Articles | Volume 14, issue 18
https://doi.org/10.5194/bg-14-4391-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/bg-14-4391-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
29 Sep 2017
Research article |
| 29 Sep 2017
Carbon and nutrient export regimes from headwater catchments to downstream reaches
Department of Aquatic Ecosystems Analysis and Management, Helmholtz Centre for Environmental Research UFZ, Magdeburg, Germany
INRA, UMR1069 SAS, 35000 Rennes, France
Andreas Musolff
Department of Hydrogeology, Helmholtz Centre for Environmental Research UFZ, Leipzig, Germany
James W. Jawitz
Soil and Water Science Department, University of Florida, Gainesville, Florida, USA
P. Suresh C. Rao
School of Civil Engineering and Department of Agronomy, Purdue University, West Lafayette, Indiana, USA
Christoph G. Jäger
Department of Aquatic Ecosystems Analysis and Management, Helmholtz Centre for Environmental Research UFZ, Magdeburg, Germany
Jan H. Fleckenstein
Department of Hydrogeology, Helmholtz Centre for Environmental Research UFZ, Leipzig, Germany
Michael Rode
Department of Aquatic Ecosystems Analysis and Management, Helmholtz Centre for Environmental Research UFZ, Magdeburg, Germany
Dietrich Borchardt
Department of Aquatic Ecosystems Analysis and Management, Helmholtz Centre for Environmental Research UFZ, Magdeburg, Germany
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We developed a parsimonious topography-based hydrologic model coupled with a soil biogeochemistry sub-model in order to improve understanding and prediction of soluble reactive phosphorus (SRP) transfer in agricultural headwater catchments. The modelling approach includes an analysis of the information contained in the calibration data and propagation of uncertainty in model predictions using a GLUE "limits of acceptability" framework.
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Katharina Blaurock, Burkhard Beudert, Benjamin S. Gilfedder, Jan H. Fleckenstein, Stefan Peiffer, and Luisa Hopp
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Dissolved organic carbon (DOC) is an important part of the global carbon cycle with regards to carbon storage, greenhouse gas emissions and drinking water treatment. In this study, we compared DOC export of a small, forested catchment during precipitation events after dry and wet preconditions. We found that the DOC export from areas that are usually important for DOC export was inhibited after long drought periods.
Nathan G. F. Reaver, David A. Kaplan, Harald Klammler, and James W. Jawitz
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2020-585, https://doi.org/10.5194/hess-2020-585, 2020
Manuscript not accepted for further review
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Ingo Heidbüchel, Jie Yang, Andreas Musolff, Peter Troch, Ty Ferré, and Jan H. Fleckenstein
Hydrol. Earth Syst. Sci., 24, 2895–2920, https://doi.org/10.5194/hess-24-2895-2020, https://doi.org/10.5194/hess-24-2895-2020, 2020
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With the help of a 3-D computer model we examined how long the water of different rain events stays inside small catchments before it is discharged and how the nature of this discharge is controlled by different catchment and climate properties. We found that one can only predict the discharge dynamics when taking into account a combination of catchment and climate properties (i.e., there was not one single most important predictor). Our results can help to manage water pollution events.
Hang Wen, Julia Perdrial, Benjamin W. Abbott, Susana Bernal, Rémi Dupas, Sarah E. Godsey, Adrian Harpold, Donna Rizzo, Kristen Underwood, Thomas Adler, Gary Sterle, and Li Li
Hydrol. Earth Syst. Sci., 24, 945–966, https://doi.org/10.5194/hess-24-945-2020, https://doi.org/10.5194/hess-24-945-2020, 2020
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Lateral carbon fluxes from terrestrial to aquatic systems remain central uncertainties in determining ecosystem carbon balance. This work explores how temperature and hydrology control production and export of dissolved organic carbon (DOC) at the catchment scale. Results illustrate the asynchrony of DOC production, controlled by temperature, and export, governed by flow paths; concentration–discharge relationships are determined by the relative contribution of shallow versus groundwater flow.
Adam S. Ward, Steven M. Wondzell, Noah M. Schmadel, Skuyler Herzog, Jay P. Zarnetske, Viktor Baranov, Phillip J. Blaen, Nicolai Brekenfeld, Rosalie Chu, Romain Derelle, Jennifer Drummond, Jan H. Fleckenstein, Vanessa Garayburu-Caruso, Emily Graham, David Hannah, Ciaran J. Harman, Jase Hixson, Julia L. A. Knapp, Stefan Krause, Marie J. Kurz, Jörg Lewandowski, Angang Li, Eugènia Martí, Melinda Miller, Alexander M. Milner, Kerry Neil, Luisa Orsini, Aaron I. Packman, Stephen Plont, Lupita Renteria, Kevin Roche, Todd Royer, Catalina Segura, James Stegen, Jason Toyoda, Jacqueline Hager, and Nathan I. Wisnoski
Hydrol. Earth Syst. Sci., 23, 5199–5225, https://doi.org/10.5194/hess-23-5199-2019, https://doi.org/10.5194/hess-23-5199-2019, 2019
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The movement of water and solutes between streams and their shallow, connected subsurface is important to many ecosystem functions. These exchanges are widely expected to vary with stream flow across space and time, but these assumptions are seldom tested across basin scales. We completed more than 60 experiments across a 5th-order river basin to document these changes, finding patterns in space but not time. We conclude space-for-time and time-for-space substitutions are not good assumptions.
Benedikt J. Werner, Andreas Musolff, Oliver J. Lechtenfeld, Gerrit H. de Rooij, Marieke R. Oosterwoud, and Jan H. Fleckenstein
Biogeosciences, 16, 4497–4516, https://doi.org/10.5194/bg-16-4497-2019, https://doi.org/10.5194/bg-16-4497-2019, 2019
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Increased dissolved organic carbon (DOC) concentration in streams can pose a threat to downstream water resources. Analyzing data from an in-stream probe we found that hydroclimatic and hydrological drivers can describe up to 72 % of the observed DOC concentration and composition variability. Variability was found to be highest during discharge events with warm and dry preconditions. The findings suggest an impact of climate change on DOC exports and thus also on downstream water quality.
Adam S. Ward, Jay P. Zarnetske, Viktor Baranov, Phillip J. Blaen, Nicolai Brekenfeld, Rosalie Chu, Romain Derelle, Jennifer Drummond, Jan H. Fleckenstein, Vanessa Garayburu-Caruso, Emily Graham, David Hannah, Ciaran J. Harman, Skuyler Herzog, Jase Hixson, Julia L. A. Knapp, Stefan Krause, Marie J. Kurz, Jörg Lewandowski, Angang Li, Eugènia Martí, Melinda Miller, Alexander M. Milner, Kerry Neil, Luisa Orsini, Aaron I. Packman, Stephen Plont, Lupita Renteria, Kevin Roche, Todd Royer, Noah M. Schmadel, Catalina Segura, James Stegen, Jason Toyoda, Jacqueline Hager, Nathan I. Wisnoski, and Steven M. Wondzell
Earth Syst. Sci. Data, 11, 1567–1581, https://doi.org/10.5194/essd-11-1567-2019, https://doi.org/10.5194/essd-11-1567-2019, 2019
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Studies of river corridor exchange commonly focus on characterization of the physical, chemical, or biological system. As a result, complimentary systems and context are often lacking, which may limit interpretation. Here, we present a characterization of all three systems at 62 sites in a 5th-order river basin, including samples of surface water, hyporheic water, and sediment. These data will allow assessment of interacting processes in the river corridor.
Sophie Ehrhardt, Rohini Kumar, Jan H. Fleckenstein, Sabine Attinger, and Andreas Musolff
Hydrol. Earth Syst. Sci., 23, 3503–3524, https://doi.org/10.5194/hess-23-3503-2019, https://doi.org/10.5194/hess-23-3503-2019, 2019
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This study shows quantitative and temporal offsets between nitrogen input and riverine output, using time series of three nested catchments in central Germany. The riverine concentrations show lagged reactions to the input, but at the same time exhibit strong inter-annual changes in the relationship between riverine discharge and concentration. The study found a strong retention of nitrogen that is dominantly assigned to a hydrological N legacy, which will affect future stream concentrations.
Julia Vanessa Kunz, Michael D. Annable, Jaehyun Cho, Wolf von Tümpling, Kirk Hatfield, Suresh Rao, Dietrich Borchardt, and Michael Rode
Biogeosciences, 14, 631–649, https://doi.org/10.5194/bg-14-631-2017, https://doi.org/10.5194/bg-14-631-2017, 2017
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The hyporheic zone, the subsurface region of streams, is a key compartment for in-stream nutrient retention. Knowledge on actual hyporheic processing rates is still limited due to methodological restrictions which are mainly related to the high local and temporal variability of subsurface flow patterns and nutrient transformation processes. We present a new device which allows quantitative assessment of hyporheic nutrient fluxes and demonstrate its advantages in an exemplary field testing.
Rémi Dupas, Jordy Salmon-Monviola, Keith J. Beven, Patrick Durand, Philip M. Haygarth, Michael J. Hollaway, and Chantal Gascuel-Odoux
Hydrol. Earth Syst. Sci., 20, 4819–4835, https://doi.org/10.5194/hess-20-4819-2016, https://doi.org/10.5194/hess-20-4819-2016, 2016
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We developed a parsimonious topography-based hydrologic model coupled with a soil biogeochemistry sub-model in order to improve understanding and prediction of soluble reactive phosphorus (SRP) transfer in agricultural headwater catchments. The modelling approach includes an analysis of the information contained in the calibration data and propagation of uncertainty in model predictions using a GLUE "limits of acceptability" framework.
Stephen T. Casey, Matthew J. Cohen, Subodh Acharya, David A. Kaplan, and James W. Jawitz
Hydrol. Earth Syst. Sci., 20, 4457–4467, https://doi.org/10.5194/hess-20-4457-2016, https://doi.org/10.5194/hess-20-4457-2016, 2016
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The ridge–slough landscape is a major part of the Everglades, a critically imperiled wetland in south Florida (USA). The landscape consists of two wetland types, shallow water ridges and deep water sloughs, interspersed in a complex pattern. Human changes to hydrology have changed this pattern, impacting water flow, fish movement, and bird habitat. Restoring pattern requires understanding its origins. We describe the pattern in detail, gaining insights relevant for management on its origins.
W. He, C. Beyer, J. H. Fleckenstein, E. Jang, O. Kolditz, D. Naumov, and T. Kalbacher
Geosci. Model Dev., 8, 3333–3348, https://doi.org/10.5194/gmd-8-3333-2015, https://doi.org/10.5194/gmd-8-3333-2015, 2015
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This technical paper presents a new tool to simulate reactive transport processes in subsurface systems and which couples the open-source software packages OpenGeoSys and IPhreeqc. A flexible parallelization scheme was developed and implemented to enable an optimized allocation of computer resources. The performance tests of the coupling interface and parallelization scheme illustrate the promising efficiency of this generally valid approach to simulate reactive transport problems.
S. Acharya, D. A. Kaplan, S. Casey, M. J. Cohen, and J. W. Jawitz
Hydrol. Earth Syst. Sci., 19, 2133–2144, https://doi.org/10.5194/hess-19-2133-2015, https://doi.org/10.5194/hess-19-2133-2015, 2015
B. J. Kopp, J. H. Fleckenstein, N. T. Roulet, E. Humphreys, J. Talbot, and C. Blodau
Hydrol. Earth Syst. Sci., 17, 3485–3498, https://doi.org/10.5194/hess-17-3485-2013, https://doi.org/10.5194/hess-17-3485-2013, 2013
S. Strohmeier, K.-H. Knorr, M. Reichert, S. Frei, J. H. Fleckenstein, S. Peiffer, and E. Matzner
Biogeosciences, 10, 905–916, https://doi.org/10.5194/bg-10-905-2013, https://doi.org/10.5194/bg-10-905-2013, 2013
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Local processes with a global impact: unraveling the dynamics of gas evasion in a step-and-pool configuration
Complex dissolved organic matter (DOM) on the roof of the world – Tibetan DOM molecular characteristics indicate sources, land use effects, and processing along the fluvial–limnic continuum
Maximum respiration rates in hyporheic zone sediments are primarily constrained by organic carbon concentration and secondarily by organic matter chemistry
Glacier loss and vegetation expansion alter organic and inorganic carbon dynamics in high-mountain streams
Particulate organic matter in the Lena River and its delta: from the permafrost catchment to the Arctic Ocean
Stable isotopic evidence for the excess leaching of unprocessed atmospheric nitrate from forested catchments under high nitrogen saturation
Nitrogen isotopes reveal a particulate-matter-driven biogeochemical reactor in a temperate estuary
High-resolution vertical biogeochemical profiles in the hyporheic zone reveal insights into microbial methane cycling
Organic matter transformations are disconnected between surface water and the hyporheic zone
CO2 emissions from peat-draining rivers regulated by water pH
Effects of peatland management on aquatic carbon concentrations and fluxes
Resistance and resilience of stream metabolism to high flow disturbances
Enhanced bioavailability of dissolved organic matter (DOM) in human-disturbed streams in Alpine fluvial networks
Spatial and temporal variability of pCO2 and CO2 emissions from the Dong River in south China
Fluvial carbon dioxide emission from the Lena River basin during the spring flood
Diel patterns in stream nitrate concentration produced by in-stream processes
Complex interactions of in-stream dissolved organic matter and nutrient spiralling unravelled by Bayesian regression analysis
Spatial–temporal variations in riverine carbon strongly influenced by local hydrological events in an alpine catchment
Rapid soil organic carbon decomposition in river systems: effects of the aquatic microbial community and hydrodynamical disturbance
Increased carbon capture by a silicate-treated forested watershed affected by acid deposition
Thermokarst amplifies fluvial inorganic carbon cycling and export across watershed scales on the Peel Plateau, Canada
Temporary and net sinks of atmospheric CO2 due to chemical weathering in subtropical catchment with mixing carbonate and silicate lithology
From canals to the coast: dissolved organic matter and trace metal composition in rivers draining degraded tropical peatlands in Indonesia
Distribution and flux of dissolved iron in the peatland-draining rivers and estuaries of Sarawak, Malaysian Borneo
Comparisons of dissolved organic matter and its optical characteristics in small low and high Arctic catchments
High-frequency measurements explain quantity and quality of dissolved organic carbon mobilization in a headwater catchment
Dissolved inorganic nitrogen in a tropical estuary in Malaysia: transport and transformation
Behaviour of Dissolved Phosphorus with the associated nutrients in relation to phytoplankton biomass of the Rajang River-South China Sea continuum
Synchrony in catchment stream colour levels is driven by both local and regional climate
The post-monsoon carbon biogeochemistry of the Hooghly–Sundarbans estuarine system under different levels of anthropogenic impacts
Riverine particulate C and N generated at the permafrost thaw front: case study of western Siberian rivers across a 1700 km latitudinal transect
Geochemistry of the dissolved loads during high-flow season of rivers in the southeastern coastal region of China: anthropogenic impact on chemical weathering and carbon sequestration
CO2 partial pressure and CO2 emission along the lower Red River (Vietnam)
Stable isotopes of nitrate reveal different nitrogen processing mechanisms in streams across a land use gradient during wet and dry periods
Riverine carbon export in the arid to semiarid Wuding River catchment on the Chinese Loess Plateau
Use of argon to measure gas exchange in turbulent mountain streams
Reviews and syntheses: Anthropogenic perturbations to carbon fluxes in Asian river systems – concepts, emerging trends, and research challenges
Shifts in stream hydrochemistry in responses to typhoon and non-typhoon precipitation
QUAL-NET, a high temporal-resolution eutrophication model for large hydrographic networks
Diel fluctuations of viscosity-driven riparian inflow affect streamflow DOC concentration
A comprehensive biogeochemical record and annual flux estimates for the Sabaki River (Kenya)
Thibault Lambert, Rémi Dupas, and Patrick Durand
Biogeosciences, 21, 4533–4547, https://doi.org/10.5194/bg-21-4533-2024, https://doi.org/10.5194/bg-21-4533-2024, 2024
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This study investigates dissolved organic carbon (DOC) export in headwater catchments. Results show small links between DOC, nitrates, and the iron cycle throughout the year, calling into question our current conceptualization of DOC export at the catchment scale. Indeed, this study evidences that the winter period, referred as a non-productive period in our current conceptual model, acts as an active period for DOC production in riparian soils and DOC export toward stream waters.
Alexander Wachholz, James W. Jawitz, and Dietrich Borchardt
Biogeosciences, 21, 3537–3550, https://doi.org/10.5194/bg-21-3537-2024, https://doi.org/10.5194/bg-21-3537-2024, 2024
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Human activities are rivers' main source of nitrogen, causing eutrophication and other hazards. However, rivers can serve as a natural defense mechanism against this by retaining nitrogen. We show that the Elbe River retains more nitrogen during times of high pollution. With improvements in water quality, less nitrogen is retained. We explain this with changed algal and bacterial activities, which correspond to pollution and have many implications for the river and adjacent ecosystems.
Katie A. Wampler, Kevin D. Bladon, and Allison N. Myers-Pigg
Biogeosciences, 21, 3093–3120, https://doi.org/10.5194/bg-21-3093-2024, https://doi.org/10.5194/bg-21-3093-2024, 2024
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Following a high-severity wildfire, we sampled 129 sites during four different times of the year across a stream network to quantify dissolved organic carbon. The results from our study suggested that dissolved organic carbon may decrease with increasing burn severity. They also suggest that landscape characteristics can override wildfire impacts, with the seasonal timing of sampling influencing the observed response of dissolved organic carbon concentrations to wildfire.
Eva L. Doting, Ian T. Stevens, Anne M. Kellerman, Pamela E. Rossel, Runa Antony, Amy M. McKenna, Martyn Tranter, Liane G. Benning, Robert G. M. Spencer, Jon R. Hawkings, and Alexandre M. Anesio
EGUsphere, https://doi.org/10.5194/egusphere-2024-492, https://doi.org/10.5194/egusphere-2024-492, 2024
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This study provides new insights into the transformation of dissolved organic matter (DOM) that takes place as meltwater flows through the porous crust of weathering ice that covers glacier ice surfaces during the melt season. Movement of water through the weathering crust is slow, allowing microorganisms and sunlight to alter the DOM in glacial meltwater. This is important as supraglacial meltwaters deliver DOM and nutrients to microorganisms living in downstream receiving aquatic environments.
Artem V. Chupakov, Anna Chupakova, Svetlana A. Zabelina, Liudmila S. Shirokova, and Oleg S. Pokrovsky
EGUsphere, https://doi.org/10.5194/egusphere-2024-233, https://doi.org/10.5194/egusphere-2024-233, 2024
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In boreal (non-permafrost) humic (>15 mg DOC/L) waters of a forest lake and a bog, the experimentally measured rate of photodegradation is 4 times higher than that of biodegradation. However, given the shallow (0.5 m) light-penetrating layer versus the full depth of water column (2–10 m), the biodegradation may provide the largest contribution to CO2 emission from the water surfaces
Kirsi H. Keskitalo, Lisa Bröder, Tommaso Tesi, Paul J. Mann, Dirk J. Jong, Sergio Bulte Garcia, Anna Davydova, Sergei Davydov, Nikita Zimov, Negar Haghipour, Timothy I. Eglinton, and Jorien E. Vonk
Biogeosciences, 21, 357–379, https://doi.org/10.5194/bg-21-357-2024, https://doi.org/10.5194/bg-21-357-2024, 2024
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Permafrost thaw releases organic carbon into waterways. Decomposition of this carbon pool emits greenhouse gases into the atmosphere, enhancing climate warming. We show that Arctic river carbon and water chemistry are different between the spring ice breakup and summer and that primary production is initiated in small Arctic rivers right after ice breakup, in contrast to in large rivers. This may have implications for fluvial carbon dynamics and greenhouse gas uptake and emission balance.
Shuai Chen, Jun Zhong, Lishan Ran, Yuanbi Yi, Wanfa Wang, Zelong Yan, Si-liang Li, and Khan M. G. Mostofa
Biogeosciences, 20, 4949–4967, https://doi.org/10.5194/bg-20-4949-2023, https://doi.org/10.5194/bg-20-4949-2023, 2023
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This study found the source of dissolved organic carbon and its optical properties (e.g., aromaticity, humification) are related to human land use and catchment slope in anthropogenically impacted subtropical mountainous rivers. The study highlights that the combination of dual carbon isotopes and optical properties represents a useful tool in tracing the origin of dissolved organic carbon and its in-stream processes.
Nele Lehmann, Hugues Lantuit, Michael Ernst Böttcher, Jens Hartmann, Antje Eulenburg, and Helmuth Thomas
Biogeosciences, 20, 3459–3479, https://doi.org/10.5194/bg-20-3459-2023, https://doi.org/10.5194/bg-20-3459-2023, 2023
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Riverine alkalinity in the silicate-dominated headwater catchment at subarctic Iskorasfjellet, northern Norway, was almost entirely derived from weathering of minor carbonate occurrences in the riparian zone. The uphill catchment appeared limited by insufficient contact time of weathering agents and weatherable material. Further, alkalinity increased with decreasing permafrost extent. Thus, with climate change, alkalinity generation is expected to increase in this permafrost-degrading landscape.
Jancoba Dorley, Joel Singley, Tim Covino, Kamini Singha, Michael Gooseff, David Van Horn, and Ricardo González-Pinzón
Biogeosciences, 20, 3353–3366, https://doi.org/10.5194/bg-20-3353-2023, https://doi.org/10.5194/bg-20-3353-2023, 2023
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We quantified how microbial respiration is controlled by discharge and the supply of C, N, and P in a stream. We ran two rounds of experiments adding a conservative tracer, an indicator of aerobic respiration, and nutrient treatments: a) N, b) N+C, c) N+P, and d) C+N+P. Microbial respiration remained similar between rounds and across nutrient treatments. This suggests that complex interactions between hydrology, resource supply, and biological community drive in-stream respiration.
Paolo Peruzzo, Matteo Cappozzo, Nicola Durighetto, and Gianluca Botter
Biogeosciences, 20, 3261–3271, https://doi.org/10.5194/bg-20-3261-2023, https://doi.org/10.5194/bg-20-3261-2023, 2023
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Small cascades greatly enhance mountain stream gas emissions through the turbulent energy dissipation rate and air bubbles entrained into the water. We numerically studied the local contribution of these mechanisms driving gas transfer velocity used to quantify the outgassing. The gas evasion is primarily due to bubbles concentrated in irregular spots of limited area. Consequently, the gas exchange velocity is scale-dependent and unpredictable, posing concerns about its use in similar scenarios.
Philipp Maurischat, Michael Seidel, Thorsten Dittmar, and Georg Guggenberger
Biogeosciences, 20, 3011–3026, https://doi.org/10.5194/bg-20-3011-2023, https://doi.org/10.5194/bg-20-3011-2023, 2023
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Production and consumption of organic matter (OM) on the Tibetan Plateau are important for this sensitive ecosystem. We investigated the chemical composition of dissolved organic matter and the most mobile fraction of OM in glaciers, wetlands, and groundwater as well as in the rivers and a large terminal lake. Our data show that the sources differ in the molecular composition of OM, that the stream is influenced by agriculture, and that the lake strongly changes the inflowing organic matter.
James C. Stegen, Vanessa A. Garayburu-Caruso, Robert E. Danczak, Amy E. Goldman, Lupita Renteria, Joshua M. Torgeson, and Jacqueline Hager
Biogeosciences, 20, 2857–2867, https://doi.org/10.5194/bg-20-2857-2023, https://doi.org/10.5194/bg-20-2857-2023, 2023
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Chemical reactions in river sediments influence how clean the water is and how much greenhouse gas comes out of a river. Our study investigates why some sediments have higher rates of chemical reactions than others. We find that to achieve high rates, sediments need to have two things: only a few different kinds of molecules, but a lot of them. This result spans about 80 rivers such that it could be a general rule, helpful for predicting the future of rivers and our planet.
Andrew L. Robison, Nicola Deluigi, Camille Rolland, Nicolas Manetti, and Tom Battin
Biogeosciences, 20, 2301–2316, https://doi.org/10.5194/bg-20-2301-2023, https://doi.org/10.5194/bg-20-2301-2023, 2023
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Climate change is affecting mountain ecosystems intensely, including the loss of glaciers and the uphill migration of plants. How these changes will affect the streams draining these landscapes is unclear. We sampled streams across a gradient of glacier and vegetation cover in Switzerland and found glacier loss reduced the carbon dioxide sink from weathering, while vegetation cover increased dissolved organic carbon in the stream. These changes are important to consider for mountains globally.
Olga Ogneva, Gesine Mollenhauer, Bennet Juhls, Tina Sanders, Juri Palmtag, Matthias Fuchs, Hendrik Grotheer, Paul J. Mann, and Jens Strauss
Biogeosciences, 20, 1423–1441, https://doi.org/10.5194/bg-20-1423-2023, https://doi.org/10.5194/bg-20-1423-2023, 2023
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Arctic warming accelerates permafrost thaw and release of terrestrial organic matter (OM) via rivers to the Arctic Ocean. We compared particulate organic carbon (POC), total suspended matter, and C isotopes (δ13C and Δ14C of POC) in the Lena delta and Lena River along a ~1600 km transect. We show that the Lena delta, as an interface between the Lena River and the Arctic Ocean, plays a crucial role in determining the qualitative and quantitative composition of OM discharged into the Arctic Ocean.
Weitian Ding, Urumu Tsunogai, Fumiko Nakagawa, Takashi Sambuichi, Masaaki Chiwa, Tamao Kasahara, and Ken'ichi Shinozuka
Biogeosciences, 20, 753–766, https://doi.org/10.5194/bg-20-753-2023, https://doi.org/10.5194/bg-20-753-2023, 2023
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By monitoring the concentration and Δ17O of stream nitrate in three forested streams, the new nitrogen saturation index of forested catchments (Matm/Datm ratio) was estimated. We found that (1) the unprocessed atmospheric nitrate in our studied forested stream (FK1 catchment) was the highest ever reported in forested streams; (2) the Matm/Datm ratio can be used as a robust index for evaluating nitrogen saturation in forested catchments as the Matm/Datm ratio is independent of the precipitation.
Kirstin Dähnke, Tina Sanders, Yoana Voynova, and Scott D. Wankel
Biogeosciences, 19, 5879–5891, https://doi.org/10.5194/bg-19-5879-2022, https://doi.org/10.5194/bg-19-5879-2022, 2022
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Nitrogen is an important macronutrient that fuels algal production in rivers and coastal regions. We investigated the production and removal of nitrogen-bearing compounds in the freshwater section of the tidal Elbe Estuary and found that particles in the water column are key for the production and removal of water column nitrate. Using a stable isotope approach, we pinpointed regions where additional removal of nitrate or input from sediments plays an important role in estuarine biogeochemistry.
Tamara Michaelis, Anja Wunderlich, Ömer K. Coskun, William Orsi, Thomas Baumann, and Florian Einsiedl
Biogeosciences, 19, 4551–4569, https://doi.org/10.5194/bg-19-4551-2022, https://doi.org/10.5194/bg-19-4551-2022, 2022
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The greenhouse gas methane (CH4) drives climate change. Microorganisms in river sediments produce CH4 when degrading organic matter, but the contribution of rivers to atmospheric CH4 concentrations is uncertain. To better understand riverine CH4 cycling, we measured concentration profiles of CH4 and relevant reactants that might influence the CH4 cycle. We found substantial CH4 production, especially in fine, organic-rich sediments during summer and signs of microbial CH4 consumption.
James C. Stegen, Sarah J. Fansler, Malak M. Tfaily, Vanessa A. Garayburu-Caruso, Amy E. Goldman, Robert E. Danczak, Rosalie K. Chu, Lupita Renteria, Jerry Tagestad, and Jason Toyoda
Biogeosciences, 19, 3099–3110, https://doi.org/10.5194/bg-19-3099-2022, https://doi.org/10.5194/bg-19-3099-2022, 2022
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Rivers are vital to Earth, and in rivers, organic matter (OM) is an energy source for microbes that make greenhouse gas and remove contaminants. Predicting Earth’s future requires understanding how and why river OM is transformed. Our results help meet this need. We found that the processes influencing OM transformations diverge between river water and riverbed sediments. This can be used to build new models for predicting the future of rivers and, in turn, the Earth system.
Alexandra Klemme, Tim Rixen, Denise Müller-Dum, Moritz Müller, Justus Notholt, and Thorsten Warneke
Biogeosciences, 19, 2855–2880, https://doi.org/10.5194/bg-19-2855-2022, https://doi.org/10.5194/bg-19-2855-2022, 2022
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Tropical peat-draining rivers contain high amounts of carbon. Surprisingly, measured carbon dioxide (CO2) emissions from those rivers are comparatively moderate. We compiled data from 10 Southeast Asian rivers and found that CO2 production within these rivers is hampered by low water pH, providing a natural threshold for CO2 emissions. Furthermore, we find that enhanced carbonate input, e.g. caused by human activities, suspends this natural threshold and causes increased CO2 emissions.
Amy E. Pickard, Marcella Branagan, Mike F. Billett, Roxane Andersen, and Kerry J. Dinsmore
Biogeosciences, 19, 1321–1334, https://doi.org/10.5194/bg-19-1321-2022, https://doi.org/10.5194/bg-19-1321-2022, 2022
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Peatlands have been subject to a range of land management regimes over the past century. This has affected the amount of carbon that drains into surrounding streams and rivers. In our study, we measured carbon concentrations in streams draining from drained, non-drained, and restored areas of the Flow Country blanket bog in N Scotland. We found that drained peatland had higher concentrations and fluxes of carbon relative to non-drained areas. Restored peatland areas were highly variable.
Brynn O'Donnell and Erin R. Hotchkiss
Biogeosciences, 19, 1111–1134, https://doi.org/10.5194/bg-19-1111-2022, https://doi.org/10.5194/bg-19-1111-2022, 2022
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A stream is defined by flowing water, but higher flow from storms is also a frequent disturbance. This paper tests how higher flow changes stream metabolism (respiration and photosynthesis, R and P). P was less resistant to changes in flow compared to R, and P took longer to recover from storms than R (2.2 versus 0.6 d). Further work on metabolic responses to flow disturbance is critical given projected increases in storms and the influence of higher flows on ecosystem health and functioning.
Thibault Lambert, Pascal Perolo, Nicolas Escoffier, and Marie-Elodie Perga
Biogeosciences, 19, 187–200, https://doi.org/10.5194/bg-19-187-2022, https://doi.org/10.5194/bg-19-187-2022, 2022
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The bacterial mineralization of dissolved organic matter (DOM) in inland waters contributes to CO2 emissions to the atmosphere. Human activities affect DOM sources. However, the implications on DOM mineralization are poorly known. Combining sampling and incubations, we showed that higher bacterial respiration in agro-urban streams related to a labile pool from aquatic origin. Therefore, human activities may have a limited impact on the net carbon exchanges between inland waters and atmosphere.
Boyi Liu, Mingyang Tian, Kaimin Shih, Chun Ngai Chan, Xiankun Yang, and Lishan Ran
Biogeosciences, 18, 5231–5245, https://doi.org/10.5194/bg-18-5231-2021, https://doi.org/10.5194/bg-18-5231-2021, 2021
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Spatial and temporal patterns of pCO2 in the subtropical Dong River basin were mainly affected by C inputs and in-stream metabolism, both of which varied due to differential catchment settings, land cover, and hydrological conditions. CO2 fluxes in the wet season were 2-fold larger than in the dry season due to high pCO2 and turbulence caused by high flow velocity. The absence of high CO2 fluxes in small rivers could be associated with the depletion effect caused by abundant precipitation.
Sergey N. Vorobyev, Jan Karlsson, Yuri Y. Kolesnichenko, Mikhail A. Korets, and Oleg S. Pokrovsky
Biogeosciences, 18, 4919–4936, https://doi.org/10.5194/bg-18-4919-2021, https://doi.org/10.5194/bg-18-4919-2021, 2021
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In order to quantify riverine carbon (C) exchange with the atmosphere in permafrost regions, we report a first assessment of CO2 and CH4 concentration and fluxes of the largest permafrost-affected river, the Lena River, during the peak of spring flow. The results allowed identification of environmental factors controlling GHG concentrations and emission in the Lena River watershed; this new knowledge can be used for foreseeing future changes in C balance in permafrost-affected Arctic rivers.
Jan Greiwe, Markus Weiler, and Jens Lange
Biogeosciences, 18, 4705–4715, https://doi.org/10.5194/bg-18-4705-2021, https://doi.org/10.5194/bg-18-4705-2021, 2021
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We analyzed variability in diel nitrate patterns at three locations in a lowland stream. Comparison of time lags between monitoring sites with water travel time indicated that diel patterns were created by in-stream processes rather than transported downstream from an upstream point of origin. Most of the patterns (70 %) could be explained by assimilatory nitrate uptake. The remaining patterns suggest seasonally varying dominance and synchronicity of different biochemical processes.
Matthias Pucher, Peter Flödl, Daniel Graeber, Klaus Felsenstein, Thomas Hein, and Gabriele Weigelhofer
Biogeosciences, 18, 3103–3122, https://doi.org/10.5194/bg-18-3103-2021, https://doi.org/10.5194/bg-18-3103-2021, 2021
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Dissolved organic matter is an important carbon source in aquatic ecosystems, yet the uptake processes are not totally understood. We found evidence for the release of degradation products, efficiency loss in the uptake with higher concentrations, stimulating effects, and quality-dependent influences from the benthic zone. To conduct this analysis, we included interactions in the equations of the nutrient spiralling concept and solve it with a Bayesian non-linear fitting algorithm.
Xin Wang, Ting Liu, Liang Wang, Zongguang Liu, Erxiong Zhu, Simin Wang, Yue Cai, Shanshan Zhu, and Xiaojuan Feng
Biogeosciences, 18, 3015–3028, https://doi.org/10.5194/bg-18-3015-2021, https://doi.org/10.5194/bg-18-3015-2021, 2021
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We show a comprehensive monitoring dataset on the discharge and carbon transport in a small alpine river on the Qinghai–Tibetan Plateau, where riverine carbon increased downstream in the pre-monsoon season due to an increasing contribution of organic matter derived from seasonal permafrost thaw while it fluctuated in the monsoon season induced by sporadic precipitation. These results indicate a high sensitivity of riverine carbon in alpine headwater catchments to local hydrological events.
Man Zhao, Liesbet Jacobs, Steven Bouillon, and Gerard Govers
Biogeosciences, 18, 1511–1523, https://doi.org/10.5194/bg-18-1511-2021, https://doi.org/10.5194/bg-18-1511-2021, 2021
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We investigate the relative importance of two individual factors (hydrodynamical disturbance and aquatic microbial community) that possibly control SOC decomposition rates in river systems. We found aquatic microbial organisms led to rapid SOC decomposition, while effect of mechanical disturbance is relative minor. We propose a simple conceptual model: hydrodynamic disturbance is only important when soil aggregates are strong enough to withstand the disruptive forces imposed by water immersions.
Lyla L. Taylor, Charles T. Driscoll, Peter M. Groffman, Greg H. Rau, Joel D. Blum, and David J. Beerling
Biogeosciences, 18, 169–188, https://doi.org/10.5194/bg-18-169-2021, https://doi.org/10.5194/bg-18-169-2021, 2021
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Enhanced rock weathering (ERW) is a carbon dioxide removal (CDR) strategy involving soil amendments with silicate rock dust. Over 15 years, a small silicate application led to net CDR of 8.5–11.5 t CO2/ha in an acid-rain-impacted New Hampshire forest. We accounted for the total carbon cost of treatment and compared effects with an adjacent, untreated forest. Our results suggest ERW can improve the greenhouse gas balance of similar forests in addition to mitigating acid rain effects.
Scott Zolkos, Suzanne E. Tank, Robert G. Striegl, Steven V. Kokelj, Justin Kokoszka, Cristian Estop-Aragonés, and David Olefeldt
Biogeosciences, 17, 5163–5182, https://doi.org/10.5194/bg-17-5163-2020, https://doi.org/10.5194/bg-17-5163-2020, 2020
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High-latitude warming thaws permafrost, exposing minerals to weathering and fluvial transport. We studied the effects of abrupt thaw and associated weathering on carbon cycling in western Canada. Permafrost collapse affected < 1 % of the landscape yet enabled carbonate weathering associated with CO2 degassing in headwaters and increased bicarbonate export across watershed scales. Weathering may become a driver of carbon cycling in ice- and mineral-rich permafrost terrain across the Arctic.
Yingjie Cao, Yingxue Xuan, Changyuan Tang, Shuai Guan, and Yisheng Peng
Biogeosciences, 17, 3875–3890, https://doi.org/10.5194/bg-17-3875-2020, https://doi.org/10.5194/bg-17-3875-2020, 2020
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About half of the global CO2 sequestration due to chemical weathering occurs in warm and high-runoff regions. To evaluate the temporary and net sinks of atmospheric CO2 due to chemical weathering, we selected a typical subtropical catchment as our study area and did fieldwork to sample surface water along the main channel and major tributaries in 1 hydrological year. The result of mass balance calculation showed that human activities dramatically decreased the CO2 net sink.
Laure Gandois, Alison M. Hoyt, Stéphane Mounier, Gaël Le Roux, Charles F. Harvey, Adrien Claustres, Mohammed Nuriman, and Gusti Anshari
Biogeosciences, 17, 1897–1909, https://doi.org/10.5194/bg-17-1897-2020, https://doi.org/10.5194/bg-17-1897-2020, 2020
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Worldwide, peatlands are important sources of dissolved organic matter (DOM) and trace metals (TMs) to surface waters, and these fluxes may increase with peatland degradation. In Southeast Asia, tropical peatlands are being rapidly deforested and drained. This work aims to address the fate of organic carbon and its role as a trace metal carrier in drained peatlands of Indonesia.
Xiaohui Zhang, Moritz Müller, Shan Jiang, Ying Wu, Xunchi Zhu, Aazani Mujahid, Zhuoyi Zhu, Mohd Fakharuddin Muhamad, Edwin Sien Aun Sia, Faddrine Holt Ajon Jang, and Jing Zhang
Biogeosciences, 17, 1805–1819, https://doi.org/10.5194/bg-17-1805-2020, https://doi.org/10.5194/bg-17-1805-2020, 2020
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This study offered detailed information on dFe concentrations, distribution and the magnitude of yield in the Rajang River, the largest river in Malaysia. Three blackwater rivers, draining from peatlands, were also included in our study. Compared with the Rajang River, the dFe concentrations and yield from three blackwater rivers were much higher. The precipitation and agricultural activities, such as palm oil plantations, may markedly increase the concentration dFe in these tropical rivers.
Caroline Coch, Bennet Juhls, Scott F. Lamoureux, Melissa J. Lafrenière, Michael Fritz, Birgit Heim, and Hugues Lantuit
Biogeosciences, 16, 4535–4553, https://doi.org/10.5194/bg-16-4535-2019, https://doi.org/10.5194/bg-16-4535-2019, 2019
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Climate change affects Arctic ecosystems. This includes thawing of permafrost (ground below 0 °C) and an increase in rainfall. Both have substantial impacts on the chemical composition of river water. We compared the composition of small rivers in the low and high Arctic with the large Arctic rivers. In comparison, dissolved organic matter in the small rivers is more susceptible to degradation; thus, it could potentially increase carbon dioxide emissions. Rainfall events have a similar effect.
Benedikt J. Werner, Andreas Musolff, Oliver J. Lechtenfeld, Gerrit H. de Rooij, Marieke R. Oosterwoud, and Jan H. Fleckenstein
Biogeosciences, 16, 4497–4516, https://doi.org/10.5194/bg-16-4497-2019, https://doi.org/10.5194/bg-16-4497-2019, 2019
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Increased dissolved organic carbon (DOC) concentration in streams can pose a threat to downstream water resources. Analyzing data from an in-stream probe we found that hydroclimatic and hydrological drivers can describe up to 72 % of the observed DOC concentration and composition variability. Variability was found to be highest during discharge events with warm and dry preconditions. The findings suggest an impact of climate change on DOC exports and thus also on downstream water quality.
Shan Jiang, Moritz Müller, Jie Jin, Ying Wu, Kun Zhu, Guosen Zhang, Aazani Mujahid, Tim Rixen, Mohd Fakharuddin Muhamad, Edwin Sien Aun Sia, Faddrine Holt Ajon Jang, and Jing Zhang
Biogeosciences, 16, 2821–2836, https://doi.org/10.5194/bg-16-2821-2019, https://doi.org/10.5194/bg-16-2821-2019, 2019
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Three cruises were conducted in the Rajang River estuary, Malaysia. The results revealed that the decomposition of terrestrial organic matter and the subsequent soil leaching were the main sources of dissolved inorganic nitrogen (DIN) in the fresh river water. Porewater exchange and ammonification enhanced DIN concentrations in the estuary water, while intensities of DIN addition varied between seasons. The riverine DIN flux could reach 101.5 ton(N) / d, supporting the coastal primary producers.
Edwin Sien Aun Sia, Jing Zhang, Shan Jiang, Zhuoyi Zhu, Gonzalo Carrasco, Faddrine Holt Jang, Aazani Mujahid, and Moritz Müller
Biogeosciences Discuss., https://doi.org/10.5194/bg-2019-219, https://doi.org/10.5194/bg-2019-219, 2019
Revised manuscript not accepted
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Nutrient loads carried by large rivers and discharged into the continental shelf and coastal waters are vital to support primary production. Our knowledge of tropical river systems is fragmented with very few seasonal studies available for Southeast Asia (SEA). We present data from three sampling campaigns on the longest river in Malaysia, the Rajang river. Our results show the generalization of SEA as a nutrient hotspot might not hold true for all regions and requires further investigation.
Brian C. Doyle, Elvira de Eyto, Mary Dillane, Russell Poole, Valerie McCarthy, Elizabeth Ryder, and Eleanor Jennings
Biogeosciences, 16, 1053–1071, https://doi.org/10.5194/bg-16-1053-2019, https://doi.org/10.5194/bg-16-1053-2019, 2019
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This study explores the drivers of variation in the water colour of rivers, and hence organic carbon export, in a blanket peatland catchment. We used 6 years of weekly river water colour data (2011 to 2016) from three proximate river sub-catchments in western Ireland. in tandem with a range of topographical, hydrological and climate data, to discover the principle environmental drivers controlling changes in colour concentration in the rivers.
Manab Kumar Dutta, Sanjeev Kumar, Rupa Mukherjee, Prasun Sanyal, and Sandip Kumar Mukhopadhyay
Biogeosciences, 16, 289–307, https://doi.org/10.5194/bg-16-289-2019, https://doi.org/10.5194/bg-16-289-2019, 2019
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The study focused on understanding C biogeochemistry of two adjacently located estuaries undergoing different levels of anthropogenic stresses. Different parameters related to C cycling were measured in an anthropogenically influenced and a mangrove-dominated estuary. Although the entire estuarine system acted as a source of carbon dioxide to the regional atmosphere, emission approximately 17 times higher was noticed from the anthropogenically affected estuary compared to mangrove-dominated one.
Ivan V. Krickov, Artem G. Lim, Rinat M. Manasypov, Sergey V. Loiko, Liudmila S. Shirokova, Sergey N. Kirpotin, Jan Karlsson, and Oleg S. Pokrovsky
Biogeosciences, 15, 6867–6884, https://doi.org/10.5194/bg-15-6867-2018, https://doi.org/10.5194/bg-15-6867-2018, 2018
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We tested the effect of climate, permafrost and physio-geographical landscape parameters on particulate C, N and P concentrations in small- and medium- sized rivers in the Western Siberian Lowland (WSL). We discovered a maximum of particulate C and N concentrations at the beginning of the permafrost appearance. A northward shift of permafrost boundaries may increase the particulate C and N export by WSL rivers to the Arctic Ocean by a factor of 2.
Wenjing Liu, Zhifang Xu, Huiguo Sun, Tong Zhao, Chao Shi, and Taoze Liu
Biogeosciences, 15, 4955–4971, https://doi.org/10.5194/bg-15-4955-2018, https://doi.org/10.5194/bg-15-4955-2018, 2018
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The southeastern coastal region is the top acid-rain-impacted area in China. It is worth evaluating the acid deposition impacts on chemical weathering and CO2 consumption there. River water geochemistry evidenced an overestimation of CO2 sequestration if H2SO4/HNO3 involvement was ignored, which accounted for 33.6 % of the total flux by silicate weathering in this area. This study quantitatively highlights the anthropogenic acid effects on chemical weathering and associated CO2 consumption.
Thi Phuong Quynh Le, Cyril Marchand, Cuong Tu Ho, Nhu Da Le, Thi Thuy Duong, XiXi Lu, Phuong Kieu Doan, Trung Kien Nguyen, Thi Mai Huong Nguyen, and Duy An Vu
Biogeosciences, 15, 4799–4814, https://doi.org/10.5194/bg-15-4799-2018, https://doi.org/10.5194/bg-15-4799-2018, 2018
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The Red River is a typical south-east Asian river, strongly affected by climate and human activity. This study showed the spatial and seasonal variability of CO2 emissions at the water–air interface of the lower part of this river due to natural conditions (meteo-hydrological-geomorphological characteristics) and human activities (dam impoundment, population, land use). The Red River water was supersaturated with CO2, providing a mean water–air CO2 flux of 530 ± 17 mmol m−2 d−1.
Wei Wen Wong, Jesse Pottage, Fiona Y. Warry, Paul Reich, Keryn L. Roberts, Michael R. Grace, and Perran L. M. Cook
Biogeosciences, 15, 3953–3965, https://doi.org/10.5194/bg-15-3953-2018, https://doi.org/10.5194/bg-15-3953-2018, 2018
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Over-enrichment of nitrate can pose substantial risk to the quality of freshwater ecosystems. Hence, understanding the dynamics of nitrate is the key to better management of waterways. This study evaluates the relationship between the effects of land use and rainfall on the major sources and processing of nitrate within and between five streams in five catchments spanning an agricultural land use gradient. We found that rainfall exerted significant control over the fate of nitrate.
Lishan Ran, Mingyang Tian, Nufang Fang, Suiji Wang, Xixi Lu, Xiankun Yang, and Frankie Cho
Biogeosciences, 15, 3857–3871, https://doi.org/10.5194/bg-15-3857-2018, https://doi.org/10.5194/bg-15-3857-2018, 2018
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We systematically assessed the transport and fate of riverine carbon in the moderate-sized Wuding catchment on the Chinese Loess Plateau by constructing a riverine carbon budget and further relating it to terrestrial ecosystem productivity. The riverine carbon export accounted for 16 % of the catchment's net ecosystem production (NEP). It seems that a significant fraction of terrestrial NEP in this catchment is laterally transported from the terrestrial biosphere to the drainage network.
Robert O. Hall Jr. and Hilary L. Madinger
Biogeosciences, 15, 3085–3092, https://doi.org/10.5194/bg-15-3085-2018, https://doi.org/10.5194/bg-15-3085-2018, 2018
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Streams exchange oxygen with the atmosphere, but this rate is difficult to measure. We added argon to small mountain streams to estimate gas exchange. We compared these rates with sulfur hexafluoride, an intense greenhouse gas. Argon worked well to measure gas exchange, but had higher-than-predicted rates than sulfur hexafluoride. Argon exchange is more likely to represent that for oxygen because they share similar physical properties. We suggest argon to measure gas exchange in small streams.
Ji-Hyung Park, Omme K. Nayna, Most S. Begum, Eliyan Chea, Jens Hartmann, Richard G. Keil, Sanjeev Kumar, Xixi Lu, Lishan Ran, Jeffrey E. Richey, Vedula V. S. S. Sarma, Shafi M. Tareq, Do Thi Xuan, and Ruihong Yu
Biogeosciences, 15, 3049–3069, https://doi.org/10.5194/bg-15-3049-2018, https://doi.org/10.5194/bg-15-3049-2018, 2018
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Human activities are drastically altering water and material flows in river systems across Asia. This review provides a conceptual framework for assessing the human impacts on Asian river C fluxes and an update on anthropogenic alterations of riverine C fluxes, focusing on the impacts of water pollution and river impoundments on CO2 outgassing from the rivers draining South, Southeast, and East Asian regions that account for the largest fraction of river discharge and C exports from Asia.
Chung-Te Chang, Jr-Chuan Huang, Lixin Wang, Yu-Ting Shih, and Teng-Chiu Lin
Biogeosciences, 15, 2379–2391, https://doi.org/10.5194/bg-15-2379-2018, https://doi.org/10.5194/bg-15-2379-2018, 2018
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Our analysis of ion input–output budget illustrates that hydrochemical responses to typhoon storms are distinctly different from those of regular storms. In addition, even mild land use change may have large impacts on nutrient exports/losses. We propose that hydrological models should separate hydrochemical processes into regular and extreme conditions to better capture the whole spectrum of hydrochemical responses to a variety of climate conditions.
Camille Minaudo, Florence Curie, Yann Jullian, Nathalie Gassama, and Florentina Moatar
Biogeosciences, 15, 2251–2269, https://doi.org/10.5194/bg-15-2251-2018, https://doi.org/10.5194/bg-15-2251-2018, 2018
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We developed the model QUALity-NETwork (QUAL-NET) to simulate water quality variations in large drainage networks. This model is accurate enough to represent processes occurring over short periods of time such as storm events and helps to fully understand water quality variations in stream networks in the context of climate change and varying human pressures. It was tested on the Loire River and provided good performances and a new understanding of the functioning of the river.
Michael P. Schwab, Julian Klaus, Laurent Pfister, and Markus Weiler
Biogeosciences, 15, 2177–2188, https://doi.org/10.5194/bg-15-2177-2018, https://doi.org/10.5194/bg-15-2177-2018, 2018
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We studied the diel fluctuations of dissolved organic carbon (DOC) concentrations in a small stream in Luxembourg. We identified an increased proportion of DOC from terrestrial sources as responsible for the peaks in DOC in the afternoon. Warmer water temperatures in the riparian zone in the afternoon increased the amount of water flowing towards the stream. Consequently, an increased amount of DOC-rich water from the riparian zone was entering the stream.
Trent R. Marwick, Fredrick Tamooh, Bernard Ogwoka, Alberto V. Borges, François Darchambeau, and Steven Bouillon
Biogeosciences, 15, 1683–1700, https://doi.org/10.5194/bg-15-1683-2018, https://doi.org/10.5194/bg-15-1683-2018, 2018
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A 2-year biogeochemical record provides annual sediment and element flux estimates for the non-dammed Sabaki River, Kenya, establishing a baseline for future research in light of impending construction of the first major upstream reservoir. Over 80 % of material fluxes occur across the wet season, with annual yields comparable to the adjacent, and dammed, Tana River. Observations at low-flow periods suggest large mammalian herbivores may be vectors of terrestrial subsidies to the water column.
Cited articles
Ågren, A. M., Buffam, I., Cooper, D. M., Tiwari, T., Evans, C. D., and Laudon, H.: Can the heterogeneity in stream dissolved organic carbon be explained by contributing landscape elements?, Biogeosciences, 11, 1199–1213, https://doi.org/10.5194/bg-11-1199-2014, 2014.
Anderson, T. R., Groffman, P. M., Kaushal, S. S., and Walter, M. T.: Shallow groundwater denitrification in riparian zones of a headwater agricultural landscape, J. Environ. Qual., 43, 732–744, https://doi.org/10.2134/jeq2013.07.0303, 2014.
Aubert, A. H., Gascuel-Odoux, C., Gruau, G., Akkal, N., Faucheux, M., Fauvel, Y., Grimaldi, C., Hamon, Y., Jaffrézic, A., Lecoz-Boutnik, M., Molénat, J., Petitjean, P., Ruiz, L., and Merot, P.: Solute transport dynamics in small, shallow groundwater-dominated agricultural catchments: insights from a high-frequency, multisolute 10 yr-long monitoring study, Hydrol. Earth Syst. Sci., 17, 1379–1391, https://doi.org/10.5194/hess-17-1379-2013, 2013.
Baronas, J. J., Torres, M. A., Clark, K. E., and West, A. J.: Mixing as a driver of temporal variations in river hydrochemistry: 2. Major and trace element concentration dynamics in the Andes-Amazon transition, Water Resour. Res., 53, 3120–3145, https://doi.org/10.1002/2016WR019729, 2017.
Basu, N. B., Destouni, G., Jawitz, J. W., Thompson, S. E., Loukinova, N. V., Darracq, A., Zanardo, S., Yaeger, M., Sivapalan, M., Rinaldo, A., and Rao, P. S. C.: Nutrient loads exported from managed catchments reveal emergent biogeochemical stationarity, Geophys. Res. Lett., 37, L23404, https://doi.org/10.1029/2010gl045168, 2010.
Beckinsale, R. P.: River regimes, in: Water, Earth and Man, edited by: Chorley, R. J., Methuen, London, UK, 176–192, 1969.
Beusen, A. H. W., Bouwman, A. F., Van Beek, L. P. H., Mogollón, J. M., and Middelburg, J. J.: Global riverine N and P transport to ocean increased during the 20th century despite increased retention along the aquatic continuum, Biogeosciences, 13, 2441–2451, https://doi.org/10.5194/bg-13-2441-2016, 2016.
Beven, K.: So how much of your error is epistemic? Lessons from Japan and Italy, Hydrol. Process., 27, 1677–1680, https://doi.org/10.1002/hyp.9648, 2013.
Bieroza, M. Z. and Heathwaite, A. L.: Seasonal variation in phosphorus concentration-discharge hysteresis inferred from high-frequency in situ monitoring, J. Hydrol., 524, 333–347, https://doi.org/10.1016/j.jhydrol.2015.02.036, 2015.
Bishop, K., Buffam, I., Erlandsson, M., Folster, J., Laudon, H., Seibert, J., and Temnerud, J.: Aqua Incognita: the unknown headwaters, Hydrol. Process., 22, 1239–1242, https://doi.org/10.1002/hyp.7049, 2008.
Blaen, P. J., Khamis, K., Lloyd, C., Comer-Warner, S., Ciocca, F., Thomas, R. M., MacKenzie, A. R., and Krause, S.: High-frequency monitoring of catchment nutrient exports reveals highly variable storm-event responses and dynamic source zone activation, J. Geophys. Res.-Biogeo., 122, https://doi.org/10.1002/2017JG003904, 2017.
Botter, G., Basso, S., Rodriguez-Iturbe, I., and Rinaldo, A.: Resilience of river flow regimes, P. Natl. Acad. Sci. USA, 110, 12925–12930, https://doi.org/10.1073/pnas.1311920110, 2013.
Bouraoui, F. and Grizzetti, B.: Long term change of nutrient concentrations of rivers discharging in European seas, Sci. Total Environ., 409, 4899–4916, https://doi.org/10.1016/j.scitotenv.2011.08.015, 2011.
Bowes, M. J., Jarvie, H. P., Naden, P. S., Old, G. H., Scarlett, P. M., Roberts, C., Armstrong, L. K., Harman, S. A., Wickham, H. D., and Collins, A. L.: Identifying priorities for nutrient mitigation using river concentration-flow relationships: the Thames basin, UK, J. Hydrol., 517, 1–12, https://doi.org/10.1016/j.jhydrol.2014.03.063, 2014.
Bowes, M. J., Jarvie, H. P., Halliday, S. J., Skeffington, R. A., Wade, A. J., Loewenthal, M., Gozzard, E., Newman, J. R., and Palmer-Felgate, E. J.: Characterising phosphorus and nitrate inputs to a rural river using high-frequency concentration-flow relationships, Sci. Total Environ., 511, 608–620, https://doi.org/10.1016/j.scitotenv.2014.12.086, 2015.
Buda, A. R. and DeWalle, D. R.: Dynamics of stream nitrate sources and flow pathways during stormflows on urban, forest and agricultural watersheds in central Pennsylvania, USA, Hydrol. Process., 23, 3292–3305, https://doi.org/10.1002/hyp.7423, 2009.
Creed, I. F., McKnight, D. M., Pellerin, B. A., Green, M. B., Bergamaschi, B. A., Aiken, G. R., Burns, D. A., Findlay, S. E. G., Shanley, J. B., Striegl, R. G., Aulenbach, B. T., Clow, D. W., Laudon, H., McGlynn, B. L., McGuire, K. J., Smith, R. A., and Stackpoole, S. M.: The river as a chemostat: fresh perspectives on dissolved organic matter flowing down the river continuum, Can. J. Fish. Aquat. Sci., 72, 1272–1285, https://doi.org/10.1139/cjfas-2014-0400, 2015.
Dick, J. J., Tetzlaff, D., Birkel, C., and Soulsby, C.: Modelling landscape controls on dissolved organic carbon sources and fluxes to streams, Biogeochemistry, 122, 361–374, https://doi.org/10.1007/s10533-014-0046-3, 2015.
Doody, D. G., Withers, P. J. A., Dils, R. M., McDowell, R. W., Smith, V., McElarney, Y. R., Dunbar, M., and Daly, D.: Optimizing land use for the delivery of catchment ecosystem services, Front. Ecol. Environ., 14, 325–332, https://doi.org/10.1002/fee.1296, 2016.
Dupas, R., Delmas, M., Dorioz, J. M., Garnier, J., Moatar, F., and Gascuel-Odoux, C.: Assessing the impact of agricultural pressures on N and P loads and eutrophication risk, Ecol. Indic., 48, 396–407, https://doi.org/10.1016/j.ecolind.2014.08.007, 2015a.
Dupas, R., Tavenard, R., Fovet, O., Gilliet, N., Grimaldi, C., and Gascuel-Odoux, C.: Identifying seasonal patterns of phosphorus storm dynamics with dynamic time warping, Water Resour. Res., 51, 8868–8882, https://doi.org/10.1002/2015wr017338, 2015b.
Dupas, R., Salmon-Monviola, J., Beven, K. J., Durand, P., Haygarth, P. M., Hollaway, M. J., and Gascuel-Odoux, C.: Uncertainty assessment of a dominant-process catchment model of dissolved phosphorus transfer, Hydrol. Earth Syst. Sci., 20, 4819–4835, https://doi.org/10.5194/hess-20-4819-2016, 2016a.
Dupas, R., S., J., Musolff, A., Borchardt, D., and Rode, M.: Disentangling the influence of hydroclimatic patterns and agricultural management on river nitrate dynamics from sub-hourly to decadal time scales, Sci. Total Environ., 571, 791–800, https://doi.org/10.1016/j.scitotenv.2016.07.053, 2016b.
Dupas, R., Mellander, P. E., Gascuel-Odoux, C., Fovet, O., McAleer, E. B., McDonald, N., Shore, M., and Jordan, P.: The role of mobilisation and delivery processes on contrasting dissolved nitrogen and phosphorus exports in groundwater fed catchments, Sci. Total Environ., 599–600, 1275–1287, 2017.
EC: Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy, Official Journal L 327, 22/12/2000, 0001–0073, 2000.
Fealy, R. M., Buckley, C., Mechan, S., Melland, A., Mellander, P. E., Shortle, G., Wall, D., and Jordan, P.: The Irish Agricultural Catchments Programme: catchment selection using spatial multi-criteria decision analysis, Soil Use Manage., 26, 225–236, https://doi.org/10.1111/j.1475-2743.2010.00291.x, 2010.
Godsey, S. E., Kirchner, J. W., and Clow, D. W.: Concentration-discharge relationships reflect chemostatic characteristics of US catchments, Hydrol. Process., 23, 1844–1864, https://doi.org/10.1002/hyp.7315, 2009.
Grathwohl, P., Rugner, H., Wohling, T., Osenbruck, K., Schwientek, M., Gayler, S., Wollschlager, U., Selle, B., Pause, M., Delfs, J. O., Grzeschik, M., Weller, U., Ivanov, M., Cirpka, O. A., Maier, U., Kuch, B., Nowak, W., Wulfmeyer, V., Warrach-Sagi, K., Streck, T., Attinger, S., Bilke, L., Dietrich, P., Fleckenstein, J. H., Kalbacher, T., Kolditz, O., Rink, K., Samaniego, L., Vogel, H. J., Werban, U., and Teutsch, G.: Catchments as reactors: a comprehensive approach for water fluxes and solute turnover, Environ. Earth Sci., 69, 317–333, https://doi.org/10.1007/s12665-013-2281-7, 2013.
Gu, S., Gruau, G., Dupas, R., Rumpel, C., Creme, A., Fovet, O., Gascuel-Odoux, C., Jeanneau, L., Humbert, G., and Petitjean, P.: Release of dissolved phosphorus from riparian wetlands: evidence for complex interactions among hydroclimate variability, topography and soil properties, Sci. Total Environ., 598, 421–431, https://doi.org/10.1016/j.scitotenv.2017.04.028, 2017.
Hartmann, A., Kobler, J., Kralik, M., Dirnböck, T., Humer, F., and Weiler, M.: Model-aided quantification of dissolved carbon and nitrogen release after windthrow disturbance in an Austrian karst system, Biogeosciences, 13, 159–174, https://doi.org/10.5194/bg-13-159-2016, 2016.
Herndon, E. M., Dere, A. L., Sullivan, P. L., Norris, D., Reynolds, B., and Brantley, S. L.: Landscape heterogeneity drives contrasting concentration–discharge relationships in shale headwater catchments, Hydrol. Earth Syst. Sci., 19, 3333–3347, https://doi.org/10.5194/hess-19-3333-2015, 2015.
Hrachowitz, M., Benettin, P., van Breukelen, B. M., Fovet, O., Howden, N. J. K., Ruiz, L., van der Velde, Y., and Wade, A. J.: Transit times – the link between hydrology and water quality at the catchment scale, WIREs Water, 3, 629–657, https://doi.org/10.1002/wat2.1155, 2016.
Humbert, G., Jaffrezic, A., Fovet, O., Gruau, G., and Durand, P.: Dry-season length and runoff control annual variability in stream DOC dynamics in a small, shallow groundwater-dominated agricultural watershed, Water Resour. Res., 51, 7860–7877, https://doi.org/10.1002/2015wr017336, 2015.
Jiang, R., Hatano, R., Zhao, Y., Kuramochi, K., Hayakawa, A., Woli, K. P., and Shimizu, M.: Factors controlling nitrogen and dissolved organic carbon exports across timescales in two watersheds with different land uses, Hydrol. Process., 28, 5105–5121, https://doi.org/10.1002/hyp.9996, 2014a.
Jiang, S. Y., Jomaa, S., and Rode, M.: Modelling inorganic nitrogen leaching in nested mesoscale catchments in central Germany, Ecohydrology, 7, 1345–1362, https://doi.org/10.1002/eco.1462, 2014b.
Kamjunke, N., Oosterwoud, M. R., Herzsprung, P., and Tittel, J.: Bacterial production and their role in the removal of dissolved organic matter from tributaries of drinking water reservoirs, Sci. Total Environ., 548, 51–59, https://doi.org/10.1016/j.scitotenv.2016.01.017, 2016.
Keck, F. and Lepori, F.: Can we predict nutrient limitation in streams and rivers?, Freshwater Biol., 57, 1410–1421, https://doi.org/10.1111/j.1365-2427.2012.02802.x, 2012.
Lambert, T., Teodoru, C. R., Nyoni, F. C., Bouillon, S., Darchambeau, F., Massicotte, P., and Borges, A. V.: Along-stream transport and transformation of dissolved organic matter in a large tropical river, Biogeosciences, 13, 2727–2741, https://doi.org/10.5194/bg-13-2727-2016, 2016.
Laudon, H., Berggren, M., Agren, A., Buffam, I., Bishop, K., Grabs, T., Jansson, M., and Kohler, S.: Patterns and dynamics of dissolved organic carbon (DOC) in boreal streams: the role of processes, connectivity, and scaling, Ecosystems, 14, 880–893, https://doi.org/10.1007/s10021-011-9452-8, 2011.
McDowell, R. W., Larned, S. T., and Houlbrooke, D. J.: Nitrogen and phosphorus in New Zealand streams and rivers: control and impact of eutrophication and the influence of land management, New Zeal. J. Mar. Fresh, 43, 985–995, 2009.
McGonigle, D. F., Burke, S. P., Collins, A. L., Gartner, R., Haft, M. R., Harris, R. C., Haygarth, P. M., Hedges, M. C., Hiscock, K. M., and Lovett, A. A.: Developing demonstration test catchments as a platform for transdisciplinary land management research in England and Wales, Environ. Sci.-Proc. Imp., 16, 1618–1628, https://doi.org/10.1039/c3em00658a, 2014.
Minaudo, C., Meybeck, M., Moatar, F., Gassama, N., and Curie, F.: Eutrophication mitigation in rivers: 30 years of trends in spatial and seasonal patterns of biogeochemistry of the Loire River (1980–2012), Biogeosciences, 12, 2549–2563, https://doi.org/10.5194/bg-12-2549-2015, 2015.
Minaudo, C., Dupas, R., Gascuel-Odoux, C., Fovet, O., Mellander, P.-E., Jordan, P., Shore, M., and Moatar, F.: Nonlinear empirical modeling to estimate phosphorus exports using continuous records of turbidity and discharge, Water Resour. Res., 53, https://doi.org/10.1002/2017WR020590, 2017.
Musolff, A., Schmidt, C., Selle, B., and Fleckenstein, J. H.: Catchment controls on solute export, Adv. Water Resour., 86, 133–146, https://doi.org/10.1016/j.advwatres.2015.09.026, 2015.
Musolff, A., Schmidt, C., Rode, M., Lischeid, G., Weise, S. M., and Fleckenstein, J. H.: Groundwater head controls nitrate export from an agricultural lowland catchment, Adv. Water Resour., 96, 95–107, https://doi.org/10.1016/j.advwatres.2016.07.003, 2016a.
Musolff, A., Selle, B., Buettner, O., Opitz, M., and Tittel, J.: Unexpected release of phosphate and organic carbon to streams linked to declining nitrogen depositions, Glob. Change Biol., 23, 1–11, https://doi.org/10.1111/gcb.13498, 2016b.
Musolff, A., Fleckenstein, J. H., Rao, P. S. C., and Jawitz, J. W.: Emergent archetype patterns of coupled hydrologic and biogeochemical responses in catchments, Geophys. Res. Lett., 44, 4143–4151, https://doi.org/10.1002/2017gl072630, 2017.
Outram, F. N., Lloyd, C. E. M., Jonczyk, J., Benskin, C. McW. H., Grant, F., Perks, M. T., Deasy, C., Burke, S. P., Collins, A. L., Freer, J., Haygarth, P. M., Hiscock, K. M., Johnes, P. J., and Lovett, A. L.: High-frequency monitoring of nitrogen and phosphorus response in three rural catchments to the end of the 2011–2012 drought in England, Hydrol. Earth Syst. Sci., 18, 3429–3448, https://doi.org/10.5194/hess-18-3429-2014, 2014.
Outram, F. N., Cooper, R. J., Sünnenberg, G., Hiscock, K. M., and Lovett, A. A.: Antecedent conditions, hydrological connectivity and anthropogenic inputs: factors affecting nitrate and phosphorus transfers to agricultural headwater streams, Sci. Total Environ., 545–546, 184–199, https://doi.org/10.1016/j.scitotenv.2015.12.025, 2016.
Pinay, G., Peiffer, S., De Dreuzy, J. R., Krause, S., Hannah, D. M., Fleckenstein, J. H., Sebilo, M., Bishop, K., and Hubert-Moy, L.: Upscaling nitrogen removal capacity from local hotspots to low stream orders' drainage basins, Ecosystems, 18, 1101–1120, https://doi.org/10.1007/s10021-015-9878-5, 2015.
Raymond, P. A., Saiers, J. E., and Sobczak, W. V.: Hydrological and biogeochemical controls on watershed dissolved organic matter transport: pulse-shunt concept, Ecology, 97, 5–16, https://doi.org/10.1890/14-1684.1, 2016.
Rode, M., Halbedel, S., Anis, M., Borchardt, D., and Weitere, M.: Continuous in-stream assimilatory nitrate uptake from high frequency sensor measurements, Environ. Sci. Technol., 50, 5685–5694, https://doi.org/10.1021/acs.est.6b00943, 2016a.
Rode, M., Wade, A. J., Cohen, M. J., Hensley, R. T., Bowes, M. J., Kirchner, J. W., Arhonditsis, G. B., Jordan, P., Kronvang, B., Halliday, S. J., Skeffington, R. A., Rozemeijer, J. C., Aubert, A. H., Rinke, K., and Jomaa, S.: Sensors in the stream: the high-frequency wave of the present, Environ. Sci. Technol., 50, 10297–10307, https://doi.org/10.1021/acs.est.6b02155, 2016b.
Salmon-Monviola, J., Moreau, P., Benhamou, C., Durand, P., Merot, P., Oehler, F., and Gascuel-Odoux, C.: Effect of climate change and increased atmospheric CO2 on hydrological and nitrogen cycling in an intensive agricultural headwater catchment in western France, Climatic Change, 120, 433–447, https://doi.org/10.1007/s10584-013-0828-y, 2013.
Sardans, J., Rivas-Ubach, A., and Penuelas, J.: The elemental stoichiometry of aquatic and terrestrial ecosystems and its relationships with organismic lifestyle and ecosystem structure and function: a review and perspectives, Biogeochemistry, 111, 1–39, https://doi.org/10.1007/s10533-011-9640-9, 2012.
Seitzinger, S. P., Mayorga, E., Bouwman, A. F., Kroeze, C., Beusen, A. H. W., Billen, G., Van Drecht, G., Dumont, E., Fekete, B. M., Garnier, J., and Harrison, J. A.: Global river nutrient export: a scenario analysis of past and future trends, Global Biogeochem. Cy., 24, GB0A08, https://doi.org/10.1029/2009gb003587, 2010.
Smolders, E., Baetens, E., Verbeek, M., Nawara, S., Diels, J., Verdievel, M., Peeters, B., De Cooman, W., and Baken, S.: Internal loading and redox cycling of sediment iron explain reactive phosphorus concentrations in lowland rivers, Environ. Sci. Technol., 51, 2584–2592, https://doi.org/10.1021/acs.est.6b04337, 2017.
Taylor, P. G. and Townsend, A. R.: Stoichiometric control of organic carbon-nitrate relationships from soils to the sea, Nature, 464, 1178–1181, https://doi.org/10.1038/nature08985, 2010.
Temnerud, J., von Brömssen, C., Fölster, J., Buffam, I., Andersson, J.-O., Nyberg, L., and Bishop, K.: Map-based prediction of organic carbon in headwater streams improved by downstream observations from the river outlet, Biogeosciences, 13, 399–413, https://doi.org/10.5194/bg-13-399-2016, 2016.
Thomas, Z., Abbott, B. W., Troccaz, O., Baudry, J., and Pinay, G.: Proximate and ultimate controls on carbon and nutrient dynamics of small agricultural catchments, Biogeosciences, 13, 1863–1875, https://doi.org/10.5194/bg-13-1863-2016, 2016.
Thompson, S. E., Basu, N. B., Lascurain, J., Jr., Aubeneau, A., and Rao, P. S. C.: Relative dominance of hydrologic versus biogeochemical factors on solute export across impact gradients, Water Resour. Res., 47, W00J05, https://doi.org/10.1029/2010wr009605, 2011.
Tiwari, T., Laudon, H., Beven, K., and Agren, A. M.: Downstream changes in DOC: inferring contributions in the face of model uncertainties, Water Resour. Res., 50, 514–525, https://doi.org/10.1002/2013wr014275, 2014.
Tiwari, T., Lidman, F., Laudon, H., Lidberg, W., and Agren, A.: GIS-based prediction of stream chemistry using landscape composition, wet areas and hydrological flow pathways, J. Geophys. Res.-Biogeo., 122, 65–79, https://doi.org/10.1002/2016JG003399, 2017.
Wall, D., Jordan, P., Melland, A. R., Mellander, P. E., Buckley, C., Reaney, S. M., and Shortie, G.: Using the nutrient transfer continuum concept to evaluate the European Union Nitrates Directive National Action Programme, Environ. Sci. Policy, 14, 664–674, https://doi.org/10.1016/j.envsci.2011.05.003, 2011.
Withers, P. J. A., Jordan, P., May, L., Jarvie, H. P., and Deal, N. E.: Do septic tank systems pose a hidden threat to water quality?, Front. Ecol. Environ., 12, 123–130, https://doi.org/10.1890/130131, 2014.
Wollschlager, U., Attinger, S., Borchardt, D., Brauns, M., Cuntz, M., Dietrich, P., Fleckenstein, J. H., Friese, K., Friesen, J., and al., e.: The Bode hydrological observatory: a platform for integrated, interdisciplinary hydro-ecological research within the TERENO Harz/Central German Lowland Observatory, Environ. Earth Sci., 76, 29, https://doi.org/10.1007/s12665-016-6327-5, 2016.
Worrall, F., Davies, H., Bhogal, A., Lilly, A., Evans, M., Turner, K., Burt, T., Barraclough, D., Smith, P., and Merrington, G.: The flux of DOC from the UK – Predicting the role of soils, land use and net watershed losses, J. Hydrol., 448, 149–160, https://doi.org/10.1016/j.jhydrol.2012.04.053, 2012.
Yates, C. A. and Johnes, P. J.: Nitrogen speciation and phosphorus fractionation dynamics in a lowland Chalk catchment, Sci. Total Environ., 444, 466–479, https://doi.org/10.1016/j.scitotenv.2012.12.002, 2013.
Zacharias, S., Bogena, H., Samaniego, L., Mauder, M., Fuss, R., Putz, T., Frenzel, M., Schwank, M., Baessler, C., Butterbach-Bahl, K., Bens, O., Borg, E., Brauer, A., Dietrich, P., Hajnsek, I., Helle, G., Kiese, R., Kunstmann, H., Klotz, S., Munch, J. C., Papen, H., Priesack, E., Schmid, H. P., Steinbrecher, R., Rosenbaum, U., Teutsch, G., and Vereecken, H.: A network of terrestrial environmental observatories in Germany, Vadose Zone J., 10, 955–973, https://doi.org/10.2136/vzj2010.0139, 2011.
Short summary
Carbon and nutrient export regimes were analyzed from archetypal headwater catchments to
downstream reaches. In headwater catchments, land use and lithology determine
land-to-stream C, N and P transfer processes. The crucial role of riparian
zones in C, N and P coupling was investigated. In downstream reaches,
point-source contributions and in-stream processes alter C, N and P export
regimes.
Carbon and nutrient export regimes were analyzed from archetypal headwater catchments...
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