Articles | Volume 22, issue 6
https://doi.org/10.5194/bg-22-1697-2025
https://doi.org/10.5194/bg-22-1697-2025
Research article
 | 
01 Apr 2025
Research article |  | 01 Apr 2025

Surface CO2 gradients challenge conventional CO2 emission quantification in lentic water bodies under calm conditions

Patrick Aurich, Uwe Spank, and Matthias Koschorreck

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Technical note: Resolving Vertical CO₂ Concentration Gradients at the Air-Water Interface Using a Novel Membrane Equilibration Technique
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EGUsphere, https://doi.org/10.5194/egusphere-2026-124,https://doi.org/10.5194/egusphere-2026-124, 2026
This preprint is open for discussion and under review for Biogeosciences (BG).
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Cited articles

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Andersson, A., Falck, E., Sjöblom, A., Kljun, N., Sahlée, E., Omar, A. M., and Rutgersson, A.: Air-sea gas transfer in high Arctic fjords, Geophys. Res. Lett., 44, 2519–2526, https://doi.org/10.1002/2016GL072373, 2017. 
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Aubinet, M., Vesala, T., and Papale, D.: Eddy covariance: a practical guide to measurement and data analysis, Springer, Dordrecht, Heidelberg, London, New York, 449 pp., ISBN 978-94-007-2350-4, e-ISBN 978-94-007-2351-1, 2012. 
Balmer, M. and Downing, J.: Carbon dioxide concentrations in eutrophic lakes: undersaturation implies atmospheric uptake, Inland Waters, 1, 125–132, https://doi.org/10.5268/IW-1.2.366, 2011. 
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Short summary
Lakes can be sources and sinks of the greenhouse gas carbon dioxide. The gas exchange between the atmosphere and the water can be measured by taking gas samples from them. However, the depth of water samples is not well defined, which may cause errors. We hypothesized that gradients of CO2 concentrations develop under the surface when wind speeds are very low. Our measurements show that such a gradient can occur on calm nights, potentially shifting lakes from a CO2 sink to a source.
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