Articles | Volume 10, issue 5
https://doi.org/10.5194/bg-10-2897-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/bg-10-2897-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
02 May 2013
Research article |
| 02 May 2013
Combining a coupled FTIR-EGA system and in situ DRIFTS for studying soil organic matter in arable soils
M. S. Demyan
Institute of Plant Production and Agroecology in the Tropics and Subtropics, Universität Hohenheim, 70593 Stuttgart, Germany
F. Rasche
Institute of Plant Production and Agroecology in the Tropics and Subtropics, Universität Hohenheim, 70593 Stuttgart, Germany
M. Schütt
Institute of Plant Production and Agroecology in the Tropics and Subtropics, Universität Hohenheim, 70593 Stuttgart, Germany
now at: Department of Soil Ecology, University of Bayreuth, 95448 Bayreuth, Germany
N. Smirnova
Institute of Soil Science and Agrochemistry, Siberian Branch of Russian Academy of Science, 630099 Novosibirsk, Russia
Institute of Crop Science, Universität Hohenheim, 70593 Stuttgart, Germany
E. Schulz
Department of Soil Ecology, Helmholz Centre for Environmental Research-UFZ, 06120 Leipzig-Halle, Germany
G. Cadisch
Institute of Plant Production and Agroecology in the Tropics and Subtropics, Universität Hohenheim, 70593 Stuttgart, Germany
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Geosci. Model Dev., 17, 931–956, https://doi.org/10.5194/gmd-17-931-2024, https://doi.org/10.5194/gmd-17-931-2024, 2024
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To manage soil organic matter (SOM) sustainably, we need a better understanding of the role that soil microbes play in aggregate protection. Here, we propose the SAMM model, which connects soil aggregate formation to microbial growth. We tested it against data from a tropical long-term experiment and show that SAMM effectively represents the microbial growth, SOM, and aggregate dynamics and that it can be used to explore the importance of aggregate formation in SOM stabilization.
Tobias K. D. Weber, Joachim Ingwersen, Petra Högy, Arne Poyda, Hans-Dieter Wizemann, Michael Scott Demyan, Kristina Bohm, Ravshan Eshonkulov, Sebastian Gayler, Pascal Kremer, Moritz Laub, Yvonne Funkiun Nkwain, Christian Troost, Irene Witte, Tim Reichenau, Thomas Berger, Georg Cadisch, Torsten Müller, Andreas Fangmeier, Volker Wulfmeyer, and Thilo Streck
Earth Syst. Sci. Data, 14, 1153–1181, https://doi.org/10.5194/essd-14-1153-2022, https://doi.org/10.5194/essd-14-1153-2022, 2022
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Presented are measurement results from six agricultural fields operated by local farmers in southwestern Germany over 9 years. Six eddy-covariance stations measuring water, energy, and carbon fluxes between the vegetated soil surface and the atmosphere provided the backbone of the measurement sites and were supplemented by extensive soil and vegetation state monitoring. The dataset is ideal for testing process models characterizing fluxes at the vegetated soil surface and in the atmosphere.
Sergio Naranjo, Francelino A. Rodrigues Jr., Georg Cadisch, Santiago Lopez-Ridaura, Mariela Fuentes Ponce, and Carsten Marohn
Hydrol. Earth Syst. Sci., 25, 5561–5588, https://doi.org/10.5194/hess-25-5561-2021, https://doi.org/10.5194/hess-25-5561-2021, 2021
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We integrate a spatially explicit soil erosion model with plot- and watershed-scale characterization and high-resolution drone imagery to assess the effect of spatial resolution digital terrain models (DTMs) on discharge and soil loss. Results showed reduction in slope due to resampling down of DTM. Higher resolution translates to higher slope, denser fluvial system, and extremer values of soil loss, reducing concentration time and increasing soil loss at the outlet. The best resolution was 4 m.
Sebastian Doetterl, Rodrigue K. Asifiwe, Geert Baert, Fernando Bamba, Marijn Bauters, Pascal Boeckx, Benjamin Bukombe, Georg Cadisch, Matthew Cooper, Landry N. Cizungu, Alison Hoyt, Clovis Kabaseke, Karsten Kalbitz, Laurent Kidinda, Annina Maier, Moritz Mainka, Julia Mayrock, Daniel Muhindo, Basile B. Mujinya, Serge M. Mukotanyi, Leon Nabahungu, Mario Reichenbach, Boris Rewald, Johan Six, Anna Stegmann, Laura Summerauer, Robin Unseld, Bernard Vanlauwe, Kristof Van Oost, Kris Verheyen, Cordula Vogel, Florian Wilken, and Peter Fiener
Earth Syst. Sci. Data, 13, 4133–4153, https://doi.org/10.5194/essd-13-4133-2021, https://doi.org/10.5194/essd-13-4133-2021, 2021
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The African Tropics are hotspots of modern-day land use change and are of great relevance for the global carbon cycle. Here, we present data collected as part of the DFG-funded project TropSOC along topographic, land use, and geochemical gradients in the eastern Congo Basin and the Albertine Rift. Our database contains spatial and temporal data on soil, vegetation, environmental properties, and land management collected from 136 pristine tropical forest and cropland plots between 2017 and 2020.
Moritz Laub, Michael Scott Demyan, Yvonne Funkuin Nkwain, Sergey Blagodatsky, Thomas Kätterer, Hans-Peter Piepho, and Georg Cadisch
Biogeosciences, 17, 1393–1413, https://doi.org/10.5194/bg-17-1393-2020, https://doi.org/10.5194/bg-17-1393-2020, 2020
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Loss of soil carbon to the atmosphere represents a global challenge. We tested an innovative way to reduce the high uncertainty related to turnover of carbon stored in soils. With the use of infrared spectra of soils from model bare fallow systems, we were able to better assess the current state of soil carbon and predict its behavior in overdecadal time spans. In agreement with recent studies, carbon turnover seems faster than earlier assumed, with potential for high loss under mismanagement.
Johanna I. F. Slaets, Hans-Peter Piepho, Petra Schmitter, Thomas Hilger, and Georg Cadisch
Hydrol. Earth Syst. Sci., 21, 571–588, https://doi.org/10.5194/hess-21-571-2017, https://doi.org/10.5194/hess-21-571-2017, 2017
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Determining measures of uncertainty on loads is not trivial, as a load is a product of concentration and discharge per time point, summed up over time. A bootstrap approach enables the calculation of confidence intervals on constituent loads. Ignoring the uncertainty on the discharge will typically underestimate the width of 95 % confidence intervals by around 10 %. Furthermore, confidence intervals are asymmetric, with the largest uncertainty on the upper limit.
Johanna I. F. Slaets, Petra Schmitter, Thomas Hilger, Tran Duc Vien, and Georg Cadisch
Biogeosciences, 13, 3267–3281, https://doi.org/10.5194/bg-13-3267-2016, https://doi.org/10.5194/bg-13-3267-2016, 2016
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Maize production on steep slopes causes erosion. Where the eroded material ends up is not well understood. This study assessed transport of sediment in mountainous Vietnam, where maize is cultivated on slopes and rice is cultivated in valleys. Per year, 64 tons per hectare of sediments are brought into the rice fields and 28 tons of those are deposited there. The sediment fraction captured by the paddies is mostly sandy, while fertile silt and clay are exported. Upland erosion thus impacts rice production.
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Petri Kiuru, Marjo Palviainen, Arianna Marchionne, Tiia Grönholm, Maarit Raivonen, Lukas Kohl, and Annamari Laurén
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Peatlands are large carbon stocks. Emissions of carbon dioxide and methane from peatlands may increase due to changes in management and climate. We studied the variation in the gas diffusivity of peat with depth using pore network simulations and laboratory experiments. Gas diffusivity was found to be lower in deeper peat with smaller pores and lower pore connectivity. However, gas diffusivity was not extremely low in wet conditions, which may reflect the distinctive structure of peat.
Rachael Akinyede, Martin Taubert, Marion Schrumpf, Susan Trumbore, and Kirsten Küsel
Biogeosciences, 19, 4011–4028, https://doi.org/10.5194/bg-19-4011-2022, https://doi.org/10.5194/bg-19-4011-2022, 2022
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Soils will likely become warmer in the future, and this can increase the release of carbon dioxide (CO2) into the atmosphere. As microbes can take up soil CO2 and prevent further escape into the atmosphere, this study compares the rate of uptake and release of CO2 at two different temperatures. With warming, the rate of CO2 uptake increases less than the rate of release, indicating that the capacity to modulate soil CO2 release into the atmosphere will decrease under future warming.
Giuseppe Cipolla, Salvatore Calabrese, Amilcare Porporato, and Leonardo V. Noto
Biogeosciences, 19, 3877–3896, https://doi.org/10.5194/bg-19-3877-2022, https://doi.org/10.5194/bg-19-3877-2022, 2022
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Enhanced weathering (EW) is a promising strategy for carbon sequestration. Since models may help to characterize field EW, the present work applies a hydro-biogeochemical model to four case studies characterized by different rainfall seasonality, vegetation and soil type. Rainfall seasonality strongly affects EW dynamics, but low carbon sequestration suggests that an in-depth analysis at the global scale is required to see if EW may be effective to mitigate climate change.
Vao Fenotiana Razanamahandry, Marjolein Dewaele, Gerard Govers, Liesa Brosens, Benjamin Campforts, Liesbet Jacobs, Tantely Razafimbelo, Tovonarivo Rafolisy, and Steven Bouillon
Biogeosciences, 19, 3825–3841, https://doi.org/10.5194/bg-19-3825-2022, https://doi.org/10.5194/bg-19-3825-2022, 2022
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In order to shed light on possible past vegetation shifts in the Central Highlands of Madagascar, we measured stable isotope ratios of organic carbon in soil profiles along both forested and grassland hillslope transects in the Lake Alaotra region. Our results show that the landscape of this region was more forested in the past: soils in the C4-dominated grasslands contained a substantial fraction of C3-derived carbon, increasing with depth.
Katherine E. O. Todd-Brown, Rose Z. Abramoff, Jeffrey Beem-Miller, Hava K. Blair, Stevan Earl, Kristen J. Frederick, Daniel R. Fuka, Mario Guevara Santamaria, Jennifer W. Harden, Katherine Heckman, Lillian J. Heran, James R. Holmquist, Alison M. Hoyt, David H. Klinges, David S. LeBauer, Avni Malhotra, Shelby C. McClelland, Lucas E. Nave, Katherine S. Rocci, Sean M. Schaeffer, Shane Stoner, Natasja van Gestel, Sophie F. von Fromm, and Marisa L. Younger
Biogeosciences, 19, 3505–3522, https://doi.org/10.5194/bg-19-3505-2022, https://doi.org/10.5194/bg-19-3505-2022, 2022
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Alessandro Montemagno, Christophe Hissler, Victor Bense, Adriaan J. Teuling, Johanna Ziebel, and Laurent Pfister
Biogeosciences, 19, 3111–3129, https://doi.org/10.5194/bg-19-3111-2022, https://doi.org/10.5194/bg-19-3111-2022, 2022
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We investigated the biogeochemical processes that dominate the release and retention of elements (nutrients and potentially toxic elements) during litter degradation. Our results show that toxic elements are retained in the litter, while nutrients are released in solution during the first stages of degradation. This seems linked to the capability of trees to distribute the elements between degradation-resistant and non-degradation-resistant compounds of leaves according to their chemical nature.
Laura Sereni, Bertrand Guenet, Charlotte Blasi, Olivier Crouzet, Jean-Christophe Lata, and Isabelle Lamy
Biogeosciences, 19, 2953–2968, https://doi.org/10.5194/bg-19-2953-2022, https://doi.org/10.5194/bg-19-2953-2022, 2022
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This study focused on the modellisation of two important drivers of soil greenhouse gas emissions: soil contamination and soil moisture change. The aim was to include a Cu function in the soil biogeochemical model DNDC for different soil moisture conditions and then to estimate variation in N2O, NO2 or NOx emissions. Our results show a larger effect of Cu on N2 and N2O emissions than on the other nitrogen species and a higher effect for the soils incubated under constant constant moisture.
Marie Spohn and Johan Stendahl
Biogeosciences, 19, 2171–2186, https://doi.org/10.5194/bg-19-2171-2022, https://doi.org/10.5194/bg-19-2171-2022, 2022
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We explored the ratios of carbon (C), nitrogen (N), and phosphorus (P) of organic matter in Swedish forest soils. The N : P ratio of the organic layer was most strongly related to the mean annual temperature, while the C : N ratios of the organic layer and mineral soil were strongly related to tree species even in the subsoil. The organic P concentration in the mineral soil was strongly affected by soil texture, which diminished the effect of tree species on the C to organic P (C : OP) ratio.
Moritz Mainka, Laura Summerauer, Daniel Wasner, Gina Garland, Marco Griepentrog, Asmeret Asefaw Berhe, and Sebastian Doetterl
Biogeosciences, 19, 1675–1689, https://doi.org/10.5194/bg-19-1675-2022, https://doi.org/10.5194/bg-19-1675-2022, 2022
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The largest share of terrestrial carbon is stored in soils, making them highly relevant as regards global change. Yet, the mechanisms governing soil carbon stabilization are not well understood. The present study contributes to a better understanding of these processes. We show that qualitative changes in soil organic matter (SOM) co-vary with alterations of the soil matrix following soil weathering. Hence, the type of SOM that is stabilized in soils might change as soils develop.
Jasmin Fetzer, Emmanuel Frossard, Klaus Kaiser, and Frank Hagedorn
Biogeosciences, 19, 1527–1546, https://doi.org/10.5194/bg-19-1527-2022, https://doi.org/10.5194/bg-19-1527-2022, 2022
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As leaching is a major pathway of nitrogen and phosphorus loss in forest soils, we investigated several potential drivers in two contrasting beech forests. The composition of leachates, obtained by zero-tension lysimeters, varied by season, and climatic extremes influenced the magnitude of leaching. Effects of nitrogen and phosphorus fertilization varied with soil nutrient status and sorption properties, and leaching from the low-nutrient soil was more sensitive to environmental factors.
Karis J. McFarlane, Heather M. Throckmorton, Jeffrey M. Heikoop, Brent D. Newman, Alexandra L. Hedgpeth, Marisa N. Repasch, Thomas P. Guilderson, and Cathy J. Wilson
Biogeosciences, 19, 1211–1223, https://doi.org/10.5194/bg-19-1211-2022, https://doi.org/10.5194/bg-19-1211-2022, 2022
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Planetary warming is increasing seasonal thaw of permafrost, making this extensive old carbon stock vulnerable. In northern Alaska, we found more and older dissolved organic carbon in small drainages later in summer as more permafrost was exposed by deepening thaw. Younger and older carbon did not differ in chemical indicators related to biological lability suggesting this carbon can cycle through aquatic systems and contribute to greenhouse gas emissions as warming increases permafrost thaw.
Pengzhi Zhao, Daniel Joseph Fallu, Sara Cucchiaro, Paolo Tarolli, Clive Waddington, David Cockcroft, Lisa Snape, Andreas Lang, Sebastian Doetterl, Antony G. Brown, and Kristof Van Oost
Biogeosciences, 18, 6301–6312, https://doi.org/10.5194/bg-18-6301-2021, https://doi.org/10.5194/bg-18-6301-2021, 2021
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We investigate the factors controlling the soil organic carbon (SOC) stability and temperature sensitivity of abandoned prehistoric agricultural terrace soils. Results suggest that the burial of former topsoil due to terracing provided an SOC stabilization mechanism. Both the soil C : N ratio and SOC mineral protection regulate soil SOC temperature sensitivity. However, which mechanism predominantly controls SOC temperature sensitivity depends on the age of the buried terrace soils.
Heleen Deroo, Masuda Akter, Samuel Bodé, Orly Mendoza, Haichao Li, Pascal Boeckx, and Steven Sleutel
Biogeosciences, 18, 5035–5051, https://doi.org/10.5194/bg-18-5035-2021, https://doi.org/10.5194/bg-18-5035-2021, 2021
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We assessed if and how incorporation of exogenous organic carbon (OC) such as straw could affect decomposition of native soil organic carbon (SOC) under different irrigation regimes. Addition of exogenous OC promoted dissolution of native SOC, partly because of increased Fe reduction, leading to more net release of Fe-bound SOC. Yet, there was no proportionate priming of SOC-derived DOC mineralisation. Water-saving irrigation can retard both priming of SOC dissolution and mineralisation.
Frances A. Podrebarac, Sharon A. Billings, Kate A. Edwards, Jérôme Laganière, Matthew J. Norwood, and Susan E. Ziegler
Biogeosciences, 18, 4755–4772, https://doi.org/10.5194/bg-18-4755-2021, https://doi.org/10.5194/bg-18-4755-2021, 2021
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Soil respiration is a large and temperature-responsive flux in the global carbon cycle. We found increases in microbial use of easy to degrade substrates enhanced the temperature response of respiration in soils layered as they are in situ. This enhanced response is consistent with soil composition differences in warm relative to cold climate forests. These results highlight the importance of the intact nature of soils rarely studied in regulating responses of CO2 fluxes to changing temperature.
Elisa Bruni, Bertrand Guenet, Yuanyuan Huang, Hugues Clivot, Iñigo Virto, Roberta Farina, Thomas Kätterer, Philippe Ciais, Manuel Martin, and Claire Chenu
Biogeosciences, 18, 3981–4004, https://doi.org/10.5194/bg-18-3981-2021, https://doi.org/10.5194/bg-18-3981-2021, 2021
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Increasing soil organic carbon (SOC) stocks is beneficial for climate change mitigation and food security. One way to enhance SOC stocks is to increase carbon input to the soil. We estimate the amount of carbon input required to reach a 4 % annual increase in SOC stocks in 14 long-term agricultural experiments around Europe. We found that annual carbon input should increase by 43 % under current temperature conditions, by 54 % for a 1 °C warming scenario and by 120 % for a 5 °C warming scenario.
Rainer Brumme, Bernd Ahrends, Joachim Block, Christoph Schulz, Henning Meesenburg, Uwe Klinck, Markus Wagner, and Partap K. Khanna
Biogeosciences, 18, 3763–3779, https://doi.org/10.5194/bg-18-3763-2021, https://doi.org/10.5194/bg-18-3763-2021, 2021
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In order to study the fate of litter nitrogen in forest soils, we combined a leaf litterfall exchange experiment using 15N-labeled leaf litter with long-term element budgets at seven European beech sites in Germany. It appears that fructification intensity, which has increased in recent decades, has a distinct impact on N retention in forest soils. Despite reduced nitrogen deposition, about 6 and 10 kg ha−1 of nitrogen were retained annually in the soils and in the forest stands, respectively.
Lorenz Gfeller, Andrea Weber, Isabelle Worms, Vera I. Slaveykova, and Adrien Mestrot
Biogeosciences, 18, 3445–3465, https://doi.org/10.5194/bg-18-3445-2021, https://doi.org/10.5194/bg-18-3445-2021, 2021
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Our incubation experiment shows that flooding of polluted floodplain soils may induce pulses of both mercury (Hg) and methylmercury to the soil solution and threaten downstream ecosystems. We demonstrate that mobilization of Hg bound to manganese oxides is a relevant process in organic-matter-poor soils. Addition of organic amendments accelerates this mobilization but also facilitates the formation of nanoparticulate Hg and the subsequent fixation of Hg from soil solution to the soil.
Yao Zhang, Jocelyn M. Lavallee, Andy D. Robertson, Rebecca Even, Stephen M. Ogle, Keith Paustian, and M. Francesca Cotrufo
Biogeosciences, 18, 3147–3171, https://doi.org/10.5194/bg-18-3147-2021, https://doi.org/10.5194/bg-18-3147-2021, 2021
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Soil organic matter (SOM) is essential for the health of soils, and the accumulation of SOM helps removal of CO2 from the atmosphere. Here we present the result of the continued development of a mathematical model that simulates SOM and its measurable fractions. In this study, we simulated several grassland sites in the US, and the model generally captured the carbon and nitrogen amounts in SOM and their distribution between the measurable fractions throughout the entire soil profile.
Zhongkui Luo, Raphael A. Viscarra-Rossel, and Tian Qian
Biogeosciences, 18, 2063–2073, https://doi.org/10.5194/bg-18-2063-2021, https://doi.org/10.5194/bg-18-2063-2021, 2021
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Using the data from 141 584 whole-soil profiles across the globe, we disentangled the relative importance of biotic, climatic and edaphic variables in controlling global SOC stocks. The results suggested that soil properties and climate contributed similarly to the explained global variance of SOC in four sequential soil layers down to 2 m. However, the most important individual controls are consistently soil-related, challenging current climate-driven framework of SOC dynamics.
Debjani Sihi, Xiaofeng Xu, Mónica Salazar Ortiz, Christine S. O'Connell, Whendee L. Silver, Carla López-Lloreda, Julia M. Brenner, Ryan K. Quinn, Jana R. Phillips, Brent D. Newman, and Melanie A. Mayes
Biogeosciences, 18, 1769–1786, https://doi.org/10.5194/bg-18-1769-2021, https://doi.org/10.5194/bg-18-1769-2021, 2021
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Humid tropical soils are important sources and sinks of methane. We used model simulation to understand how different kinds of microbes and observed soil moisture and oxygen dynamics contribute to production and consumption of methane along a wet tropical hillslope during normal and drought conditions. Drought alters the diffusion of oxygen and microbial substrates into and out of soil microsites, resulting in enhanced methane release from the entire hillslope during drought recovery.
Mathieu Chassé, Suzanne Lutfalla, Lauric Cécillon, François Baudin, Samuel Abiven, Claire Chenu, and Pierre Barré
Biogeosciences, 18, 1703–1718, https://doi.org/10.5194/bg-18-1703-2021, https://doi.org/10.5194/bg-18-1703-2021, 2021
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Evolution of organic carbon content in soils could be a major driver of atmospheric greenhouse gas concentrations over the next century. Understanding factors controlling carbon persistence in soil is a challenge. Our study of unique long-term bare-fallow samples, depleted in labile organic carbon, helps improve the separation, evaluation and characterization of carbon pools with distinct residence time in soils and gives insight into the mechanisms explaining soil organic carbon persistence.
Melisa A. Diaz, Christopher B. Gardner, Susan A. Welch, W. Andrew Jackson, Byron J. Adams, Diana H. Wall, Ian D. Hogg, Noah Fierer, and W. Berry Lyons
Biogeosciences, 18, 1629–1644, https://doi.org/10.5194/bg-18-1629-2021, https://doi.org/10.5194/bg-18-1629-2021, 2021
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Water-soluble salt and nutrient concentrations of soils collected along the Shackleton Glacier, Antarctica, show distinct geochemical gradients related to latitude, longitude, elevation, soil moisture, and distance from coast and glacier. Machine learning algorithms were used to estimate geochemical gradients for the region given the relationship with geography. Geography and surface exposure age drive salt and nutrient abundances, influencing invertebrate habitat suitability and biogeography.
Marion Schrumpf, Klaus Kaiser, Allegra Mayer, Günter Hempel, and Susan Trumbore
Biogeosciences, 18, 1241–1257, https://doi.org/10.5194/bg-18-1241-2021, https://doi.org/10.5194/bg-18-1241-2021, 2021
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A large amount of organic carbon (OC) in soil is protected against decay by bonding to minerals. We studied the release of mineral-bonded OC by NaF–NaOH extraction and H2O2 oxidation. Unexpectedly, extraction and oxidation removed mineral-bonded OC at roughly constant portions and of similar age distributions, irrespective of mineral composition, land use, and soil depth. The results suggest uniform modes of interactions between OC and minerals across soils in quasi-steady state with inputs.
Lena Rohe, Bernd Apelt, Hans-Jörg Vogel, Reinhard Well, Gi-Mick Wu, and Steffen Schlüter
Biogeosciences, 18, 1185–1201, https://doi.org/10.5194/bg-18-1185-2021, https://doi.org/10.5194/bg-18-1185-2021, 2021
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Total denitrification, i.e. N2O and (N2O + N2) fluxes, of repacked soil cores were analysed for different combinations of soils and water contents. Prediction accuracy of (N2O + N2) fluxes was highest with combined proxies for oxygen demand (CO2 flux) and oxygen supply (anaerobic soil volume fraction). Knowledge of denitrification completeness (product ratio) improved N2O predictions. Substitutions with cheaper proxies (soil organic matter, empirical diffusivity) reduced prediction accuracy.
Severin-Luca Bellè, Asmeret Asefaw Berhe, Frank Hagedorn, Cristina Santin, Marcus Schiedung, Ilja van Meerveld, and Samuel Abiven
Biogeosciences, 18, 1105–1126, https://doi.org/10.5194/bg-18-1105-2021, https://doi.org/10.5194/bg-18-1105-2021, 2021
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Controls of pyrogenic carbon (PyC) redistribution under rainfall are largely unknown. However, PyC mobility can be substantial after initial rain in post-fire landscapes. We conducted a controlled simulation experiment on plots where PyC was applied on the soil surface. We identified redistribution of PyC by runoff and splash and vertical movement in the soil depending on soil texture and PyC characteristics (material and size). PyC also induced changes in exports of native soil organic carbon.
Michael Rinderer, Jaane Krüger, Friederike Lang, Heike Puhlmann, and Markus Weiler
Biogeosciences, 18, 1009–1027, https://doi.org/10.5194/bg-18-1009-2021, https://doi.org/10.5194/bg-18-1009-2021, 2021
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We quantified the lateral and vertical subsurface flow (SSF) and P concentrations of three beech forest plots with contrasting soil properties during sprinkling experiments. Vertical SSF was 2 orders of magnitude larger than lateral SSF, and both consisted mainly of pre-event water. P concentrations in SSF were high during the first 1 to 2 h (nutrient flushing) but nearly constant thereafter. This suggests that P in the soil solution was replenished fast by mineral or organic sources.
Kirsty C. Paterson, Joanna M. Cloy, Robert M. Rees, Elizabeth M. Baggs, Hugh Martineau, Dario Fornara, Andrew J. Macdonald, and Sarah Buckingham
Biogeosciences, 18, 605–620, https://doi.org/10.5194/bg-18-605-2021, https://doi.org/10.5194/bg-18-605-2021, 2021
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Soil organic carbon sequestration across agroecosystems worldwide can contribute to mitigating the effects of climate change by reducing levels of atmospheric carbon dioxide. The maximum carbon sequestration potential is frequently estimated using the linear regression equation developed by Hassink (1997). This work examines the suitability of this equation for use in grasslands across the United Kingdom. The results highlight the need to ensure the fit of equations to the soils being studied.
Hannah Gies, Frank Hagedorn, Maarten Lupker, Daniel Montluçon, Negar Haghipour, Tessa Sophia van der Voort, and Timothy Ian Eglinton
Biogeosciences, 18, 189–205, https://doi.org/10.5194/bg-18-189-2021, https://doi.org/10.5194/bg-18-189-2021, 2021
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Understanding controls on the persistence of organic matter in soils is essential to constrain its role in the carbon cycle. Emerging concepts suggest that the soil carbon pool is predominantly comprised of stabilized microbial residues. To test this hypothesis we isolated microbial membrane lipids from two Swiss soil profiles and measured their radiocarbon age. We find that the ages of these compounds are in the range of millenia and thus provide evidence for stabilized microbial mass in soils.
Frederick Büks, Gilles Kayser, Antonia Zieger, Friederike Lang, and Martin Kaupenjohann
Biogeosciences, 18, 159–167, https://doi.org/10.5194/bg-18-159-2021, https://doi.org/10.5194/bg-18-159-2021, 2021
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Ultrasonication/density fractionation is a common method used to extract particulate organic matter (POM) and, recently, microplastic (MP) from soil samples. In this study, ultrasonic treatment with mechanical stress increasing from 0 to 500 J mL−1 caused comminution and a reduced recovery rate of soil-derived POMs but no such effects with MP particles. In consequence, the extraction of MP from soils is not affected by particle size and recovery rate artifacts.
Hang Wen, Pamela L. Sullivan, Gwendolyn L. Macpherson, Sharon A. Billings, and Li Li
Biogeosciences, 18, 55–75, https://doi.org/10.5194/bg-18-55-2021, https://doi.org/10.5194/bg-18-55-2021, 2021
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Carbonate weathering is essential in regulating carbon cycle at the century timescale. Plant roots accelerate weathering by elevating soil CO2 via respiration. It however remains poorly understood how and how much rooting characteristics modify flow paths and weathering. This work indicates that deepening roots in woodlands can enhance carbonate weathering by promoting recharge and CO2–carbonate contact in the deep, carbonate-abundant subsurface.
Marcus Schiedung, Severin-Luca Bellè, Gabriel Sigmund, Karsten Kalbitz, and Samuel Abiven
Biogeosciences, 17, 6457–6474, https://doi.org/10.5194/bg-17-6457-2020, https://doi.org/10.5194/bg-17-6457-2020, 2020
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The mobility of pyrogenic organic matter (PyOM) in soils is largely unknow, while it is a major and persistent component of the soil organic matter. With a soil column experiment, we identified that only a small proportion of PyOM can migrate through the soil, but its export is continuous. Aging and associated oxidation increase its mobility but also its retention in soils. Further, PyOM can alter the vertical mobility of native soil organic carbon during its downward migration.
Patrick Wordell-Dietrich, Anja Wotte, Janet Rethemeyer, Jörg Bachmann, Mirjam Helfrich, Kristina Kirfel, Christoph Leuschner, and Axel Don
Biogeosciences, 17, 6341–6356, https://doi.org/10.5194/bg-17-6341-2020, https://doi.org/10.5194/bg-17-6341-2020, 2020
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The release of CO2 from soils, known as soil respiration, plays a major role in the global carbon cycle. However, the contributions of different soil depths or the sources of soil CO2 have hardly been studied. We quantified the CO2 production for different soil layers (up to 1.5 m) in three soil profiles for 2 years. We found that 90 % of CO2 production occurs in the first 30 cm of the soil profile, and that the CO2 originated from young carbon sources, as revealed by radiocarbon measurements.
Cited articles
Anderson, J. U.: An improved pretreatment for mineralogical analyses of samples containing organic matter, Clay. Clay Miner., 10, 380–388, 1963.
Anderson, J. P. E. and Domsch, K. H.: A physiological method for the quantitative measurement of microbial biomass in soils, Soil Biol. Biochem., 10, 215–221, 1978.
Baldry, P. J., Cullis, C. F., Goring, D., and Hirschler, M. M.: The combustion of cigarette paper, Fire Mater., 12, 25–33, 1988.
Blumstein, A.: Polymerization of adsorbed monolayers. II. Thermal degradation of the inserted polymer, J. Polym. Sci. Part A, 3, 2665–2672, 1965.
Cadisch, G., Imhof, H., Urquiaga, S., Boddey, R. M., and Giller, K. E.: Carbon turnover (δ13C) and nitrogen mineralization potential of particulate light soil organic matter after rainforest clearing, Soil Biol. Biochem., 28, 1555–1567, 1996.
Conzen, J.: Multivariate Calibration, A practical guide for developing methods in the quantitative analytical chemistry, Bruker Optik GmbH, Germany, 2003.
Court, R. W. and Sephton, M. A.: Quantitative flash pyrolysis Fourier transform infrared spectroscopy of organic materials, Anal. Chim. Acta, 639, 62–66, 2009.
Dell'Abate, M. T., Benedetti, A., and Sequi, P.: Thermal methods of organic matter maturation monitoring during a composting process, J. Therm. Anal. Calorim., 61, 389–396, 2000.
Dell'Abate, M. T., Benedetti, A., and Brookes, P. C.: Hyphenated techniques of thermal analysis for characterisation of soil humic substances, J. Sep. Sci., 26, 433–440, 2003.
Demyan, M. S., Rasche, F., Schulz, E., Breulmann, M., Müller, T., and Cadisch, G.: Use of specific peaks obtained by diffuse reflectance Fourier transform mid-infrared spectroscopy to study the composition of organic matter in a Haplic Chernozem, Eur. J. Soil Sci., 63, 189–199, 2012.
Dorodnikov, M., Fangmeier, A., and Kuzyakov, Y.: Thermal stability of soil organic matter pools and their δ13C values after C3–C4 vegetation change, Soil Biol. Biochem., 39, 1173–1180, 2007.
Dorodnikov, M., Fangmeier, A., Giesemann, A., Weigel, H., Stahr, K., and Kuzyakov, Y.: Thermal stability of soil organic matter pools and their turnover times calculated by δ13C under elevated CO2 and two levels of N fertilisation, Isot. Environ. Healt. S., 44, 365–376, 2008.
Dreibrodt, S., Kleber, M., and Jahn, R.: Das Mineralinventar der Versuchsfläche "Statischer Dauerdüngungsversuch v120, Bad lauchstädt", Arch. Acker. Pfl. Boden, 48, 227–240, 2002.
Eckmeier, E., Gerlach, R., Gehrt, E., and Schmidt, M. W. I.: Pedogenesis of Chernozems in Central Europe – A review, Geoderma, 139, 288–299, 2007.
Fernández, J., Plante, A., Leifeld, J., and Rasmussen, C.: Methodological considerations for using thermal analysis in the characterization of soil organic matter, J. Therm. Anal. Calorim., 104, 389–398, 2011.
Fernández, J. M., Peltre, C., Craine, J. M., and Plante, A. F.: Improved characterization of soil organic matter by thermal analysis using CO2/H2O evolved gas analysis, Environ. Sci. Technol., 46, 8921–8927, 2012.
Gaál, F., Szöllosy, I., Arnold, M., and Paulik, F.: Determination of the organic matter, metal carbonate and mobile water in soils simultaneous TG, DTG, DTA and EGA techniques, J. Therm. Anal., 42, 1007–1016, 1994.
Harris, D., Horwáth, W. R., and Van Kessel, C.: Acid fumigation of soils to remove carbonates prior to total organic carbon or carbon-13 isotopic analysis, Soil Sci. Soc. Am. J., 65, 1853–1856, 2001.
Haselsteiner, T., Erbel, C., Kunze, C., and Spliethoff, H.: An in situ optical gas phase analysis approach for TGA: Its assessment and application, Appl. Energy, 88, 5200–5207, 2011.
Helfrich, M., Flessa, H., Dreves, A., and Ludwig, B.: Is thermal oxidation at different temperatures suitable to isolate soil organic carbon fractions with different turnover?, J. Plant Nutr. Soil Sc., 173, 61–66, 2010.
IUSS Working Group WRB: World Reference Base for Soil Resources 2006, first update 2007, World Soil Resources Reports, FAO, Rome, 2007.
Janković, B.: Kinetic analysis of isothermal decomposition process of sodium bicarbonate using the weibull probability function-estimation of density distribution functions of the apparent activation energies, Metall Mater Trans B, 40, 712–726, 2009.
Kiem, R., Knicker, H., Körschens, M., and Kögel-Knabner, I.: Refractory organic carbon in C-depleted arable soils, as studied by 13C NMR spectroscopy and carbohydrate analysis, Org. Geochem., 31, 655–668, 2000.
Körschens, M., Stegemann, K., Pfefferkorn, A., Weise, V., and Müller, A.: Der Statische Düngungsversuch Bad Lauchstädt nach 90 Jahren, Einflu{ß} der Düngung auf Boden, Pflanze und Umwelt, Stuttgart: B. G. Teubner Verlagsgesellschaft, 1994.
Leifeld, J., Franko, U., and Schulz, E.: Thermal stability responses of soil organic matter to long-term fertilization practices, Biogeosciences, 3, 371–374, https://doi.org/10.5194/bg-3-371-2006, 2006.
Leinweber, P. and Schulten, H.: Dynamics of soil organic matter studied by pyrolysis – field ionization mass spectrometry, J. Anal. Appl. Pyrol., 25, 123–136, 1993.
Leinweber, P., Schulten, H., and Horte, C.: Differential thermal analysis, thermogravimetry and pyrolysis-field ionisation mass spectrometry of soil organic matter in particle-size fractions and bulk soil samples, Thermochim. Acta, 194, 175–187, 1992.
Lopez-Capel, E., Sohi, S. P., Gaunt, J. L., and Manning, D. A. C.: Use of thermogravimetry-differential scanning calorimetry to characterize modelable soil organic matter fractions, Soil Sci. Soc. Am. J., 69, 136–140, 2005.
Lu, X. Q., Vassallo, A. M., and Johnson, W. D.: Thermal stability of humic substances and their metal forms: An investigation using FTIR emission spectroscopy, J. Anal. Appl. Pyrol., 43, 103–114, 1997.
Mertz, C., Kleber, M., and Jahn, R.: Soil organic matter stabilization pathways in clay sub-fractions from a time series of fertilizer deprivation, Org. Geochem., 36, 1311–1322, 2005.
Mikutta, R., Kleber, M., Kaiser, K., and Jahn, R.: Review: Organic Matter Removal from Soils using Hydrogen Peroxide, Sodium Hypochlorite, and Disodium Peroxodisulfate, Soil Sci. Soc. Am. J., 69, 120–135, 2005.
Murakami, K., Shirato, H., and Nishiyama, Y.: In situ infrared spectroscopic study of the effects of exchanged cations on thermal decomposition of a brown coal, Fuel, 76, 655–661, 1997.
Mittleman, M.: Quantitative TG/IR, Thermochim. Acta, 166, 301–308, 1990.
Nguyen, T. T., Janik, L. J., and Raupach, M.: Diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy in soil studies, Aust. J. Soil Res., 29, 49–67, 1991.
Pansu, M. and Gautheyrou, J.: Handbook of Soil Analysis. Mineralogical, Organic and Inorganic Methods, Springer Verlag Berlin Heidelberg, the Netherlands, 2006.
Plante, A. F., Fernández, J. M., and Leifeld, J.: Application of thermal analysis techniques in soil science, Geoderma, 153, 1–10, 2009.
Plante, A. F., Fernández, J. M., Haddix, M. L., Steinweg, J. M., and Conant, R. T.: Biological, chemical and thermal indices of soil organic matter stability in four grassland soils, Soil Biol. Biochem., 43, 1051–1058, 2011.
Rovira, P. and Vallejo, V. R.: Examination of thermal and acid hydrolysis procedures in characterization of soil organic matter, Commun. Soil Sci. Plan., 31, 81–100, 2000.
Schlichting, E., Blume, H. P., and Stahr, K.: Bodenkundliches Praktikum. , Blackwell Wissenschafts-Verlag, Berlin, Vienna, 1995.
Schulten, H. and Leinweber, P.: Pyrolysis-field ionization mass spectrometry of agricultural soils and humic substances: Effect of cropping systems and influence of the mineral matrix, Plant Soil, 151, 77–90, 1993.
Schulten, H. and Leinweber, P.: Thermal stability and composition of mineral-bound organic matter in density fractions of soil, Eur. J. Soil Sci., 50, 237–248, 1999.
Siewert, C.: Rapid screening of soil properties using thermogravimetry, Soil Sci. Soc. Am. J., 68, 1656–1661, 2004.
Sleutel, S., Leinweber, P., Ara Begum, S., Kader, M. A., and De Neve, S.: Shifts in soil organic matter composition following treatment with sodium hypochlorite and hydrofluoric acid, Geoderma, 149, 257–266, 2009.
Sleutel, S., Leinweber, P., Van Ranst, E., Kader, M. A., and Jegajeevagan, K.: Organic matter in clay density fractions from sandy cropland soils with differing land-use history, Soil Sci. Soc. Am. J., 75, 521–532, 2011.
Toops, T. J., Smith, D. B., and Partridge, W. P.: Quantification of the in situ DRIFT spectra of Pt/K/γ-A12O3 NOx adsorber catalysts, Appl. Catal., 58, 245–254, 2005.
von Lützow, M., Kögel-Knabner, I., Ekschmitt, K., Flessa, H., Guggenberger, G., Matzner, E., and Marschner, B.: SOM fractionation methods: Relevance to functional pools and to stabilization mechanisms, Soil Biol. Biochem., 39, 2183–2207, 2007.
von Lützow, M., Kögel-Knabner, I., Ludwig, B., Matzner, E., Flessa, H., Ekschmitt, K., Guggenberger, G., Marschner, B., and Kalbitz, K.: Stabilization mechanisms of organic matter in four temperate soils: Development and application of a conceptual model, J. Plant Nutr. Soil Sc., 171, 111–124, 2008.
Woelki, G. and Salzer, R.: Thermal investigations of the structure of two humic acid salts by in situ FTIR spectroscopy, Fresen. J. Anal. Chem., 352, 529–531, 1995.
Zimmermann, M., Leifeld, J., Abiven, S., Schmidt, M. W. I., and Fuhrer, J.: Sodium hypochlorite separates an older soil organic matter fraction than acid hydrolysis, Geoderma, 139, 171–179, 2007a.
Zimmermann, M., Leifeld, J., and Fuhrer, J.: Quantifying soil organic carbon fractions by infrared-spectroscopy, Soil Biol. Biochem., 39, 224–231, 2007b.
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