Articles | Volume 21, issue 5
https://doi.org/10.5194/bg-21-1191-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/bg-21-1191-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Technical note
| 
13 Mar 2024
Technical note |
| 13 Mar 2024
| 13 Mar 2024
Technical note: Assessment of float pH data quality control methods – a case study in the subpolar northwest Atlantic Ocean
Cathy Wimart-Rousseau
CORRESPONDING AUTHOR
GEOMAR Helmholtz Centre for Ocean Research Kiel, 24148 Kiel, Germany
Tobias Steinhoff
GEOMAR Helmholtz Centre for Ocean Research Kiel, 24148 Kiel, Germany
Birgit Klein
Federal Maritime and Hydrographic Agency (BSH), 20359 Hamburg, Germany
Henry Bittig
Marine Chemistry, Leibniz Institute for Baltic Sea Research Warnemuende (IOW), Seestrasse 15, 18119 Rostock, Germany
Arne Körtzinger
GEOMAR Helmholtz Centre for Ocean Research Kiel, 24148 Kiel, Germany
Faculty of Mathematics and Natural Sciences, Christian-Albrechts-Universität zu Kiel, 24118 Kiel, Germany
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Earth Syst. Sci. Data, 15, 5301–5369, https://doi.org/10.5194/essd-15-5301-2023, https://doi.org/10.5194/essd-15-5301-2023, 2023
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Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Hongmei Li, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Carla F. Berghoff, Henry C. Bittig, Laurent Bopp, Patricia Cadule, Katie Campbell, Matthew A. Chamberlain, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Thomas Colligan, Jeanne Decayeux, Laique Djeutchouang, Xinyu Dou, Carolina Duran Rojas, Kazutaka Enyo, Wiley Evans, Amanda Fay, Richard A. Feely, Daniel J. Ford, Adrianna Foster, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Siv K. Lauvset, Nathalie Lefèvre, Zhu Liu, Junjie Liu, Lei Ma, Shamil Maksyutov, Gregg Marland, Nicolas Mayot, Patrick McGuire, Nicolas Metzl, Natalie M. Monacci, Eric J. Morgan, Shin-Ichiro Nakaoka, Craig Neill, Yosuke Niwa, Tobias Nützel, Lea Olivier, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Zhangcai Qin, Laure Resplandy, Alizée Roobaert, Thais M. Rosan, Christian Rödenbeck, Jörg Schwinger, T. Luke Smallman, Stephen Smith, Reinel Sospedra-Alfonso, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Roland Séférian, Shintaro Takao, Hiroaki Tatebe, Hanqin Tian, Bronte Tilbrook, Olivier Torres, Etienne Tourigny, Hiroyuki Tsujino, Francesco Tubiello, Guido van der Werf, Rik Wanninkhof, Xuhui Wang, Dongxu Yang, Xiaojuan Yang, Zhen Yu, Wenping Yuan, Xu Yue, Sönke Zaehle, Ning Zeng, and Jiye Zeng
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Preprint under review for ESSD
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The Global Carbon Budget 2024 describes the methodology, main results, and data sets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2024). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Daniel Pönisch, Henry C. Bittig, Martin Kolbe, Ingo Schuffenhauer, Stefan Otto, Peter Holtermann, Kusala Premaratne, and Gregor Rehder
EGUsphere, https://doi.org/10.5194/egusphere-2024-3246, https://doi.org/10.5194/egusphere-2024-3246, 2024
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Rewetted peatlands exhibit natural spatial and temporal biogeochemical heterogeneity, influenced by water level and vegetation. This study investigated the variability of the distribution of GHGs in a brackish-rewetted peatland. Two innovative sensor-equipped landers were used to measure a wide range of marine physicochemical variables at high temporal resolution. The measurements revealed strong fluctuations in CO2 and CH4, expressed as multi-day, diurnal and event-based variability.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 16, 2047–2072, https://doi.org/10.5194/essd-16-2047-2024, https://doi.org/10.5194/essd-16-2047-2024, 2024
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Earth Syst. Sci. Data, 16, 1901–1931, https://doi.org/10.5194/essd-16-1901-2024, https://doi.org/10.5194/essd-16-1901-2024, 2024
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Henry C. Bittig, Erik Jacobs, Thomas Neumann, and Gregor Rehder
Earth Syst. Sci. Data, 16, 753–773, https://doi.org/10.5194/essd-16-753-2024, https://doi.org/10.5194/essd-16-753-2024, 2024
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Nicolas Metzl, Jonathan Fin, Claire Lo Monaco, Claude Mignon, Samir Alliouane, David Antoine, Guillaume Bourdin, Jacqueline Boutin, Yann Bozec, Pascal Conan, Laurent Coppola, Frédéric Diaz, Eric Douville, Xavier Durrieu de Madron, Jean-Pierre Gattuso, Frédéric Gazeau, Melek Golbol, Bruno Lansard, Dominique Lefèvre, Nathalie Lefèvre, Fabien Lombard, Férial Louanchi, Liliane Merlivat, Léa Olivier, Anne Petrenko, Sébastien Petton, Mireille Pujo-Pay, Christophe Rabouille, Gilles Reverdin, Céline Ridame, Aline Tribollet, Vincenzo Vellucci, Thibaut Wagener, and Cathy Wimart-Rousseau
Earth Syst. Sci. Data, 16, 89–120, https://doi.org/10.5194/essd-16-89-2024, https://doi.org/10.5194/essd-16-89-2024, 2024
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This work presents a synthesis of 44 000 total alkalinity and dissolved inorganic carbon observations obtained between 1993 and 2022 in the Global Ocean and the Mediterranean Sea at the surface and in the water column. Seawater samples were measured using the same method and calibrated with international Certified Reference Material. We describe the data assemblage, quality control and some potential uses of this dataset.
Louise C. V. Rewrie, Burkard Baschek, Justus E. E. van Beusekom, Arne Körtzinger, Gregor Ollesch, and Yoana G. Voynova
Biogeosciences, 20, 4931–4947, https://doi.org/10.5194/bg-20-4931-2023, https://doi.org/10.5194/bg-20-4931-2023, 2023
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After heavy pollution in the 1980s, a long-term inorganic carbon increase in the Elbe Estuary (1997–2020) was fueled by phytoplankton and organic carbon production in the upper estuary, associated with improved water quality. A recent drought (2014–2020) modulated the trend, extending the water residence time and the dry summer season into May. The drought enhanced production of inorganic carbon in the estuary but significantly decreased the annual inorganic carbon export to coastal waters.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Ingrid T. Luijkx, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Peter Anthoni, Leticia Barbero, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Bertrand Decharme, Laurent Bopp, Ida Bagus Mandhara Brasika, Patricia Cadule, Matthew A. Chamberlain, Naveen Chandra, Thi-Tuyet-Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Xinyu Dou, Kazutaka Enyo, Wiley Evans, Stefanie Falk, Richard A. Feely, Liang Feng, Daniel J. Ford, Thomas Gasser, Josefine Ghattas, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Fortunat Joos, Etsushi Kato, Ralph F. Keeling, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Xin Lan, Nathalie Lefèvre, Hongmei Li, Junjie Liu, Zhiqiang Liu, Lei Ma, Greg Marland, Nicolas Mayot, Patrick C. McGuire, Galen A. McKinley, Gesa Meyer, Eric J. Morgan, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin M. O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Melf Paulsen, Denis Pierrot, Katie Pocock, Benjamin Poulter, Carter M. Powis, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Roland Séférian, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Erik van Ooijen, Rik Wanninkhof, Michio Watanabe, Cathy Wimart-Rousseau, Dongxu Yang, Xiaojuan Yang, Wenping Yuan, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 15, 5301–5369, https://doi.org/10.5194/essd-15-5301-2023, https://doi.org/10.5194/essd-15-5301-2023, 2023
Short summary
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The Global Carbon Budget 2023 describes the methodology, main results, and data sets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2023). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Simone Alin, Marta Álvarez, Kumiko Azetsu-Scott, Leticia Barbero, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Li-Qing Jiang, Steve D. Jones, Claire Lo Monaco, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 14, 5543–5572, https://doi.org/10.5194/essd-14-5543-2022, https://doi.org/10.5194/essd-14-5543-2022, 2022
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2022 is the fourth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1085 hydrographic cruises covering the world's oceans from 1972 to 2021.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Luke Gregor, Judith Hauck, Corinne Le Quéré, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Ramdane Alkama, Almut Arneth, Vivek K. Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Henry C. Bittig, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Wiley Evans, Stefanie Falk, Richard A. Feely, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Lucas Gloege, Giacomo Grassi, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Atul K. Jain, Annika Jersild, Koji Kadono, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Keith Lindsay, Junjie Liu, Zhu Liu, Gregg Marland, Nicolas Mayot, Matthew J. McGrath, Nicolas Metzl, Natalie M. Monacci, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Naiqing Pan, Denis Pierrot, Katie Pocock, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Carmen Rodriguez, Thais M. Rosan, Jörg Schwinger, Roland Séférian, Jamie D. Shutler, Ingunn Skjelvan, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Toste Tanhua, Pieter P. Tans, Xiangjun Tian, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Anthony P. Walker, Rik Wanninkhof, Chris Whitehead, Anna Willstrand Wranne, Rebecca Wright, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 14, 4811–4900, https://doi.org/10.5194/essd-14-4811-2022, https://doi.org/10.5194/essd-14-4811-2022, 2022
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The Global Carbon Budget 2022 describes the datasets and methodology used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, the land ecosystems, and the ocean. These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Karel Castro-Morales, Anna Canning, Sophie Arzberger, Will A. Overholt, Kirsten Küsel, Olaf Kolle, Mathias Göckede, Nikita Zimov, and Arne Körtzinger
Biogeosciences, 19, 5059–5077, https://doi.org/10.5194/bg-19-5059-2022, https://doi.org/10.5194/bg-19-5059-2022, 2022
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Permafrost thaw releases methane that can be emitted into the atmosphere or transported by Arctic rivers. Methane measurements are lacking in large Arctic river regions. In the Kolyma River (northeast Siberia), we measured dissolved methane to map its distribution with great spatial detail. The river’s edge and river junctions had the highest methane concentrations compared to other river areas. Microbial communities in the river showed that the river’s methane likely is from the adjacent land.
Léa Olivier, Jacqueline Boutin, Gilles Reverdin, Nathalie Lefèvre, Peter Landschützer, Sabrina Speich, Johannes Karstensen, Matthieu Labaste, Christophe Noisel, Markus Ritschel, Tobias Steinhoff, and Rik Wanninkhof
Biogeosciences, 19, 2969–2988, https://doi.org/10.5194/bg-19-2969-2022, https://doi.org/10.5194/bg-19-2969-2022, 2022
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We investigate the impact of the interactions between eddies and the Amazon River plume on the CO2 air–sea fluxes to better characterize the ocean carbon sink in winter 2020. The region is a strong CO2 sink, previously underestimated by a factor of 10 due to a lack of data and understanding of the processes responsible for the variability in ocean carbon parameters. The CO2 absorption is mainly driven by freshwater from the Amazon entrained by eddies and by the winter seasonal cooling.
Pierre Friedlingstein, Matthew W. Jones, Michael O'Sullivan, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Corinne Le Quéré, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Rob B. Jackson, Simone R. Alin, Peter Anthoni, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Laurent Bopp, Thi Tuyet Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Kim I. Currie, Bertrand Decharme, Laique M. Djeutchouang, Xinyu Dou, Wiley Evans, Richard A. Feely, Liang Feng, Thomas Gasser, Dennis Gilfillan, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Ingrid T. Luijkx, Atul Jain, Steve D. Jones, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Sebastian Lienert, Junjie Liu, Gregg Marland, Patrick C. McGuire, Joe R. Melton, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Yosuke Niwa, Tsuneo Ono, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Clemens Schwingshackl, Roland Séférian, Adrienne J. Sutton, Colm Sweeney, Toste Tanhua, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco Tubiello, Guido R. van der Werf, Nicolas Vuichard, Chisato Wada, Rik Wanninkhof, Andrew J. Watson, David Willis, Andrew J. Wiltshire, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, and Jiye Zeng
Earth Syst. Sci. Data, 14, 1917–2005, https://doi.org/10.5194/essd-14-1917-2022, https://doi.org/10.5194/essd-14-1917-2022, 2022
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The Global Carbon Budget 2021 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Gerhard Fischer, Oscar E. Romero, Johannes Karstensen, Karl-Heinz Baumann, Nasrollah Moradi, Morten Iversen, Götz Ruhland, Marco Klann, and Arne Körtzinger
Biogeosciences, 18, 6479–6500, https://doi.org/10.5194/bg-18-6479-2021, https://doi.org/10.5194/bg-18-6479-2021, 2021
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Low-oxygen eddies in the eastern subtropical North Atlantic can form an oasis for phytoplankton growth. Here we report on particle flux dynamics at the oligotrophic Cape Verde Ocean Observatory. We observed consistent flux patterns during the passages of low-oxygen eddies. We found distinct flux peaks in late winter, clearly exceeding background fluxes. Our findings suggest that the low-oxygen eddies sequester higher organic carbon than expected for oligotrophic settings.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Steven van Heuven, Mario Hoppema, Masao Ishii, Emil Jeansson, Sara Jutterström, Steve D. Jones, Maren K. Karlsen, Claire Lo Monaco, Patrick Michaelis, Akihiko Murata, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Anton Velo, Rik Wanninkhof, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 13, 5565–5589, https://doi.org/10.5194/essd-13-5565-2021, https://doi.org/10.5194/essd-13-5565-2021, 2021
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2021 is the third update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality control, including systematic evaluation of measurement biases. This version contains data from 989 hydrographic cruises covering the world's oceans from 1972 to 2020.
Anna Canning, Bernhard Wehrli, and Arne Körtzinger
Biogeosciences, 18, 3961–3979, https://doi.org/10.5194/bg-18-3961-2021, https://doi.org/10.5194/bg-18-3961-2021, 2021
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Inland waters are usually not well restrained in terms of greenhouse gas measurements. One of these regions is the Danube Delta, Romania. Therefore, we measured continuously with sensors to collect high-resolution data for CH4 and O2 throughout the Delta. We found significant variation for all concentrations over the day and night and between regions, as well as large spatial variation throughout all regions, with large CH4 concentrations flowing in from the reed beds to the lakes.
Erik Jacobs, Henry C. Bittig, Ulf Gräwe, Carolyn A. Graves, Michael Glockzin, Jens D. Müller, Bernd Schneider, and Gregor Rehder
Biogeosciences, 18, 2679–2709, https://doi.org/10.5194/bg-18-2679-2021, https://doi.org/10.5194/bg-18-2679-2021, 2021
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We use a unique data set of 8 years of continuous carbon dioxide (CO2) and methane (CH4) surface water measurements from a commercial ferry to study upwelling in the Baltic Sea. Its seasonality and regional and interannual variability are examined. Strong upwelling events drastically increase local surface CO2 and CH4 levels and are mostly detected in late summer after long periods of impaired mixing. We introduce an extrapolation method to estimate regional upwelling-induced trace gas fluxes.
Anna Rose Canning, Peer Fietzek, Gregor Rehder, and Arne Körtzinger
Biogeosciences, 18, 1351–1373, https://doi.org/10.5194/bg-18-1351-2021, https://doi.org/10.5194/bg-18-1351-2021, 2021
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The paper describes a novel, fully autonomous, multi-gas flow-through set-up for multiple gases that combines established, high-quality oceanographic sensors in a small and robust system designed for use across all salinities and all types of platforms. We describe the system and its performance in all relevant detail, including the corrections which improve the accuracy of these sensors, and illustrate how simultaneous multi-gas set-ups can provide an extremely high spatiotemporal resolution.
Are Olsen, Nico Lange, Robert M. Key, Toste Tanhua, Henry C. Bittig, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Steven van Heuven, Mario Hoppema, Masao Ishii, Emil Jeansson, Sara Jutterström, Camilla S. Landa, Siv K. Lauvset, Patrick Michaelis, Akihiko Murata, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Anton Velo, Rik Wanninkhof, and Ryan J. Woosley
Earth Syst. Sci. Data, 12, 3653–3678, https://doi.org/10.5194/essd-12-3653-2020, https://doi.org/10.5194/essd-12-3653-2020, 2020
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by chemical analysis of water bottle samples at scientific cruises. GLODAPv2.2020 is the second update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality control, including systematic evaluation of measurement biases. This version contains data from 946 hydrographic cruises covering the world's oceans from 1972 to 2019.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Corinne Le Quéré, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone Alin, Luiz E. O. C. Aragão, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Alice Benoit-Cattin, Henry C. Bittig, Laurent Bopp, Selma Bultan, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Wiley Evans, Liesbeth Florentie, Piers M. Forster, Thomas Gasser, Marion Gehlen, Dennis Gilfillan, Thanos Gkritzalis, Luke Gregor, Nicolas Gruber, Ian Harris, Kerstin Hartung, Vanessa Haverd, Richard A. Houghton, Tatiana Ilyina, Atul K. Jain, Emilie Joetzjer, Koji Kadono, Etsushi Kato, Vassilis Kitidis, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Zhu Liu, Danica Lombardozzi, Gregg Marland, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Adam J. P. Smith, Adrienne J. Sutton, Toste Tanhua, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Guido van der Werf, Nicolas Vuichard, Anthony P. Walker, Rik Wanninkhof, Andrew J. Watson, David Willis, Andrew J. Wiltshire, Wenping Yuan, Xu Yue, and Sönke Zaehle
Earth Syst. Sci. Data, 12, 3269–3340, https://doi.org/10.5194/essd-12-3269-2020, https://doi.org/10.5194/essd-12-3269-2020, 2020
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The Global Carbon Budget 2020 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Dagmar Hainbucher, Marta Álvarez, Blanca Astray Uceda, Giancarlo Bachi, Vanessa Cardin, Paolo Celentano, Spyros Chaikalis, Maria del Mar Chaves Montero, Giuseppe Civitarese, Noelia M. Fajar, Francois Fripiat, Lennart Gerke, Alexandra Gogou, Elisa F. Guallart, Birte Gülk, Abed El Rahman Hassoun, Nico Lange, Andrea Rochner, Chiara Santinelli, Tobias Steinhoff, Toste Tanhua, Lidia Urbini, Dimitrios Velaoras, Fabian Wolf, and Andreas Welsch
Earth Syst. Sci. Data, 12, 2747–2763, https://doi.org/10.5194/essd-12-2747-2020, https://doi.org/10.5194/essd-12-2747-2020, 2020
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We report on data from an oceanographic cruise in the Mediterranean Sea (MSM72, March 2018). The main objective of the cruise was to contribute to the understanding of long-term changes and trends in physical and biogeochemical parameters, such as the anthropogenic carbon uptake, and further assess the hydrographical situation after the Eastern and Western Mediterranean Transients. Multidisciplinary measurements were conducted on a predominantly
zonal section throughout the Mediterranean Sea.
Katharina Seelmann, Martha Gledhill, Steffen Aßmann, and Arne Körtzinger
Ocean Sci., 16, 535–544, https://doi.org/10.5194/os-16-535-2020, https://doi.org/10.5194/os-16-535-2020, 2020
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We investigated the impact of indicator dye impurities on spectrophotometric seawater measurements, especially how they may influence the drift behavior and the measurement quality of an autonomous analyzer using this indicator. These measurements are important for ocean carbon observations. This work revealed that impurities up to a quantity of 2 % do not influence the measurement drift and quality. Higher impurity levels lead to a changing drift behavior and quality deteriorations.
Philippe Massicotte, Rémi Amiraux, Marie-Pier Amyot, Philippe Archambault, Mathieu Ardyna, Laurent Arnaud, Lise Artigue, Cyril Aubry, Pierre Ayotte, Guislain Bécu, Simon Bélanger, Ronald Benner, Henry C. Bittig, Annick Bricaud, Éric Brossier, Flavienne Bruyant, Laurent Chauvaud, Debra Christiansen-Stowe, Hervé Claustre, Véronique Cornet-Barthaux, Pierre Coupel, Christine Cox, Aurelie Delaforge, Thibaud Dezutter, Céline Dimier, Florent Domine, Francis Dufour, Christiane Dufresne, Dany Dumont, Jens Ehn, Brent Else, Joannie Ferland, Marie-Hélène Forget, Louis Fortier, Martí Galí, Virginie Galindo, Morgane Gallinari, Nicole Garcia, Catherine Gérikas Ribeiro, Margaux Gourdal, Priscilla Gourvil, Clemence Goyens, Pierre-Luc Grondin, Pascal Guillot, Caroline Guilmette, Marie-Noëlle Houssais, Fabien Joux, Léo Lacour, Thomas Lacour, Augustin Lafond, José Lagunas, Catherine Lalande, Julien Laliberté, Simon Lambert-Girard, Jade Larivière, Johann Lavaud, Anita LeBaron, Karine Leblanc, Florence Le Gall, Justine Legras, Mélanie Lemire, Maurice Levasseur, Edouard Leymarie, Aude Leynaert, Adriana Lopes dos Santos, Antonio Lourenço, David Mah, Claudie Marec, Dominique Marie, Nicolas Martin, Constance Marty, Sabine Marty, Guillaume Massé, Atsushi Matsuoka, Lisa Matthes, Brivaela Moriceau, Pierre-Emmanuel Muller, Christopher-John Mundy, Griet Neukermans, Laurent Oziel, Christos Panagiotopoulos, Jean-Jacques Pangrazi, Ghislain Picard, Marc Picheral, France Pinczon du Sel, Nicole Pogorzelec, Ian Probert, Bernard Quéguiner, Patrick Raimbault, Joséphine Ras, Eric Rehm, Erin Reimer, Jean-François Rontani, Søren Rysgaard, Blanche Saint-Béat, Makoto Sampei, Julie Sansoulet, Catherine Schmechtig, Sabine Schmidt, Richard Sempéré, Caroline Sévigny, Yuan Shen, Margot Tragin, Jean-Éric Tremblay, Daniel Vaulot, Gauthier Verin, Frédéric Vivier, Anda Vladoiu, Jeremy Whitehead, and Marcel Babin
Earth Syst. Sci. Data, 12, 151–176, https://doi.org/10.5194/essd-12-151-2020, https://doi.org/10.5194/essd-12-151-2020, 2020
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The Green Edge initiative was developed to understand the processes controlling the primary productivity and the fate of organic matter produced during the Arctic spring bloom (PSB). In this article, we present an overview of an extensive and comprehensive dataset acquired during two expeditions conducted in 2015 and 2016 on landfast ice southeast of Qikiqtarjuaq Island in Baffin Bay.
Eric J. Morgan, Jost V. Lavric, Damian L. Arévalo-Martínez, Hermann W. Bange, Tobias Steinhoff, Thomas Seifert, and Martin Heimann
Biogeosciences, 16, 4065–4084, https://doi.org/10.5194/bg-16-4065-2019, https://doi.org/10.5194/bg-16-4065-2019, 2019
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Taking a 2-year atmospheric record of atmospheric oxygen and the greenhouse gases N2O, CO2, and CH4, made at a coastal site in the Namib Desert, we estimated the fluxes of these gases from upwelling events in the northern Benguela Current region. We compared these results with flux measurements made on a research vessel in the study area at the same time and found that the two approaches agreed well. The study region was a source of N2O, CO2, and CH4 to the atmosphere during upwelling events.
Henk-Jan Hoving, Svenja Christiansen, Eduard Fabrizius, Helena Hauss, Rainer Kiko, Peter Linke, Philipp Neitzel, Uwe Piatkowski, and Arne Körtzinger
Ocean Sci., 15, 1327–1340, https://doi.org/10.5194/os-15-1327-2019, https://doi.org/10.5194/os-15-1327-2019, 2019
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The pelagic in situ observation system (PELAGIOS) is a towed observation system with HD video camera and environmental sensors. It is used for pelagic video transects down to 3000 m. The system enables the visualization and exploration of pelagic organisms (> 1 cm), in particular delicate gelatinous fauna, which cannot be captured by nets. The video and hydrographic data give insight into the biodiversity, abundance, and distribution of oceanic pelagic organisms from the surface to the deep sea.
Are Olsen, Nico Lange, Robert M. Key, Toste Tanhua, Marta Álvarez, Susan Becker, Henry C. Bittig, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Steven van Heuven, Mario Hoppema, Masao Ishii, Emil Jeansson, Steve D. Jones, Sara Jutterström, Maren K. Karlsen, Alex Kozyr, Siv K. Lauvset, Claire Lo Monaco, Akihiko Murata, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Maciej Telszewski, Bronte Tilbrook, Anton Velo, and Rik Wanninkhof
Earth Syst. Sci. Data, 11, 1437–1461, https://doi.org/10.5194/essd-11-1437-2019, https://doi.org/10.5194/essd-11-1437-2019, 2019
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by chemical analysis of water bottle samples at scientific cruises. GLODAPv2.2019 is the first update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality control, including systematic evaluation of measurement biases. This version contains data from 840 hydrographic cruises covering the world's oceans from 1972 to 2017.
Sinikka T. Lennartz, Marc von Hobe, Dennis Booge, Henry C. Bittig, Tim Fischer, Rafael Gonçalves-Araujo, Kerstin B. Ksionzek, Boris P. Koch, Astrid Bracher, Rüdiger Röttgers, Birgit Quack, and Christa A. Marandino
Ocean Sci., 15, 1071–1090, https://doi.org/10.5194/os-15-1071-2019, https://doi.org/10.5194/os-15-1071-2019, 2019
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The ocean emits the gases carbonyl sulfide (OCS) and carbon disulfide (CS2), which affect our climate. The goal of this study was to quantify the rates at which both gases are produced in the eastern tropical South Pacific (ETSP), one of the most productive oceanic regions worldwide. Both gases are produced by reactions triggered by sunlight, but we found that the amount produced depends on different factors. Our results improve numerical models to predict oceanic concentrations of both gases.
William J. Jenkins, Scott C. Doney, Michaela Fendrock, Rana Fine, Toshitaka Gamo, Philippe Jean-Baptiste, Robert Key, Birgit Klein, John E. Lupton, Robert Newton, Monika Rhein, Wolfgang Roether, Yuji Sano, Reiner Schlitzer, Peter Schlosser, and Jim Swift
Earth Syst. Sci. Data, 11, 441–454, https://doi.org/10.5194/essd-11-441-2019, https://doi.org/10.5194/essd-11-441-2019, 2019
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This paper describes an assembled dataset containing measurements of certain trace substances in the ocean, their distributions, and evolution with time. These substances, called tracers, result from a combination of natural and artificial processes, and their distribution and evolution provide important clues about ocean circulation, mixing, and ventilation. In addition, they give information about the global hydrologic cycle and volcanic and hydrothermal processes.
Corinne Le Quéré, Robbie M. Andrew, Pierre Friedlingstein, Stephen Sitch, Judith Hauck, Julia Pongratz, Penelope A. Pickers, Jan Ivar Korsbakken, Glen P. Peters, Josep G. Canadell, Almut Arneth, Vivek K. Arora, Leticia Barbero, Ana Bastos, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Scott C. Doney, Thanos Gkritzalis, Daniel S. Goll, Ian Harris, Vanessa Haverd, Forrest M. Hoffman, Mario Hoppema, Richard A. Houghton, George Hurtt, Tatiana Ilyina, Atul K. Jain, Truls Johannessen, Chris D. Jones, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Peter Landschützer, Nathalie Lefèvre, Sebastian Lienert, Zhu Liu, Danica Lombardozzi, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Craig Neill, Are Olsen, Tsueno Ono, Prabir Patra, Anna Peregon, Wouter Peters, Philippe Peylin, Benjamin Pfeil, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Matthias Rocher, Christian Rödenbeck, Ute Schuster, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Tobias Steinhoff, Adrienne Sutton, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco N. Tubiello, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Nicolas Viovy, Anthony P. Walker, Andrew J. Wiltshire, Rebecca Wright, Sönke Zaehle, and Bo Zheng
Earth Syst. Sci. Data, 10, 2141–2194, https://doi.org/10.5194/essd-10-2141-2018, https://doi.org/10.5194/essd-10-2141-2018, 2018
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The Global Carbon Budget 2018 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Vincent Taillandier, Thibaut Wagener, Fabrizio D'Ortenzio, Nicolas Mayot, Hervé Legoff, Joséphine Ras, Laurent Coppola, Orens Pasqueron de Fommervault, Catherine Schmechtig, Emilie Diamond, Henry Bittig, Dominique Lefevre, Edouard Leymarie, Antoine Poteau, and Louis Prieur
Earth Syst. Sci. Data, 10, 627–641, https://doi.org/10.5194/essd-10-627-2018, https://doi.org/10.5194/essd-10-627-2018, 2018
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We report on data from an oceanographic cruise, covering western, central and eastern parts of the Mediterranean Sea. This cruise was fully dedicated to the maintenance and the metrological verification of a biogeochemical observing system based on a fleet of BGC-Argo floats.
Corinne Le Quéré, Robbie M. Andrew, Pierre Friedlingstein, Stephen Sitch, Julia Pongratz, Andrew C. Manning, Jan Ivar Korsbakken, Glen P. Peters, Josep G. Canadell, Robert B. Jackson, Thomas A. Boden, Pieter P. Tans, Oliver D. Andrews, Vivek K. Arora, Dorothee C. E. Bakker, Leticia Barbero, Meike Becker, Richard A. Betts, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Catherine E. Cosca, Jessica Cross, Kim Currie, Thomas Gasser, Ian Harris, Judith Hauck, Vanessa Haverd, Richard A. Houghton, Christopher W. Hunt, George Hurtt, Tatiana Ilyina, Atul K. Jain, Etsushi Kato, Markus Kautz, Ralph F. Keeling, Kees Klein Goldewijk, Arne Körtzinger, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Ivan Lima, Danica Lombardozzi, Nicolas Metzl, Frank Millero, Pedro M. S. Monteiro, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Yukihiro Nojiri, X. Antonio Padin, Anna Peregon, Benjamin Pfeil, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Janet Reimer, Christian Rödenbeck, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Benjamin D. Stocker, Hanqin Tian, Bronte Tilbrook, Francesco N. Tubiello, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Steven van Heuven, Nicolas Viovy, Nicolas Vuichard, Anthony P. Walker, Andrew J. Watson, Andrew J. Wiltshire, Sönke Zaehle, and Dan Zhu
Earth Syst. Sci. Data, 10, 405–448, https://doi.org/10.5194/essd-10-405-2018, https://doi.org/10.5194/essd-10-405-2018, 2018
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The Global Carbon Budget 2017 describes data sets and methodology to quantify the five major components of the global carbon budget and their uncertainties. It is the 12th annual update and the 6th published in this journal.
Vincent Saderne, Peer Fietzek, Jens Daniel Müller, Arne Körtzinger, and Claas Hiebenthal
Biogeosciences Discuss., https://doi.org/10.5194/bg-2017-351, https://doi.org/10.5194/bg-2017-351, 2017
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Johannes Karstensen, Florian Schütte, Alice Pietri, Gerd Krahmann, Björn Fiedler, Damian Grundle, Helena Hauss, Arne Körtzinger, Carolin R. Löscher, Pierre Testor, Nuno Vieira, and Martin Visbeck
Biogeosciences, 14, 2167–2181, https://doi.org/10.5194/bg-14-2167-2017, https://doi.org/10.5194/bg-14-2167-2017, 2017
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High-resolution observational data from underwater gliders and ships are used to investigate drivers and pathways of nutrient upwelling in high-productive whirling ecosystems (eddies). The data suggest that the upwelling is created by the interaction of wind-induced internal waves with the local rotation of the eddy. Because of differences in nutrient and oxygen pathways, a low-oxygen core is established at shallow depth in the high-productive eddies.
Henry C. Bittig and Arne Körtzinger
Ocean Sci., 13, 1–11, https://doi.org/10.5194/os-13-1-2017, https://doi.org/10.5194/os-13-1-2017, 2017
Sinikka T. Lennartz, Christa A. Marandino, Marc von Hobe, Pau Cortes, Birgit Quack, Rafel Simo, Dennis Booge, Andrea Pozzer, Tobias Steinhoff, Damian L. Arevalo-Martinez, Corinna Kloss, Astrid Bracher, Rüdiger Röttgers, Elliot Atlas, and Kirstin Krüger
Atmos. Chem. Phys., 17, 385–402, https://doi.org/10.5194/acp-17-385-2017, https://doi.org/10.5194/acp-17-385-2017, 2017
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We present new sea surface and marine boundary layer measurements of carbonyl sulfide, the most abundant sulfur gas in the atmosphere, and calculate an oceanic emission estimate. Our results imply that oceanic emissions are very unlikely to account for the missing source in the atmospheric budget that is currently discussed for OCS.
Corinne Le Quéré, Robbie M. Andrew, Josep G. Canadell, Stephen Sitch, Jan Ivar Korsbakken, Glen P. Peters, Andrew C. Manning, Thomas A. Boden, Pieter P. Tans, Richard A. Houghton, Ralph F. Keeling, Simone Alin, Oliver D. Andrews, Peter Anthoni, Leticia Barbero, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Kim Currie, Christine Delire, Scott C. Doney, Pierre Friedlingstein, Thanos Gkritzalis, Ian Harris, Judith Hauck, Vanessa Haverd, Mario Hoppema, Kees Klein Goldewijk, Atul K. Jain, Etsushi Kato, Arne Körtzinger, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Danica Lombardozzi, Joe R. Melton, Nicolas Metzl, Frank Millero, Pedro M. S. Monteiro, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Kevin O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Denis Pierrot, Benjamin Poulter, Christian Rödenbeck, Joe Salisbury, Ute Schuster, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Benjamin D. Stocker, Adrienne J. Sutton, Taro Takahashi, Hanqin Tian, Bronte Tilbrook, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Nicolas Viovy, Anthony P. Walker, Andrew J. Wiltshire, and Sönke Zaehle
Earth Syst. Sci. Data, 8, 605–649, https://doi.org/10.5194/essd-8-605-2016, https://doi.org/10.5194/essd-8-605-2016, 2016
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The Global Carbon Budget 2016 is the 11th annual update of emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land, and ocean. This data synthesis brings together measurements, statistical information, and analyses of model results in order to provide an assessment of the global carbon budget and their uncertainties for years 1959 to 2015, with a projection for year 2016.
Florian Schütte, Johannes Karstensen, Gerd Krahmann, Helena Hauss, Björn Fiedler, Peter Brandt, Martin Visbeck, and Arne Körtzinger
Biogeosciences, 13, 5865–5881, https://doi.org/10.5194/bg-13-5865-2016, https://doi.org/10.5194/bg-13-5865-2016, 2016
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Mesoscale eddies with very low–oxygen concentrations at shallow depth have been recently discovered in the eastern tropical North Atlantic. Our analysis shows that low oxygen eddies occur more frequent than expected and are found even close to the equator (8° N). From budget calculations we show that an oxygen reduction of 7 µmol/kg in the depth range of 50–150 m in the eastern tropical North Atlantic (peak reduction is 16 µmol/kg at 100 m depth) can be associated with the dispersion of these eddies.
Meike Becker, Nils Andersen, Helmut Erlenkeuser, Matthew P. Humphreys, Toste Tanhua, and Arne Körtzinger
Earth Syst. Sci. Data, 8, 559–570, https://doi.org/10.5194/essd-8-559-2016, https://doi.org/10.5194/essd-8-559-2016, 2016
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The stable carbon isotope composition of dissolved inorganic carbon (δ13C-DIC) can be used to quantify fluxes within the marine carbon system such as the exchange between ocean and atmosphere or the amount of anthropogenic carbon in the water column. In this study, an internally consistent δ13C-DIC dataset for the North Atlantic is presented. The data have undergone a secondary quality control during which systematic biases between the respective cruises have been quantified and adjusted.
Björn Fiedler, Damian S. Grundle, Florian Schütte, Johannes Karstensen, Carolin R. Löscher, Helena Hauss, Hannes Wagner, Alexandra Loginova, Rainer Kiko, Péricles Silva, Toste Tanhua, and Arne Körtzinger
Biogeosciences, 13, 5633–5647, https://doi.org/10.5194/bg-13-5633-2016, https://doi.org/10.5194/bg-13-5633-2016, 2016
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Oxygen-depleted mesoscale features in the open eastern tropical North Atlantic, which are formed in the Mauritanian upwelling region, were discovered recently. This study examines biogeochemical structure and magnitudes of related processes within these isolated water masses. We found very low oxygen concentrations and strongly enhanced acidity at near-surface depth. Oxygen utilization and downward carbon export were found to exceed known values for this ocean region.
Dorothee C. E. Bakker, Benjamin Pfeil, Camilla S. Landa, Nicolas Metzl, Kevin M. O'Brien, Are Olsen, Karl Smith, Cathy Cosca, Sumiko Harasawa, Stephen D. Jones, Shin-ichiro Nakaoka, Yukihiro Nojiri, Ute Schuster, Tobias Steinhoff, Colm Sweeney, Taro Takahashi, Bronte Tilbrook, Chisato Wada, Rik Wanninkhof, Simone R. Alin, Carlos F. Balestrini, Leticia Barbero, Nicholas R. Bates, Alejandro A. Bianchi, Frédéric Bonou, Jacqueline Boutin, Yann Bozec, Eugene F. Burger, Wei-Jun Cai, Robert D. Castle, Liqi Chen, Melissa Chierici, Kim Currie, Wiley Evans, Charles Featherstone, Richard A. Feely, Agneta Fransson, Catherine Goyet, Naomi Greenwood, Luke Gregor, Steven Hankin, Nick J. Hardman-Mountford, Jérôme Harlay, Judith Hauck, Mario Hoppema, Matthew P. Humphreys, Christopher W. Hunt, Betty Huss, J. Severino P. Ibánhez, Truls Johannessen, Ralph Keeling, Vassilis Kitidis, Arne Körtzinger, Alex Kozyr, Evangelia Krasakopoulou, Akira Kuwata, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Claire Lo Monaco, Ansley Manke, Jeremy T. Mathis, Liliane Merlivat, Frank J. Millero, Pedro M. S. Monteiro, David R. Munro, Akihiko Murata, Timothy Newberger, Abdirahman M. Omar, Tsuneo Ono, Kristina Paterson, David Pearce, Denis Pierrot, Lisa L. Robbins, Shu Saito, Joe Salisbury, Reiner Schlitzer, Bernd Schneider, Roland Schweitzer, Rainer Sieger, Ingunn Skjelvan, Kevin F. Sullivan, Stewart C. Sutherland, Adrienne J. Sutton, Kazuaki Tadokoro, Maciej Telszewski, Matthias Tuma, Steven M. A. C. van Heuven, Doug Vandemark, Brian Ward, Andrew J. Watson, and Suqing Xu
Earth Syst. Sci. Data, 8, 383–413, https://doi.org/10.5194/essd-8-383-2016, https://doi.org/10.5194/essd-8-383-2016, 2016
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Version 3 of the Surface Ocean CO2 Atlas (www.socat.info) has 14.5 million CO2 (carbon dioxide) values for the years 1957 to 2014 covering the global oceans and coastal seas. Version 3 is an update to version 2 with a longer record and 44 % more CO2 values. The CO2 measurements have been made on ships, fixed moorings and drifting buoys. SOCAT enables quantification of the ocean carbon sink and ocean acidification, as well as model evaluation, thus informing climate negotiations.
Gerhard Fischer, Johannes Karstensen, Oscar Romero, Karl-Heinz Baumann, Barbara Donner, Jens Hefter, Gesine Mollenhauer, Morten Iversen, Björn Fiedler, Ivanice Monteiro, and Arne Körtzinger
Biogeosciences, 13, 3203–3223, https://doi.org/10.5194/bg-13-3203-2016, https://doi.org/10.5194/bg-13-3203-2016, 2016
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Particle fluxes at the Cape Verde Ocean Observatory in the eastern tropical North Atlantic for the period December 2009 until May 2011 are discussed based on deep sediment trap time-series data collected at 1290 and 3439 m water depths. The typically open-ocean flux pattern with weak seasonality is modified by the appearance of a highly productive and low oxygen eddy in winter 2010. The eddy passage was accompanied by high biogenic and lithogenic fluxes, lasting from December 2009 to May 2010.
Helena Hauss, Svenja Christiansen, Florian Schütte, Rainer Kiko, Miryam Edvam Lima, Elizandro Rodrigues, Johannes Karstensen, Carolin R. Löscher, Arne Körtzinger, and Björn Fiedler
Biogeosciences, 13, 1977–1989, https://doi.org/10.5194/bg-13-1977-2016, https://doi.org/10.5194/bg-13-1977-2016, 2016
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In a low-oxygen eddy in the tropical Atlantic, total zooplankton biomass was increased. Larger plankton avoided the oxygen minimum zone (OMZ, < 20 µmol O2 kg−1). We identified four strategies by different plankton groups: (i) shallow OMZ avoidance and compression at surface, (ii) migration to shallow OMZ core during daytime, migration to surface at nighttime, (iii) residing in shallow OMZ day and night and (iv) migration through the shallow OMZ from oxygenated depths to surface and back.
S. Walter, A. Kock, T. Steinhoff, B. Fiedler, P. Fietzek, J. Kaiser, M. Krol, M. E. Popa, Q. Chen, T. Tanhua, and T. Röckmann
Biogeosciences, 13, 323–340, https://doi.org/10.5194/bg-13-323-2016, https://doi.org/10.5194/bg-13-323-2016, 2016
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Oceans are a source of H2, an indirect greenhouse gas. Measurements constraining the temporal and spatial patterns of oceanic H2 emissions are sparse and although H2 is assumed to be produced mainly biologically, direct evidence for biogenic marine production was lacking. By analyzing the H2 isotopic composition (δD) we were able to constrain the global H2 budget in more detail, verify biogenic production and point to additional sources. We also showed that current models are reasonably working.
C. R. Löscher, M. A. Fischer, S. C. Neulinger, B. Fiedler, M. Philippi, F. Schütte, A. Singh, H. Hauss, J. Karstensen, A. Körtzinger, S. Künzel, and R. A. Schmitz
Biogeosciences, 12, 7467–7482, https://doi.org/10.5194/bg-12-7467-2015, https://doi.org/10.5194/bg-12-7467-2015, 2015
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The waters of the tropical Atlantic Open Ocean usually contain comparably high concentrations of oxygen. Now, it became clear that there are watermasses related to eddies that are nearly anoxic. We surveyed one of those eddies and found a biosphere that largely differed from the usual biosphere present in this area with a specific community responsible for primary production and for degradation processes. Further, we found the very first indication for active nitrogen loss in the open Atlantic.
C. Le Quéré, R. Moriarty, R. M. Andrew, J. G. Canadell, S. Sitch, J. I. Korsbakken, P. Friedlingstein, G. P. Peters, R. J. Andres, T. A. Boden, R. A. Houghton, J. I. House, R. F. Keeling, P. Tans, A. Arneth, D. C. E. Bakker, L. Barbero, L. Bopp, J. Chang, F. Chevallier, L. P. Chini, P. Ciais, M. Fader, R. A. Feely, T. Gkritzalis, I. Harris, J. Hauck, T. Ilyina, A. K. Jain, E. Kato, V. Kitidis, K. Klein Goldewijk, C. Koven, P. Landschützer, S. K. Lauvset, N. Lefèvre, A. Lenton, I. D. Lima, N. Metzl, F. Millero, D. R. Munro, A. Murata, J. E. M. S. Nabel, S. Nakaoka, Y. Nojiri, K. O'Brien, A. Olsen, T. Ono, F. F. Pérez, B. Pfeil, D. Pierrot, B. Poulter, G. Rehder, C. Rödenbeck, S. Saito, U. Schuster, J. Schwinger, R. Séférian, T. Steinhoff, B. D. Stocker, A. J. Sutton, T. Takahashi, B. Tilbrook, I. T. van der Laan-Luijkx, G. R. van der Werf, S. van Heuven, D. Vandemark, N. Viovy, A. Wiltshire, S. Zaehle, and N. Zeng
Earth Syst. Sci. Data, 7, 349–396, https://doi.org/10.5194/essd-7-349-2015, https://doi.org/10.5194/essd-7-349-2015, 2015
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Accurate assessment of anthropogenic carbon dioxide emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to understand the global carbon cycle, support the development of climate policies, and project future climate change. We describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on a range of data and models and their interpretation by a broad scientific community.
V. Saderne, P. Fietzek, S. Aßmann, A. Körtzinger, and C. Hiebenthal
Biogeosciences Discuss., https://doi.org/10.5194/bgd-12-11423-2015, https://doi.org/10.5194/bgd-12-11423-2015, 2015
Revised manuscript not accepted
C. Le Quéré, R. Moriarty, R. M. Andrew, G. P. Peters, P. Ciais, P. Friedlingstein, S. D. Jones, S. Sitch, P. Tans, A. Arneth, T. A. Boden, L. Bopp, Y. Bozec, J. G. Canadell, L. P. Chini, F. Chevallier, C. E. Cosca, I. Harris, M. Hoppema, R. A. Houghton, J. I. House, A. K. Jain, T. Johannessen, E. Kato, R. F. Keeling, V. Kitidis, K. Klein Goldewijk, C. Koven, C. S. Landa, P. Landschützer, A. Lenton, I. D. Lima, G. Marland, J. T. Mathis, N. Metzl, Y. Nojiri, A. Olsen, T. Ono, S. Peng, W. Peters, B. Pfeil, B. Poulter, M. R. Raupach, P. Regnier, C. Rödenbeck, S. Saito, J. E. Salisbury, U. Schuster, J. Schwinger, R. Séférian, J. Segschneider, T. Steinhoff, B. D. Stocker, A. J. Sutton, T. Takahashi, B. Tilbrook, G. R. van der Werf, N. Viovy, Y.-P. Wang, R. Wanninkhof, A. Wiltshire, and N. Zeng
Earth Syst. Sci. Data, 7, 47–85, https://doi.org/10.5194/essd-7-47-2015, https://doi.org/10.5194/essd-7-47-2015, 2015
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Carbon dioxide (CO2) emissions from human activities (burning fossil fuels and cement production, deforestation and other land-use change) are set to rise again in 2014.
This study (updated yearly) makes an accurate assessment of anthropogenic CO2 emissions and their redistribution between the atmosphere, ocean, and terrestrial biosphere in order to better understand the global carbon cycle, support the development of climate policies, and project future climate change.
J. Karstensen, B. Fiedler, F. Schütte, P. Brandt, A. Körtzinger, G. Fischer, R. Zantopp, J. Hahn, M. Visbeck, and D. Wallace
Biogeosciences, 12, 2597–2605, https://doi.org/10.5194/bg-12-2597-2015, https://doi.org/10.5194/bg-12-2597-2015, 2015
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This study is the first report of the formation of dead zones in the open ocean. A combination of multiple ocean observing system elements (mooring, floats, satellites, ships) allowed us to reconstruct the generation of the dead zones and to connect the formation to enhanced respiration within mesoscale ocean eddies. The dead zones present specific threats to the ecosystem, such as the interruption of the diurnal migration of zooplankters.
P. Brandt, H. W. Bange, D. Banyte, M. Dengler, S.-H. Didwischus, T. Fischer, R. J. Greatbatch, J. Hahn, T. Kanzow, J. Karstensen, A. Körtzinger, G. Krahmann, S. Schmidtko, L. Stramma, T. Tanhua, and M. Visbeck
Biogeosciences, 12, 489–512, https://doi.org/10.5194/bg-12-489-2015, https://doi.org/10.5194/bg-12-489-2015, 2015
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Our observational study looks at the structure of the eastern tropical North Atlantic (ETNA) oxygen minimum zone (OMZ) in comparison with the less-ventilated, eastern tropical South Pacific OMZ. We quantify the OMZ’s oxygen budget composed of consumption, advection, lateral and vertical mixing. Substantial oxygen variability is observed on interannual to multidecadal timescales. The deoxygenation of the ETNA OMZ during the last decades represents a substantial imbalance of the oxygen budget.
C. Le Quéré, G. P. Peters, R. J. Andres, R. M. Andrew, T. A. Boden, P. Ciais, P. Friedlingstein, R. A. Houghton, G. Marland, R. Moriarty, S. Sitch, P. Tans, A. Arneth, A. Arvanitis, D. C. E. Bakker, L. Bopp, J. G. Canadell, L. P. Chini, S. C. Doney, A. Harper, I. Harris, J. I. House, A. K. Jain, S. D. Jones, E. Kato, R. F. Keeling, K. Klein Goldewijk, A. Körtzinger, C. Koven, N. Lefèvre, F. Maignan, A. Omar, T. Ono, G.-H. Park, B. Pfeil, B. Poulter, M. R. Raupach, P. Regnier, C. Rödenbeck, S. Saito, J. Schwinger, J. Segschneider, B. D. Stocker, T. Takahashi, B. Tilbrook, S. van Heuven, N. Viovy, R. Wanninkhof, A. Wiltshire, and S. Zaehle
Earth Syst. Sci. Data, 6, 235–263, https://doi.org/10.5194/essd-6-235-2014, https://doi.org/10.5194/essd-6-235-2014, 2014
D. C. E. Bakker, B. Pfeil, K. Smith, S. Hankin, A. Olsen, S. R. Alin, C. Cosca, S. Harasawa, A. Kozyr, Y. Nojiri, K. M. O'Brien, U. Schuster, M. Telszewski, B. Tilbrook, C. Wada, J. Akl, L. Barbero, N. R. Bates, J. Boutin, Y. Bozec, W.-J. Cai, R. D. Castle, F. P. Chavez, L. Chen, M. Chierici, K. Currie, H. J. W. de Baar, W. Evans, R. A. Feely, A. Fransson, Z. Gao, B. Hales, N. J. Hardman-Mountford, M. Hoppema, W.-J. Huang, C. W. Hunt, B. Huss, T. Ichikawa, T. Johannessen, E. M. Jones, S. D. Jones, S. Jutterström, V. Kitidis, A. Körtzinger, P. Landschützer, S. K. Lauvset, N. Lefèvre, A. B. Manke, J. T. Mathis, L. Merlivat, N. Metzl, A. Murata, T. Newberger, A. M. Omar, T. Ono, G.-H. Park, K. Paterson, D. Pierrot, A. F. Ríos, C. L. Sabine, S. Saito, J. Salisbury, V. V. S. S. Sarma, R. Schlitzer, R. Sieger, I. Skjelvan, T. Steinhoff, K. F. Sullivan, H. Sun, A. J. Sutton, T. Suzuki, C. Sweeney, T. Takahashi, J. Tjiputra, N. Tsurushima, S. M. A. C. van Heuven, D. Vandemark, P. Vlahos, D. W. R. Wallace, R. Wanninkhof, and A. J. Watson
Earth Syst. Sci. Data, 6, 69–90, https://doi.org/10.5194/essd-6-69-2014, https://doi.org/10.5194/essd-6-69-2014, 2014
D. L. Arévalo-Martínez, M. Beyer, M. Krumbholz, I. Piller, A. Kock, T. Steinhoff, A. Körtzinger, and H. W. Bange
Ocean Sci., 9, 1071–1087, https://doi.org/10.5194/os-9-1071-2013, https://doi.org/10.5194/os-9-1071-2013, 2013
Related subject area
Biogeochemistry: Open Ocean
Sedimentary organic matter signature hints at the phytoplankton-driven biological carbon pump in the central Arabian Sea
Hydrological cycle amplification imposes spatial patterns on the climate change response of ocean pH and carbonate chemistry
Assessing the tropical Atlantic biogeochemical processes in the Norwegian Earth System Model
Evolution of oxygen and stratification and their relationship in the North Pacific Ocean in CMIP6 Earth system models
Evaluation of CMIP6 model performance in simulating historical biogeochemistry across the southern South China Sea
Drivers of decadal trends in the ocean carbon sink in the past, present, and future in Earth system models
Anthropogenic carbon storage and its decadal changes in the Atlantic between 1990–2020
Ocean alkalinity enhancement impacts: regrowth of marine microalgae in alkaline mineral concentrations simulating the initial concentrations after ship-based dispersions
Climatic controls on metabolic constraints in the ocean
Effects of grain size and seawater salinity on magnesium hydroxide dissolution and secondary calcium carbonate precipitation kinetics: implications for ocean alkalinity enhancement
Short-term response of Emiliania huxleyi growth and morphology to abrupt salinity stress
Assessing the impact of CO2-equilibrated ocean alkalinity enhancement on microbial metabolic rates in an oligotrophic system
Ocean Acidification trends and Carbonate System dynamics in the North Atlantic Subpolar Gyre during 2009–2019
Phosphomonoesterase and phosphodiesterase activities in the eastern Mediterranean in two contrasting seasonal situations
Net primary production annual maxima in the North Atlantic projected to shift in the 21st century
Testing the influence of light on nitrite cycling in the eastern tropical North Pacific
Loss of nitrogen via anaerobic ammonium oxidation (anammox) in the California Current system during the late Quaternary
Linking northeastern North Pacific oxygen changes to upstream surface outcrop variations
Underestimation of multi-decadal global O2 loss due to an optimal interpolation method
Reviews and syntheses: expanding the global coverage of gross primary production and net community production measurements using Biogeochemical-Argo floats
Characteristics of surface physical and biogeochemical parameters within mesoscale eddies in the Southern Ocean
Seasonal dynamics and annual budget of dissolved inorganic carbon in the northwestern Mediterranean deep-convection region
The fingerprint of climate variability on the surface ocean cycling of iron and its isotopes
Reconstructing the ocean's mesopelagic zone carbon budget: sensitivity and estimation of parameters associated with prokaryotic remineralization
Seasonal cycles of biogeochemical fluxes in the Scotia Sea, Southern Ocean: a stable isotope approach
Absence of photophysiological response to iron addition in autumn phytoplankton in the Antarctic sea-ice zone
Optimal parameters for the ocean's nutrient, carbon, and oxygen cycles compensate for circulation biases but replumb the biological pump
Importance of multiple sources of iron for the upper-ocean biogeochemistry over the northern Indian Ocean
Exploring the role of different data types and timescales in the quality of marine biogeochemical model calibration
All about nitrite: exploring nitrite sources and sinks in the eastern tropical North Pacific oxygen minimum zone
Fossil coccolith morphological attributes as a new proxy for deep ocean carbonate chemistry
Reconstructing ocean carbon storage with CMIP6 Earth system models and synthetic Argo observations
Using machine learning and Biogeochemical-Argo (BGC-Argo) floats to assess biogeochemical models and optimize observing system design
The representation of alkalinity and the carbonate pump from CMIP5 to CMIP6 Earth system models and implications for the carbon cycle
Model estimates of metazoans' contributions to the biological carbon pump
Tracing differences in iron supply to the Mid-Atlantic Ridge valley between hydrothermal vent sites: implications for the addition of iron to the deep ocean
Nitrite cycling in the primary nitrite maxima of the eastern tropical North Pacific
Hotspots and drivers of compound marine heatwaves and low net primary production extremes
Ecosystem impacts of marine heat waves in the northeast Pacific
Tracing the role of Arctic shelf processes in Si and N cycling and export through the Fram Strait: insights from combined silicon and nitrate isotopes
Controls on the relative abundances and rates of nitrifying microorganisms in the ocean
The response of diazotrophs to nutrient amendment in the South China Sea and western North Pacific
Influence of GEOTRACES data distribution and misfit function choice on objective parameter retrieval in a marine zinc cycle model
Physiological flexibility of phytoplankton impacts modelled chlorophyll and primary production across the North Pacific Ocean
Observation-constrained estimates of the global ocean carbon sink from Earth system models
Early winter barium excess in the southern Indian Ocean as an annual remineralisation proxy (GEOTRACES GIPr07 cruise)
Controlling factors on the global distribution of a representative marine non-cyanobacterial diazotroph phylotype (Gamma A)
Summer trends and drivers of sea surface fCO2 and pH changes observed in the southern Indian Ocean over the last two decades (1998–2019)
Global nutrient cycling by commercially targeted marine fish
Major processes of the dissolved cobalt cycle in the North and equatorial Pacific Ocean
Medhavi Pandey, Haimanti Biswas, Daniel Birgel, Nicole Burdanowitz, and Birgit Gaye
Biogeosciences, 21, 4681–4698, https://doi.org/10.5194/bg-21-4681-2024, https://doi.org/10.5194/bg-21-4681-2024, 2024
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We analysed sea surface temperature (SST) proxy and plankton biomarkers in sediments that accumulate sinking material signatures from surface waters in the central Arabian Sea (21°–11° N, 64° E), a tropical basin impacted by monsoons. We saw a north–south SST gradient, and the biological proxies showed more organic matter from larger algae in the north. Smaller algae and zooplankton were more numerous in the south. These trends were related to ocean–atmospheric processes and oxygen availability.
Allison Hogikyan and Laure Resplandy
Biogeosciences, 21, 4621–4636, https://doi.org/10.5194/bg-21-4621-2024, https://doi.org/10.5194/bg-21-4621-2024, 2024
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Rising atmospheric CO2 influences ocean carbon chemistry, leading to ocean acidification. Global warming introduces spatial patterns in the intensity of ocean acidification. We show that the most prominent spatial patterns are controlled by warming-driven changes in rainfall and evaporation, not by the direct effect of warming on carbon chemistry and pH. These evaporation and rainfall patterns oppose acidification in saltier parts of the ocean and enhance acidification in fresher regions.
Shunya Koseki, Lander R. Crespo, Jerry Tjiputra, Filippa Fransner, Noel S. Keenlyside, and David Rivas
Biogeosciences, 21, 4149–4168, https://doi.org/10.5194/bg-21-4149-2024, https://doi.org/10.5194/bg-21-4149-2024, 2024
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We investigated how the physical biases of an Earth system model influence the marine biogeochemical processes in the tropical Atlantic. With four different configurations of the model, we have shown that the versions with better SST reproduction tend to better represent the primary production and air–sea CO2 flux in terms of climatology, seasonal cycle, and response to climate variability.
Lyuba Novi, Annalisa Bracco, Takamitsu Ito, and Yohei Takano
Biogeosciences, 21, 3985–4005, https://doi.org/10.5194/bg-21-3985-2024, https://doi.org/10.5194/bg-21-3985-2024, 2024
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We explored the relationship between oxygen and stratification in the North Pacific Ocean using a combination of data mining and machine learning. We used isopycnic potential vorticity (IPV) as an indicator to quantify ocean ventilation and analyzed its predictability, a strong O2–IPV connection, and predictability for IPV in the tropical Pacific. This opens new routes for monitoring ocean O2 through few observational sites co-located with more abundant IPV measurements in the tropical Pacific.
Winfred Marshal, Jing Xiang Chung, Nur Hidayah Roseli, Roswati Md Amin, and Mohd Fadzil Bin Mohd Akhir
Biogeosciences, 21, 4007–4035, https://doi.org/10.5194/bg-21-4007-2024, https://doi.org/10.5194/bg-21-4007-2024, 2024
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This study stands out for thoroughly examining CMIP6 ESMs' ability to simulate biogeochemical variables in the southern South China Sea, an economically important region. It assesses variables like chlorophyll, phytoplankton, nitrate, and oxygen on annual and seasonal scales. While global assessments exist, this study addresses a gap by objectively ranking 13 CMIP6 ocean biogeochemistry models' performance at a regional level, focusing on replicating specific observed biogeochemical variables.
Jens Terhaar
Biogeosciences, 21, 3903–3926, https://doi.org/10.5194/bg-21-3903-2024, https://doi.org/10.5194/bg-21-3903-2024, 2024
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Despite the ocean’s importance in the carbon cycle and hence the climate, observing the ocean carbon sink remains challenging. Here, I use an ensemble of 12 models to understand drivers of decadal trends of the past, present, and future ocean carbon sink. I show that 80 % of the decadal trends in the multi-model mean ocean carbon sink can be explained by changes in decadal trends in atmospheric CO2. The remaining 20 % are due to internal climate variability and ocean heat uptake.
Reiner Steinfeldt, Monika Rhein, and Dagmar Kieke
Biogeosciences, 21, 3839–3867, https://doi.org/10.5194/bg-21-3839-2024, https://doi.org/10.5194/bg-21-3839-2024, 2024
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We calculate the amount of anthropogenic carbon (Cant) in the Atlantic for the years 1990, 2000, 2010 and 2020. Cant is the carbon that is taken up by the ocean as a result of humanmade CO2 emissions. To determine the amount of Cant, we apply a technique that is based on the observations of other humanmade gases (e.g., chlorofluorocarbons). Regionally, changes in ocean ventilation have an impact on the storage of Cant. Overall, the increase in Cant is driven by the rising CO2 in the atmosphere.
Stephanie Delacroix, Tor Jensen Nystuen, August E. Dessen Tobiesen, Andrew L. King, and Erik Höglund
Biogeosciences, 21, 3677–3690, https://doi.org/10.5194/bg-21-3677-2024, https://doi.org/10.5194/bg-21-3677-2024, 2024
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The addition of alkaline minerals into the ocean might reduce excessive anthropogenic CO2 emissions. Magnesium hydroxide can be added in large amounts because of its low seawater solubility without reaching harmful pH levels. The toxicity effect results of magnesium hydroxide, by simulating the expected concentrations from a ship's dispersion scenario, demonstrated low impacts on both sensitive and local assemblages of marine microalgae when compared to calcium hydroxide.
Precious Mongwe, Matthew Long, Takamitsu Ito, Curtis Deutsch, and Yeray Santana-Falcón
Biogeosciences, 21, 3477–3490, https://doi.org/10.5194/bg-21-3477-2024, https://doi.org/10.5194/bg-21-3477-2024, 2024
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We use a collection of measurements that capture the physiological sensitivity of organisms to temperature and oxygen and a CESM1 large ensemble to investigate how natural climate variations and climate warming will impact the ability of marine heterotrophic marine organisms to support habitats in the future. We find that warming and dissolved oxygen loss over the next several decades will reduce the volume of ocean habitats and will increase organisms' vulnerability to extremes.
Charly A. Moras, Tyler Cyronak, Lennart T. Bach, Renaud Joannes-Boyau, and Kai G. Schulz
Biogeosciences, 21, 3463–3475, https://doi.org/10.5194/bg-21-3463-2024, https://doi.org/10.5194/bg-21-3463-2024, 2024
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We investigate the effects of mineral grain size and seawater salinity on magnesium hydroxide dissolution and calcium carbonate precipitation kinetics for ocean alkalinity enhancement. Salinity did not affect the dissolution, but calcium carbonate formed earlier at lower salinities due to the lower magnesium and dissolved organic carbon concentrations. Smaller grain sizes dissolved faster but calcium carbonate precipitated earlier, suggesting that medium grain sizes are optimal for kinetics.
Rosie M. Sheward, Christina Gebühr, Jörg Bollmann, and Jens O. Herrle
Biogeosciences, 21, 3121–3141, https://doi.org/10.5194/bg-21-3121-2024, https://doi.org/10.5194/bg-21-3121-2024, 2024
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How quickly do marine microorganisms respond to salinity stress? Our experiments with the calcifying marine plankton Emiliania huxleyi show that growth and cell morphology responded to salinity stress within as little as 24–48 hours, demonstrating that morphology and calcification are sensitive to salinity over a range of timescales. Our results have implications for understanding the short-term role of E. huxleyi in biogeochemical cycles and in size-based paleoproxies for salinity.
Laura Marín-Samper, Javier Arístegui, Nauzet Hernández-Hernández, Joaquín Ortiz, Stephen D. Archer, Andrea Ludwig, and Ulf Riebesell
Biogeosciences, 21, 2859–2876, https://doi.org/10.5194/bg-21-2859-2024, https://doi.org/10.5194/bg-21-2859-2024, 2024
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Our planet is facing a climate crisis. Scientists are working on innovative solutions that will aid in capturing the hard to abate emissions before it is too late. Exciting research reveals that ocean alkalinity enhancement, a key climate change mitigation strategy, does not harm phytoplankton, the cornerstone of marine ecosystems. Through meticulous study, we may have uncovered a positive relationship: up to a specific limit, enhancing ocean alkalinity boosts photosynthesis by certain species.
David Curbelo-Hernández, Fiz F. Pérez, Melchor González-Dávila, Sergey V. Gladyshev, Aridane G. González, David González-Santana, Antón Velo, Alexey Sokov, and J. Magdalena Santana-Casiano
EGUsphere, https://doi.org/10.5194/egusphere-2024-1388, https://doi.org/10.5194/egusphere-2024-1388, 2024
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The study evaluated CO2-carbonate system dynamics in the North Atlantic Subpolar Gyre from 2009 to 2019. Significant ocean acidification, largely due to rising anthropogenic CO2 levels, was found. Cooling, freshening, and enhanced convective processes intensified this trend, affecting calcite and aragonite saturation. The findings contribute to a deeper understanding of Ocean Acidification and improve our knowledge about its impact on marine ecosystems.
France Van Wambeke, Pascal Conan, Mireille Pujo-Pay, Vincent Taillandier, Olivier Crispi, Alexandra Pavlidou, Sandra Nunige, Morgane Didry, Christophe Salmeron, and Elvira Pulido-Villena
Biogeosciences, 21, 2621–2640, https://doi.org/10.5194/bg-21-2621-2024, https://doi.org/10.5194/bg-21-2621-2024, 2024
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Phosphomonoesterase (PME) and phosphodiesterase (PDE) activities over the epipelagic zone are described in the eastern Mediterranean Sea in winter and autumn. The types of concentration kinetics obtained for PDE (saturation at 50 µM, high Km, high turnover times) compared to those of PME (saturation at 1 µM, low Km, low turnover times) are discussed in regard to the possible inequal distribution of PDE and PME in the size continuum of organic material and accessibility to phosphodiesters.
Jenny Hieronymus, Magnus Hieronymus, Matthias Gröger, Jörg Schwinger, Raffaele Bernadello, Etienne Tourigny, Valentina Sicardi, Itzel Ruvalcaba Baroni, and Klaus Wyser
Biogeosciences, 21, 2189–2206, https://doi.org/10.5194/bg-21-2189-2024, https://doi.org/10.5194/bg-21-2189-2024, 2024
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The timing of the net primary production annual maxima in the North Atlantic in the period 1750–2100 is investigated using two Earth system models and the high-emissions scenario SSP5-8.5. It is found that, for most of the region, the annual maxima occur progressively earlier, with the most change occurring after the year 2000. Shifts in the seasonality of the primary production may impact the entire ecosystem, which highlights the need for long-term monitoring campaigns in this area.
Nicole M. Travis, Colette L. Kelly, and Karen L. Casciotti
Biogeosciences, 21, 1985–2004, https://doi.org/10.5194/bg-21-1985-2024, https://doi.org/10.5194/bg-21-1985-2024, 2024
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We conducted experimental manipulations of light level on microbial communities from the primary nitrite maximum. Overall, while individual microbial processes have different directions and magnitudes in their response to increasing light, the net community response is a decline in nitrite production with increasing light. We conclude that while increased light may decrease net nitrite production, high-light conditions alone do not exclude nitrification from occurring in the surface ocean.
Zoë Rebecca van Kemenade, Zeynep Erdem, Ellen Christine Hopmans, Jaap Smede Sinninghe Damsté, and Darci Rush
Biogeosciences, 21, 1517–1532, https://doi.org/10.5194/bg-21-1517-2024, https://doi.org/10.5194/bg-21-1517-2024, 2024
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The California Current system (CCS) hosts the eastern subtropical North Pacific oxygen minimum zone (ESTNP OMZ). This study shows anaerobic ammonium oxidizing (anammox) bacteria cause a loss of bioavailable nitrogen (N) in the ESTNP OMZ throughout the late Quaternary. Anammox occurred during both glacial and interglacial periods and was driven by the supply of organic matter and changes in ocean currents. These findings may have important consequences for biogeochemical models of the CCS.
Sabine Mecking and Kyla Drushka
Biogeosciences, 21, 1117–1133, https://doi.org/10.5194/bg-21-1117-2024, https://doi.org/10.5194/bg-21-1117-2024, 2024
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This study investigates whether northeastern North Pacific oxygen changes may be caused by surface density changes in the northwest as water moves along density horizons from the surface into the subsurface ocean. A correlation is found with a lag that about matches the travel time of water from the northwest to the northeast. Salinity is the main driver causing decadal changes in surface density, whereas salinity and temperature contribute about equally to long-term declining density trends.
Takamitsu Ito, Hernan E. Garcia, Zhankun Wang, Shoshiro Minobe, Matthew C. Long, Just Cebrian, James Reagan, Tim Boyer, Christopher Paver, Courtney Bouchard, Yohei Takano, Seth Bushinsky, Ahron Cervania, and Curtis A. Deutsch
Biogeosciences, 21, 747–759, https://doi.org/10.5194/bg-21-747-2024, https://doi.org/10.5194/bg-21-747-2024, 2024
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This study aims to estimate how much oceanic oxygen has been lost and its uncertainties. One major source of uncertainty comes from the statistical gap-filling methods. Outputs from Earth system models are used to generate synthetic observations where oxygen data are extracted from the model output at the location and time of historical oceanographic cruises. Reconstructed oxygen trend is approximately two-thirds of the true trend.
Robert W. Izett, Katja Fennel, Adam C. Stoer, and David P. Nicholson
Biogeosciences, 21, 13–47, https://doi.org/10.5194/bg-21-13-2024, https://doi.org/10.5194/bg-21-13-2024, 2024
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This paper provides an overview of the capacity to expand the global coverage of marine primary production estimates using autonomous ocean-going instruments, called Biogeochemical-Argo floats. We review existing approaches to quantifying primary production using floats, provide examples of the current implementation of the methods, and offer insights into how they can be better exploited. This paper is timely, given the ongoing expansion of the Biogeochemical-Argo array.
Qian Liu, Yingjie Liu, and Xiaofeng Li
Biogeosciences, 20, 4857–4874, https://doi.org/10.5194/bg-20-4857-2023, https://doi.org/10.5194/bg-20-4857-2023, 2023
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In the Southern Ocean, abundant eddies behave opposite to our expectations. That is, anticyclonic (cyclonic) eddies are cold (warm). By investigating the variations of physical and biochemical parameters in eddies, we find that abnormal eddies have unique and significant effects on modulating the parameters. This study fills a gap in understanding the effects of abnormal eddies on physical and biochemical parameters in the Southern Ocean.
Caroline Ulses, Claude Estournel, Patrick Marsaleix, Karline Soetaert, Marine Fourrier, Laurent Coppola, Dominique Lefèvre, Franck Touratier, Catherine Goyet, Véronique Guglielmi, Fayçal Kessouri, Pierre Testor, and Xavier Durrieu de Madron
Biogeosciences, 20, 4683–4710, https://doi.org/10.5194/bg-20-4683-2023, https://doi.org/10.5194/bg-20-4683-2023, 2023
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Deep convection plays a key role in the circulation, thermodynamics, and biogeochemical cycles in the Mediterranean Sea, considered to be a hotspot of biodiversity and climate change. In this study, we investigate the seasonal and annual budget of dissolved inorganic carbon in the deep-convection area of the northwestern Mediterranean Sea.
Daniela König and Alessandro Tagliabue
Biogeosciences, 20, 4197–4212, https://doi.org/10.5194/bg-20-4197-2023, https://doi.org/10.5194/bg-20-4197-2023, 2023
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Using model simulations, we show that natural and anthropogenic changes in the global climate leave a distinct fingerprint in the isotopic signatures of iron in the surface ocean. We find that these climate effects on iron isotopes are often caused by the redistribution of iron from different external sources to the ocean, due to changes in ocean currents, and by changes in algal growth, which take up iron. Thus, isotopes may help detect climate-induced changes in iron supply and algal uptake.
Chloé Baumas, Robin Fuchs, Marc Garel, Jean-Christophe Poggiale, Laurent Memery, Frédéric A. C. Le Moigne, and Christian Tamburini
Biogeosciences, 20, 4165–4182, https://doi.org/10.5194/bg-20-4165-2023, https://doi.org/10.5194/bg-20-4165-2023, 2023
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Through the sink of particles in the ocean, carbon (C) is exported and sequestered when reaching 1000 m. Attempts to quantify C exported vs. C consumed by heterotrophs have increased. Yet most of the conducted estimations have led to C demands several times higher than C export. The choice of parameters greatly impacts the results. As theses parameters are overlooked, non-accurate values are often used. In this study we show that C budgets can be well balanced when using appropriate values.
Anna Belcher, Sian F. Henley, Katharine Hendry, Marianne Wootton, Lisa Friberg, Ursula Dallman, Tong Wang, Christopher Coath, and Clara Manno
Biogeosciences, 20, 3573–3591, https://doi.org/10.5194/bg-20-3573-2023, https://doi.org/10.5194/bg-20-3573-2023, 2023
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The oceans play a crucial role in the uptake of atmospheric carbon dioxide, particularly the Southern Ocean. The biological pumping of carbon from the surface to the deep ocean is key to this. Using sediment trap samples from the Scotia Sea, we examine biogeochemical fluxes of carbon, nitrogen, and biogenic silica and their stable isotope compositions. We find phytoplankton community structure and physically mediated processes are important controls on particulate fluxes to the deep ocean.
Asmita Singh, Susanne Fietz, Sandy J. Thomalla, Nicolas Sanchez, Murat V. Ardelan, Sébastien Moreau, Hanna M. Kauko, Agneta Fransson, Melissa Chierici, Saumik Samanta, Thato N. Mtshali, Alakendra N. Roychoudhury, and Thomas J. Ryan-Keogh
Biogeosciences, 20, 3073–3091, https://doi.org/10.5194/bg-20-3073-2023, https://doi.org/10.5194/bg-20-3073-2023, 2023
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Despite the scarcity of iron in the Southern Ocean, seasonal blooms occur due to changes in nutrient and light availability. Surprisingly, during an autumn bloom in the Antarctic sea-ice zone, the results from incubation experiments showed no significant photophysiological response of phytoplankton to iron addition. This suggests that ambient iron concentrations were sufficient, challenging the notion of iron deficiency in the Southern Ocean through extended iron-replete post-bloom conditions.
Benoît Pasquier, Mark Holzer, Matthew A. Chamberlain, Richard J. Matear, Nathaniel L. Bindoff, and François W. Primeau
Biogeosciences, 20, 2985–3009, https://doi.org/10.5194/bg-20-2985-2023, https://doi.org/10.5194/bg-20-2985-2023, 2023
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Modeling the ocean's carbon and oxygen cycles accurately is challenging. Parameter optimization improves the fit to observed tracers but can introduce artifacts in the biological pump. Organic-matter production and subsurface remineralization rates adjust to compensate for circulation biases, changing the pathways and timescales with which nutrients return to the surface. Circulation biases can thus strongly alter the system’s response to ecological change, even when parameters are optimized.
Priyanka Banerjee
Biogeosciences, 20, 2613–2643, https://doi.org/10.5194/bg-20-2613-2023, https://doi.org/10.5194/bg-20-2613-2023, 2023
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This study shows that atmospheric deposition is the most important source of iron to the upper northern Indian Ocean for phytoplankton growth. This is followed by iron from continental-shelf sediment. Phytoplankton increase following iron addition is possible only with high background levels of nitrate. Vertical mixing is the most important physical process supplying iron to the upper ocean in this region throughout the year. The importance of ocean currents in supplying iron varies seasonally.
Iris Kriest, Julia Getzlaff, Angela Landolfi, Volkmar Sauerland, Markus Schartau, and Andreas Oschlies
Biogeosciences, 20, 2645–2669, https://doi.org/10.5194/bg-20-2645-2023, https://doi.org/10.5194/bg-20-2645-2023, 2023
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Global biogeochemical ocean models are often subjectively assessed and tuned against observations. We applied different strategies to calibrate a global model against observations. Although the calibrated models show similar tracer distributions at the surface, they differ in global biogeochemical fluxes, especially in global particle flux. Simulated global volume of oxygen minimum zones varies strongly with calibration strategy and over time, rendering its temporal extrapolation difficult.
John C. Tracey, Andrew R. Babbin, Elizabeth Wallace, Xin Sun, Katherine L. DuRussel, Claudia Frey, Donald E. Martocello III, Tyler Tamasi, Sergey Oleynik, and Bess B. Ward
Biogeosciences, 20, 2499–2523, https://doi.org/10.5194/bg-20-2499-2023, https://doi.org/10.5194/bg-20-2499-2023, 2023
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Nitrogen (N) is essential for life; thus, its availability plays a key role in determining marine productivity. Using incubations of seawater spiked with a rare form of N measurable on a mass spectrometer, we quantified microbial pathways that determine marine N availability. The results show that pathways that recycle N have higher rates than those that result in its loss from biomass and present new evidence for anaerobic nitrite oxidation, a process long thought to be strictly aerobic.
Amanda Gerotto, Hongrui Zhang, Renata Hanae Nagai, Heather M. Stoll, Rubens César Lopes Figueira, Chuanlian Liu, and Iván Hernández-Almeida
Biogeosciences, 20, 1725–1739, https://doi.org/10.5194/bg-20-1725-2023, https://doi.org/10.5194/bg-20-1725-2023, 2023
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Based on the analysis of the response of coccolithophores’ morphological attributes in a laboratory dissolution experiment and surface sediment samples from the South China Sea, we proposed that the thickness shape (ks) factor of fossil coccoliths together with the normalized ks variation, which is the ratio of the standard deviation of ks (σ) over the mean ks (σ/ks), is a robust and novel proxy to reconstruct past changes in deep ocean carbon chemistry.
Katherine E. Turner, Doug M. Smith, Anna Katavouta, and Richard G. Williams
Biogeosciences, 20, 1671–1690, https://doi.org/10.5194/bg-20-1671-2023, https://doi.org/10.5194/bg-20-1671-2023, 2023
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We present a new method for reconstructing ocean carbon using climate models and temperature and salinity observations. To test this method, we reconstruct modelled carbon using synthetic observations consistent with current sampling programmes. Sensitivity tests show skill in reconstructing carbon trends and variability within the upper 2000 m. Our results indicate that this method can be used for a new global estimate for ocean carbon content.
Alexandre Mignot, Hervé Claustre, Gianpiero Cossarini, Fabrizio D'Ortenzio, Elodie Gutknecht, Julien Lamouroux, Paolo Lazzari, Coralie Perruche, Stefano Salon, Raphaëlle Sauzède, Vincent Taillandier, and Anna Teruzzi
Biogeosciences, 20, 1405–1422, https://doi.org/10.5194/bg-20-1405-2023, https://doi.org/10.5194/bg-20-1405-2023, 2023
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Numerical models of ocean biogeochemistry are becoming a major tool to detect and predict the impact of climate change on marine resources and monitor ocean health. Here, we demonstrate the use of the global array of BGC-Argo floats for the assessment of biogeochemical models. We first detail the handling of the BGC-Argo data set for model assessment purposes. We then present 23 assessment metrics to quantify the consistency of BGC model simulations with respect to BGC-Argo data.
Alban Planchat, Lester Kwiatkowski, Laurent Bopp, Olivier Torres, James R. Christian, Momme Butenschön, Tomas Lovato, Roland Séférian, Matthew A. Chamberlain, Olivier Aumont, Michio Watanabe, Akitomo Yamamoto, Andrew Yool, Tatiana Ilyina, Hiroyuki Tsujino, Kristen M. Krumhardt, Jörg Schwinger, Jerry Tjiputra, John P. Dunne, and Charles Stock
Biogeosciences, 20, 1195–1257, https://doi.org/10.5194/bg-20-1195-2023, https://doi.org/10.5194/bg-20-1195-2023, 2023
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Ocean alkalinity is critical to the uptake of atmospheric carbon and acidification in surface waters. We review the representation of alkalinity and the associated calcium carbonate cycle in Earth system models. While many parameterizations remain present in the latest generation of models, there is a general improvement in the simulated alkalinity distribution. This improvement is related to an increase in the export of biotic calcium carbonate, which closer resembles observations.
Jérôme Pinti, Tim DeVries, Tommy Norin, Camila Serra-Pompei, Roland Proud, David A. Siegel, Thomas Kiørboe, Colleen M. Petrik, Ken H. Andersen, Andrew S. Brierley, and André W. Visser
Biogeosciences, 20, 997–1009, https://doi.org/10.5194/bg-20-997-2023, https://doi.org/10.5194/bg-20-997-2023, 2023
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Large numbers of marine organisms such as zooplankton and fish perform daily vertical migration between the surface (at night) and the depths (in the daytime). This fascinating migration is important for the carbon cycle, as these organisms actively bring carbon to depths where it is stored away from the atmosphere for a long time. Here, we quantify the contributions of different animals to this carbon drawdown and storage and show that fish are important to the biological carbon pump.
Alastair J. M. Lough, Alessandro Tagliabue, Clément Demasy, Joseph A. Resing, Travis Mellett, Neil J. Wyatt, and Maeve C. Lohan
Biogeosciences, 20, 405–420, https://doi.org/10.5194/bg-20-405-2023, https://doi.org/10.5194/bg-20-405-2023, 2023
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Iron is a key nutrient for ocean primary productivity. Hydrothermal vents are a source of iron to the oceans, but the size of this source is poorly understood. This study examines the variability in iron inputs between hydrothermal vents in different geological settings. The vents studied release different amounts of Fe, resulting in plumes with similar dissolved iron concentrations but different particulate concentrations. This will help to refine modelling of iron-limited ocean productivity.
Nicole M. Travis, Colette L. Kelly, Margaret R. Mulholland, and Karen L. Casciotti
Biogeosciences, 20, 325–347, https://doi.org/10.5194/bg-20-325-2023, https://doi.org/10.5194/bg-20-325-2023, 2023
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The primary nitrite maximum is a ubiquitous upper ocean feature where nitrite accumulates, but we still do not understand its formation and the co-occurring microbial processes involved. Using correlative methods and rates measurements, we found strong spatial patterns between environmental conditions and depths of the nitrite maxima, but not the maximum concentrations. Nitrification was the dominant source of nitrite, with occasional high nitrite production from phytoplankton near the coast.
Natacha Le Grix, Jakob Zscheischler, Keith B. Rodgers, Ryohei Yamaguchi, and Thomas L. Frölicher
Biogeosciences, 19, 5807–5835, https://doi.org/10.5194/bg-19-5807-2022, https://doi.org/10.5194/bg-19-5807-2022, 2022
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Compound events threaten marine ecosystems. Here, we investigate the potentially harmful combination of marine heatwaves with low phytoplankton productivity. Using satellite-based observations, we show that these compound events are frequent in the low latitudes. We then investigate the drivers of these compound events using Earth system models. The models share similar drivers in the low latitudes but disagree in the high latitudes due to divergent factors limiting phytoplankton production.
Abigale M. Wyatt, Laure Resplandy, and Adrian Marchetti
Biogeosciences, 19, 5689–5705, https://doi.org/10.5194/bg-19-5689-2022, https://doi.org/10.5194/bg-19-5689-2022, 2022
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Marine heat waves (MHWs) are a frequent event in the northeast Pacific, with a large impact on the region's ecosystems. Large phytoplankton in the North Pacific Transition Zone are greatly affected by decreased nutrients, with less of an impact in the Alaskan Gyre. For small phytoplankton, MHWs increase the spring small phytoplankton population in both regions thanks to reduced light limitation. In both zones, this results in a significant decrease in the ratio of large to small phytoplankton.
Margot C. F. Debyser, Laetitia Pichevin, Robyn E. Tuerena, Paul A. Dodd, Antonia Doncila, and Raja S. Ganeshram
Biogeosciences, 19, 5499–5520, https://doi.org/10.5194/bg-19-5499-2022, https://doi.org/10.5194/bg-19-5499-2022, 2022
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We focus on the exchange of key nutrients for algae production between the Arctic and Atlantic oceans through the Fram Strait. We show that the export of dissolved silicon here is controlled by the availability of nitrate which is influenced by denitrification on Arctic shelves. We suggest that any future changes in the river inputs of silica and changes in denitrification due to climate change will impact the amount of silicon exported, with impacts on Atlantic algal productivity and ecology.
Emily J. Zakem, Barbara Bayer, Wei Qin, Alyson E. Santoro, Yao Zhang, and Naomi M. Levine
Biogeosciences, 19, 5401–5418, https://doi.org/10.5194/bg-19-5401-2022, https://doi.org/10.5194/bg-19-5401-2022, 2022
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We use a microbial ecosystem model to quantitatively explain the mechanisms controlling observed relative abundances and nitrification rates of ammonia- and nitrite-oxidizing microorganisms in the ocean. We also estimate how much global carbon fixation can be associated with chemoautotrophic nitrification. Our results improve our understanding of the controls on nitrification, laying the groundwork for more accurate predictions in global climate models.
Zuozhu Wen, Thomas J. Browning, Rongbo Dai, Wenwei Wu, Weiying Li, Xiaohua Hu, Wenfang Lin, Lifang Wang, Xin Liu, Zhimian Cao, Haizheng Hong, and Dalin Shi
Biogeosciences, 19, 5237–5250, https://doi.org/10.5194/bg-19-5237-2022, https://doi.org/10.5194/bg-19-5237-2022, 2022
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Fe and P are key factors controlling the biogeography and activity of marine N2-fixing microorganisms. We found lower abundance and activity of N2 fixers in the northern South China Sea than around the western boundary of the North Pacific, and N2 fixation rates switched from Fe–P co-limitation to P limitation. We hypothesize the Fe supply rates and Fe utilization strategies of each N2 fixer are important in regulating spatial variability in community structure across the study area.
Claudia Eisenring, Sophy E. Oliver, Samar Khatiwala, and Gregory F. de Souza
Biogeosciences, 19, 5079–5106, https://doi.org/10.5194/bg-19-5079-2022, https://doi.org/10.5194/bg-19-5079-2022, 2022
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Given the sparsity of observational constraints on micronutrients such as zinc (Zn), we assess the sensitivities of a framework for objective parameter optimisation in an oceanic Zn cycling model. Our ensemble of optimisations towards synthetic data with varying kinds of uncertainty shows that deficiencies related to model complexity and the choice of the misfit function generally have a greater impact on the retrieval of model Zn uptake behaviour than does the limitation of data coverage.
Yoshikazu Sasai, Sherwood Lan Smith, Eko Siswanto, Hideharu Sasaki, and Masami Nonaka
Biogeosciences, 19, 4865–4882, https://doi.org/10.5194/bg-19-4865-2022, https://doi.org/10.5194/bg-19-4865-2022, 2022
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We have investigated the adaptive response of phytoplankton growth to changing light, nutrients, and temperature over the North Pacific using two physical-biological models. We compare modeled chlorophyll and primary production from an inflexible control model (InFlexPFT), which assumes fixed carbon (C):nitrogen (N):chlorophyll (Chl) ratios, to a recently developed flexible phytoplankton functional type model (FlexPFT), which incorporates photoacclimation and variable C:N:Chl ratios.
Jens Terhaar, Thomas L. Frölicher, and Fortunat Joos
Biogeosciences, 19, 4431–4457, https://doi.org/10.5194/bg-19-4431-2022, https://doi.org/10.5194/bg-19-4431-2022, 2022
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Estimates of the ocean sink of anthropogenic carbon vary across various approaches. We show that the global ocean carbon sink can be estimated by three parameters, two of which approximate the ocean ventilation in the Southern Ocean and the North Atlantic, and one of which approximates the chemical capacity of the ocean to take up carbon. With observations of these parameters, we estimate that the global ocean carbon sink is 10 % larger than previously assumed, and we cut uncertainties in half.
Natasha René van Horsten, Hélène Planquette, Géraldine Sarthou, Thomas James Ryan-Keogh, Nolwenn Lemaitre, Thato Nicholas Mtshali, Alakendra Roychoudhury, and Eva Bucciarelli
Biogeosciences, 19, 3209–3224, https://doi.org/10.5194/bg-19-3209-2022, https://doi.org/10.5194/bg-19-3209-2022, 2022
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The remineralisation proxy, barite, was measured along 30°E in the southern Indian Ocean during early austral winter. To our knowledge this is the first reported Southern Ocean winter study. Concentrations throughout the water column were comparable to observations during spring to autumn. By linking satellite primary production to this proxy a possible annual timescale is proposed. These findings also suggest possible carbon remineralisation from satellite data on a basin scale.
Zhibo Shao and Ya-Wei Luo
Biogeosciences, 19, 2939–2952, https://doi.org/10.5194/bg-19-2939-2022, https://doi.org/10.5194/bg-19-2939-2022, 2022
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Non-cyanobacterial diazotrophs (NCDs) may be an important player in fixing N2 in the ocean. By conducting meta-analyses, we found that a representative marine NCD phylotype, Gamma A, tends to inhabit ocean environments with high productivity, low iron concentration and high light intensity. It also appears to be more abundant inside cyclonic eddies. Our study suggests a niche differentiation of NCDs from cyanobacterial diazotrophs as the latter prefers low-productivity and high-iron oceans.
Coraline Leseurre, Claire Lo Monaco, Gilles Reverdin, Nicolas Metzl, Jonathan Fin, Claude Mignon, and Léa Benito
Biogeosciences, 19, 2599–2625, https://doi.org/10.5194/bg-19-2599-2022, https://doi.org/10.5194/bg-19-2599-2022, 2022
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Decadal trends of fugacity of CO2 (fCO2), total alkalinity (AT), total carbon (CT) and pH in surface waters are investigated in different domains of the southern Indian Ocean (45°S–57°S) from ongoing and station observations regularly conducted in summer over the period 1998–2019. The fCO2 increase and pH decrease are mainly driven by anthropogenic CO2 estimated just below the summer mixed layer, as well as by a warming south of the polar front or in the fertilized waters near Kerguelen Island.
Priscilla Le Mézo, Jérôme Guiet, Kim Scherrer, Daniele Bianchi, and Eric Galbraith
Biogeosciences, 19, 2537–2555, https://doi.org/10.5194/bg-19-2537-2022, https://doi.org/10.5194/bg-19-2537-2022, 2022
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This study quantifies the role of commercially targeted fish biomass in the cycling of three important nutrients (N, P, and Fe), relative to nutrients otherwise available in water and to nutrients required by primary producers, and the impact of fishing. We use a model of commercially targeted fish biomass constrained by fish catch and stock assessment data to assess the contributions of fish at the global scale, at the time of the global peak catch and prior to industrial fishing.
Rebecca Chmiel, Nathan Lanning, Allison Laubach, Jong-Mi Lee, Jessica Fitzsimmons, Mariko Hatta, William Jenkins, Phoebe Lam, Matthew McIlvin, Alessandro Tagliabue, and Mak Saito
Biogeosciences, 19, 2365–2395, https://doi.org/10.5194/bg-19-2365-2022, https://doi.org/10.5194/bg-19-2365-2022, 2022
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Dissolved cobalt is present in trace amounts in seawater and is a necessary nutrient for marine microbes. On a transect from the Alaskan coast to Tahiti, we measured seawater concentrations of dissolved cobalt. Here, we describe several interesting features of the Pacific cobalt cycle including cobalt sources along the Alaskan coast and Hawaiian vents, deep-ocean particle formation, cobalt activity in low-oxygen regions, and how our samples compare to a global biogeochemical model’s predictions.
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Short summary
The marine CO2 system can be measured independently and continuously by BGC-Argo floats since numerous pH sensors have been developed to suit these autonomous measurements platforms. By applying the Argo correction routines to float pH data acquired in the subpolar North Atlantic Ocean, we report the uncertainty and lack of objective criteria associated with the choice of the reference method as well the reference depth for the pH correction.
The marine CO2 system can be measured independently and continuously by BGC-Argo floats since...
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