653-2018, 2018
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The fugacity of carbon dioxide in seawater (fCO2) was measured hourly in the surface waters of the NW Mediterranean Sea during two 3-year sequences separated by 18 years. A decrease of pH of 0.0022 yr−1 was computed. About 85 % of the accumulation of dissolved inorganic carbon (DIC) comes from chemical equilibration with increasing atmospheric CO2; the remaining 15 % accumulation is consistent with estimates of transfer of Atlantic waters through the Gibraltar Strait.
Amanda R. Fay, Nicole S. Lovenduski, Galen A. McKinley, David R. Munro, Colm Sweeney, Alison R. Gray, Peter Landschützer, Britton B. Stephens, Taro Takahashi, and Nancy Williams
Biogeosciences, 15, 3841–3855, https://doi.org/10.5194/bg-15-3841-2018, https://doi.org/10.5194/bg-15-3841-2018, 2018
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The Southern Ocean is highly under-sampled and since this region dominates the ocean sink for CO2, understanding change is critical. Here we utilize available observations to evaluate how the seasonal cycle, variability, and trends in surface ocean carbon in the well-sampled Drake Passage region compare to that of the broader subpolar Southern Ocean. Results indicate that the Drake Passage is representative of the broader region; however, additional winter observations would improve comparisons.
Cui-Ci Sun, Martin Sperling, and Anja Engel
Biogeosciences, 15, 3577–3589, https://doi.org/10.5194/bg-15-3577-2018, https://doi.org/10.5194/bg-15-3577-2018, 2018
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Biogenic gel particles such as transparent exopolymer particles (TEP) and Coomassie stainable particles (CSP) are important components in the sea-surface microlayer (SML). Their potential role in air–sea gas exchange and in primary organic aerosol emission has generated considerable research interest. Our wind wave channel experiment revealed how wind speed controls the accumulation and size distribution of biogenic gel particles in the SML.
N. Precious Mongwe, Marcello Vichi, and Pedro M. S. Monteiro
Biogeosciences, 15, 2851–2872, https://doi.org/10.5194/bg-15-2851-2018, https://doi.org/10.5194/bg-15-2851-2018, 2018
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Here we analyze seasonal cycle of CO2 biases in 10 CMIP5 models in the SO. We find two main model biases; exaggeration of primary production such that biologically driven DIC changes mainly regulates FCO2 variability, and an overestimation of the role of solubility, such that changes in temperature dominantly drive FCO2 seasonal changes to an extent of opposing biological CO2 uptake in spring. CMIP5 models show greater zonal homogeneity in the seasonal cycle of FCO2 than observational products.
Allison R. Moreno, George I. Hagstrom, Francois W. Primeau, Simon A. Levin, and Adam C. Martiny
Biogeosciences, 15, 2761–2779, https://doi.org/10.5194/bg-15-2761-2018, https://doi.org/10.5194/bg-15-2761-2018, 2018
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To bridge the missing links between variable marine elemental stoichiometry, phytoplankton physiology and carbon cycling, we embed four environmentally controlled stoichiometric models into a five-box ocean model. As predicted each model varied in its influence on the biological pump. Surprisingly, we found that variation can lead to nonlinear controls on atmospheric CO2 and carbon export, suggesting the need for further studies of ocean C : P and the impact on ocean carbon cycling.
Luke Gregor, Schalk Kok, and Pedro M. S. Monteiro
Biogeosciences, 15, 2361–2378, https://doi.org/10.5194/bg-15-2361-2018, https://doi.org/10.5194/bg-15-2361-2018, 2018
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The Southern Ocean accounts for a large portion of the variability in oceanic CO2 uptake. However, the drivers of these changes are not understood due to a lack of observations. In this study, we used an ensemble of gap-filling methods to estimate surface CO2. We found that winter was a more important driver of longer-term variability driven by changes in wind stress. Summer variability of CO2 was driven primarily by increases in primary production.
Erik T. Buitenhuis, Parvadha Suntharalingam, and Corinne Le Quéré
Biogeosciences, 15, 2161–2175, https://doi.org/10.5194/bg-15-2161-2018, https://doi.org/10.5194/bg-15-2161-2018, 2018
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Thanks to decreases in CFC concentrations, N2O is now the third-most important greenhouse gas, and the dominant contributor to stratospheric ozone depletion. Here we estimate the ocean–atmosphere N2O flux. We find that an estimate based on observations alone has a large uncertainty. By combining observations and a range of model simulations we find that the uncertainty is much reduced to 2.45 ± 0.8 Tg N yr−1, and better constrained and at the lower end of the estimate in the latest IPCC report.
Sayaka Yasunaka, Eko Siswanto, Are Olsen, Mario Hoppema, Eiji Watanabe, Agneta Fransson, Melissa Chierici, Akihiko Murata, Siv K. Lauvset, Rik Wanninkhof, Taro Takahashi, Naohiro Kosugi, Abdirahman M. Omar, Steven van Heuven, and Jeremy T. Mathis
Biogeosciences, 15, 1643–1661, https://doi.org/10.5194/bg-15-1643-2018, https://doi.org/10.5194/bg-15-1643-2018, 2018
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We estimated monthly air–sea CO2 fluxes in the Arctic Ocean and its adjacent seas north of 60° N from 1997 to 2014, after mapping pCO2 in the surface water using a self-organizing map technique. The addition of Chl a as a parameter enabled us to improve the estimate of pCO2 via better representation of its decline in spring. The uncertainty in the CO2 flux estimate was reduced, and a net annual Arctic Ocean CO2 uptake of 180 ± 130 Tg C y−1 was determined to be significant.
Alizée Roobaert, Goulven G. Laruelle, Peter Landschützer, and Pierre Regnier
Biogeosciences, 15, 1701–1720, https://doi.org/10.5194/bg-15-1701-2018, https://doi.org/10.5194/bg-15-1701-2018, 2018
Chao Zhang, Huiwang Gao, Xiaohong Yao, Zongbo Shi, Jinhui Shi, Yang Yu, Ling Meng, and Xinyu Guo
Biogeosciences, 15, 749–765, https://doi.org/10.5194/bg-15-749-2018, https://doi.org/10.5194/bg-15-749-2018, 2018
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This study compares the response of phytoplankton growth in the northwest Pacific to those in the Yellow Sea. In general, larger positive responses of phytoplankton induced by combined nutrients (in the subtropical gyre of the northwest Pacific) than those induced by a single nutrient (in the Kuroshio Extension and the Yellow Sea) from the dust are observed. We also emphasize the importance of an increase in bioavailable P stock for phytoplankton growth following dust addition.
Goulven G. Laruelle, Peter Landschützer, Nicolas Gruber, Jean-Louis Tison, Bruno Delille, and Pierre Regnier
Biogeosciences, 14, 4545–4561, https://doi.org/10.5194/bg-14-4545-2017, https://doi.org/10.5194/bg-14-4545-2017, 2017
Melchor González-Dávila, J. Magdalena Santana Casiano, and Francisco Machín
Biogeosciences, 14, 3859–3871, https://doi.org/10.5194/bg-14-3859-2017, https://doi.org/10.5194/bg-14-3859-2017, 2017
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The Mauritanian–Cap Vert upwelling is shown to be sensitive to climate change forcing on upwelling processes, which strongly affects the CO2 surface distribution, ocean acidification rates, and air–sea CO2 exchange. We confirmed an upwelling intensification, an increase in the CO2 outgassing, and an important decrease in the pH of the surface waters. Upwelling areas are poorly studied and VOS lines are shown as one of the most significant contributors to our knowledge of the ocean's response.
Rachel Hussherr, Maurice Levasseur, Martine Lizotte, Jean-Éric Tremblay, Jacoba Mol, Helmuth Thomas, Michel Gosselin, Michel Starr, Lisa A. Miller, Tereza Jarniková, Nina Schuback, and Alfonso Mucci
Biogeosciences, 14, 2407–2427, https://doi.org/10.5194/bg-14-2407-2017, https://doi.org/10.5194/bg-14-2407-2017, 2017
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This study assesses the impact of ocean acidification on phytoplankton and its synthesis of the climate-active gas dimethyl sulfide (DMS), as well as its modulation, by two contrasting light regimes in the Arctic. The light regimes tested had no significant impact on either the phytoplankton or DMS concentration, whereas both variables decreased linearly with the decrease in pH. Thus, a rapid decrease in surface water pH could alter the algal biomass and inhibit DMS production in the Arctic.
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Short summary
The oceans represent a poorly understood source of organic carbon to the atmosphere. In this paper, we present ship-based measurements of specific compounds in ambient air and seawater of the Southern Ocean. We present fluxes of these gases between air and sea at very high resolution. The data also contain evidence for day and night variations in some of these compounds. These measurements can be used to better understand the role of the Southern Ocean in the cycling of these compounds.
The oceans represent a poorly understood source of organic carbon to the atmosphere. In this...
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