Articles | Volume 14, issue 5
https://doi.org/10.5194/bg-14-1153-2017
https://doi.org/10.5194/bg-14-1153-2017
Research article
 | 
09 Mar 2017
Research article |  | 09 Mar 2017

Colloid-bound and dissolved phosphorus species in topsoil water extracts along a grassland transect from Cambisol to Stagnosol

Xiaoqian Jiang, Roland Bol, Barbara J. Cade-Menun, Volker Nischwitz, Sabine Willbold, Sara L. Bauke, Harry Vereecken, Wulf Amelung, and Erwin Klumpp

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Cited articles

Cade-Menun, B. J.: Characterizing phosphorus in environmental and agricultural samples by 31P nuclear magnetic resonance spectroscopy, Talanta, 66, 359–371, 2005.
Cade-Menun, B. J.: Characterizing phosphorus in animal waste with solution 31P NMR spectroscopy, in: Environmental Chemistry of Animal Manure, edited by: He, Z., 275–299, Nova Science Publishers, Inc. New York, 2011.
Cade-Menun, B. J.: Improved peak identification in 31P-NMR spectra of environmental samples with a standardized method and peak library, Geoderma, 257–258, 102–114, 2015.
Cade-Menun, B. J. and Liu, C. W.: Solution 31P-NMR spectroscopy of soils from 2005–2013, A review of sample preparation and experimental parameters, Soil Sci. Soc. Am. J., 78, 19–37, 2014.
Cade-Menun, B. J. and Preston, C. M.: A comparison of soil extraction procedures for 31P NMR spectroscopy, Soil Sci., 161, 770–785, 1996.
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Short summary
It is the first study to distinguish the species of nano-sized (d=1−20 nm), small-sized (d=20−450 nm) colloidal P, and dissolved P (d<1 nm) of hydromorphic surface grassland soils from Cambisol, Stagnic Cambisol to Stagnosol using FFF and 31P-NMR. Evidence of nano-sized associations of OC–Fe(Al)–PO43/pyrophosphate in Stagnosol. Stagnic properties affect P speciation and availability by releasing dissolved inorganic and ester-bound P forms as well as nano-sized organic matter–Fe/Al–P colloids.
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