Articles | Volume 8, issue 9
https://doi.org/10.5194/bg-8-2621-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/bg-8-2621-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
19 Sep 2011
Research article |
| 19 Sep 2011
Transport and fate of hexachlorocyclohexanes in the oceanic air and surface seawater
Z. Xie
Helmholtz-Zentrum Geesthacht, Centre for Materials and Coastal Research GmbH, Institute of Coastal Research, Max-Planck Street 1, 21502 Geesthacht, Germany
B. P. Koch
Alfred Wegener Institute for Polar and Marine Research, Bremerhaven, Germany
University of Applied Sciences, Bremerhaven, Germany
A. Möller
Helmholtz-Zentrum Geesthacht, Centre for Materials and Coastal Research GmbH, Institute of Coastal Research, Max-Planck Street 1, 21502 Geesthacht, Germany
R. Sturm
Helmholtz-Zentrum Geesthacht, Centre for Materials and Coastal Research GmbH, Institute of Coastal Research, Max-Planck Street 1, 21502 Geesthacht, Germany
R. Ebinghaus
Helmholtz-Zentrum Geesthacht, Centre for Materials and Coastal Research GmbH, Institute of Coastal Research, Max-Planck Street 1, 21502 Geesthacht, Germany
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Ryo Dobashi and David T. Ho
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Valérie Gros, Bernard Bonsang, Roland Sarda-Estève, Anna Nikolopoulos, Katja Metfies, Matthias Wietz, and Ilka Peeken
Biogeosciences, 20, 851–867, https://doi.org/10.5194/bg-20-851-2023, https://doi.org/10.5194/bg-20-851-2023, 2023
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The oceans are both sources and sinks for trace gases important for atmospheric chemistry and marine ecology. Here, we quantified selected trace gases (including the biological metabolites dissolved dimethyl sulfide, methanethiol and isoprene) along a 2500 km transect from the North Atlantic to the Arctic Ocean. In the context of phytoplankton and bacterial communities, our study suggests that methanethiol (rarely measured before) might substantially influence ocean–atmosphere cycling.
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Biogeosciences, 20, 439–449, https://doi.org/10.5194/bg-20-439-2023, https://doi.org/10.5194/bg-20-439-2023, 2023
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Water-soluble organic nitrogen (WSON) in marine aerosols is important for biogeochemical cycling of bioelements. Our shipboard measurements suggested that reactive nitrogen produced and exuded by nitrogen-fixing microorganisms in surface seawater likely contributed to the formation of WSON aerosols in the subtropical North Pacific. This study provides new implications for the role of marine microbial activity in the formation of WSON aerosols in the ocean surface.
Lukas Eickhoff, Maddalena Bayer-Giraldi, Naama Reicher, Yinon Rudich, and Thomas Koop
Biogeosciences, 20, 1–14, https://doi.org/10.5194/bg-20-1-2023, https://doi.org/10.5194/bg-20-1-2023, 2023
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The formation of ice is an important process in Earth’s atmosphere, biosphere, and cryosphere, in particular in polar regions. Our research focuses on the influence of the sea ice diatom Fragilariopsis cylindrus and of molecules produced by it upon heterogenous ice nucleation. For that purpose, we studied the freezing of tiny droplets containing the diatoms in a microfluidic device. Together with previous studies, our results suggest a common freezing behaviour of various sea ice diatoms.
Lucía Gutiérrez-Loza, Erik Nilsson, Marcus B. Wallin, Erik Sahlée, and Anna Rutgersson
Biogeosciences, 19, 5645–5665, https://doi.org/10.5194/bg-19-5645-2022, https://doi.org/10.5194/bg-19-5645-2022, 2022
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The exchange of CO2 between the ocean and the atmosphere is an essential aspect of the global carbon cycle and is highly relevant for the Earth's climate. In this study, we used 9 years of in situ measurements to evaluate the temporal variability in the air–sea CO2 fluxes in the Baltic Sea. Furthermore, using this long record, we assessed the effect of atmospheric and water-side mechanisms controlling the efficiency of the air–sea CO2 exchange under different wind-speed conditions.
Li Zhou, Dennis Booge, Miming Zhang, and Christa A. Marandino
Biogeosciences, 19, 5021–5040, https://doi.org/10.5194/bg-19-5021-2022, https://doi.org/10.5194/bg-19-5021-2022, 2022
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Trace gas air–sea exchange exerts an important control on air quality and climate, especially in the Southern Ocean (SO). Almost all of the measurements there are skewed to summer, but it is essential to expand our measurement database over greater temporal and spatial scales. Therefore, we report measured concentrations of dimethylsulfide (DMS, as well as related sulfur compounds) and isoprene in the Atlantic sector of the SO. The observations of isoprene are the first in the winter in the SO.
Theresa Barthelmeß and Anja Engel
Biogeosciences, 19, 4965–4992, https://doi.org/10.5194/bg-19-4965-2022, https://doi.org/10.5194/bg-19-4965-2022, 2022
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Greenhouse gases released by human activity cause a global rise in mean temperatures. While scientists can predict how much of these gases accumulate in the atmosphere based on not only human-derived sources but also oceanic sinks, it is rather difficult to predict the major influence of coastal ecosystems. We provide a detailed study on the occurrence, composition, and controls of substances that suppress gas exchange. We thus help to determine what controls coastal greenhouse gas fluxes.
Daniel J. Ford, Gavin H. Tilstone, Jamie D. Shutler, and Vassilis Kitidis
Biogeosciences, 19, 4287–4304, https://doi.org/10.5194/bg-19-4287-2022, https://doi.org/10.5194/bg-19-4287-2022, 2022
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This study explores the seasonal, inter-annual, and multi-year drivers of the South Atlantic air–sea CO2 flux. Our analysis showed seasonal sea surface temperatures dominate in the subtropics, and the subpolar regions correlated with biological processes. Inter-annually, the El Niño–Southern Oscillation correlated with the CO2 flux by modifying sea surface temperatures and biological activity. Long-term trends indicated an important biological contribution to changes in the air–sea CO2 flux.
Laique M. Djeutchouang, Nicolette Chang, Luke Gregor, Marcello Vichi, and Pedro M. S. Monteiro
Biogeosciences, 19, 4171–4195, https://doi.org/10.5194/bg-19-4171-2022, https://doi.org/10.5194/bg-19-4171-2022, 2022
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Based on observing system simulation experiments using a mesoscale-resolving model, we found that to significantly improve uncertainties and biases in carbon dioxide (CO2) mapping in the Southern Ocean, it is essential to resolve the seasonal cycle (SC) of the meridional gradient of CO2 through high frequency (at least daily) observations that also span the region's meridional axis. We also showed that the estimated SC anomaly and mean annual CO2 are highly sensitive to seasonal sampling biases.
Liliane Merlivat, Michael Hemming, Jacqueline Boutin, David Antoine, Vincenzo Vellucci, Melek Golbol, Gareth A. Lee, and Laurence Beaumont
Biogeosciences, 19, 3911–3920, https://doi.org/10.5194/bg-19-3911-2022, https://doi.org/10.5194/bg-19-3911-2022, 2022
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We use in situ high-temporal-resolution measurements of dissolved inorganic carbon and atmospheric parameters at the air–sea interface to analyse phytoplankton bloom initiation identified as the net rate of biological carbon uptake in the Mediterranean Sea. The shift from wind-driven to buoyancy-driven mixing creates conditions for blooms to begin. Active mixing at the air–sea interface leads to the onset of the surface phytoplankton bloom due to the relaxation of wind speed following storms.
Léa Olivier, Jacqueline Boutin, Gilles Reverdin, Nathalie Lefèvre, Peter Landschützer, Sabrina Speich, Johannes Karstensen, Matthieu Labaste, Christophe Noisel, Markus Ritschel, Tobias Steinhoff, and Rik Wanninkhof
Biogeosciences, 19, 2969–2988, https://doi.org/10.5194/bg-19-2969-2022, https://doi.org/10.5194/bg-19-2969-2022, 2022
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We investigate the impact of the interactions between eddies and the Amazon River plume on the CO2 air–sea fluxes to better characterize the ocean carbon sink in winter 2020. The region is a strong CO2 sink, previously underestimated by a factor of 10 due to a lack of data and understanding of the processes responsible for the variability in ocean carbon parameters. The CO2 absorption is mainly driven by freshwater from the Amazon entrained by eddies and by the winter seasonal cooling.
Hana Jurikova, Osamu Abe, Fuh-Kwo Shiah, and Mao-Chang Liang
Biogeosciences, 19, 2043–2058, https://doi.org/10.5194/bg-19-2043-2022, https://doi.org/10.5194/bg-19-2043-2022, 2022
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We studied the isotopic composition of oxygen dissolved in seawater in the South China Sea. This tells us about the origin of oxygen in the water column, distinguishing between biological oxygen produced by phytoplankton communities and atmospheric oxygen entering seawater through gas exchange. We found that the East Asian Monsoon plays an important role in determining the amount of oxygen produced vs. consumed by the phytoplankton, as well as in inducing vertical water mass mixing.
Richard P. Sims, Michael Bedington, Ute Schuster, Andrew J. Watson, Vassilis Kitidis, Ricardo Torres, Helen S. Findlay, James R. Fishwick, Ian Brown, and Thomas G. Bell
Biogeosciences, 19, 1657–1674, https://doi.org/10.5194/bg-19-1657-2022, https://doi.org/10.5194/bg-19-1657-2022, 2022
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The amount of carbon dioxide (CO2) being absorbed by the ocean is relevant to the earth's climate. CO2 values in the coastal ocean and estuaries are not well known because of the instrumentation used. We used a new approach to measure CO2 across the coastal and estuarine zone. We found that CO2 and salinity were linked to the state of the tide. We used our CO2 measurements and model salinity to predict CO2. Previous studies overestimate how much CO2 the coastal ocean draws down at our site.
Thi Tuyet Trang Chau, Marion Gehlen, and Frédéric Chevallier
Biogeosciences, 19, 1087–1109, https://doi.org/10.5194/bg-19-1087-2022, https://doi.org/10.5194/bg-19-1087-2022, 2022
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Air–sea CO2 fluxes and associated uncertainty over the open ocean to coastal shelves are estimated with a new ensemble-based reconstruction of pCO2 trained on observation-based data. The regional distribution and seasonality of CO2 sources and sinks are consistent with those suggested in previous studies as well as mechanisms discussed therein. The ensemble-based uncertainty field allows identifying critical regions where improvements in pCO2 and air–sea CO2 flux estimates should be a priority.
Charel Wohl, Anna E. Jones, William T. Sturges, Philip D. Nightingale, Brent Else, Brian J. Butterworth, and Mingxi Yang
Biogeosciences, 19, 1021–1045, https://doi.org/10.5194/bg-19-1021-2022, https://doi.org/10.5194/bg-19-1021-2022, 2022
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We measured concentrations of five different organic gases in seawater in the high Arctic during summer. We found higher concentrations near the surface of the water column (top 5–10 m) and in areas of partial ice cover. This suggests that sea ice influences the concentrations of these gases. These gases indirectly exert a slight cooling effect on the climate, and it is therefore important to measure the levels accurately for future climate predictions.
Alain de Verneil, Zouhair Lachkar, Shafer Smith, and Marina Lévy
Biogeosciences, 19, 907–929, https://doi.org/10.5194/bg-19-907-2022, https://doi.org/10.5194/bg-19-907-2022, 2022
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The Arabian Sea is a natural CO2 source to the atmosphere, but previous work highlights discrepancies between data and models in estimating air–sea CO2 flux. In this study, we use a regional ocean model, achieve a flux closer to available data, and break down the seasonal cycles that impact it, with one result being the great importance of monsoon winds. As demonstrated in a meta-analysis, differences from data still remain, highlighting the great need for further regional data collection.
Jesse M. Vance, Kim Currie, John Zeldis, Peter W. Dillingham, and Cliff S. Law
Biogeosciences, 19, 241–269, https://doi.org/10.5194/bg-19-241-2022, https://doi.org/10.5194/bg-19-241-2022, 2022
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Long-term monitoring is needed to detect changes in our environment. Time series of ocean carbon have aided our understanding of seasonal cycles and provided evidence for ocean acidification. Data gaps are inevitable, yet no standard method for filling gaps exists. We present a regression approach here and compare it to seven other common methods to understand the impact of different approaches when assessing seasonal to climatic variability in ocean carbon.
Daniel J. Ford, Gavin H. Tilstone, Jamie D. Shutler, and Vassilis Kitidis
Biogeosciences, 19, 93–115, https://doi.org/10.5194/bg-19-93-2022, https://doi.org/10.5194/bg-19-93-2022, 2022
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This study identifies the most accurate biological proxy for the estimation of seawater pCO2 fields, which are key to assessing the ocean carbon sink. Our analysis shows that the net community production (NCP), the balance between photosynthesis and respiration, was more accurate than chlorophyll a within a neural network scheme. The improved pCO2 estimates, based on NCP, identified the South Atlantic Ocean as a net CO2 source, compared to a CO2 sink using chlorophyll a.
Birthe Zäncker, Michael Cunliffe, and Anja Engel
Biogeosciences, 18, 2107–2118, https://doi.org/10.5194/bg-18-2107-2021, https://doi.org/10.5194/bg-18-2107-2021, 2021
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Fungi are found in numerous marine environments. Our study found an increased importance of fungi in the Ionian Sea, where bacterial and phytoplankton counts were reduced, but organic matter was still available, suggesting fungi might benefit from the reduced competition from bacteria in low-nutrient, low-chlorophyll (LNLC) regions.
Jon Olafsson, Solveig R. Olafsdottir, Taro Takahashi, Magnus Danielsen, and Thorarinn S. Arnarson
Biogeosciences, 18, 1689–1701, https://doi.org/10.5194/bg-18-1689-2021, https://doi.org/10.5194/bg-18-1689-2021, 2021
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The Atlantic north of 50° N is an intense ocean sink area for atmospheric CO2. Observations in the vicinity of Iceland reveal a previously unrecognized Arctic contribution to the North Atlantic CO2 sink. Sustained CO2 influx to waters flowing from the Arctic Ocean is linked to their excess alkalinity derived from sources in the changing Arctic. The results relate to the following question: will the North Atlantic continue to absorb CO2 in the future as it has in the past?
Wei-Lei Wang, Guisheng Song, François Primeau, Eric S. Saltzman, Thomas G. Bell, and J. Keith Moore
Biogeosciences, 17, 5335–5354, https://doi.org/10.5194/bg-17-5335-2020, https://doi.org/10.5194/bg-17-5335-2020, 2020
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Dimethyl sulfide, a volatile compound produced as a byproduct of marine phytoplankton activity, can be emitted to the atmosphere via gas exchange. In the atmosphere, DMS is oxidized to cloud condensation nuclei, thus contributing to cloud formation. Therefore, oceanic DMS plays an important role in regulating the planet's climate by influencing the radiation budget. In this study, we use an artificial neural network model to update the global DMS climatology and estimate the sea-to-air flux.
Yuri Galletti, Silvia Becagli, Alcide di Sarra, Margherita Gonnelli, Elvira Pulido-Villena, Damiano M. Sferlazzo, Rita Traversi, Stefano Vestri, and Chiara Santinelli
Biogeosciences, 17, 3669–3684, https://doi.org/10.5194/bg-17-3669-2020, https://doi.org/10.5194/bg-17-3669-2020, 2020
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This paper reports the first data about atmospheric deposition of dissolved organic matter (DOM) on the island of Lampedusa. It also shows the implications for the surface marine layer by studying the impact of atmospheric organic carbon deposition in the marine ecosystem. It is a preliminary study, but it is pioneering and important for having new data that can be crucial in order to understand the impact of atmospheric deposition on the marine carbon cycle in a global climate change scenario.
Charel Wohl, Ian Brown, Vassilis Kitidis, Anna E. Jones, William T. Sturges, Philip D. Nightingale, and Mingxi Yang
Biogeosciences, 17, 2593–2619, https://doi.org/10.5194/bg-17-2593-2020, https://doi.org/10.5194/bg-17-2593-2020, 2020
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The oceans represent a poorly understood source of organic carbon to the atmosphere. In this paper, we present ship-based measurements of specific compounds in ambient air and seawater of the Southern Ocean. We present fluxes of these gases between air and sea at very high resolution. The data also contain evidence for day and night variations in some of these compounds. These measurements can be used to better understand the role of the Southern Ocean in the cycling of these compounds.
Rebecca L. Jackson, Albert J. Gabric, Roger Cropp, and Matthew T. Woodhouse
Biogeosciences, 17, 2181–2204, https://doi.org/10.5194/bg-17-2181-2020, https://doi.org/10.5194/bg-17-2181-2020, 2020
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Coral reefs are a strong source of atmospheric sulfur through stress-induced emissions of dimethylsulfide (DMS). This biogenic sulfur can influence aerosol and cloud properties and, consequently, the radiative balance over the ocean. DMS emissions may therefore help to mitigate coral physiological stress via increased low-level cloud cover and reduced sea surface temperature. The importance of DMS in coral physiology and climate is reviewed and the implications for coral bleaching are discussed.
Louise Delaigue, Helmuth Thomas, and Alfonso Mucci
Biogeosciences, 17, 547–566, https://doi.org/10.5194/bg-17-547-2020, https://doi.org/10.5194/bg-17-547-2020, 2020
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This paper reports on the first compilation and analysis of the surface water pCO2 distribution in the Saguenay Fjord, the southernmost subarctic fjord in the Northern Hemisphere, and thus fills a significant knowledge gap in current regional estimates of estuarine CO2 emissions.
Tim Fischer, Annette Kock, Damian L. Arévalo-Martínez, Marcus Dengler, Peter Brandt, and Hermann W. Bange
Biogeosciences, 16, 2307–2328, https://doi.org/10.5194/bg-16-2307-2019, https://doi.org/10.5194/bg-16-2307-2019, 2019
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We investigated air–sea gas exchange in oceanic upwelling regions for the case of nitrous oxide off Peru. In this region, routine concentration measurements from ships at 5 m or 10 m depth prove to overestimate surface (bulk) concentration. Thus, standard estimates of gas exchange will show systematic error. This is due to very shallow stratified layers that inhibit exchange between surface water and waters below and can exist for several days. Maximum bias occurs in moderate wind conditions.
Mingxi Yang, Thomas G. Bell, Ian J. Brown, James R. Fishwick, Vassilis Kitidis, Philip D. Nightingale, Andrew P. Rees, and Timothy J. Smyth
Biogeosciences, 16, 961–978, https://doi.org/10.5194/bg-16-961-2019, https://doi.org/10.5194/bg-16-961-2019, 2019
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We quantify the emissions and uptake of the greenhouse gases carbon dioxide and methane from the coastal seas of the UK over 1 year using the state-of-the-art eddy covariance technique. Our measurements show how these air–sea fluxes vary twice a day (tidal), diurnally (circadian) and seasonally. We also estimate the air–sea gas transfer velocity, which is essential for modelling and predicting coastal air-sea exchange.
Riley X. Brady, Nicole S. Lovenduski, Michael A. Alexander, Michael Jacox, and Nicolas Gruber
Biogeosciences, 16, 329–346, https://doi.org/10.5194/bg-16-329-2019, https://doi.org/10.5194/bg-16-329-2019, 2019
Stelios Myriokefalitakis, Akinori Ito, Maria Kanakidou, Athanasios Nenes, Maarten C. Krol, Natalie M. Mahowald, Rachel A. Scanza, Douglas S. Hamilton, Matthew S. Johnson, Nicholas Meskhidze, Jasper F. Kok, Cecile Guieu, Alex R. Baker, Timothy D. Jickells, Manmohan M. Sarin, Srinivas Bikkina, Rachel Shelley, Andrew Bowie, Morgane M. G. Perron, and Robert A. Duce
Biogeosciences, 15, 6659–6684, https://doi.org/10.5194/bg-15-6659-2018, https://doi.org/10.5194/bg-15-6659-2018, 2018
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The first atmospheric iron (Fe) deposition model intercomparison is presented in this study, as a result of the deliberations of the United Nations Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection (GESAMP; http://www.gesamp.org/) Working Group 38. We conclude that model diversity over remote oceans reflects uncertainty in the Fe content parameterizations of dust aerosols, combustion aerosol emissions and the size distribution of transported aerosol Fe.
Liliane Merlivat, Jacqueline Boutin, David Antoine, Laurence Beaumont, Melek Golbol, and Vincenzo Vellucci
Biogeosciences, 15, 5653–5662, https://doi.org/10.5194/bg-15-5653-2018, https://doi.org/10.5194/bg-15-5653-2018, 2018
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The fugacity of carbon dioxide in seawater (fCO2) was measured hourly in the surface waters of the NW Mediterranean Sea during two 3-year sequences separated by 18 years. A decrease of pH of 0.0022 yr−1 was computed. About 85 % of the accumulation of dissolved inorganic carbon (DIC) comes from chemical equilibration with increasing atmospheric CO2; the remaining 15 % accumulation is consistent with estimates of transfer of Atlantic waters through the Gibraltar Strait.
Amanda R. Fay, Nicole S. Lovenduski, Galen A. McKinley, David R. Munro, Colm Sweeney, Alison R. Gray, Peter Landschützer, Britton B. Stephens, Taro Takahashi, and Nancy Williams
Biogeosciences, 15, 3841–3855, https://doi.org/10.5194/bg-15-3841-2018, https://doi.org/10.5194/bg-15-3841-2018, 2018
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The Southern Ocean is highly under-sampled and since this region dominates the ocean sink for CO2, understanding change is critical. Here we utilize available observations to evaluate how the seasonal cycle, variability, and trends in surface ocean carbon in the well-sampled Drake Passage region compare to that of the broader subpolar Southern Ocean. Results indicate that the Drake Passage is representative of the broader region; however, additional winter observations would improve comparisons.
Cui-Ci Sun, Martin Sperling, and Anja Engel
Biogeosciences, 15, 3577–3589, https://doi.org/10.5194/bg-15-3577-2018, https://doi.org/10.5194/bg-15-3577-2018, 2018
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Biogenic gel particles such as transparent exopolymer particles (TEP) and Coomassie stainable particles (CSP) are important components in the sea-surface microlayer (SML). Their potential role in air–sea gas exchange and in primary organic aerosol emission has generated considerable research interest. Our wind wave channel experiment revealed how wind speed controls the accumulation and size distribution of biogenic gel particles in the SML.
N. Precious Mongwe, Marcello Vichi, and Pedro M. S. Monteiro
Biogeosciences, 15, 2851–2872, https://doi.org/10.5194/bg-15-2851-2018, https://doi.org/10.5194/bg-15-2851-2018, 2018
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Here we analyze seasonal cycle of CO2 biases in 10 CMIP5 models in the SO. We find two main model biases; exaggeration of primary production such that biologically driven DIC changes mainly regulates FCO2 variability, and an overestimation of the role of solubility, such that changes in temperature dominantly drive FCO2 seasonal changes to an extent of opposing biological CO2 uptake in spring. CMIP5 models show greater zonal homogeneity in the seasonal cycle of FCO2 than observational products.
Allison R. Moreno, George I. Hagstrom, Francois W. Primeau, Simon A. Levin, and Adam C. Martiny
Biogeosciences, 15, 2761–2779, https://doi.org/10.5194/bg-15-2761-2018, https://doi.org/10.5194/bg-15-2761-2018, 2018
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To bridge the missing links between variable marine elemental stoichiometry, phytoplankton physiology and carbon cycling, we embed four environmentally controlled stoichiometric models into a five-box ocean model. As predicted each model varied in its influence on the biological pump. Surprisingly, we found that variation can lead to nonlinear controls on atmospheric CO2 and carbon export, suggesting the need for further studies of ocean C : P and the impact on ocean carbon cycling.
Luke Gregor, Schalk Kok, and Pedro M. S. Monteiro
Biogeosciences, 15, 2361–2378, https://doi.org/10.5194/bg-15-2361-2018, https://doi.org/10.5194/bg-15-2361-2018, 2018
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The Southern Ocean accounts for a large portion of the variability in oceanic CO2 uptake. However, the drivers of these changes are not understood due to a lack of observations. In this study, we used an ensemble of gap-filling methods to estimate surface CO2. We found that winter was a more important driver of longer-term variability driven by changes in wind stress. Summer variability of CO2 was driven primarily by increases in primary production.
Erik T. Buitenhuis, Parvadha Suntharalingam, and Corinne Le Quéré
Biogeosciences, 15, 2161–2175, https://doi.org/10.5194/bg-15-2161-2018, https://doi.org/10.5194/bg-15-2161-2018, 2018
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Thanks to decreases in CFC concentrations, N2O is now the third-most important greenhouse gas, and the dominant contributor to stratospheric ozone depletion. Here we estimate the ocean–atmosphere N2O flux. We find that an estimate based on observations alone has a large uncertainty. By combining observations and a range of model simulations we find that the uncertainty is much reduced to 2.45 ± 0.8 Tg N yr−1, and better constrained and at the lower end of the estimate in the latest IPCC report.
Sayaka Yasunaka, Eko Siswanto, Are Olsen, Mario Hoppema, Eiji Watanabe, Agneta Fransson, Melissa Chierici, Akihiko Murata, Siv K. Lauvset, Rik Wanninkhof, Taro Takahashi, Naohiro Kosugi, Abdirahman M. Omar, Steven van Heuven, and Jeremy T. Mathis
Biogeosciences, 15, 1643–1661, https://doi.org/10.5194/bg-15-1643-2018, https://doi.org/10.5194/bg-15-1643-2018, 2018
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We estimated monthly air–sea CO2 fluxes in the Arctic Ocean and its adjacent seas north of 60° N from 1997 to 2014, after mapping pCO2 in the surface water using a self-organizing map technique. The addition of Chl a as a parameter enabled us to improve the estimate of pCO2 via better representation of its decline in spring. The uncertainty in the CO2 flux estimate was reduced, and a net annual Arctic Ocean CO2 uptake of 180 ± 130 Tg C y−1 was determined to be significant.
Alizée Roobaert, Goulven G. Laruelle, Peter Landschützer, and Pierre Regnier
Biogeosciences, 15, 1701–1720, https://doi.org/10.5194/bg-15-1701-2018, https://doi.org/10.5194/bg-15-1701-2018, 2018
Chao Zhang, Huiwang Gao, Xiaohong Yao, Zongbo Shi, Jinhui Shi, Yang Yu, Ling Meng, and Xinyu Guo
Biogeosciences, 15, 749–765, https://doi.org/10.5194/bg-15-749-2018, https://doi.org/10.5194/bg-15-749-2018, 2018
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This study compares the response of phytoplankton growth in the northwest Pacific to those in the Yellow Sea. In general, larger positive responses of phytoplankton induced by combined nutrients (in the subtropical gyre of the northwest Pacific) than those induced by a single nutrient (in the Kuroshio Extension and the Yellow Sea) from the dust are observed. We also emphasize the importance of an increase in bioavailable P stock for phytoplankton growth following dust addition.
Goulven G. Laruelle, Peter Landschützer, Nicolas Gruber, Jean-Louis Tison, Bruno Delille, and Pierre Regnier
Biogeosciences, 14, 4545–4561, https://doi.org/10.5194/bg-14-4545-2017, https://doi.org/10.5194/bg-14-4545-2017, 2017
Melchor González-Dávila, J. Magdalena Santana Casiano, and Francisco Machín
Biogeosciences, 14, 3859–3871, https://doi.org/10.5194/bg-14-3859-2017, https://doi.org/10.5194/bg-14-3859-2017, 2017
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The Mauritanian–Cap Vert upwelling is shown to be sensitive to climate change forcing on upwelling processes, which strongly affects the CO2 surface distribution, ocean acidification rates, and air–sea CO2 exchange. We confirmed an upwelling intensification, an increase in the CO2 outgassing, and an important decrease in the pH of the surface waters. Upwelling areas are poorly studied and VOS lines are shown as one of the most significant contributors to our knowledge of the ocean's response.
Cited articles
Becker, S., Halsall, C. J., Tych, W., Kallenborn, R., Su, Y., and Hung, H.: Long-term trends in atmospheric concentrations of alpha- and gamma-HCH in the Arctic provide insight into the effects of legislation and climatic fluctuations on contaminant levels, Atmos. Environ, 42, 8225–8233, 2008.
Berrojalbiz, N., Dachs, J., Del Vento, S., Ojeda, M., Valle, M., Castro-Jiménez, J., Mariani, G., Wollgast, J., and Hanke, G.: Persistent Organic Pollutants in Mediterranean Seawater and Processes Affecting Their Accumulation in Plankton, Environ. Sci. Technol., 45, 4315–4322, 2011.
Bidleman, T. F. and McConnell, L. L.: A review of field experiments to determine air-water gas exchange of persistent organic pollutants, Sci. Total Environ., 159, 101–117, 1995.
Bidleman, T. F., Cotham, W. E., Addison, R. F., and Zinck, M. E.: Organic contamination in the Northwest Atlantic atmosphere at Sable Island, Nova-Scotia, 1988–89, Chemosphere, 24, 1389–1412, 1992.
Bidleman, T. F., Walla, M. D., Roura, R., Carr, E., and Schmidt, S.: Organochlorine pesticides in the atmosphere of the Southern Ocean and Antarctica, January–March, 1990, Mar. Pollut. Bull., 26, 258–262, 1993.
Bidleman, T. F., Jantunen, L. M., Falconer, R. L., Barrie, L. A., and Fellin, P.: Decline of hexachlorocyclohexane in the Arctic atmosphere and reversal of air-sea gas-exchange, Geophys. Res. Lett., 22, 219–222, 1995.
Bidleman, T. F., Kylin, H., Jantunen, L. M., Helm, P. A., and Macdonald, R. W.: Hexachlorocyclohexanes in the Canadian Archipelago. 1. Spatial Distribution and Pathways of α-, β-, and γ-HCHs in Surface Water, Environ. Sci. Technol., 41, 2688–2695, 2007.
Breivik, K., Pacyna, J. M., and Münch, J.: Use of [alpha]-, [beta]- and [gamma]-hexachlorocyclohexane in Europe, 1970–1996, Sci. Total Environ., 239, 151–163, 1999.
Brown, T. N. and Wania, F.: Screening Chemicals for the Potential to be Persistent Organic Pollutants: A Case Study of Arctic Contaminants, Environ. Sci. Technol., 42, 5202–5209, 2008.
Bruhn, R., Lakaschus, S., and McLachlan, M. S.: Air/sea gas exchange of PCBs in the southern Baltic Sea, Atmos. Environ., 37, 3445–3454, 2003.
Cetin, B. and Odabasi, M.: Measurement of Henry's law constants of seven polybrominated diphenyl ether (PBDE) congeners as a function of temperature, Atmos. Environ., 39, 5273–5280, 2005.
Cole, J. M., Goldstein, S. L., deMenocal, P. B., Hemming, S. R., and Grousset, F. E.: Contrasting compositions of Saharan dust in the eastern Atlantic Ocean during the last deglaciation and African Humid Period, Earth Planet. Sc. Lett., 278, 257–266, 2009.
Dachs, J., Lohmann, R., Ockenden, W. A., Mejanelle, L., Eisenreich, S. J., and Jones, K. C.: Oceanic biogeochemical controls on global dynamics of persistent organic pollutants, Environ. Sci. Technol., 36, 4229–4237, 2002.
Dickhut, R. M., Cincinelli, A., Cochran, M., and Ducklow, H. W.: Atmospheric concentrations and air-water flux of organochlorine pesticides along the western Antarctic Peninsula, Environ. Sci. Technol., 39, 465–470, 2005.
Ding, X., Wang, X. M., Xie, Z. Q., Xiang, C. H., Mai, B. X., Sun, L. G., Zheng, M., Sheng, G. Y., and Fu, J. M.: Atmospheric hexachlorocyclohexanes in the North Pacific Ocean and the adjacent Arctic region: Spatial patterns, chiral signatures, and sea-air exchanges, Environ. Sci. Technol., 41, 5204–5209, 2007.
Fenner, K., Scheringer, M., and Hungerbühler, K.: Prediction of overall persistence and long-range transport potential with multimedia fate models: robustness and sensitivity of results, Environ. Pollut., 128, 189–204, 2004.
Fernández, A., Mouriño-Carballido, B., Bode, A., Varela, M., and Marañón, E.: Latitudinal distribution of Trichodesmium spp. and N2 fixation in the Atlantic Ocean, Biogeosciences, 7, 3167–3176, https://doi.org/10.5194/bg-7-3167-2010, 2010.
Fuller, E. N., Schettler, P. D., and Giddings, J. C.: New method for prediction of binary gas-phase diffuesion coefficients, Industry and Engineering Chemistry, 58, 18–27, 1966.
Gioia, R., Offenberg, J. H., Gigliotti, C. L., Totten, L. A., Du, S. Y., and Eisenreich, S. J.: Atmospheric concentrations and deposition of organochlorine pesticides in the US Mid-Atlantic region, Atmos. Environ., 39, 2309–2322, 2005.
Guieu, C., Dulac, F., Desboeufs, K., Wagener, T., Pulido-Villena, E., Grisoni, J.-M., Louis, F., Ridame, C., Blain, S., Brunet, C., Bon Nguyen, E., Tran, S., Labiadh, M., and Dominici, J.-M.: Large clean mesocosms and simulated dust deposition: a new methodology to investigate responses of marine oligotrophic ecosystems to atmospheric inputs, Biogeosciences, 7, 2765–2784, https://doi.org/10.5194/bg-7-2765-2010, 2010.
Harner, T., Kylin, H., Bidleman, T. F., Strachan, W. M. J.: Removal of alpha- and gamma-hexachlorocyclohexane and enantiomers of alpha-hexachlorocyclohexane in the eastern Arctic Ocean, Environ. Sci. Technol., 33, 1157–1164, 1999.
Hayduk, W. and Laudie, H.: Prediction of diffusion coefficients for nonelectrolytes in dilute aqueous solutions, AIChE Journal, 20, 611–615, 1974.
Hung, H., Halsall, C. J., Blanchard, P., Li, H. H., Fellin, P., Stern, G., and Rosenberg, B.: Temporal trends of organochlorine pesticides in the Canadian Arctic atmosphere, Environ. Sci. Technol., 36, 862–868. 2002.
Iwata, H., Tanabe, S., Sakal, N., and Tatsukawa, R.: Distribution of persistent organochlorines in the oceanic air and surface seawater and the role of ocean on their global transport and fate, Environ. Sci. Technol., 27, 1080–1098, 1993.
Jantunen, L. M. and Bidleman, T. F.: Reversal of the air-water gas-exchange direction of hexachlorocyclohexanes in the Bering and Chukchi seas – 1993 versus 1988, Environ. Sci. Technol., 29, 1081–1089, 1995.
Jantunen, L. M. M. and Bidleman, T. F.: Organochlorine pesticides and enantiomers of chiral pesticides in Arctic Ocean water, Arch. Environ. Con. Tox., 35, 218–228, 1998.
Jantunen, L. M., Kylin, H., and Bidleman, T. F.: Air-water gas exchange of alpha-hexachlorocyclohexane enantiomers in the South Atlantic Ocean and Antarctica, Deep-Sea Res. Pt. II, 51, 2661–2672, 2004.
Jantunen, L. M., Helm, P. A., Kylin, H., and Bidlemant, T. F.: Hexachlorocyclohexanes (HCHs) in the Canadian archipelago. 2. Air-water gas exchange of alpha- and gamma-HCH, Environ. Sci. Technol., 42, 465–470, 2008.
Jaward, F. M., Barber, J. L., Booij, K., Dachs, J., Lohmann, R., and Jones, K. C.: Evidence for dynamic air-water coupling and cycling of persistent organic pollutants over the open Atlantic Ocean, Environ. Sci. Technol., 38, 2617–2625, 2004.
Jullien, E., Grousset, F., Malaizé, B., Duprat, J., Sanchez-Goni, M. F., Eynaud, F., Charlier, K., Schneider, R., Bory, A., Bout, V., and Flores, J. A.: Low-latitude "dusty events" vs. high-latitude "icy Heinrich events", Quaternary Res., 68, 379–386, 2007.
Kallenborn, R., Oehme, M., Wynn-Williams, D. D., Schlabach, M., and Harris, J.: Ambient air levels and atmospheric long-range transport of persistent organochlorines to Signy Island, Antarctica, Sci. Total Environ., 220, 167–180, 1998.
Lakaschus, S., Weber, K., Wania, F., Bruhn, R., and Schrems, O.: The air-sea equilibrium and time trend of hexachlorocyclohexanes in the Atlantic Ocean between the Arctic and Antarctica, Environ. Sci. Technol., 36, 138–145, 2002.
Li, Y. F. and Macdonald, R. W.: Sources and pathways of selected organochlorine pesticides to the Arctic and the effect of pathway divergence on HCH trends in biota: a review, Sci. Total Environ., 342, 87–106, 2005.
Liss, P. S. and Slater, P. G.: 1 Flux of gases across air-sea interface, Nature, 247, 181–184, 1974.
Lohmann, R., Jurado, E., Pilson, M. E. Q., and Dachs, J.: Oceanic deep water formation as a sink of persistent organic pollutants, Geophys. Res. Lett., 33, L12607, https://doi.org/10.1029/2006GL025953, 2006.
Lohmann, R., Breivik, K., Dachs, J., and Muir, D.: Global fate of POPs: Current and future research directions, Environ. Pollut., 150, 150–165, 2007.
Lohmann, R., Gioia, R., Jones, K. C., Nizzetto, L., Temme, C., Xie, Z., Schulz-Bull, D., Hand, I., Morgan, E., and Jantunen, L.: Organochlorine Pesticides and PAHs in the Surface Water and Atmosphere of the North Atlantic and Arctic Ocean, Environ. Sci. Technol., 43, 5633–5639, 2009.
Nizzetto, L., Lohmann, R., Gioia, R., Dachs, J., and Jones, K. C.: Atlantic Ocean Surface Waters Buffer Declining Atmospheric Concentrations of Persistent Organic Pollutants, Environ. Sci. Technol., 44, 6978–6984, 2010.
Neogi, S. B., Koch, B. P., Schmitt-Kopplin, P., Pohl, C., Kattner, G., Yamasaki, S., and Lara, R. J.: Biogeochemical controls on the bacterial population in the eastern Atlantic Ocean, Biogeosciences Discuss., 8, 7791–7821, https://doi.org/10.5194/bgd-8-7791-2011, 2011.
Oehme, M., Haugen, J. E., and Schlabach, M.: Seasonal changes and relations between levels of organochlorines in arctic ambient air: First results of an all-year-round monitoring program at Ny-Alesund, Svalbard, Norway, Environ. Sci. Technol., 30, 2294–2304, 1996.
Pohl, C., Hennings, U., Croot, P., Daberkow, T., Budeus, G., and Rutgers v.d. Loeff, M.: Synoptic transects on the distribution of trace elements (Hg, Pb, Cd, Cu, Ni, Zn, Co, Mn, Fe, Al) in surface waters of the Northern- and Southern East-Atlantic, J. Marine Syst., 84, 28–41, 2011.
Sahsuvar, L., Helm, P. A., Jantunen, L. M., and Bidleman, T. F.: Henry's law constants for alpha-, beta-, and gamma-hexachlorocyclohexanes (HCHs) as a function of temperature and revised estimates of gas exchange in Arctic regions, Atmos. Environ., 37, 983–992, 2003.
Schreitmuller, J. and Ballschmiter, K.: Air-water equilibrium of hexachlorocyclohexanes and chloromethoxybenzenes in the north and south-Atlantic, Environ. Sci. Technol., 29, 207–215, 1995.
Schwarzenbach, R. P., Gschwend, P. M., and Imboden, D. M.: Environmental Organic Chemistry, John Wiley and Sons, New Jersey, 2003.
Shen, L., Wania, F., Lei, Y. D., Teixeira, C., Muir, D. C. G., and Bidleman, T. F.: Hexachlorocyclohexanes in the north American atmosphere, Environ. Sci. Technol., 38, 965–975, 2004.
Su, Y., Hung, H., Blanchard, P., Patton, G. W., Kallenborn, R., Konoplev, A., Fellin, P., Li, H., Geen, C., Stern, G., Rosenberg, B., and Barrie, L. A.: Spatial and seasonal variations of hexachlorocyclohexanes (HCHs) and hexachlorobenzene (HCB) in the Arctic atmosphere, Environ. Sci. Technol., 40, 6601–6607, 2006.
Taylor, B. B., Torrecilla, E., Bernhardt, A., Röttger, R., Piera, J., Peeken, I., and Bracher, A.: Characterization of phytoplankton communities by optical properties in the eastern Atlantic Ocean, Biogeosciences, in preparation, 2011.
Weber, J., Halsall, C. J., Muir, D. C. G., Teixeira, C., Burniston, D. A., Strachan, W. M. J., Hung, H., Mackay, N., Arnold, D., and Kylin, H.: Endosulfan and gamma-HCH in the Arctic: An assessment of surface seawater concentrations and air-sea exchange, Environ. Sci. Technol., 40, 7570–7576, 2006.
Wong, F., Jantunen, L. M., Pucko, M., Papakyriakou, T., Staebler, R. M., Stern, G. A., and Bidleman, T. F.: Air-Water Exchange of Anthropogenic and Natural Organohalogens on International Polar Year (IPY) Expeditions in the Canadian Arctic, Environ. Sci. Technol., 45, 876–881, 2011.
Wu, X. G., Lam, J. C. W., Xia, C. H., Kang, H., Sun, L. G., Xie, Z. Q., and Lam, P. K. S.: Atmospheric HCH Concentrations over the Marine Boundary Layer from Shanghai, China to the Arctic Ocean: Role of Human Activity and Climate Change, Environ. Sci. Technol., 44, 8422–8428, 2010.
Xie, Z., Moller, A., Ahrens, L., Sturm, R., and Ebinghaus, R.: Brominated Flame Retardants in Seawater and Atmosphere of the Atlantic and the Southern Ocean, Environ. Sci. Technol., 45, 1820–1826, 2011.
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