Articles | Volume 13, issue 2
https://doi.org/10.5194/bg-13-551-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/bg-13-551-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| Highlight paper
| 
01 Feb 2016
Research article | Highlight paper |
| 01 Feb 2016
Runoff- and erosion-driven transport of cattle slurry: linking molecular tracers to hydrological processes
C. E. M. Lloyd
CORRESPONDING AUTHOR
Organic Geochemistry Unit, Bristol Biogeochemistry Research Centre, School of
Chemistry, University of Bristol, Cantocks Close, Bristol, BS8 1TS, UK
School of Geographical Sciences, University of Bristol, University Road, Bristol, BS8 1SS, UK
K. Michaelides
School of Geographical Sciences, University of Bristol, University Road, Bristol, BS8 1SS, UK
D. R. Chadwick
School of Environment, Natural Resources and Geography, Bangor University, Deiniol Road,
Bangor, Gwynedd, LL57 2UW, UK
J. A. J. Dungait
Department of Sustainable Soils and Grassland Systems, Rothamsted Research-North Wyke,
Okehampton, EX20 2SB, UK
R. P. Evershed
Organic Geochemistry Unit, Bristol Biogeochemistry Research Centre, School of
Chemistry, University of Bristol, Cantocks Close, Bristol, BS8 1TS, UK
Related authors
Catherine M. Heppell, Andrew Binley, Mark Trimmer, Tegan Darch, Ashley Jones, Ed Malone, Adrian L. Collins, Penny J. Johnes, Jim E. Freer, and Charlotte E. M. Lloyd
Hydrol. Earth Syst. Sci., 21, 4785–4802, https://doi.org/10.5194/hess-21-4785-2017, https://doi.org/10.5194/hess-21-4785-2017, 2017
Short summary
Short summary
The role that hydrology plays in controlling the interplay between dissolved organic carbon (DOC) and nitrogen in rivers of lowland, agricultural landscapes is poorly understood, yet important to assess given the potential changes to production and delivery of DOC and nitrate arising from climate change. We measured DOC and nitrate concentrations in river water of the lowland river Hampshire Avon (Wiltshire, southern UK), revealing significant seasonal variations in DOC : nitrate transport.
C. E. M. Lloyd, J. E. Freer, P. J. Johnes, and A. L. Collins
Hydrol. Earth Syst. Sci., 20, 625–632, https://doi.org/10.5194/hess-20-625-2016, https://doi.org/10.5194/hess-20-625-2016, 2016
Short summary
Short summary
This paper examines the current methodologies for quantifying storm behaviour through hysteresis analysis, and explores a new method. Each method is systematically tested and the impact on the results is examined. Recommendations are made regarding the most effective method of calculating a hysteresis index. This new method allows storm hysteresis behaviour to be directly compared between storms, parameters, and catchments, meaning it has wide application potential in water quality research.
F. N. Outram, C. E. M. Lloyd, J. Jonczyk, C. McW. H. Benskin, F. Grant, M. T. Perks, C. Deasy, S. P. Burke, A. L. Collins, J. Freer, P. M. Haygarth, K. M. Hiscock, P. J. Johnes, and A. L. Lovett
Hydrol. Earth Syst. Sci., 18, 3429–3448, https://doi.org/10.5194/hess-18-3429-2014, https://doi.org/10.5194/hess-18-3429-2014, 2014
Manuel F. Rios Gaona, Katerina Michaelides, and Michael Bliss Singer
Geosci. Model Dev., 17, 5387–5412, https://doi.org/10.5194/gmd-17-5387-2024, https://doi.org/10.5194/gmd-17-5387-2024, 2024
Short summary
Short summary
STORM v.2 (short for STOchastic Rainfall Model version 2.0) is an open-source and user-friendly modelling framework for simulating rainfall fields over a basin. It also allows simulating the impact of plausible climate change either on the total seasonal rainfall or the storm’s maximum intensity.
Dagmawi Teklu Asfaw, Michael Bliss Singer, Rafael Rosolem, David MacLeod, Mark Cuthbert, Edisson Quichimbo Miguitama, Manuel F. Rios Gaona, and Katerina Michaelides
Geosci. Model Dev., 16, 557–571, https://doi.org/10.5194/gmd-16-557-2023, https://doi.org/10.5194/gmd-16-557-2023, 2023
Short summary
Short summary
stoPET is a new stochastic potential evapotranspiration (PET) generator for the globe at hourly resolution. Many stochastic weather generators are used to generate stochastic rainfall time series; however, no such model exists for stochastically generating plausible PET time series. As such, stoPET represents a significant methodological advance. stoPET generate many realizations of PET to conduct climate studies related to the water balance, agriculture, water resources, and ecology.
Shiuan-An Chen, Katerina Michaelides, David A. Richards, and Michael Bliss Singer
Earth Surf. Dynam., 10, 1055–1078, https://doi.org/10.5194/esurf-10-1055-2022, https://doi.org/10.5194/esurf-10-1055-2022, 2022
Short summary
Short summary
Drainage basin erosion rates influence landscape evolution through controlling land surface lowering and sediment flux, but gaps remain in understanding their large-scale patterns and drivers between timescales. We analysed global erosion rates and show that long-term erosion rates are controlled by rainfall, former glacial processes, and basin landform, whilst human activities enhance short-term erosion rates. The results highlight the complex interplay of controls on land surface processes.
E. Andrés Quichimbo, Michael Bliss Singer, Katerina Michaelides, Daniel E. J. Hobley, Rafael Rosolem, and Mark O. Cuthbert
Geosci. Model Dev., 14, 6893–6917, https://doi.org/10.5194/gmd-14-6893-2021, https://doi.org/10.5194/gmd-14-6893-2021, 2021
Short summary
Short summary
Understanding and quantifying water partitioning in dryland regions are of key importance to anticipate the future impacts of climate change in water resources and dryland ecosystems. Here, we have developed a simple hydrological model (DRYP) that incorporates the key processes of water partitioning in drylands. DRYP is a modular, versatile, and parsimonious model that can be used to anticipate and plan for climatic and anthropogenic changes to water fluxes and storage in dryland regions.
Isaac Kipkemoi, Katerina Michaelides, Rafael Rosolem, and Michael Bliss Singer
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-48, https://doi.org/10.5194/hess-2021-48, 2021
Manuscript not accepted for further review
Short summary
Short summary
The work is a novel investigation of the role of temporal rainfall resolution and intensity in affecting the water balance of soil in a dryland environment. This research has implications for what rainfall data are used to assess the impact of climate and climate change on the regional water balance. This information is critical for anticipating the impact of a changing climate on dryland communities globally who need it to know when to plant their seeds or where livestock pasture is available.
Thomas Turpin-Jelfs, Katerina Michaelides, Joel A. Biederman, and Alexandre M. Anesio
Biogeosciences, 16, 369–381, https://doi.org/10.5194/bg-16-369-2019, https://doi.org/10.5194/bg-16-369-2019, 2019
Short summary
Short summary
Increasing shrub cover promotes land degradation in semi-arid grasslands and has the potential to impact the soil nitrogen pool, which is essential to primary production. Our study showed that increasing shrub cover concentrates soil nitrogen into localised patches beneath shrub canopies. Further, we determined that increasing shrub cover inhibits inputs of nitrogen by the soil microbial community. Thus, we conclude this phenomenon can perturb nitrogen cycling in these ecosystems.
Michael Bliss Singer, Katerina Michaelides, and Daniel E. J. Hobley
Geosci. Model Dev., 11, 3713–3726, https://doi.org/10.5194/gmd-11-3713-2018, https://doi.org/10.5194/gmd-11-3713-2018, 2018
Short summary
Short summary
For various applications, a regional or local characterization of rainfall is required, particularly at the watershed scale, where there is spatial heterogeneity. Furthermore, simple models are needed that can simulate various scenarios of climate change including changes in seasonal wetness and rainstorm intensity. To this end, we have developed the STOchastic Rainstorm Model (STORM). We explain its developments and data requirements, and illustrate how it simulates rainstorms over a basin.
Xiao Han, Cong Xu, Jennifer A. J. Dungait, Roland Bol, Xiaojie Wang, Wenliang Wu, and Fanqiao Meng
Biogeosciences, 15, 1933–1946, https://doi.org/10.5194/bg-15-1933-2018, https://doi.org/10.5194/bg-15-1933-2018, 2018
Short summary
Short summary
Straw incorporation increases soil organic carbon (SOC) stocks and crop yields in experimental trials across China, regardless of the climate or land use. This conclusion is based on a wide range of soils and climate conditions and suggests that farmers across the world may use this simple management tool to increase their outputs by improving the quality of their outputs by improving the quality of their soil, while mitigating climate change.
Catherine M. Heppell, Andrew Binley, Mark Trimmer, Tegan Darch, Ashley Jones, Ed Malone, Adrian L. Collins, Penny J. Johnes, Jim E. Freer, and Charlotte E. M. Lloyd
Hydrol. Earth Syst. Sci., 21, 4785–4802, https://doi.org/10.5194/hess-21-4785-2017, https://doi.org/10.5194/hess-21-4785-2017, 2017
Short summary
Short summary
The role that hydrology plays in controlling the interplay between dissolved organic carbon (DOC) and nitrogen in rivers of lowland, agricultural landscapes is poorly understood, yet important to assess given the potential changes to production and delivery of DOC and nitrate arising from climate change. We measured DOC and nitrate concentrations in river water of the lowland river Hampshire Avon (Wiltshire, southern UK), revealing significant seasonal variations in DOC : nitrate transport.
C. E. M. Lloyd, J. E. Freer, P. J. Johnes, and A. L. Collins
Hydrol. Earth Syst. Sci., 20, 625–632, https://doi.org/10.5194/hess-20-625-2016, https://doi.org/10.5194/hess-20-625-2016, 2016
Short summary
Short summary
This paper examines the current methodologies for quantifying storm behaviour through hysteresis analysis, and explores a new method. Each method is systematically tested and the impact on the results is examined. Recommendations are made regarding the most effective method of calculating a hysteresis index. This new method allows storm hysteresis behaviour to be directly compared between storms, parameters, and catchments, meaning it has wide application potential in water quality research.
A. F. Charteris, T. D. J. Knowles, K. Michaelides, and R. P. Evershed
SOIL Discuss., https://doi.org/10.5194/soild-2-1135-2015, https://doi.org/10.5194/soild-2-1135-2015, 2015
Manuscript not accepted for further review
F. N. Outram, C. E. M. Lloyd, J. Jonczyk, C. McW. H. Benskin, F. Grant, M. T. Perks, C. Deasy, S. P. Burke, A. L. Collins, J. Freer, P. M. Haygarth, K. M. Hiscock, P. J. Johnes, and A. L. Lovett
Hydrol. Earth Syst. Sci., 18, 3429–3448, https://doi.org/10.5194/hess-18-3429-2014, https://doi.org/10.5194/hess-18-3429-2014, 2014
Related subject area
Biogeochemistry: Rivers & Streams
Molecular-level characterization of supraglacial dissolved and water-extractable organic matter along a hydrological flow path in a Greenland Ice Sheet micro-catchment
Seasonal and spatial pattern of dissolved organic matter biodegradation and photodegradation in boreal humic waters
The role of nitrogen and iron biogeochemical cycles in the production and export of dissolved organic matter in agricultural headwater catchments
From Iron Curtain to green belt: shift from heterotrophic to autotrophic nitrogen retention in the Elbe River over 35 years of passive restoration
The influence of burn severity on dissolved organic carbon concentrations across a stream network differs based on seasonal wetness conditions
Temporal dynamics and environmental controls of carbon dioxide and methane fluxes measured by the eddy covariance method over a boreal river
Seasonal particulate organic carbon dynamics of the Kolyma River tributaries, Siberia
Geomorphologic controls and anthropogenic impacts on dissolved organic carbon from mountainous rivers: insights from optical properties and carbon isotopes
Shifts in organic matter character and microbial community structure from glacial headwaters to downstream reaches in Canadian Rocky Mountain rivers
Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway
Physical and stoichiometric controls on stream respiration in a headwater stream
Local processes with a global impact: unraveling the dynamics of gas evasion in a step-and-pool configuration
Complex dissolved organic matter (DOM) on the roof of the world – Tibetan DOM molecular characteristics indicate sources, land use effects, and processing along the fluvial–limnic continuum
Maximum respiration rates in hyporheic zone sediments are primarily constrained by organic carbon concentration and secondarily by organic matter chemistry
Glacier loss and vegetation expansion alter organic and inorganic carbon dynamics in high-mountain streams
Particulate organic matter in the Lena River and its delta: from the permafrost catchment to the Arctic Ocean
Stable isotopic evidence for the excess leaching of unprocessed atmospheric nitrate from forested catchments under high nitrogen saturation
Nitrogen isotopes reveal a particulate-matter-driven biogeochemical reactor in a temperate estuary
High-resolution vertical biogeochemical profiles in the hyporheic zone reveal insights into microbial methane cycling
Organic matter transformations are disconnected between surface water and the hyporheic zone
CO2 emissions from peat-draining rivers regulated by water pH
Effects of peatland management on aquatic carbon concentrations and fluxes
Resistance and resilience of stream metabolism to high flow disturbances
Enhanced bioavailability of dissolved organic matter (DOM) in human-disturbed streams in Alpine fluvial networks
Spatial and temporal variability of pCO2 and CO2 emissions from the Dong River in south China
Fluvial carbon dioxide emission from the Lena River basin during the spring flood
Diel patterns in stream nitrate concentration produced by in-stream processes
Complex interactions of in-stream dissolved organic matter and nutrient spiralling unravelled by Bayesian regression analysis
Spatial–temporal variations in riverine carbon strongly influenced by local hydrological events in an alpine catchment
Rapid soil organic carbon decomposition in river systems: effects of the aquatic microbial community and hydrodynamical disturbance
Increased carbon capture by a silicate-treated forested watershed affected by acid deposition
Thermokarst amplifies fluvial inorganic carbon cycling and export across watershed scales on the Peel Plateau, Canada
Temporary and net sinks of atmospheric CO2 due to chemical weathering in subtropical catchment with mixing carbonate and silicate lithology
From canals to the coast: dissolved organic matter and trace metal composition in rivers draining degraded tropical peatlands in Indonesia
Distribution and flux of dissolved iron in the peatland-draining rivers and estuaries of Sarawak, Malaysian Borneo
Comparisons of dissolved organic matter and its optical characteristics in small low and high Arctic catchments
High-frequency measurements explain quantity and quality of dissolved organic carbon mobilization in a headwater catchment
Dissolved inorganic nitrogen in a tropical estuary in Malaysia: transport and transformation
Behaviour of Dissolved Phosphorus with the associated nutrients in relation to phytoplankton biomass of the Rajang River-South China Sea continuum
Synchrony in catchment stream colour levels is driven by both local and regional climate
The post-monsoon carbon biogeochemistry of the Hooghly–Sundarbans estuarine system under different levels of anthropogenic impacts
Riverine particulate C and N generated at the permafrost thaw front: case study of western Siberian rivers across a 1700 km latitudinal transect
Geochemistry of the dissolved loads during high-flow season of rivers in the southeastern coastal region of China: anthropogenic impact on chemical weathering and carbon sequestration
CO2 partial pressure and CO2 emission along the lower Red River (Vietnam)
Stable isotopes of nitrate reveal different nitrogen processing mechanisms in streams across a land use gradient during wet and dry periods
Riverine carbon export in the arid to semiarid Wuding River catchment on the Chinese Loess Plateau
Use of argon to measure gas exchange in turbulent mountain streams
Reviews and syntheses: Anthropogenic perturbations to carbon fluxes in Asian river systems – concepts, emerging trends, and research challenges
Shifts in stream hydrochemistry in responses to typhoon and non-typhoon precipitation
QUAL-NET, a high temporal-resolution eutrophication model for large hydrographic networks
Eva L. Doting, Ian T. Stevens, Anne M. Kellerman, Pamela E. Rossel, Runa Antony, Amy M. McKenna, Martyn Tranter, Liane G. Benning, Robert G. M. Spencer, Jon R. Hawkings, and Alexandre M. Anesio
Biogeosciences, 22, 41–53, https://doi.org/10.5194/bg-22-41-2025, https://doi.org/10.5194/bg-22-41-2025, 2025
Short summary
Short summary
This study provides the first evidence for biogeochemical cycling of supraglacial dissolved organic matter (DOM) in meltwater flowing through the porous crust of weathering ice that covers glacier ice surfaces during the melt season. Movement of water through the weathering crust is slow, allowing microbes and solar radiation to alter the DOM in glacial meltwaters. This is important as supraglacial meltwaters deliver DOM to downstream aquatic environments.
Artem V. Chupakov, Natalia V. Neverova, Anna A. Chupakova, Svetlana A. Zabelina, Liudmila S. Shirokova, Taissia Ya. Vorobyeva, and Oleg S. Pokrovsky
Biogeosciences, 21, 5725–5743, https://doi.org/10.5194/bg-21-5725-2024, https://doi.org/10.5194/bg-21-5725-2024, 2024
Short summary
Short summary
In the boreal humic waters of a forest lake and bog, the rate of dissolved organic matter photodegradation is 4 times higher than that of biodegradation. However, given the shallow, light-penetrating layer, the biodegradation provides the largest contribution to CO2 emissions from water surfaces. Trace metals were partially removed (1–10 %) during photodegradation and biodegradation via precipitation of Fe(III) hydroxides after destabilization of organoferric colloids and organic complexes.
Thibault Lambert, Rémi Dupas, and Patrick Durand
Biogeosciences, 21, 4533–4547, https://doi.org/10.5194/bg-21-4533-2024, https://doi.org/10.5194/bg-21-4533-2024, 2024
Short summary
Short summary
This study investigates dissolved organic carbon (DOC) export in headwater catchments. Results show small links between DOC, nitrates, and the iron cycle throughout the year, calling into question our current conceptualization of DOC export at the catchment scale. Indeed, this study evidences that the winter period, referred as a non-productive period in our current conceptual model, acts as an active period for DOC production in riparian soils and DOC export toward stream waters.
Alexander Wachholz, James W. Jawitz, and Dietrich Borchardt
Biogeosciences, 21, 3537–3550, https://doi.org/10.5194/bg-21-3537-2024, https://doi.org/10.5194/bg-21-3537-2024, 2024
Short summary
Short summary
Human activities are rivers' main source of nitrogen, causing eutrophication and other hazards. However, rivers can serve as a natural defense mechanism against this by retaining nitrogen. We show that the Elbe River retains more nitrogen during times of high pollution. With improvements in water quality, less nitrogen is retained. We explain this with changed algal and bacterial activities, which correspond to pollution and have many implications for the river and adjacent ecosystems.
Katie A. Wampler, Kevin D. Bladon, and Allison N. Myers-Pigg
Biogeosciences, 21, 3093–3120, https://doi.org/10.5194/bg-21-3093-2024, https://doi.org/10.5194/bg-21-3093-2024, 2024
Short summary
Short summary
Following a high-severity wildfire, we sampled 129 sites during four different times of the year across a stream network to quantify dissolved organic carbon. The results from our study suggested that dissolved organic carbon may decrease with increasing burn severity. They also suggest that landscape characteristics can override wildfire impacts, with the seasonal timing of sampling influencing the observed response of dissolved organic carbon concentrations to wildfire.
Aki Vähä, Timo Vesala, Sofya Guseva, Anders Lindroth, Andreas Lorke, Sally MacIntyre, and Ivan Mammarella
EGUsphere, https://doi.org/10.5194/egusphere-2024-1644, https://doi.org/10.5194/egusphere-2024-1644, 2024
Short summary
Short summary
Boreal rivers are significant sources of carbon dioxide (CO2) and methane (CH4) to the atmosphere but the controls of these emissions are uncertain. We measured four months of CO2 and CH4 exchange between a regulated boreal river and the atmosphere with eddy covariance. We found statistical relationships between the gas exchange and several environmental variables, the most important of which were dissolved CO2 partial pressure in water, wind speed, and water temperature.
Kirsi H. Keskitalo, Lisa Bröder, Tommaso Tesi, Paul J. Mann, Dirk J. Jong, Sergio Bulte Garcia, Anna Davydova, Sergei Davydov, Nikita Zimov, Negar Haghipour, Timothy I. Eglinton, and Jorien E. Vonk
Biogeosciences, 21, 357–379, https://doi.org/10.5194/bg-21-357-2024, https://doi.org/10.5194/bg-21-357-2024, 2024
Short summary
Short summary
Permafrost thaw releases organic carbon into waterways. Decomposition of this carbon pool emits greenhouse gases into the atmosphere, enhancing climate warming. We show that Arctic river carbon and water chemistry are different between the spring ice breakup and summer and that primary production is initiated in small Arctic rivers right after ice breakup, in contrast to in large rivers. This may have implications for fluvial carbon dynamics and greenhouse gas uptake and emission balance.
Shuai Chen, Jun Zhong, Lishan Ran, Yuanbi Yi, Wanfa Wang, Zelong Yan, Si-liang Li, and Khan M. G. Mostofa
Biogeosciences, 20, 4949–4967, https://doi.org/10.5194/bg-20-4949-2023, https://doi.org/10.5194/bg-20-4949-2023, 2023
Short summary
Short summary
This study found the source of dissolved organic carbon and its optical properties (e.g., aromaticity, humification) are related to human land use and catchment slope in anthropogenically impacted subtropical mountainous rivers. The study highlights that the combination of dual carbon isotopes and optical properties represents a useful tool in tracing the origin of dissolved organic carbon and its in-stream processes.
Hayley F. Drapeau, Suzanne E. Tank, Maria Cavaco, Jessica A. Serbu, Vincent St.Louis, and Maya P. Bhatia
Biogeosciences Discuss., https://doi.org/10.5194/bg-2023-121, https://doi.org/10.5194/bg-2023-121, 2023
Revised manuscript accepted for BG
Short summary
Short summary
From glacial headwaters to 100 km downstream, we found clear organic matter gradients in Canadian Rocky Mountain rivers. In contrast, microbial communities exhibited overall cohesion, indicating that species dispersal may be an over-riding control on community dynamics in these connected rivers. Identification of glacial-specific microbes suggest that glaciers seed headwater microbial communities; these findings show the importance of glacial waters and microbiomes in changing mountain systems.
Nele Lehmann, Hugues Lantuit, Michael Ernst Böttcher, Jens Hartmann, Antje Eulenburg, and Helmuth Thomas
Biogeosciences, 20, 3459–3479, https://doi.org/10.5194/bg-20-3459-2023, https://doi.org/10.5194/bg-20-3459-2023, 2023
Short summary
Short summary
Riverine alkalinity in the silicate-dominated headwater catchment at subarctic Iskorasfjellet, northern Norway, was almost entirely derived from weathering of minor carbonate occurrences in the riparian zone. The uphill catchment appeared limited by insufficient contact time of weathering agents and weatherable material. Further, alkalinity increased with decreasing permafrost extent. Thus, with climate change, alkalinity generation is expected to increase in this permafrost-degrading landscape.
Jancoba Dorley, Joel Singley, Tim Covino, Kamini Singha, Michael Gooseff, David Van Horn, and Ricardo González-Pinzón
Biogeosciences, 20, 3353–3366, https://doi.org/10.5194/bg-20-3353-2023, https://doi.org/10.5194/bg-20-3353-2023, 2023
Short summary
Short summary
We quantified how microbial respiration is controlled by discharge and the supply of C, N, and P in a stream. We ran two rounds of experiments adding a conservative tracer, an indicator of aerobic respiration, and nutrient treatments: a) N, b) N+C, c) N+P, and d) C+N+P. Microbial respiration remained similar between rounds and across nutrient treatments. This suggests that complex interactions between hydrology, resource supply, and biological community drive in-stream respiration.
Paolo Peruzzo, Matteo Cappozzo, Nicola Durighetto, and Gianluca Botter
Biogeosciences, 20, 3261–3271, https://doi.org/10.5194/bg-20-3261-2023, https://doi.org/10.5194/bg-20-3261-2023, 2023
Short summary
Short summary
Small cascades greatly enhance mountain stream gas emissions through the turbulent energy dissipation rate and air bubbles entrained into the water. We numerically studied the local contribution of these mechanisms driving gas transfer velocity used to quantify the outgassing. The gas evasion is primarily due to bubbles concentrated in irregular spots of limited area. Consequently, the gas exchange velocity is scale-dependent and unpredictable, posing concerns about its use in similar scenarios.
Philipp Maurischat, Michael Seidel, Thorsten Dittmar, and Georg Guggenberger
Biogeosciences, 20, 3011–3026, https://doi.org/10.5194/bg-20-3011-2023, https://doi.org/10.5194/bg-20-3011-2023, 2023
Short summary
Short summary
Production and consumption of organic matter (OM) on the Tibetan Plateau are important for this sensitive ecosystem. We investigated the chemical composition of dissolved organic matter and the most mobile fraction of OM in glaciers, wetlands, and groundwater as well as in the rivers and a large terminal lake. Our data show that the sources differ in the molecular composition of OM, that the stream is influenced by agriculture, and that the lake strongly changes the inflowing organic matter.
James C. Stegen, Vanessa A. Garayburu-Caruso, Robert E. Danczak, Amy E. Goldman, Lupita Renteria, Joshua M. Torgeson, and Jacqueline Hager
Biogeosciences, 20, 2857–2867, https://doi.org/10.5194/bg-20-2857-2023, https://doi.org/10.5194/bg-20-2857-2023, 2023
Short summary
Short summary
Chemical reactions in river sediments influence how clean the water is and how much greenhouse gas comes out of a river. Our study investigates why some sediments have higher rates of chemical reactions than others. We find that to achieve high rates, sediments need to have two things: only a few different kinds of molecules, but a lot of them. This result spans about 80 rivers such that it could be a general rule, helpful for predicting the future of rivers and our planet.
Andrew L. Robison, Nicola Deluigi, Camille Rolland, Nicolas Manetti, and Tom Battin
Biogeosciences, 20, 2301–2316, https://doi.org/10.5194/bg-20-2301-2023, https://doi.org/10.5194/bg-20-2301-2023, 2023
Short summary
Short summary
Climate change is affecting mountain ecosystems intensely, including the loss of glaciers and the uphill migration of plants. How these changes will affect the streams draining these landscapes is unclear. We sampled streams across a gradient of glacier and vegetation cover in Switzerland and found glacier loss reduced the carbon dioxide sink from weathering, while vegetation cover increased dissolved organic carbon in the stream. These changes are important to consider for mountains globally.
Olga Ogneva, Gesine Mollenhauer, Bennet Juhls, Tina Sanders, Juri Palmtag, Matthias Fuchs, Hendrik Grotheer, Paul J. Mann, and Jens Strauss
Biogeosciences, 20, 1423–1441, https://doi.org/10.5194/bg-20-1423-2023, https://doi.org/10.5194/bg-20-1423-2023, 2023
Short summary
Short summary
Arctic warming accelerates permafrost thaw and release of terrestrial organic matter (OM) via rivers to the Arctic Ocean. We compared particulate organic carbon (POC), total suspended matter, and C isotopes (δ13C and Δ14C of POC) in the Lena delta and Lena River along a ~1600 km transect. We show that the Lena delta, as an interface between the Lena River and the Arctic Ocean, plays a crucial role in determining the qualitative and quantitative composition of OM discharged into the Arctic Ocean.
Weitian Ding, Urumu Tsunogai, Fumiko Nakagawa, Takashi Sambuichi, Masaaki Chiwa, Tamao Kasahara, and Ken'ichi Shinozuka
Biogeosciences, 20, 753–766, https://doi.org/10.5194/bg-20-753-2023, https://doi.org/10.5194/bg-20-753-2023, 2023
Short summary
Short summary
By monitoring the concentration and Δ17O of stream nitrate in three forested streams, the new nitrogen saturation index of forested catchments (Matm/Datm ratio) was estimated. We found that (1) the unprocessed atmospheric nitrate in our studied forested stream (FK1 catchment) was the highest ever reported in forested streams; (2) the Matm/Datm ratio can be used as a robust index for evaluating nitrogen saturation in forested catchments as the Matm/Datm ratio is independent of the precipitation.
Kirstin Dähnke, Tina Sanders, Yoana Voynova, and Scott D. Wankel
Biogeosciences, 19, 5879–5891, https://doi.org/10.5194/bg-19-5879-2022, https://doi.org/10.5194/bg-19-5879-2022, 2022
Short summary
Short summary
Nitrogen is an important macronutrient that fuels algal production in rivers and coastal regions. We investigated the production and removal of nitrogen-bearing compounds in the freshwater section of the tidal Elbe Estuary and found that particles in the water column are key for the production and removal of water column nitrate. Using a stable isotope approach, we pinpointed regions where additional removal of nitrate or input from sediments plays an important role in estuarine biogeochemistry.
Tamara Michaelis, Anja Wunderlich, Ömer K. Coskun, William Orsi, Thomas Baumann, and Florian Einsiedl
Biogeosciences, 19, 4551–4569, https://doi.org/10.5194/bg-19-4551-2022, https://doi.org/10.5194/bg-19-4551-2022, 2022
Short summary
Short summary
The greenhouse gas methane (CH4) drives climate change. Microorganisms in river sediments produce CH4 when degrading organic matter, but the contribution of rivers to atmospheric CH4 concentrations is uncertain. To better understand riverine CH4 cycling, we measured concentration profiles of CH4 and relevant reactants that might influence the CH4 cycle. We found substantial CH4 production, especially in fine, organic-rich sediments during summer and signs of microbial CH4 consumption.
James C. Stegen, Sarah J. Fansler, Malak M. Tfaily, Vanessa A. Garayburu-Caruso, Amy E. Goldman, Robert E. Danczak, Rosalie K. Chu, Lupita Renteria, Jerry Tagestad, and Jason Toyoda
Biogeosciences, 19, 3099–3110, https://doi.org/10.5194/bg-19-3099-2022, https://doi.org/10.5194/bg-19-3099-2022, 2022
Short summary
Short summary
Rivers are vital to Earth, and in rivers, organic matter (OM) is an energy source for microbes that make greenhouse gas and remove contaminants. Predicting Earth’s future requires understanding how and why river OM is transformed. Our results help meet this need. We found that the processes influencing OM transformations diverge between river water and riverbed sediments. This can be used to build new models for predicting the future of rivers and, in turn, the Earth system.
Alexandra Klemme, Tim Rixen, Denise Müller-Dum, Moritz Müller, Justus Notholt, and Thorsten Warneke
Biogeosciences, 19, 2855–2880, https://doi.org/10.5194/bg-19-2855-2022, https://doi.org/10.5194/bg-19-2855-2022, 2022
Short summary
Short summary
Tropical peat-draining rivers contain high amounts of carbon. Surprisingly, measured carbon dioxide (CO2) emissions from those rivers are comparatively moderate. We compiled data from 10 Southeast Asian rivers and found that CO2 production within these rivers is hampered by low water pH, providing a natural threshold for CO2 emissions. Furthermore, we find that enhanced carbonate input, e.g. caused by human activities, suspends this natural threshold and causes increased CO2 emissions.
Amy E. Pickard, Marcella Branagan, Mike F. Billett, Roxane Andersen, and Kerry J. Dinsmore
Biogeosciences, 19, 1321–1334, https://doi.org/10.5194/bg-19-1321-2022, https://doi.org/10.5194/bg-19-1321-2022, 2022
Short summary
Short summary
Peatlands have been subject to a range of land management regimes over the past century. This has affected the amount of carbon that drains into surrounding streams and rivers. In our study, we measured carbon concentrations in streams draining from drained, non-drained, and restored areas of the Flow Country blanket bog in N Scotland. We found that drained peatland had higher concentrations and fluxes of carbon relative to non-drained areas. Restored peatland areas were highly variable.
Brynn O'Donnell and Erin R. Hotchkiss
Biogeosciences, 19, 1111–1134, https://doi.org/10.5194/bg-19-1111-2022, https://doi.org/10.5194/bg-19-1111-2022, 2022
Short summary
Short summary
A stream is defined by flowing water, but higher flow from storms is also a frequent disturbance. This paper tests how higher flow changes stream metabolism (respiration and photosynthesis, R and P). P was less resistant to changes in flow compared to R, and P took longer to recover from storms than R (2.2 versus 0.6 d). Further work on metabolic responses to flow disturbance is critical given projected increases in storms and the influence of higher flows on ecosystem health and functioning.
Thibault Lambert, Pascal Perolo, Nicolas Escoffier, and Marie-Elodie Perga
Biogeosciences, 19, 187–200, https://doi.org/10.5194/bg-19-187-2022, https://doi.org/10.5194/bg-19-187-2022, 2022
Short summary
Short summary
The bacterial mineralization of dissolved organic matter (DOM) in inland waters contributes to CO2 emissions to the atmosphere. Human activities affect DOM sources. However, the implications on DOM mineralization are poorly known. Combining sampling and incubations, we showed that higher bacterial respiration in agro-urban streams related to a labile pool from aquatic origin. Therefore, human activities may have a limited impact on the net carbon exchanges between inland waters and atmosphere.
Boyi Liu, Mingyang Tian, Kaimin Shih, Chun Ngai Chan, Xiankun Yang, and Lishan Ran
Biogeosciences, 18, 5231–5245, https://doi.org/10.5194/bg-18-5231-2021, https://doi.org/10.5194/bg-18-5231-2021, 2021
Short summary
Short summary
Spatial and temporal patterns of pCO2 in the subtropical Dong River basin were mainly affected by C inputs and in-stream metabolism, both of which varied due to differential catchment settings, land cover, and hydrological conditions. CO2 fluxes in the wet season were 2-fold larger than in the dry season due to high pCO2 and turbulence caused by high flow velocity. The absence of high CO2 fluxes in small rivers could be associated with the depletion effect caused by abundant precipitation.
Sergey N. Vorobyev, Jan Karlsson, Yuri Y. Kolesnichenko, Mikhail A. Korets, and Oleg S. Pokrovsky
Biogeosciences, 18, 4919–4936, https://doi.org/10.5194/bg-18-4919-2021, https://doi.org/10.5194/bg-18-4919-2021, 2021
Short summary
Short summary
In order to quantify riverine carbon (C) exchange with the atmosphere in permafrost regions, we report a first assessment of CO2 and CH4 concentration and fluxes of the largest permafrost-affected river, the Lena River, during the peak of spring flow. The results allowed identification of environmental factors controlling GHG concentrations and emission in the Lena River watershed; this new knowledge can be used for foreseeing future changes in C balance in permafrost-affected Arctic rivers.
Jan Greiwe, Markus Weiler, and Jens Lange
Biogeosciences, 18, 4705–4715, https://doi.org/10.5194/bg-18-4705-2021, https://doi.org/10.5194/bg-18-4705-2021, 2021
Short summary
Short summary
We analyzed variability in diel nitrate patterns at three locations in a lowland stream. Comparison of time lags between monitoring sites with water travel time indicated that diel patterns were created by in-stream processes rather than transported downstream from an upstream point of origin. Most of the patterns (70 %) could be explained by assimilatory nitrate uptake. The remaining patterns suggest seasonally varying dominance and synchronicity of different biochemical processes.
Matthias Pucher, Peter Flödl, Daniel Graeber, Klaus Felsenstein, Thomas Hein, and Gabriele Weigelhofer
Biogeosciences, 18, 3103–3122, https://doi.org/10.5194/bg-18-3103-2021, https://doi.org/10.5194/bg-18-3103-2021, 2021
Short summary
Short summary
Dissolved organic matter is an important carbon source in aquatic ecosystems, yet the uptake processes are not totally understood. We found evidence for the release of degradation products, efficiency loss in the uptake with higher concentrations, stimulating effects, and quality-dependent influences from the benthic zone. To conduct this analysis, we included interactions in the equations of the nutrient spiralling concept and solve it with a Bayesian non-linear fitting algorithm.
Xin Wang, Ting Liu, Liang Wang, Zongguang Liu, Erxiong Zhu, Simin Wang, Yue Cai, Shanshan Zhu, and Xiaojuan Feng
Biogeosciences, 18, 3015–3028, https://doi.org/10.5194/bg-18-3015-2021, https://doi.org/10.5194/bg-18-3015-2021, 2021
Short summary
Short summary
We show a comprehensive monitoring dataset on the discharge and carbon transport in a small alpine river on the Qinghai–Tibetan Plateau, where riverine carbon increased downstream in the pre-monsoon season due to an increasing contribution of organic matter derived from seasonal permafrost thaw while it fluctuated in the monsoon season induced by sporadic precipitation. These results indicate a high sensitivity of riverine carbon in alpine headwater catchments to local hydrological events.
Man Zhao, Liesbet Jacobs, Steven Bouillon, and Gerard Govers
Biogeosciences, 18, 1511–1523, https://doi.org/10.5194/bg-18-1511-2021, https://doi.org/10.5194/bg-18-1511-2021, 2021
Short summary
Short summary
We investigate the relative importance of two individual factors (hydrodynamical disturbance and aquatic microbial community) that possibly control SOC decomposition rates in river systems. We found aquatic microbial organisms led to rapid SOC decomposition, while effect of mechanical disturbance is relative minor. We propose a simple conceptual model: hydrodynamic disturbance is only important when soil aggregates are strong enough to withstand the disruptive forces imposed by water immersions.
Lyla L. Taylor, Charles T. Driscoll, Peter M. Groffman, Greg H. Rau, Joel D. Blum, and David J. Beerling
Biogeosciences, 18, 169–188, https://doi.org/10.5194/bg-18-169-2021, https://doi.org/10.5194/bg-18-169-2021, 2021
Short summary
Short summary
Enhanced rock weathering (ERW) is a carbon dioxide removal (CDR) strategy involving soil amendments with silicate rock dust. Over 15 years, a small silicate application led to net CDR of 8.5–11.5 t CO2/ha in an acid-rain-impacted New Hampshire forest. We accounted for the total carbon cost of treatment and compared effects with an adjacent, untreated forest. Our results suggest ERW can improve the greenhouse gas balance of similar forests in addition to mitigating acid rain effects.
Scott Zolkos, Suzanne E. Tank, Robert G. Striegl, Steven V. Kokelj, Justin Kokoszka, Cristian Estop-Aragonés, and David Olefeldt
Biogeosciences, 17, 5163–5182, https://doi.org/10.5194/bg-17-5163-2020, https://doi.org/10.5194/bg-17-5163-2020, 2020
Short summary
Short summary
High-latitude warming thaws permafrost, exposing minerals to weathering and fluvial transport. We studied the effects of abrupt thaw and associated weathering on carbon cycling in western Canada. Permafrost collapse affected < 1 % of the landscape yet enabled carbonate weathering associated with CO2 degassing in headwaters and increased bicarbonate export across watershed scales. Weathering may become a driver of carbon cycling in ice- and mineral-rich permafrost terrain across the Arctic.
Yingjie Cao, Yingxue Xuan, Changyuan Tang, Shuai Guan, and Yisheng Peng
Biogeosciences, 17, 3875–3890, https://doi.org/10.5194/bg-17-3875-2020, https://doi.org/10.5194/bg-17-3875-2020, 2020
Short summary
Short summary
About half of the global CO2 sequestration due to chemical weathering occurs in warm and high-runoff regions. To evaluate the temporary and net sinks of atmospheric CO2 due to chemical weathering, we selected a typical subtropical catchment as our study area and did fieldwork to sample surface water along the main channel and major tributaries in 1 hydrological year. The result of mass balance calculation showed that human activities dramatically decreased the CO2 net sink.
Laure Gandois, Alison M. Hoyt, Stéphane Mounier, Gaël Le Roux, Charles F. Harvey, Adrien Claustres, Mohammed Nuriman, and Gusti Anshari
Biogeosciences, 17, 1897–1909, https://doi.org/10.5194/bg-17-1897-2020, https://doi.org/10.5194/bg-17-1897-2020, 2020
Short summary
Short summary
Worldwide, peatlands are important sources of dissolved organic matter (DOM) and trace metals (TMs) to surface waters, and these fluxes may increase with peatland degradation. In Southeast Asia, tropical peatlands are being rapidly deforested and drained. This work aims to address the fate of organic carbon and its role as a trace metal carrier in drained peatlands of Indonesia.
Xiaohui Zhang, Moritz Müller, Shan Jiang, Ying Wu, Xunchi Zhu, Aazani Mujahid, Zhuoyi Zhu, Mohd Fakharuddin Muhamad, Edwin Sien Aun Sia, Faddrine Holt Ajon Jang, and Jing Zhang
Biogeosciences, 17, 1805–1819, https://doi.org/10.5194/bg-17-1805-2020, https://doi.org/10.5194/bg-17-1805-2020, 2020
Short summary
Short summary
This study offered detailed information on dFe concentrations, distribution and the magnitude of yield in the Rajang River, the largest river in Malaysia. Three blackwater rivers, draining from peatlands, were also included in our study. Compared with the Rajang River, the dFe concentrations and yield from three blackwater rivers were much higher. The precipitation and agricultural activities, such as palm oil plantations, may markedly increase the concentration dFe in these tropical rivers.
Caroline Coch, Bennet Juhls, Scott F. Lamoureux, Melissa J. Lafrenière, Michael Fritz, Birgit Heim, and Hugues Lantuit
Biogeosciences, 16, 4535–4553, https://doi.org/10.5194/bg-16-4535-2019, https://doi.org/10.5194/bg-16-4535-2019, 2019
Short summary
Short summary
Climate change affects Arctic ecosystems. This includes thawing of permafrost (ground below 0 °C) and an increase in rainfall. Both have substantial impacts on the chemical composition of river water. We compared the composition of small rivers in the low and high Arctic with the large Arctic rivers. In comparison, dissolved organic matter in the small rivers is more susceptible to degradation; thus, it could potentially increase carbon dioxide emissions. Rainfall events have a similar effect.
Benedikt J. Werner, Andreas Musolff, Oliver J. Lechtenfeld, Gerrit H. de Rooij, Marieke R. Oosterwoud, and Jan H. Fleckenstein
Biogeosciences, 16, 4497–4516, https://doi.org/10.5194/bg-16-4497-2019, https://doi.org/10.5194/bg-16-4497-2019, 2019
Short summary
Short summary
Increased dissolved organic carbon (DOC) concentration in streams can pose a threat to downstream water resources. Analyzing data from an in-stream probe we found that hydroclimatic and hydrological drivers can describe up to 72 % of the observed DOC concentration and composition variability. Variability was found to be highest during discharge events with warm and dry preconditions. The findings suggest an impact of climate change on DOC exports and thus also on downstream water quality.
Shan Jiang, Moritz Müller, Jie Jin, Ying Wu, Kun Zhu, Guosen Zhang, Aazani Mujahid, Tim Rixen, Mohd Fakharuddin Muhamad, Edwin Sien Aun Sia, Faddrine Holt Ajon Jang, and Jing Zhang
Biogeosciences, 16, 2821–2836, https://doi.org/10.5194/bg-16-2821-2019, https://doi.org/10.5194/bg-16-2821-2019, 2019
Short summary
Short summary
Three cruises were conducted in the Rajang River estuary, Malaysia. The results revealed that the decomposition of terrestrial organic matter and the subsequent soil leaching were the main sources of dissolved inorganic nitrogen (DIN) in the fresh river water. Porewater exchange and ammonification enhanced DIN concentrations in the estuary water, while intensities of DIN addition varied between seasons. The riverine DIN flux could reach 101.5 ton(N) / d, supporting the coastal primary producers.
Edwin Sien Aun Sia, Jing Zhang, Shan Jiang, Zhuoyi Zhu, Gonzalo Carrasco, Faddrine Holt Jang, Aazani Mujahid, and Moritz Müller
Biogeosciences Discuss., https://doi.org/10.5194/bg-2019-219, https://doi.org/10.5194/bg-2019-219, 2019
Revised manuscript not accepted
Short summary
Short summary
Nutrient loads carried by large rivers and discharged into the continental shelf and coastal waters are vital to support primary production. Our knowledge of tropical river systems is fragmented with very few seasonal studies available for Southeast Asia (SEA). We present data from three sampling campaigns on the longest river in Malaysia, the Rajang river. Our results show the generalization of SEA as a nutrient hotspot might not hold true for all regions and requires further investigation.
Brian C. Doyle, Elvira de Eyto, Mary Dillane, Russell Poole, Valerie McCarthy, Elizabeth Ryder, and Eleanor Jennings
Biogeosciences, 16, 1053–1071, https://doi.org/10.5194/bg-16-1053-2019, https://doi.org/10.5194/bg-16-1053-2019, 2019
Short summary
Short summary
This study explores the drivers of variation in the water colour of rivers, and hence organic carbon export, in a blanket peatland catchment. We used 6 years of weekly river water colour data (2011 to 2016) from three proximate river sub-catchments in western Ireland. in tandem with a range of topographical, hydrological and climate data, to discover the principle environmental drivers controlling changes in colour concentration in the rivers.
Manab Kumar Dutta, Sanjeev Kumar, Rupa Mukherjee, Prasun Sanyal, and Sandip Kumar Mukhopadhyay
Biogeosciences, 16, 289–307, https://doi.org/10.5194/bg-16-289-2019, https://doi.org/10.5194/bg-16-289-2019, 2019
Short summary
Short summary
The study focused on understanding C biogeochemistry of two adjacently located estuaries undergoing different levels of anthropogenic stresses. Different parameters related to C cycling were measured in an anthropogenically influenced and a mangrove-dominated estuary. Although the entire estuarine system acted as a source of carbon dioxide to the regional atmosphere, emission approximately 17 times higher was noticed from the anthropogenically affected estuary compared to mangrove-dominated one.
Ivan V. Krickov, Artem G. Lim, Rinat M. Manasypov, Sergey V. Loiko, Liudmila S. Shirokova, Sergey N. Kirpotin, Jan Karlsson, and Oleg S. Pokrovsky
Biogeosciences, 15, 6867–6884, https://doi.org/10.5194/bg-15-6867-2018, https://doi.org/10.5194/bg-15-6867-2018, 2018
Short summary
Short summary
We tested the effect of climate, permafrost and physio-geographical landscape parameters on particulate C, N and P concentrations in small- and medium- sized rivers in the Western Siberian Lowland (WSL). We discovered a maximum of particulate C and N concentrations at the beginning of the permafrost appearance. A northward shift of permafrost boundaries may increase the particulate C and N export by WSL rivers to the Arctic Ocean by a factor of 2.
Wenjing Liu, Zhifang Xu, Huiguo Sun, Tong Zhao, Chao Shi, and Taoze Liu
Biogeosciences, 15, 4955–4971, https://doi.org/10.5194/bg-15-4955-2018, https://doi.org/10.5194/bg-15-4955-2018, 2018
Short summary
Short summary
The southeastern coastal region is the top acid-rain-impacted area in China. It is worth evaluating the acid deposition impacts on chemical weathering and CO2 consumption there. River water geochemistry evidenced an overestimation of CO2 sequestration if H2SO4/HNO3 involvement was ignored, which accounted for 33.6 % of the total flux by silicate weathering in this area. This study quantitatively highlights the anthropogenic acid effects on chemical weathering and associated CO2 consumption.
Thi Phuong Quynh Le, Cyril Marchand, Cuong Tu Ho, Nhu Da Le, Thi Thuy Duong, XiXi Lu, Phuong Kieu Doan, Trung Kien Nguyen, Thi Mai Huong Nguyen, and Duy An Vu
Biogeosciences, 15, 4799–4814, https://doi.org/10.5194/bg-15-4799-2018, https://doi.org/10.5194/bg-15-4799-2018, 2018
Short summary
Short summary
The Red River is a typical south-east Asian river, strongly affected by climate and human activity. This study showed the spatial and seasonal variability of CO2 emissions at the water–air interface of the lower part of this river due to natural conditions (meteo-hydrological-geomorphological characteristics) and human activities (dam impoundment, population, land use). The Red River water was supersaturated with CO2, providing a mean water–air CO2 flux of 530 ± 17 mmol m−2 d−1.
Wei Wen Wong, Jesse Pottage, Fiona Y. Warry, Paul Reich, Keryn L. Roberts, Michael R. Grace, and Perran L. M. Cook
Biogeosciences, 15, 3953–3965, https://doi.org/10.5194/bg-15-3953-2018, https://doi.org/10.5194/bg-15-3953-2018, 2018
Short summary
Short summary
Over-enrichment of nitrate can pose substantial risk to the quality of freshwater ecosystems. Hence, understanding the dynamics of nitrate is the key to better management of waterways. This study evaluates the relationship between the effects of land use and rainfall on the major sources and processing of nitrate within and between five streams in five catchments spanning an agricultural land use gradient. We found that rainfall exerted significant control over the fate of nitrate.
Lishan Ran, Mingyang Tian, Nufang Fang, Suiji Wang, Xixi Lu, Xiankun Yang, and Frankie Cho
Biogeosciences, 15, 3857–3871, https://doi.org/10.5194/bg-15-3857-2018, https://doi.org/10.5194/bg-15-3857-2018, 2018
Short summary
Short summary
We systematically assessed the transport and fate of riverine carbon in the moderate-sized Wuding catchment on the Chinese Loess Plateau by constructing a riverine carbon budget and further relating it to terrestrial ecosystem productivity. The riverine carbon export accounted for 16 % of the catchment's net ecosystem production (NEP). It seems that a significant fraction of terrestrial NEP in this catchment is laterally transported from the terrestrial biosphere to the drainage network.
Robert O. Hall Jr. and Hilary L. Madinger
Biogeosciences, 15, 3085–3092, https://doi.org/10.5194/bg-15-3085-2018, https://doi.org/10.5194/bg-15-3085-2018, 2018
Short summary
Short summary
Streams exchange oxygen with the atmosphere, but this rate is difficult to measure. We added argon to small mountain streams to estimate gas exchange. We compared these rates with sulfur hexafluoride, an intense greenhouse gas. Argon worked well to measure gas exchange, but had higher-than-predicted rates than sulfur hexafluoride. Argon exchange is more likely to represent that for oxygen because they share similar physical properties. We suggest argon to measure gas exchange in small streams.
Ji-Hyung Park, Omme K. Nayna, Most S. Begum, Eliyan Chea, Jens Hartmann, Richard G. Keil, Sanjeev Kumar, Xixi Lu, Lishan Ran, Jeffrey E. Richey, Vedula V. S. S. Sarma, Shafi M. Tareq, Do Thi Xuan, and Ruihong Yu
Biogeosciences, 15, 3049–3069, https://doi.org/10.5194/bg-15-3049-2018, https://doi.org/10.5194/bg-15-3049-2018, 2018
Short summary
Short summary
Human activities are drastically altering water and material flows in river systems across Asia. This review provides a conceptual framework for assessing the human impacts on Asian river C fluxes and an update on anthropogenic alterations of riverine C fluxes, focusing on the impacts of water pollution and river impoundments on CO2 outgassing from the rivers draining South, Southeast, and East Asian regions that account for the largest fraction of river discharge and C exports from Asia.
Chung-Te Chang, Jr-Chuan Huang, Lixin Wang, Yu-Ting Shih, and Teng-Chiu Lin
Biogeosciences, 15, 2379–2391, https://doi.org/10.5194/bg-15-2379-2018, https://doi.org/10.5194/bg-15-2379-2018, 2018
Short summary
Short summary
Our analysis of ion input–output budget illustrates that hydrochemical responses to typhoon storms are distinctly different from those of regular storms. In addition, even mild land use change may have large impacts on nutrient exports/losses. We propose that hydrological models should separate hydrochemical processes into regular and extreme conditions to better capture the whole spectrum of hydrochemical responses to a variety of climate conditions.
Camille Minaudo, Florence Curie, Yann Jullian, Nathalie Gassama, and Florentina Moatar
Biogeosciences, 15, 2251–2269, https://doi.org/10.5194/bg-15-2251-2018, https://doi.org/10.5194/bg-15-2251-2018, 2018
Short summary
Short summary
We developed the model QUALity-NETwork (QUAL-NET) to simulate water quality variations in large drainage networks. This model is accurate enough to represent processes occurring over short periods of time such as storm events and helps to fully understand water quality variations in stream networks in the context of climate change and varying human pressures. It was tested on the Loire River and provided good performances and a new understanding of the functioning of the river.
Cited articles
Aksoy, H., Unal, N. E., Cokgor, S., Gedikli, A., Yoon, J., Koca, K., Inci,
S. B., and Eris, E.: A rainfall simulator for laboratory-scale assessment of
rainfall–runoff-sediment transport processes over a two-dimensional flume,
Catena, 98, 63–72, https://doi.org/10.1016/j.catena.2012.06.009, 2012.
Asam, Z. U., Kaila, A., Nieminen, M., Sarkkola, S., O'Driscoll, C., O'Connor,
M., Sana, A., Rodgers, M., and Xiao, L. W.: Assessment of phosphorus
retention efficiency of blanket peat buffer areas using a laboratory flume
approach, Ecol. Eng., 49, 160–169, https://doi.org/10.1016/j.ecoleng.2012.08.020,
2012.
Baker, A.: Spectrophotometric discrimination of river dissolved organic
matter, Hydrol. Process., 16, 3203–3213, https://doi.org/10.1002/hyp.1097, 2002a.
Baker, A.: Fluorescence properties of some farm wastes: implications for
water quality monitoring, Water Res., 36, 189–195, 2002b.
Barker, J. D., Sharp, M. J., and Turner, R. J.: Using synchronous
fluorescence spectroscopy and principal components analysis to monitor
dissolved organic matter dynamics in a glacier system, Hydrol. Process., 23,
1487–1500, https://doi.org/10.1002/hyp.7274, 2009.
Berthelot, M. P. E.: Berthelot's reaction mechanism, Report Chim Appl., 384,
p. 284, 1859.
Birdwell, J. E. and Engel, A. S.: Characterization of dissolved organic
matter in cave and spring waters using UV-Vis absorbance and fluorescence
spectroscopy, Org. Geochem., 41, 270–280,
https://doi.org/10.1016/j.orggeochem.2009.11.002, 2010.
Blanchard, P. E. and Lerch, R. N.: Watershed vulnerability to losses of
agricultural chemicals: interactions of chemistry, hydrology, and land-use,
Environ. Sci. Technol., 34, 3315–3322, https://doi.org/10.1021/es991115+, 2000.
Buda, A. R. and DeWalle, D. R.: Dynamics of stream nitrate sources and flow
pathways during stormflows on urban, forest and agricultural watersheds in
central Pennsylvania, USA, Hydrol. Process., 23, 3292–3305,
https://doi.org/10.1002/hyp.7423, 2009.
Bull, I. D., Van Bergen, P. F., Poulton, P. R., and Evershed, R. P.: Organic
geochemical studies of soils from the Rothamsted Classical Experiments – II,
Soils from the Hoosfield Spring Barley Experiment treated with different
quantities of manure, Org. Geochem., 28, 11–26, 1998.
Bull, I. D., Lockheart, M. J., Elhmmali, M. M., Roberts, D. J., and Evershed,
R. P.: The origin of faeces by means of biomarker detection, Environ. Int.,
27, 647–654, 2002.
Burow, K. R., Nolan, B. T., Rupert, M. G., and Dubrovsky, N. M.: Nitrate in
groundwater of the United States, 1991–2003, Environ. Sci. Technol., 44,
4988–4997, https://doi.org/10.1021/es100546y, 2010.
Chadwick, D. R. and Chen, S.: Manures, in: Agriculature, Hydrology and Water
Quality, edited by: Haygarth, P. M. and C., J. S., CAB International,
Wallingford, UK, 57–82, 2003.
Chambers, B. J., Smith, K. A., and Pain, B. F.: Strategies to encourage
better use of nitrogen in animal manures, Soil Use Manage., 16, 157–161,
2000.
Coelho, B. B., Lapen, D., Murray, R., Topp, E., Bruin, A., and Khan, B.:
Nitrogen loading to offsite waters from liquid swine manure application under
different drainage and tillage practices, Agr. Water Manage., 104, 40–50,
https://doi.org/10.1016/j.agwat.2011.11.014, 2012.
CSF Evidence Team: Catchment Sensitive Farming ECSFDI Phase 1 & 2, Full
Evaluation Report, London, 2011.
Delconte, C. A., Sacchi, E., Racchetti, E., Bartoli, M., Mas-Pla, J., and Re,
V.: Nitrogen inputs to a river course in a heavily impacted watershed:
a combined hydrochemical and isotopic evaluation (Oglio River Basin, N
Italy), Sci. Total Environ., 466, 924–938,
https://doi.org/10.1016/j.scitotenv.2013.07.092, 2014.
Delpla, I., Baures, E., Jung, A.-V., and Thomas, O.: Impacts of rainfall
events on runoff water quality in an agricultural environment in temperate
areas, Sci. Total Environ., 409, 1683–1688,
https://doi.org/10.1016/j.scitotenv.2011.01.033, 2011.
Diaz, R. J. and Rosenberg, R.: Spreading dead zones and consequences for
marine ecosystems, Science, 321, 926–929, https://doi.org/10.1126/science.1156401,
2008.
Dungait, J. A. J., Cardenas, L. M., Blackwell, M. S. A., Wu, L., Withers,
P. J. A., Chadwick, D. R., Bol, R., Murray, P. J., Macdonald, A. J.,
Whitmore, A. P., and Goulding, K. W. T.: Advances in the understanding of
nutrient dynamics and management in UK agriculture, Sci. Total Environ., 434,
39–50, https://doi.org/10.1016/j.scitotenv.2012.04.029, 2012.
Durand, P., Breuer, L., and Johnes, P. J.: Nitrogen process in aquatic
systems, in: The European Nitrogen Assessment: Sources, Effects and
Policy Perspectives, edited by: Sutton, M. A., Howard, C. M.,
Erisman, J. W., Billen, G., Bleeker, A., Grennfelt, P., van
Grinsven, H., and Grizzetti, B., Cambridge University Press,
Cambridge, 126–146, 2011.
Eastman, M., Gollamudi, A., Stampfli, N., Madramootoo, C. A., and Sarangi,
A.: Comparative evaluation of phosphorus losses from subsurface and naturally
drained agricultural fields in the Pike River watershed of Quebec, Canada,
Agr. Water Manage., 97, 596–604, https://doi.org/10.1016/j.agwat.2009.11.010, 2010.
Edwards, A. C., Watson, H. A., and Cook, Y. E. M.: Source strengths,
transport pathways and delivery mechanisms of nutrients, suspended solids and
coliforms within a small agricultural headwater catchment, Sci. Total
Environ., 434, 123–129, https://doi.org/10.1016/j.scitotenv.2011.10.055, 2012.
Elhmmali, M. M., Roberts, D. J., and Evershed, R. P.: Combined analysis of
bile acids and sterols/stanols from riverine particulates to assess sewage
discharges and other fecal sources, Environ. Sci. Technol., 34, 39–46, 2000.
Evans, D. J. and Johnes, P. J.: Physico-chemical controls on phosphorus
cycling in two lowland streams. Part 1 – The water column, Sci. Total
Environ., 329, 145–163, 2004.
Evershed, R. P., Bethell, P. H., Reynolds, P. J., and Walsh, N. J.:
5β-Stigmastanol and Related 5β-Stanols as Biomarkers of Manuring:
Analysis of Modern Experimental Material and Assessment of the Archaeological
Potential, J. Archaeol. Sci., 24, 485–495, https://doi.org/10.1006/jasc.1996.0132,
1997.
Foy, R. H. and Kirk, M.: Agriculture and water-quality – a regional study,
J. Chart. Inst. Water E., 9, 247–256, 1995.
Gao, B., Walter, M. T., Steenhuis, T. S., Hogarth, W. L., and Parlange,
J. Y.: Rainfall induced chemical transport from soil to runoff: theory and
experiments, J. Hydrol., 295, 291–304, https://doi.org/10.1016/j.jhydrol.2004.03.026,
2004.
Granger, S. J., Bol, R., Dixon, L., Naden, P. S., Old, G. H., Marsh, J. K.,
Bilotta, G., Brazier, R., White, S. M., and Haygarth, P. M.: Assessing
multiple novel tracers to improve the understanding of the contribution of
agricultural farm waste to diffuse water pollution, J. Environ. Monitor., 12,
1159–1169, https://doi.org/10.1039/b915929k, 2010.
Guo, T., Wang, Q., Li, D., and Wu, L.: Sediment and solute transport on soil
slope under simultaneous influence of rainfall impact and scouring flow,
Hydrol. Process., 24, 1446–1454, https://doi.org/10.1002/hyp.7605, 2010.
Haygarth, P. M., Wood, F. L., Heathwaite, A. L., and Butler, P. J.:
Phosphorus dynamics observed through increasing scales in a nested
headwater-to-river channel study, Sci. Total Environ., 344, 83–106, 2005.
Haygarth, P. M., Page, T. J. C., Beven, K. J., Freer, J., Joynes, A., Butler,
P., Wood, G. A., and Owens, P. N.: Scaling up the phosphorus signal from soil
hillslopes to headwater catchments, Freshwater Biol., 57, 7–25,
https://doi.org/10.1111/j.1365-2427.2012.02748.x, 2012.
Heathwaite, A. L. and Johnes, P. J.: Contribution of nitrogen species and
phosphorus fractions to stream water quality in agricultural catchments,
Hydrol. Process., 10, 971–983,
https://doi.org/10.1002/(sici)1099-1085(199607)10:7<971::aid-hyp351>3.0.co;2-n,
1996.
HELCOM: Eutrophication in the Baltic Sea: An integrated assessment of the
effects of nutrient enrichment in the Baltic Sea Region, Baltic Marine
Environment Protection Commission Helsinki, Finland, 2009.
Hudson, N., Baker, A., and Reynolds, D.: Fluorescence analysis of dissolved
organic matter in natural, waste and polluted waters – a review, River Res.
Appl., 23, 631–649, https://doi.org/10.1002/rra.1005, 2007.
Johnes, P. J. and Burt, T. P.: Water-quality trends in the windrush catchment
– nitrogen speciation and sediment interactions, in: Sediment and Stream
Water Quality in a Changing Environment: Trends and Explanation, IAHS
Publications, Wallingford, UK, 203, 349–357, 1991.
Jones, D. L., Healey, J. R., Willett, V. B., Farrar, J. F., and Hodge, A.:
Dissolved organic nitrogen uptake by plants – an important N uptake
pathway?, Soil Biol. Biochem., 37, 413–423,
https://doi.org/10.1016/j.soilbio.2004.08.008, 2005.
Khaleel, R., Reddy, K. R., and Overcash, M. R.: Transport of potential
pollutants in runoff water from land areas receiving animal wastes –
a review, Water Res., 14, 421–436, 1980.
Kirkby, M. J.: Infiltration, throughflow and overland flow, in: Water, Earth
and Man a Synthesis of Hydrology Geomorphology and Socio-Economic Geography,
edited by: Chorley, R. J., Methuen and Co. Ltd., London, UK, 215–227, 1969.
Lakowicz, J. R.: Principles of Fluorescence Spectroscopy, Plenum, New York,
1983.
Leeming, R., Ball, A., Ashbolt, N., and Nichols, P.: Using faecal sterols
from humans and animals to distinguish faecal pollution in receiving waters,
Water Res., 30, 2893–2900, 1996.
Lloyd, C. E. M., Michaelides, K., Chadwick, D. R., Dungait, J. A. J., and
Evershed, R. P.: Tracing the flow-driven vertical transport of
livestock-derived organic matter through soil using biomarkers, Org.
Geochem., 43, 56–66, https://doi.org/10.1016/j.orggeochem.2011.11.001, 2012.
Malone, R. W., Weatherington-Rice, J., Shipitalo, M. J., Fausey, N., Ma,
L. W., Ahuja, L. R., Wauchope, R. D., and Ma, Q. L.: Herbicide leaching as
affected by macropore flow and within-storm rainfall intensity variation:
a RZWQM simulation, Pest Manag. Sci., 60, 277–285, https://doi.org/10.1002/ps.791,
2004.
Melo, A., Pinto, E., Aguiar, A., Mansilha, C., Pinho, O., and Ferreira,
I. M. P. L. V. O.: Impact of intensive horticulture practices on groundwater
content of nitrates, sodium, potassium, and pesticides, Environ. Monit.
Assess., 184, 4539–4551, https://doi.org/10.1007/s10661-011-2283-4, 2012.
Michaelides, K., Ibraim, I., Nord, G., and Esteves, M.: Tracing sediment
redistribution across a break in slope using rare earth elements, Earth Surf.
Proc. Land., 35, 575–587, https://doi.org/10.1002/esp.1956, 2010.
Michaelides, K., Lister, D., Wainwright, J., and Parsons, A .J.: Linking
runoff and erosion dynamics to nutrient fluxes in a degrading dryland
landscape, J. Geophys. Res., 117, G00N15, https://doi.org/10.1029/2012JG002071, 2012.
Mitsch, W. J., Day, J. W., Gilliam, J. W., Groffman, P. M., Hey, D. L.,
Randall, G. W., and Wang, N. M.: Reducing nitrogen loading to the Gulf of
Mexico from the Mississippi River Basin: strategies to counter a persistent
ecological problem, Bioscience, 51, 373–388,
https://doi.org/10.1641/0006-3568(2001)051[0373:rnlttg]2.0.co;2, 2001.
Montenegro, A. A. A., Abrantes, J. R. C. B., de Lima, J. L. M. P., Singh,
V. P., and Santos, T. E. M.: Impact of mulching on soil and water dynamics
under intermittent simulated rainfall, Catena, 109, 139–149,
https://doi.org/10.1016/j.catena.2013.03.018, 2013.
Morari, F., Lugato, E., Polese, R., Berti, A., and Giardini, L.: Nitrate
concentrations in groundwater under contrasting agricultural management
practices in the low plains of Italy, Agr. Ecosyst. Environ., 147, 47–56,
https://doi.org/10.1016/j.agee.2011.03.001, 2012.
Naden, P. S., Old, G. H., Eliot-Laize, C., Granger, S. J., Hawkins, J. M. B.,
Bol, R., and Haygarth, P.: Assessment of natural fluorescence as a tracer of
diffuse agricultural pollution from slurry spreading on intensely-farmed
grasslands, Water Res., 44, 1701–1712, 2010.
Nash, D., Leeming, R., Clemow, L., Hannah, M., Halliwell, D., and Allen, D.:
Quantitative determination of sterols and other alcohols in overland flow
from grazing land and possible source materials, Water Res., 39, 2964–2978,
https://doi.org/10.1016/j.watres.2005.04.063, 2005.
Ohno, T.: Fluorescence inner-filtering correction for determining the
humification index of dissolved organic matter, Environ. Sci. Technol., 36,
742–746, https://doi.org/10.1021/es0155276, 2002.
Old, G. H., Naden, P. S., Granger, S. J., Bilotta, G. S., Brazier, R. E.,
Macleod, C. J. A., Krueger, T., Bol, R., Hawkins, J. M. B., Haygarth, P., and
Freer, J.: A novel application of natural fluorescence to understand the
sources and transport pathways of pollutants from livestock farming in small
headwater catchments, Sci. Total Environ., 417, 169–182,
https://doi.org/10.1016/j.scitotenv.2011.12.013, 2012.
Osterman, L. E., Poore, R. Z., Swarzenski, P. W., Senn, D. B., and DiMarco,
S. F.: The 20th-century development and expansion of Louisiana shelf hypoxia,
Gulf of Mexico, Geo-Mar. Lett., 29, 405–414,
https://doi.org/10.1007/s00367-009-0158-2, 2009.
Peukert, S., Griffith, B. A., Murray, P. J., Macleod, C. J. A., and Brazier,
R. E.: Intensive management in grasslands causes diffuse water pollution at
the farm scale, J. Environ. Qual., 43, 2009–2023,
https://doi.org/10.2134/jeq2014.04.0193, 2014.
Peuravuori, J., Koivikko, R., and Pihlaja, K.: Characterization.
differentiation and classification of aquatic humic matter separated with
different sorbents: synchronous scanning fluorescence spectroscopy, Water
Res., 36, 4552–4562, 2002.
Pretty, J. N., Brett, C., Gee, D., Hine, R. E., Mason, C. F., Morison,
J. I. L., Raven, H., Rayment, M. D., and van der Bijl, G.: An assessment of
the total external costs of UK agriculture, Agr. Syst., 65, 113–136,
https://doi.org/10.1016/s0308-521x(00)00031-7, 2000.
Quemada, M., Baranski, M., Nobel-de Lange, M. N. J., Vallejo, A., and Cooper,
J. M.: Meta-analysis of strategies to control nitrate leaching in irrigated
agricultural systems and their effects on crop yield, Agr. Ecosyst. Environ.,
174, 1–10, https://doi.org/10.1016/j.agee.2013.04.018, 2013.
Rozemeijer, J. C. and Broers, H. P.: The groundwater contribution to surface
water contamination in a region with intensive agricultural land use
(Noord-Brabant, the Netherlands), Environ. Pollut., 148, 695–706,
https://doi.org/10.1016/j.envpol.2007.01.028, 2007.
Sutton, M. A.: The European Nitrogen Assessment: Sources, Effects, and Policy
Perspectives, Cambridge University Press, Cambridge, 612 pp., 2011.
van Bergen, P. F., Bull, I. D., Poulton, P. R., and Evershed, R. P.: Organic
geochemical studies of soils from the Rothamsted classical experiments –
I. Total lipid extracts, solvent insoluble residues and humic acids from
Broadbalk wilderness, Org. Geochem., 26, 117–135, 1997.
Vinolas, L. C., Healey, J. R., and Jones, D. L.: Kinetics of soil microbial
uptake of free amino acids, Biol. Fert. Soils, 33, 67–74,
https://doi.org/10.1007/s003740000291, 2001.
Vitousek, P. M., Naylor, R., Crews, T., David, M. B., Drinkwater, L. E.,
Holland, E., Johnes, P. J., Katzenberger, J., Martinelli, L. A., Matson,
P. A., Nziguheba, G., Ojima, D., Palm, C. A., Robertson, G. P., Sanchez,
P. A., Townsend, A. R., and Zhang, F. S.: Nutrient imbalances in agricultural
development, Science, 324, 1519–1520, https://doi.org/:10.1126/science.1170261, 2009.
Willett, V. B., Reynolds, B. A., Stevens, P. A., Ormerod, S. J., and Jones,
D. L.: Dissolved organic nitrogen regulation in freshwaters, J. Environ.
Qual., 33, 201–209, 2004.
Zhang, X. C., Norton, D., and Nearing, M. A.: Chemical transfer from soil
solution to surface runoff, Water Resour. Res., 33, 809–815,
https://doi.org/10.1029/96wr03908, 1997.
Short summary
Our interdisciplinary research brings together methodologies from hydrology, soil science and biogeochemistry to address key questions about the transport of cattle slurry in the environment. The paper provides a novel approach to trace dissolved and particulate components of cattle slurry through an experimental hillslope system. This work provides one of the first examples of using biomarkers to assess the effects of slope gradient and rainfall intensity on the movement of slurry derived-OM.
Our interdisciplinary research brings together methodologies from hydrology, soil science and...
Altmetrics
Final-revised paper
Preprint