Articles | Volume 20, issue 16
https://doi.org/10.5194/bg-20-3459-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/bg-20-3459-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway
Institute of Carbon Cycles, Helmholtz-Zentrum Hereon, 21502 Geesthacht, Germany
Section Permafrost Research, Alfred Wegener Institute Helmholtz Centre for Polar and Marine
Research, 14473 Potsdam, Germany
Institute for Chemistry and Biology of the Marine Environment (ICBM),
University of Oldenburg, 26129 Oldenburg, Germany
Hugues Lantuit
Section Permafrost Research, Alfred Wegener Institute Helmholtz Centre for Polar and Marine
Research, 14473 Potsdam, Germany
Institute for Geosciences, University of Potsdam, 14476 Potsdam,
Germany
Michael Ernst Böttcher
Geochemistry and Isotope Biogeochemistry, Leibniz Institute for Baltic
Sea Research (IOW), 18119 Warnemünde, Germany
Marine Geochemistry, University of Greifswald, 17489 Greifswald,
Germany
Interdisciplinary Faculty, University of Rostock, 18059 Rostock,
Germany
Jens Hartmann
Institute for Geology, Center for Earth System Research and
Sustainability, University of Hamburg, 20146 Hamburg, Germany
Antje Eulenburg
Section Permafrost Research, Alfred Wegener Institute Helmholtz Centre for Polar and Marine
Research, 14473 Potsdam, Germany
Institute of Carbon Cycles, Helmholtz-Zentrum Hereon, 21502 Geesthacht, Germany
Institute for Chemistry and Biology of the Marine Environment (ICBM),
University of Oldenburg, 26129 Oldenburg, Germany
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Cordula Nina Gutekunst, Susanne Liebner, Anna-Kathrina Jenner, Klaus-Holger Knorr, Viktoria Unger, Franziska Koebsch, Erwin Don Racasa, Sizhong Yang, Michael Ernst Böttcher, Manon Janssen, Jens Kallmeyer, Denise Otto, Iris Schmiedinger, Lucas Winski, and Gerald Jurasinski
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Niek Jesse Speetjens, George Tanski, Victoria Martin, Julia Wagner, Andreas Richter, Gustaf Hugelius, Chris Boucher, Rachele Lodi, Christian Knoblauch, Boris P. Koch, Urban Wünsch, Hugues Lantuit, and Jorien E. Vonk
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Biogeosciences, 17, 2107–2133, https://doi.org/10.5194/bg-17-2107-2020, https://doi.org/10.5194/bg-17-2107-2020, 2020
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Thorben Amann, Jens Hartmann, Eric Struyf, Wagner de Oliveira Garcia, Elke K. Fischer, Ivan Janssens, Patrick Meire, and Jonas Schoelynck
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Weathering is a major control on atmospheric CO2 at geologic timescales. Enhancement of this process can be used to actively remove CO2 from the atmosphere. Field results are still scarce and with this experiment we try to add some near-natural insights into dissolution processes. Results show CO2 sequestration potentials but also highlight the strong variability of outcomes that can be expected in natural environments. Such experiments are of the utmost importance to identify key processes.
Fabrice Lacroix, Tatiana Ilyina, and Jens Hartmann
Biogeosciences, 17, 55–88, https://doi.org/10.5194/bg-17-55-2020, https://doi.org/10.5194/bg-17-55-2020, 2020
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Contributions of rivers to the oceanic cycling of carbon have been poorly represented in global models until now. Here, we assess the long–term implications of preindustrial riverine loads in the ocean in a novel framework which estimates the loads through a hierarchy of weathering and land–ocean export models. We investigate their impacts for the oceanic biological production and air–sea carbon flux. Finally, we assess the potential incorporation of the framework in an Earth system model.
Caroline Coch, Bennet Juhls, Scott F. Lamoureux, Melissa J. Lafrenière, Michael Fritz, Birgit Heim, and Hugues Lantuit
Biogeosciences, 16, 4535–4553, https://doi.org/10.5194/bg-16-4535-2019, https://doi.org/10.5194/bg-16-4535-2019, 2019
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Climate change affects Arctic ecosystems. This includes thawing of permafrost (ground below 0 °C) and an increase in rainfall. Both have substantial impacts on the chemical composition of river water. We compared the composition of small rivers in the low and high Arctic with the large Arctic rivers. In comparison, dissolved organic matter in the small rivers is more susceptible to degradation; thus, it could potentially increase carbon dioxide emissions. Rainfall events have a similar effect.
Thorben Amann and Jens Hartmann
Biogeosciences, 16, 2949–2960, https://doi.org/10.5194/bg-16-2949-2019, https://doi.org/10.5194/bg-16-2949-2019, 2019
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Andrew M. Cunliffe, George Tanski, Boris Radosavljevic, William F. Palmer, Torsten Sachs, Hugues Lantuit, Jeffrey T. Kerby, and Isla H. Myers-Smith
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Episodic changes of permafrost coastlines are poorly understood in the Arctic. By using drones, satellite images, and historic photos we surveyed a permafrost coastline on Qikiqtaruk – Herschel Island. We observed short-term coastline retreat of 14.5 m per year (2016–2017), exceeding long-term average rates of 2.2 m per year (1952–2017). Our study highlights the value of these tools to assess understudied episodic changes of eroding permafrost coastlines in the context of a warming Arctic.
Franziska Koebsch, Matthias Winkel, Susanne Liebner, Bo Liu, Julia Westphal, Iris Schmiedinger, Alejandro Spitzy, Matthias Gehre, Gerald Jurasinski, Stefan Köhler, Viktoria Unger, Marian Koch, Torsten Sachs, and Michael E. Böttcher
Biogeosciences, 16, 1937–1953, https://doi.org/10.5194/bg-16-1937-2019, https://doi.org/10.5194/bg-16-1937-2019, 2019
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In natural coastal wetlands, high supplies of marine sulfate suppress methane production. We found these natural methane suppression mechanisms to be suspended by humane interference in a brackish wetland. Here, diking and freshwater rewetting had caused an efficient depletion of the sulfate reservoir and opened up favorable conditions for an intensive methane production. Our results demonstrate how human disturbance can turn coastal wetlands into distinct sources of the greenhouse gas methane.
Janine Börker, Jens Hartmann, Gibran Romero-Mujalli, and Gaojun Li
Earth Surf. Dynam., 7, 191–197, https://doi.org/10.5194/esurf-7-191-2019, https://doi.org/10.5194/esurf-7-191-2019, 2019
Rachel M. Horwitz, Alex E. Hay, William J. Burt, Richard A. Cheel, Joseph Salisbury, and Helmuth Thomas
Biogeosciences, 16, 605–616, https://doi.org/10.5194/bg-16-605-2019, https://doi.org/10.5194/bg-16-605-2019, 2019
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High-frequency CO2 measurements are used to quantify the daily and tidal cycles of dissolved carbon in the Bay of Fundy – home to the world's largest tides. The oscillating tidal flows drive a net carbon transport, and these results suggest that previously unaccounted for tidal variation could substantially modulate the coastal ocean's response to global ocean acidification. Evaluating the impact of rising atmospheric CO2 on coastal systems requires understanding this short-term variability.
Hagen Radtke, Marko Lipka, Dennis Bunke, Claudia Morys, Jana Woelfel, Bronwyn Cahill, Michael E. Böttcher, Stefan Forster, Thomas Leipe, Gregor Rehder, and Thomas Neumann
Geosci. Model Dev., 12, 275–320, https://doi.org/10.5194/gmd-12-275-2019, https://doi.org/10.5194/gmd-12-275-2019, 2019
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This paper describes a coupled benthic–pelagic biogeochemical model, ERGOM-SED. We demonstrate its use in a one-dimensional physical model, which is horizontally integrated and vertically resolved. We describe the application of the model to seven stations in the south-western Baltic Sea. The model was calibrated using pore water profiles from these stations. We compare the model results to these and to measured sediment compositions, benthopelagic fluxes and bioturbation intensities.
Xi Wen, Viktoria Unger, Gerald Jurasinski, Franziska Koebsch, Fabian Horn, Gregor Rehder, Torsten Sachs, Dominik Zak, Gunnar Lischeid, Klaus-Holger Knorr, Michael E. Böttcher, Matthias Winkel, Paul L. E. Bodelier, and Susanne Liebner
Biogeosciences, 15, 6519–6536, https://doi.org/10.5194/bg-15-6519-2018, https://doi.org/10.5194/bg-15-6519-2018, 2018
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Rewetting drained peatlands may lead to prolonged emission of the greenhouse gas methane, but the underlying factors are not well described. In this study, we found two rewetted fens with known high methane fluxes had a high ratio of microbial methane producers to methane consumers and a low abundance of methane consumers compared to pristine wetlands. We therefore suggest abundances of methane-cycling microbes as potential indicators for prolonged high methane emissions in rewetted peatlands.
Yilong Wang, Philippe Ciais, Daniel Goll, Yuanyuan Huang, Yiqi Luo, Ying-Ping Wang, A. Anthony Bloom, Grégoire Broquet, Jens Hartmann, Shushi Peng, Josep Penuelas, Shilong Piao, Jordi Sardans, Benjamin D. Stocker, Rong Wang, Sönke Zaehle, and Sophie Zechmeister-Boltenstern
Geosci. Model Dev., 11, 3903–3928, https://doi.org/10.5194/gmd-11-3903-2018, https://doi.org/10.5194/gmd-11-3903-2018, 2018
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We present a new modeling framework called Global Observation-based Land-ecosystems Utilization Model of Carbon, Nitrogen and Phosphorus (GOLUM-CNP) that combines a data-constrained C-cycle analysis with data-driven estimates of N and P inputs and losses and with observed stoichiometric ratios. GOLUM-CNP provides a traceable tool, where a consistency between different datasets of global C, N, and P cycles has been achieved.
Ji-Hyung Park, Omme K. Nayna, Most S. Begum, Eliyan Chea, Jens Hartmann, Richard G. Keil, Sanjeev Kumar, Xixi Lu, Lishan Ran, Jeffrey E. Richey, Vedula V. S. S. Sarma, Shafi M. Tareq, Do Thi Xuan, and Ruihong Yu
Biogeosciences, 15, 3049–3069, https://doi.org/10.5194/bg-15-3049-2018, https://doi.org/10.5194/bg-15-3049-2018, 2018
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Human activities are drastically altering water and material flows in river systems across Asia. This review provides a conceptual framework for assessing the human impacts on Asian river C fluxes and an update on anthropogenic alterations of riverine C fluxes, focusing on the impacts of water pollution and river impoundments on CO2 outgassing from the rivers draining South, Southeast, and East Asian regions that account for the largest fraction of river discharge and C exports from Asia.
Jonathan Lemay, Helmuth Thomas, Susanne E. Craig, William J. Burt, Katja Fennel, and Blair J. W. Greenan
Biogeosciences, 15, 2111–2123, https://doi.org/10.5194/bg-15-2111-2018, https://doi.org/10.5194/bg-15-2111-2018, 2018
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We report a detailed mechanistic investigation of the impact of Hurricane Arthur on the CO2 cycling on the Scotian Shelf. We can show that in contrast to common thinking, the deepening of the surface during the summer months can lead to increased CO2 uptake as carbon-poor waters from subsurface water are brought up to the surface. Only during prolonged storm events is the deepening of the mixed layer strong enough to bring the (expected) carbon-rich water to the surface.
Justine L. Ramage, Anna M. Irrgang, Anne Morgenstern, and Hugues Lantuit
Biogeosciences, 15, 1483–1495, https://doi.org/10.5194/bg-15-1483-2018, https://doi.org/10.5194/bg-15-1483-2018, 2018
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We describe the evolution of thaw slumps between 1952 and 2011 along the Yukon Coast, Canada, and calculate the contribution of the slumps to the carbon budget in this area. The number of slumps has increased by 73 % over the period. These slumps displaced more than 16 billion m3 of material and mobilized 146 t of carbon. This represents 0.6 % of the annual carbon flux released from shoreline retreat, which shows that the contribution of slumps to the nearshore carbon budget is non-negligible.
Sha Ni, Isabelle Taubner, Florian Böhm, Vera Winde, and Michael E. Böttcher
Biogeosciences, 15, 1425–1445, https://doi.org/10.5194/bg-15-1425-2018, https://doi.org/10.5194/bg-15-1425-2018, 2018
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Spirorbis tube worms are common epibionts on brown algae in the Baltic Sea. We made experiments with Spirorbis in the
Kiel Outdoor Benthocosmsat CO2 and temperature conditions predicted for the year 2100. The worms were able to grow tubes even at CO2 levels favouring shell dissolution but did not survive at mean temperatures over 24° C. This indicates that Spirorbis worms will suffer from future excessive ocean warming and from ocean acidification fostering corrosion of their protective tubes.
Jacoba Mol, Helmuth Thomas, Paul G. Myers, Xianmin Hu, and Alfonso Mucci
Biogeosciences, 15, 1011–1027, https://doi.org/10.5194/bg-15-1011-2018, https://doi.org/10.5194/bg-15-1011-2018, 2018
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In the fall of 2014, the upwelling of water from the deep Canada Basin brought water onto the shallower Mackenzie Shelf in the Beaufort Sea. This increased the concentration of CO2 in water on the shelf, which alters pH and changes the transfer of CO2 between the ocean and atmosphere. These findings were a combined result of water sampling for CO2 parameters and the use of a computer model that simulates water movement in the ocean.
Jakob Zscheischler, Miguel D. Mahecha, Valerio Avitabile, Leonardo Calle, Nuno Carvalhais, Philippe Ciais, Fabian Gans, Nicolas Gruber, Jens Hartmann, Martin Herold, Kazuhito Ichii, Martin Jung, Peter Landschützer, Goulven G. Laruelle, Ronny Lauerwald, Dario Papale, Philippe Peylin, Benjamin Poulter, Deepak Ray, Pierre Regnier, Christian Rödenbeck, Rosa M. Roman-Cuesta, Christopher Schwalm, Gianluca Tramontana, Alexandra Tyukavina, Riccardo Valentini, Guido van der Werf, Tristram O. West, Julie E. Wolf, and Markus Reichstein
Biogeosciences, 14, 3685–3703, https://doi.org/10.5194/bg-14-3685-2017, https://doi.org/10.5194/bg-14-3685-2017, 2017
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Here we synthesize a wide range of global spatiotemporal observational data on carbon exchanges between the Earth surface and the atmosphere. A key challenge was to consistently combining observational products of terrestrial and aquatic surfaces. Our primary goal is to identify today’s key uncertainties and observational shortcomings that would need to be addressed in future measurement campaigns or expansions of in situ observatories.
Rachel Hussherr, Maurice Levasseur, Martine Lizotte, Jean-Éric Tremblay, Jacoba Mol, Helmuth Thomas, Michel Gosselin, Michel Starr, Lisa A. Miller, Tereza Jarniková, Nina Schuback, and Alfonso Mucci
Biogeosciences, 14, 2407–2427, https://doi.org/10.5194/bg-14-2407-2017, https://doi.org/10.5194/bg-14-2407-2017, 2017
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This study assesses the impact of ocean acidification on phytoplankton and its synthesis of the climate-active gas dimethyl sulfide (DMS), as well as its modulation, by two contrasting light regimes in the Arctic. The light regimes tested had no significant impact on either the phytoplankton or DMS concentration, whereas both variables decreased linearly with the decrease in pH. Thus, a rapid decrease in surface water pH could alter the algal biomass and inhibit DMS production in the Arctic.
William J. Burt, Helmuth Thomas, Lisa A. Miller, Mats A. Granskog, Tim N. Papakyriakou, and Leah Pengelly
Biogeosciences, 13, 4659–4671, https://doi.org/10.5194/bg-13-4659-2016, https://doi.org/10.5194/bg-13-4659-2016, 2016
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This study assesses the state of the carbon cycle in Hudson Bay, an ecologically important region of the Canadian Arctic. Results show that river input, sea-ice melt, biological activity, and general circulation patterns all have significant, and regionally dependent, impacts on the carbon cycle. The study also highlights the importance of detailed sampling procedures in highly stratified waters, and reveals that the deep Hudson Bay is primarily filled with waters of Pacific origin.
Fabian Große, Naomi Greenwood, Markus Kreus, Hermann-Josef Lenhart, Detlev Machoczek, Johannes Pätsch, Lesley Salt, and Helmuth Thomas
Biogeosciences, 13, 2511–2535, https://doi.org/10.5194/bg-13-2511-2016, https://doi.org/10.5194/bg-13-2511-2016, 2016
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We used the ECOHAM5 model to provide a consistent picture of the physical and biological drivers of oxygen deficiency in the North Sea. Regions susceptible to oxygen deficiency are characterised by low tidal mixing and moderate water depth (~ 40 m). Variations in upper layer productivity drive the year-to-year variability of bottom oxygen conditions. The model-based analysis reveals that benthic and pelagic remineralisation account for 90 % of bottom oxygen consumption observed at North Dogger.
B. K. Biskaborn, J.-P. Lanckman, H. Lantuit, K. Elger, D. A. Streletskiy, W. L. Cable, and V. E. Romanovsky
Earth Syst. Sci. Data, 7, 245–259, https://doi.org/10.5194/essd-7-245-2015, https://doi.org/10.5194/essd-7-245-2015, 2015
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This paper introduces the new database of the Global Terrestrial Network for Permafrost (GTN-P) on permafrost temperature and active layer thickness data. It describes the operability of the Data Management System and the data quality. By applying statistics on GTN-P metadata, we analyze the spatial sample representation of permafrost monitoring sites. Comparison with environmental variables and climate projection data enable identification of potential future research locations.
M. Fritz, T. Opel, G. Tanski, U. Herzschuh, H. Meyer, A. Eulenburg, and H. Lantuit
The Cryosphere, 9, 737–752, https://doi.org/10.5194/tc-9-737-2015, https://doi.org/10.5194/tc-9-737-2015, 2015
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Ground ice in permafrost has not, until now, been considered to be a source of dissolved organic carbon (DOC), dissolved inorganic carbon (DIC) and other elements that are important for ecosystems and carbon cycling.
Ice wedges in the Arctic Yedoma region hold 45.2 Tg DOC (Tg = 10^12g), 33.6 Tg DIC and a freshwater reservoir of 4200 km³.
Leaching of terrestrial organic matter is the most relevant process of DOC sequestration into ground ice.
G. G. Laruelle, R. Lauerwald, J. Rotschi, P. A. Raymond, J. Hartmann, and P. Regnier
Biogeosciences, 12, 1447–1458, https://doi.org/10.5194/bg-12-1447-2015, https://doi.org/10.5194/bg-12-1447-2015, 2015
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This study quantifies the exchange of carbon dioxide (CO2) between the atmosphere and the land-ocean aquatic continuum (LOAC) of the northeast North American coast, which consists of rivers, estuaries, and the coastal ocean. Our analysis reveals significant variations of the flux intensity both in time and space across the study area. Ice cover, snowmelt, and the intensity of the estuarine filter are identified as important control factors of the CO2 exchange along the LOAC.
I. Fedorova, A. Chetverova, D. Bolshiyanov, A. Makarov, J. Boike, B. Heim, A. Morgenstern, P. P. Overduin, C. Wegner, V. Kashina, A. Eulenburg, E. Dobrotina, and I. Sidorina
Biogeosciences, 12, 345–363, https://doi.org/10.5194/bg-12-345-2015, https://doi.org/10.5194/bg-12-345-2015, 2015
N. Jiao, C. Robinson, F. Azam, H. Thomas, F. Baltar, H. Dang, N. J. Hardman-Mountford, M. Johnson, D. L. Kirchman, B. P. Koch, L. Legendre, C. Li, J. Liu, T. Luo, Y.-W. Luo, A. Mitra, A. Romanou, K. Tang, X. Wang, C. Zhang, and R. Zhang
Biogeosciences, 11, 5285–5306, https://doi.org/10.5194/bg-11-5285-2014, https://doi.org/10.5194/bg-11-5285-2014, 2014
B. Heim, E. Abramova, R. Doerffer, F. Günther, J. Hölemann, A. Kraberg, H. Lantuit, A. Loginova, F. Martynov, P. P. Overduin, and C. Wegner
Biogeosciences, 11, 4191–4210, https://doi.org/10.5194/bg-11-4191-2014, https://doi.org/10.5194/bg-11-4191-2014, 2014
M. Dietzel, A. Leis, R. Abdalla, J. Savarino, S. Morin, M. E. Böttcher, and S. Köhler
Biogeosciences, 11, 3149–3161, https://doi.org/10.5194/bg-11-3149-2014, https://doi.org/10.5194/bg-11-3149-2014, 2014
R. Valentini, A. Arneth, A. Bombelli, S. Castaldi, R. Cazzolla Gatti, F. Chevallier, P. Ciais, E. Grieco, J. Hartmann, M. Henry, R. A. Houghton, M. Jung, W. L. Kutsch, Y. Malhi, E. Mayorga, L. Merbold, G. Murray-Tortarolo, D. Papale, P. Peylin, B. Poulter, P. A. Raymond, M. Santini, S. Sitch, G. Vaglio Laurin, G. R. van der Werf, C. A. Williams, and R. J. Scholes
Biogeosciences, 11, 381–407, https://doi.org/10.5194/bg-11-381-2014, https://doi.org/10.5194/bg-11-381-2014, 2014
S. E. Craig, H. Thomas, C. T. Jones, W. K. W. Li, B. J. W. Greenan, E. H. Shadwick, and W. J. Burt
Biogeosciences Discuss., https://doi.org/10.5194/bgd-10-11255-2013, https://doi.org/10.5194/bgd-10-11255-2013, 2013
Revised manuscript not accepted
G. G. Laruelle, H. H. Dürr, R. Lauerwald, J. Hartmann, C. P. Slomp, N. Goossens, and P. A. G. Regnier
Hydrol. Earth Syst. Sci., 17, 2029–2051, https://doi.org/10.5194/hess-17-2029-2013, https://doi.org/10.5194/hess-17-2029-2013, 2013
J. A. Collins, A. Govin, S. Mulitza, D. Heslop, M. Zabel, J. Hartmann, U. Röhl, and G. Wefer
Clim. Past, 9, 1181–1191, https://doi.org/10.5194/cp-9-1181-2013, https://doi.org/10.5194/cp-9-1181-2013, 2013
P. K. Patra, J. G. Canadell, R. A. Houghton, S. L. Piao, N.-H. Oh, P. Ciais, K. R. Manjunath, A. Chhabra, T. Wang, T. Bhattacharya, P. Bousquet, J. Hartman, A. Ito, E. Mayorga, Y. Niwa, P. A. Raymond, V. V. S. S. Sarma, and R. Lasco
Biogeosciences, 10, 513–527, https://doi.org/10.5194/bg-10-513-2013, https://doi.org/10.5194/bg-10-513-2013, 2013
W. J. Burt, H. Thomas, K. Fennel, and E. Horne
Biogeosciences, 10, 53–66, https://doi.org/10.5194/bg-10-53-2013, https://doi.org/10.5194/bg-10-53-2013, 2013
Related subject area
Biogeochemistry: Rivers & Streams
The role of nitrogen and iron biogeochemical cycles in the production and export of dissolved organic matter in agricultural headwater catchments
From Iron Curtain to green belt: shift from heterotrophic to autotrophic nitrogen retention in the Elbe River over 35 years of passive restoration
The influence of burn severity on dissolved organic carbon concentrations across a stream network differs based on seasonal wetness conditions
Molecular level characterization of supraglacial dissolved organic matter sources and exported pools on the southern Greenland Ice Sheet
High seasonal and spatial dynamics of bio- and photodegradation in boreal humic waters
Seasonal particulate organic carbon dynamics of the Kolyma River tributaries, Siberia
Geomorphologic controls and anthropogenic impacts on dissolved organic carbon from mountainous rivers: insights from optical properties and carbon isotopes
Shifts in organic matter character and microbial community structure from glacial headwaters to downstream reaches in Canadian Rocky Mountain rivers
Physical and stoichiometric controls on stream respiration in a headwater stream
Local processes with a global impact: unraveling the dynamics of gas evasion in a step-and-pool configuration
Complex dissolved organic matter (DOM) on the roof of the world – Tibetan DOM molecular characteristics indicate sources, land use effects, and processing along the fluvial–limnic continuum
Maximum respiration rates in hyporheic zone sediments are primarily constrained by organic carbon concentration and secondarily by organic matter chemistry
Glacier loss and vegetation expansion alter organic and inorganic carbon dynamics in high-mountain streams
Particulate organic matter in the Lena River and its delta: from the permafrost catchment to the Arctic Ocean
Stable isotopic evidence for the excess leaching of unprocessed atmospheric nitrate from forested catchments under high nitrogen saturation
Nitrogen isotopes reveal a particulate-matter-driven biogeochemical reactor in a temperate estuary
High-resolution vertical biogeochemical profiles in the hyporheic zone reveal insights into microbial methane cycling
Organic matter transformations are disconnected between surface water and the hyporheic zone
CO2 emissions from peat-draining rivers regulated by water pH
Effects of peatland management on aquatic carbon concentrations and fluxes
Resistance and resilience of stream metabolism to high flow disturbances
Enhanced bioavailability of dissolved organic matter (DOM) in human-disturbed streams in Alpine fluvial networks
Spatial and temporal variability of pCO2 and CO2 emissions from the Dong River in south China
Fluvial carbon dioxide emission from the Lena River basin during the spring flood
Diel patterns in stream nitrate concentration produced by in-stream processes
Complex interactions of in-stream dissolved organic matter and nutrient spiralling unravelled by Bayesian regression analysis
Spatial–temporal variations in riverine carbon strongly influenced by local hydrological events in an alpine catchment
Rapid soil organic carbon decomposition in river systems: effects of the aquatic microbial community and hydrodynamical disturbance
Increased carbon capture by a silicate-treated forested watershed affected by acid deposition
Thermokarst amplifies fluvial inorganic carbon cycling and export across watershed scales on the Peel Plateau, Canada
Temporary and net sinks of atmospheric CO2 due to chemical weathering in subtropical catchment with mixing carbonate and silicate lithology
From canals to the coast: dissolved organic matter and trace metal composition in rivers draining degraded tropical peatlands in Indonesia
Distribution and flux of dissolved iron in the peatland-draining rivers and estuaries of Sarawak, Malaysian Borneo
Comparisons of dissolved organic matter and its optical characteristics in small low and high Arctic catchments
High-frequency measurements explain quantity and quality of dissolved organic carbon mobilization in a headwater catchment
Dissolved inorganic nitrogen in a tropical estuary in Malaysia: transport and transformation
Behaviour of Dissolved Phosphorus with the associated nutrients in relation to phytoplankton biomass of the Rajang River-South China Sea continuum
Synchrony in catchment stream colour levels is driven by both local and regional climate
The post-monsoon carbon biogeochemistry of the Hooghly–Sundarbans estuarine system under different levels of anthropogenic impacts
Riverine particulate C and N generated at the permafrost thaw front: case study of western Siberian rivers across a 1700 km latitudinal transect
Geochemistry of the dissolved loads during high-flow season of rivers in the southeastern coastal region of China: anthropogenic impact on chemical weathering and carbon sequestration
CO2 partial pressure and CO2 emission along the lower Red River (Vietnam)
Stable isotopes of nitrate reveal different nitrogen processing mechanisms in streams across a land use gradient during wet and dry periods
Riverine carbon export in the arid to semiarid Wuding River catchment on the Chinese Loess Plateau
Use of argon to measure gas exchange in turbulent mountain streams
Reviews and syntheses: Anthropogenic perturbations to carbon fluxes in Asian river systems – concepts, emerging trends, and research challenges
Shifts in stream hydrochemistry in responses to typhoon and non-typhoon precipitation
QUAL-NET, a high temporal-resolution eutrophication model for large hydrographic networks
Diel fluctuations of viscosity-driven riparian inflow affect streamflow DOC concentration
A comprehensive biogeochemical record and annual flux estimates for the Sabaki River (Kenya)
Thibault Lambert, Rémi Dupas, and Patrick Durand
Biogeosciences, 21, 4533–4547, https://doi.org/10.5194/bg-21-4533-2024, https://doi.org/10.5194/bg-21-4533-2024, 2024
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This study investigates dissolved organic carbon (DOC) export in headwater catchments. Results show small links between DOC, nitrates, and the iron cycle throughout the year, calling into question our current conceptualization of DOC export at the catchment scale. Indeed, this study evidences that the winter period, referred as a non-productive period in our current conceptual model, acts as an active period for DOC production in riparian soils and DOC export toward stream waters.
Alexander Wachholz, James W. Jawitz, and Dietrich Borchardt
Biogeosciences, 21, 3537–3550, https://doi.org/10.5194/bg-21-3537-2024, https://doi.org/10.5194/bg-21-3537-2024, 2024
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Human activities are rivers' main source of nitrogen, causing eutrophication and other hazards. However, rivers can serve as a natural defense mechanism against this by retaining nitrogen. We show that the Elbe River retains more nitrogen during times of high pollution. With improvements in water quality, less nitrogen is retained. We explain this with changed algal and bacterial activities, which correspond to pollution and have many implications for the river and adjacent ecosystems.
Katie A. Wampler, Kevin D. Bladon, and Allison N. Myers-Pigg
Biogeosciences, 21, 3093–3120, https://doi.org/10.5194/bg-21-3093-2024, https://doi.org/10.5194/bg-21-3093-2024, 2024
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Following a high-severity wildfire, we sampled 129 sites during four different times of the year across a stream network to quantify dissolved organic carbon. The results from our study suggested that dissolved organic carbon may decrease with increasing burn severity. They also suggest that landscape characteristics can override wildfire impacts, with the seasonal timing of sampling influencing the observed response of dissolved organic carbon concentrations to wildfire.
Eva L. Doting, Ian T. Stevens, Anne M. Kellerman, Pamela E. Rossel, Runa Antony, Amy M. McKenna, Martyn Tranter, Liane G. Benning, Robert G. M. Spencer, Jon R. Hawkings, and Alexandre M. Anesio
EGUsphere, https://doi.org/10.5194/egusphere-2024-492, https://doi.org/10.5194/egusphere-2024-492, 2024
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This study provides new insights into the transformation of dissolved organic matter (DOM) that takes place as meltwater flows through the porous crust of weathering ice that covers glacier ice surfaces during the melt season. Movement of water through the weathering crust is slow, allowing microorganisms and sunlight to alter the DOM in glacial meltwater. This is important as supraglacial meltwaters deliver DOM and nutrients to microorganisms living in downstream receiving aquatic environments.
Artem V. Chupakov, Anna Chupakova, Svetlana A. Zabelina, Liudmila S. Shirokova, and Oleg S. Pokrovsky
EGUsphere, https://doi.org/10.5194/egusphere-2024-233, https://doi.org/10.5194/egusphere-2024-233, 2024
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In boreal (non-permafrost) humic (>15 mg DOC/L) waters of a forest lake and a bog, the experimentally measured rate of photodegradation is 4 times higher than that of biodegradation. However, given the shallow (0.5 m) light-penetrating layer versus the full depth of water column (2–10 m), the biodegradation may provide the largest contribution to CO2 emission from the water surfaces
Kirsi H. Keskitalo, Lisa Bröder, Tommaso Tesi, Paul J. Mann, Dirk J. Jong, Sergio Bulte Garcia, Anna Davydova, Sergei Davydov, Nikita Zimov, Negar Haghipour, Timothy I. Eglinton, and Jorien E. Vonk
Biogeosciences, 21, 357–379, https://doi.org/10.5194/bg-21-357-2024, https://doi.org/10.5194/bg-21-357-2024, 2024
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Permafrost thaw releases organic carbon into waterways. Decomposition of this carbon pool emits greenhouse gases into the atmosphere, enhancing climate warming. We show that Arctic river carbon and water chemistry are different between the spring ice breakup and summer and that primary production is initiated in small Arctic rivers right after ice breakup, in contrast to in large rivers. This may have implications for fluvial carbon dynamics and greenhouse gas uptake and emission balance.
Shuai Chen, Jun Zhong, Lishan Ran, Yuanbi Yi, Wanfa Wang, Zelong Yan, Si-liang Li, and Khan M. G. Mostofa
Biogeosciences, 20, 4949–4967, https://doi.org/10.5194/bg-20-4949-2023, https://doi.org/10.5194/bg-20-4949-2023, 2023
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This study found the source of dissolved organic carbon and its optical properties (e.g., aromaticity, humification) are related to human land use and catchment slope in anthropogenically impacted subtropical mountainous rivers. The study highlights that the combination of dual carbon isotopes and optical properties represents a useful tool in tracing the origin of dissolved organic carbon and its in-stream processes.
Hayley F. Drapeau, Suzanne E. Tank, Maria Cavaco, Jessica A. Serbu, Vincent St.Louis, and Maya P. Bhatia
Biogeosciences Discuss., https://doi.org/10.5194/bg-2023-121, https://doi.org/10.5194/bg-2023-121, 2023
Revised manuscript accepted for BG
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From glacial headwaters to 100 km downstream, we found clear organic matter gradients in Canadian Rocky Mountain rivers. In contrast, microbial communities exhibited overall cohesion, indicating that species dispersal may be an over-riding control on community dynamics in these connected rivers. Identification of glacial-specific microbes suggest that glaciers seed headwater microbial communities; these findings show the importance of glacial waters and microbiomes in changing mountain systems.
Jancoba Dorley, Joel Singley, Tim Covino, Kamini Singha, Michael Gooseff, David Van Horn, and Ricardo González-Pinzón
Biogeosciences, 20, 3353–3366, https://doi.org/10.5194/bg-20-3353-2023, https://doi.org/10.5194/bg-20-3353-2023, 2023
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We quantified how microbial respiration is controlled by discharge and the supply of C, N, and P in a stream. We ran two rounds of experiments adding a conservative tracer, an indicator of aerobic respiration, and nutrient treatments: a) N, b) N+C, c) N+P, and d) C+N+P. Microbial respiration remained similar between rounds and across nutrient treatments. This suggests that complex interactions between hydrology, resource supply, and biological community drive in-stream respiration.
Paolo Peruzzo, Matteo Cappozzo, Nicola Durighetto, and Gianluca Botter
Biogeosciences, 20, 3261–3271, https://doi.org/10.5194/bg-20-3261-2023, https://doi.org/10.5194/bg-20-3261-2023, 2023
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Small cascades greatly enhance mountain stream gas emissions through the turbulent energy dissipation rate and air bubbles entrained into the water. We numerically studied the local contribution of these mechanisms driving gas transfer velocity used to quantify the outgassing. The gas evasion is primarily due to bubbles concentrated in irregular spots of limited area. Consequently, the gas exchange velocity is scale-dependent and unpredictable, posing concerns about its use in similar scenarios.
Philipp Maurischat, Michael Seidel, Thorsten Dittmar, and Georg Guggenberger
Biogeosciences, 20, 3011–3026, https://doi.org/10.5194/bg-20-3011-2023, https://doi.org/10.5194/bg-20-3011-2023, 2023
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Production and consumption of organic matter (OM) on the Tibetan Plateau are important for this sensitive ecosystem. We investigated the chemical composition of dissolved organic matter and the most mobile fraction of OM in glaciers, wetlands, and groundwater as well as in the rivers and a large terminal lake. Our data show that the sources differ in the molecular composition of OM, that the stream is influenced by agriculture, and that the lake strongly changes the inflowing organic matter.
James C. Stegen, Vanessa A. Garayburu-Caruso, Robert E. Danczak, Amy E. Goldman, Lupita Renteria, Joshua M. Torgeson, and Jacqueline Hager
Biogeosciences, 20, 2857–2867, https://doi.org/10.5194/bg-20-2857-2023, https://doi.org/10.5194/bg-20-2857-2023, 2023
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Chemical reactions in river sediments influence how clean the water is and how much greenhouse gas comes out of a river. Our study investigates why some sediments have higher rates of chemical reactions than others. We find that to achieve high rates, sediments need to have two things: only a few different kinds of molecules, but a lot of them. This result spans about 80 rivers such that it could be a general rule, helpful for predicting the future of rivers and our planet.
Andrew L. Robison, Nicola Deluigi, Camille Rolland, Nicolas Manetti, and Tom Battin
Biogeosciences, 20, 2301–2316, https://doi.org/10.5194/bg-20-2301-2023, https://doi.org/10.5194/bg-20-2301-2023, 2023
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Climate change is affecting mountain ecosystems intensely, including the loss of glaciers and the uphill migration of plants. How these changes will affect the streams draining these landscapes is unclear. We sampled streams across a gradient of glacier and vegetation cover in Switzerland and found glacier loss reduced the carbon dioxide sink from weathering, while vegetation cover increased dissolved organic carbon in the stream. These changes are important to consider for mountains globally.
Olga Ogneva, Gesine Mollenhauer, Bennet Juhls, Tina Sanders, Juri Palmtag, Matthias Fuchs, Hendrik Grotheer, Paul J. Mann, and Jens Strauss
Biogeosciences, 20, 1423–1441, https://doi.org/10.5194/bg-20-1423-2023, https://doi.org/10.5194/bg-20-1423-2023, 2023
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Arctic warming accelerates permafrost thaw and release of terrestrial organic matter (OM) via rivers to the Arctic Ocean. We compared particulate organic carbon (POC), total suspended matter, and C isotopes (δ13C and Δ14C of POC) in the Lena delta and Lena River along a ~1600 km transect. We show that the Lena delta, as an interface between the Lena River and the Arctic Ocean, plays a crucial role in determining the qualitative and quantitative composition of OM discharged into the Arctic Ocean.
Weitian Ding, Urumu Tsunogai, Fumiko Nakagawa, Takashi Sambuichi, Masaaki Chiwa, Tamao Kasahara, and Ken'ichi Shinozuka
Biogeosciences, 20, 753–766, https://doi.org/10.5194/bg-20-753-2023, https://doi.org/10.5194/bg-20-753-2023, 2023
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By monitoring the concentration and Δ17O of stream nitrate in three forested streams, the new nitrogen saturation index of forested catchments (Matm/Datm ratio) was estimated. We found that (1) the unprocessed atmospheric nitrate in our studied forested stream (FK1 catchment) was the highest ever reported in forested streams; (2) the Matm/Datm ratio can be used as a robust index for evaluating nitrogen saturation in forested catchments as the Matm/Datm ratio is independent of the precipitation.
Kirstin Dähnke, Tina Sanders, Yoana Voynova, and Scott D. Wankel
Biogeosciences, 19, 5879–5891, https://doi.org/10.5194/bg-19-5879-2022, https://doi.org/10.5194/bg-19-5879-2022, 2022
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Nitrogen is an important macronutrient that fuels algal production in rivers and coastal regions. We investigated the production and removal of nitrogen-bearing compounds in the freshwater section of the tidal Elbe Estuary and found that particles in the water column are key for the production and removal of water column nitrate. Using a stable isotope approach, we pinpointed regions where additional removal of nitrate or input from sediments plays an important role in estuarine biogeochemistry.
Tamara Michaelis, Anja Wunderlich, Ömer K. Coskun, William Orsi, Thomas Baumann, and Florian Einsiedl
Biogeosciences, 19, 4551–4569, https://doi.org/10.5194/bg-19-4551-2022, https://doi.org/10.5194/bg-19-4551-2022, 2022
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The greenhouse gas methane (CH4) drives climate change. Microorganisms in river sediments produce CH4 when degrading organic matter, but the contribution of rivers to atmospheric CH4 concentrations is uncertain. To better understand riverine CH4 cycling, we measured concentration profiles of CH4 and relevant reactants that might influence the CH4 cycle. We found substantial CH4 production, especially in fine, organic-rich sediments during summer and signs of microbial CH4 consumption.
James C. Stegen, Sarah J. Fansler, Malak M. Tfaily, Vanessa A. Garayburu-Caruso, Amy E. Goldman, Robert E. Danczak, Rosalie K. Chu, Lupita Renteria, Jerry Tagestad, and Jason Toyoda
Biogeosciences, 19, 3099–3110, https://doi.org/10.5194/bg-19-3099-2022, https://doi.org/10.5194/bg-19-3099-2022, 2022
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Rivers are vital to Earth, and in rivers, organic matter (OM) is an energy source for microbes that make greenhouse gas and remove contaminants. Predicting Earth’s future requires understanding how and why river OM is transformed. Our results help meet this need. We found that the processes influencing OM transformations diverge between river water and riverbed sediments. This can be used to build new models for predicting the future of rivers and, in turn, the Earth system.
Alexandra Klemme, Tim Rixen, Denise Müller-Dum, Moritz Müller, Justus Notholt, and Thorsten Warneke
Biogeosciences, 19, 2855–2880, https://doi.org/10.5194/bg-19-2855-2022, https://doi.org/10.5194/bg-19-2855-2022, 2022
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Tropical peat-draining rivers contain high amounts of carbon. Surprisingly, measured carbon dioxide (CO2) emissions from those rivers are comparatively moderate. We compiled data from 10 Southeast Asian rivers and found that CO2 production within these rivers is hampered by low water pH, providing a natural threshold for CO2 emissions. Furthermore, we find that enhanced carbonate input, e.g. caused by human activities, suspends this natural threshold and causes increased CO2 emissions.
Amy E. Pickard, Marcella Branagan, Mike F. Billett, Roxane Andersen, and Kerry J. Dinsmore
Biogeosciences, 19, 1321–1334, https://doi.org/10.5194/bg-19-1321-2022, https://doi.org/10.5194/bg-19-1321-2022, 2022
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Peatlands have been subject to a range of land management regimes over the past century. This has affected the amount of carbon that drains into surrounding streams and rivers. In our study, we measured carbon concentrations in streams draining from drained, non-drained, and restored areas of the Flow Country blanket bog in N Scotland. We found that drained peatland had higher concentrations and fluxes of carbon relative to non-drained areas. Restored peatland areas were highly variable.
Brynn O'Donnell and Erin R. Hotchkiss
Biogeosciences, 19, 1111–1134, https://doi.org/10.5194/bg-19-1111-2022, https://doi.org/10.5194/bg-19-1111-2022, 2022
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A stream is defined by flowing water, but higher flow from storms is also a frequent disturbance. This paper tests how higher flow changes stream metabolism (respiration and photosynthesis, R and P). P was less resistant to changes in flow compared to R, and P took longer to recover from storms than R (2.2 versus 0.6 d). Further work on metabolic responses to flow disturbance is critical given projected increases in storms and the influence of higher flows on ecosystem health and functioning.
Thibault Lambert, Pascal Perolo, Nicolas Escoffier, and Marie-Elodie Perga
Biogeosciences, 19, 187–200, https://doi.org/10.5194/bg-19-187-2022, https://doi.org/10.5194/bg-19-187-2022, 2022
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The bacterial mineralization of dissolved organic matter (DOM) in inland waters contributes to CO2 emissions to the atmosphere. Human activities affect DOM sources. However, the implications on DOM mineralization are poorly known. Combining sampling and incubations, we showed that higher bacterial respiration in agro-urban streams related to a labile pool from aquatic origin. Therefore, human activities may have a limited impact on the net carbon exchanges between inland waters and atmosphere.
Boyi Liu, Mingyang Tian, Kaimin Shih, Chun Ngai Chan, Xiankun Yang, and Lishan Ran
Biogeosciences, 18, 5231–5245, https://doi.org/10.5194/bg-18-5231-2021, https://doi.org/10.5194/bg-18-5231-2021, 2021
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Spatial and temporal patterns of pCO2 in the subtropical Dong River basin were mainly affected by C inputs and in-stream metabolism, both of which varied due to differential catchment settings, land cover, and hydrological conditions. CO2 fluxes in the wet season were 2-fold larger than in the dry season due to high pCO2 and turbulence caused by high flow velocity. The absence of high CO2 fluxes in small rivers could be associated with the depletion effect caused by abundant precipitation.
Sergey N. Vorobyev, Jan Karlsson, Yuri Y. Kolesnichenko, Mikhail A. Korets, and Oleg S. Pokrovsky
Biogeosciences, 18, 4919–4936, https://doi.org/10.5194/bg-18-4919-2021, https://doi.org/10.5194/bg-18-4919-2021, 2021
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In order to quantify riverine carbon (C) exchange with the atmosphere in permafrost regions, we report a first assessment of CO2 and CH4 concentration and fluxes of the largest permafrost-affected river, the Lena River, during the peak of spring flow. The results allowed identification of environmental factors controlling GHG concentrations and emission in the Lena River watershed; this new knowledge can be used for foreseeing future changes in C balance in permafrost-affected Arctic rivers.
Jan Greiwe, Markus Weiler, and Jens Lange
Biogeosciences, 18, 4705–4715, https://doi.org/10.5194/bg-18-4705-2021, https://doi.org/10.5194/bg-18-4705-2021, 2021
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We analyzed variability in diel nitrate patterns at three locations in a lowland stream. Comparison of time lags between monitoring sites with water travel time indicated that diel patterns were created by in-stream processes rather than transported downstream from an upstream point of origin. Most of the patterns (70 %) could be explained by assimilatory nitrate uptake. The remaining patterns suggest seasonally varying dominance and synchronicity of different biochemical processes.
Matthias Pucher, Peter Flödl, Daniel Graeber, Klaus Felsenstein, Thomas Hein, and Gabriele Weigelhofer
Biogeosciences, 18, 3103–3122, https://doi.org/10.5194/bg-18-3103-2021, https://doi.org/10.5194/bg-18-3103-2021, 2021
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Dissolved organic matter is an important carbon source in aquatic ecosystems, yet the uptake processes are not totally understood. We found evidence for the release of degradation products, efficiency loss in the uptake with higher concentrations, stimulating effects, and quality-dependent influences from the benthic zone. To conduct this analysis, we included interactions in the equations of the nutrient spiralling concept and solve it with a Bayesian non-linear fitting algorithm.
Xin Wang, Ting Liu, Liang Wang, Zongguang Liu, Erxiong Zhu, Simin Wang, Yue Cai, Shanshan Zhu, and Xiaojuan Feng
Biogeosciences, 18, 3015–3028, https://doi.org/10.5194/bg-18-3015-2021, https://doi.org/10.5194/bg-18-3015-2021, 2021
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We show a comprehensive monitoring dataset on the discharge and carbon transport in a small alpine river on the Qinghai–Tibetan Plateau, where riverine carbon increased downstream in the pre-monsoon season due to an increasing contribution of organic matter derived from seasonal permafrost thaw while it fluctuated in the monsoon season induced by sporadic precipitation. These results indicate a high sensitivity of riverine carbon in alpine headwater catchments to local hydrological events.
Man Zhao, Liesbet Jacobs, Steven Bouillon, and Gerard Govers
Biogeosciences, 18, 1511–1523, https://doi.org/10.5194/bg-18-1511-2021, https://doi.org/10.5194/bg-18-1511-2021, 2021
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We investigate the relative importance of two individual factors (hydrodynamical disturbance and aquatic microbial community) that possibly control SOC decomposition rates in river systems. We found aquatic microbial organisms led to rapid SOC decomposition, while effect of mechanical disturbance is relative minor. We propose a simple conceptual model: hydrodynamic disturbance is only important when soil aggregates are strong enough to withstand the disruptive forces imposed by water immersions.
Lyla L. Taylor, Charles T. Driscoll, Peter M. Groffman, Greg H. Rau, Joel D. Blum, and David J. Beerling
Biogeosciences, 18, 169–188, https://doi.org/10.5194/bg-18-169-2021, https://doi.org/10.5194/bg-18-169-2021, 2021
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Enhanced rock weathering (ERW) is a carbon dioxide removal (CDR) strategy involving soil amendments with silicate rock dust. Over 15 years, a small silicate application led to net CDR of 8.5–11.5 t CO2/ha in an acid-rain-impacted New Hampshire forest. We accounted for the total carbon cost of treatment and compared effects with an adjacent, untreated forest. Our results suggest ERW can improve the greenhouse gas balance of similar forests in addition to mitigating acid rain effects.
Scott Zolkos, Suzanne E. Tank, Robert G. Striegl, Steven V. Kokelj, Justin Kokoszka, Cristian Estop-Aragonés, and David Olefeldt
Biogeosciences, 17, 5163–5182, https://doi.org/10.5194/bg-17-5163-2020, https://doi.org/10.5194/bg-17-5163-2020, 2020
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High-latitude warming thaws permafrost, exposing minerals to weathering and fluvial transport. We studied the effects of abrupt thaw and associated weathering on carbon cycling in western Canada. Permafrost collapse affected < 1 % of the landscape yet enabled carbonate weathering associated with CO2 degassing in headwaters and increased bicarbonate export across watershed scales. Weathering may become a driver of carbon cycling in ice- and mineral-rich permafrost terrain across the Arctic.
Yingjie Cao, Yingxue Xuan, Changyuan Tang, Shuai Guan, and Yisheng Peng
Biogeosciences, 17, 3875–3890, https://doi.org/10.5194/bg-17-3875-2020, https://doi.org/10.5194/bg-17-3875-2020, 2020
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About half of the global CO2 sequestration due to chemical weathering occurs in warm and high-runoff regions. To evaluate the temporary and net sinks of atmospheric CO2 due to chemical weathering, we selected a typical subtropical catchment as our study area and did fieldwork to sample surface water along the main channel and major tributaries in 1 hydrological year. The result of mass balance calculation showed that human activities dramatically decreased the CO2 net sink.
Laure Gandois, Alison M. Hoyt, Stéphane Mounier, Gaël Le Roux, Charles F. Harvey, Adrien Claustres, Mohammed Nuriman, and Gusti Anshari
Biogeosciences, 17, 1897–1909, https://doi.org/10.5194/bg-17-1897-2020, https://doi.org/10.5194/bg-17-1897-2020, 2020
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Worldwide, peatlands are important sources of dissolved organic matter (DOM) and trace metals (TMs) to surface waters, and these fluxes may increase with peatland degradation. In Southeast Asia, tropical peatlands are being rapidly deforested and drained. This work aims to address the fate of organic carbon and its role as a trace metal carrier in drained peatlands of Indonesia.
Xiaohui Zhang, Moritz Müller, Shan Jiang, Ying Wu, Xunchi Zhu, Aazani Mujahid, Zhuoyi Zhu, Mohd Fakharuddin Muhamad, Edwin Sien Aun Sia, Faddrine Holt Ajon Jang, and Jing Zhang
Biogeosciences, 17, 1805–1819, https://doi.org/10.5194/bg-17-1805-2020, https://doi.org/10.5194/bg-17-1805-2020, 2020
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This study offered detailed information on dFe concentrations, distribution and the magnitude of yield in the Rajang River, the largest river in Malaysia. Three blackwater rivers, draining from peatlands, were also included in our study. Compared with the Rajang River, the dFe concentrations and yield from three blackwater rivers were much higher. The precipitation and agricultural activities, such as palm oil plantations, may markedly increase the concentration dFe in these tropical rivers.
Caroline Coch, Bennet Juhls, Scott F. Lamoureux, Melissa J. Lafrenière, Michael Fritz, Birgit Heim, and Hugues Lantuit
Biogeosciences, 16, 4535–4553, https://doi.org/10.5194/bg-16-4535-2019, https://doi.org/10.5194/bg-16-4535-2019, 2019
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Climate change affects Arctic ecosystems. This includes thawing of permafrost (ground below 0 °C) and an increase in rainfall. Both have substantial impacts on the chemical composition of river water. We compared the composition of small rivers in the low and high Arctic with the large Arctic rivers. In comparison, dissolved organic matter in the small rivers is more susceptible to degradation; thus, it could potentially increase carbon dioxide emissions. Rainfall events have a similar effect.
Benedikt J. Werner, Andreas Musolff, Oliver J. Lechtenfeld, Gerrit H. de Rooij, Marieke R. Oosterwoud, and Jan H. Fleckenstein
Biogeosciences, 16, 4497–4516, https://doi.org/10.5194/bg-16-4497-2019, https://doi.org/10.5194/bg-16-4497-2019, 2019
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Increased dissolved organic carbon (DOC) concentration in streams can pose a threat to downstream water resources. Analyzing data from an in-stream probe we found that hydroclimatic and hydrological drivers can describe up to 72 % of the observed DOC concentration and composition variability. Variability was found to be highest during discharge events with warm and dry preconditions. The findings suggest an impact of climate change on DOC exports and thus also on downstream water quality.
Shan Jiang, Moritz Müller, Jie Jin, Ying Wu, Kun Zhu, Guosen Zhang, Aazani Mujahid, Tim Rixen, Mohd Fakharuddin Muhamad, Edwin Sien Aun Sia, Faddrine Holt Ajon Jang, and Jing Zhang
Biogeosciences, 16, 2821–2836, https://doi.org/10.5194/bg-16-2821-2019, https://doi.org/10.5194/bg-16-2821-2019, 2019
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Three cruises were conducted in the Rajang River estuary, Malaysia. The results revealed that the decomposition of terrestrial organic matter and the subsequent soil leaching were the main sources of dissolved inorganic nitrogen (DIN) in the fresh river water. Porewater exchange and ammonification enhanced DIN concentrations in the estuary water, while intensities of DIN addition varied between seasons. The riverine DIN flux could reach 101.5 ton(N) / d, supporting the coastal primary producers.
Edwin Sien Aun Sia, Jing Zhang, Shan Jiang, Zhuoyi Zhu, Gonzalo Carrasco, Faddrine Holt Jang, Aazani Mujahid, and Moritz Müller
Biogeosciences Discuss., https://doi.org/10.5194/bg-2019-219, https://doi.org/10.5194/bg-2019-219, 2019
Revised manuscript not accepted
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Nutrient loads carried by large rivers and discharged into the continental shelf and coastal waters are vital to support primary production. Our knowledge of tropical river systems is fragmented with very few seasonal studies available for Southeast Asia (SEA). We present data from three sampling campaigns on the longest river in Malaysia, the Rajang river. Our results show the generalization of SEA as a nutrient hotspot might not hold true for all regions and requires further investigation.
Brian C. Doyle, Elvira de Eyto, Mary Dillane, Russell Poole, Valerie McCarthy, Elizabeth Ryder, and Eleanor Jennings
Biogeosciences, 16, 1053–1071, https://doi.org/10.5194/bg-16-1053-2019, https://doi.org/10.5194/bg-16-1053-2019, 2019
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This study explores the drivers of variation in the water colour of rivers, and hence organic carbon export, in a blanket peatland catchment. We used 6 years of weekly river water colour data (2011 to 2016) from three proximate river sub-catchments in western Ireland. in tandem with a range of topographical, hydrological and climate data, to discover the principle environmental drivers controlling changes in colour concentration in the rivers.
Manab Kumar Dutta, Sanjeev Kumar, Rupa Mukherjee, Prasun Sanyal, and Sandip Kumar Mukhopadhyay
Biogeosciences, 16, 289–307, https://doi.org/10.5194/bg-16-289-2019, https://doi.org/10.5194/bg-16-289-2019, 2019
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The study focused on understanding C biogeochemistry of two adjacently located estuaries undergoing different levels of anthropogenic stresses. Different parameters related to C cycling were measured in an anthropogenically influenced and a mangrove-dominated estuary. Although the entire estuarine system acted as a source of carbon dioxide to the regional atmosphere, emission approximately 17 times higher was noticed from the anthropogenically affected estuary compared to mangrove-dominated one.
Ivan V. Krickov, Artem G. Lim, Rinat M. Manasypov, Sergey V. Loiko, Liudmila S. Shirokova, Sergey N. Kirpotin, Jan Karlsson, and Oleg S. Pokrovsky
Biogeosciences, 15, 6867–6884, https://doi.org/10.5194/bg-15-6867-2018, https://doi.org/10.5194/bg-15-6867-2018, 2018
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We tested the effect of climate, permafrost and physio-geographical landscape parameters on particulate C, N and P concentrations in small- and medium- sized rivers in the Western Siberian Lowland (WSL). We discovered a maximum of particulate C and N concentrations at the beginning of the permafrost appearance. A northward shift of permafrost boundaries may increase the particulate C and N export by WSL rivers to the Arctic Ocean by a factor of 2.
Wenjing Liu, Zhifang Xu, Huiguo Sun, Tong Zhao, Chao Shi, and Taoze Liu
Biogeosciences, 15, 4955–4971, https://doi.org/10.5194/bg-15-4955-2018, https://doi.org/10.5194/bg-15-4955-2018, 2018
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The southeastern coastal region is the top acid-rain-impacted area in China. It is worth evaluating the acid deposition impacts on chemical weathering and CO2 consumption there. River water geochemistry evidenced an overestimation of CO2 sequestration if H2SO4/HNO3 involvement was ignored, which accounted for 33.6 % of the total flux by silicate weathering in this area. This study quantitatively highlights the anthropogenic acid effects on chemical weathering and associated CO2 consumption.
Thi Phuong Quynh Le, Cyril Marchand, Cuong Tu Ho, Nhu Da Le, Thi Thuy Duong, XiXi Lu, Phuong Kieu Doan, Trung Kien Nguyen, Thi Mai Huong Nguyen, and Duy An Vu
Biogeosciences, 15, 4799–4814, https://doi.org/10.5194/bg-15-4799-2018, https://doi.org/10.5194/bg-15-4799-2018, 2018
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The Red River is a typical south-east Asian river, strongly affected by climate and human activity. This study showed the spatial and seasonal variability of CO2 emissions at the water–air interface of the lower part of this river due to natural conditions (meteo-hydrological-geomorphological characteristics) and human activities (dam impoundment, population, land use). The Red River water was supersaturated with CO2, providing a mean water–air CO2 flux of 530 ± 17 mmol m−2 d−1.
Wei Wen Wong, Jesse Pottage, Fiona Y. Warry, Paul Reich, Keryn L. Roberts, Michael R. Grace, and Perran L. M. Cook
Biogeosciences, 15, 3953–3965, https://doi.org/10.5194/bg-15-3953-2018, https://doi.org/10.5194/bg-15-3953-2018, 2018
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Over-enrichment of nitrate can pose substantial risk to the quality of freshwater ecosystems. Hence, understanding the dynamics of nitrate is the key to better management of waterways. This study evaluates the relationship between the effects of land use and rainfall on the major sources and processing of nitrate within and between five streams in five catchments spanning an agricultural land use gradient. We found that rainfall exerted significant control over the fate of nitrate.
Lishan Ran, Mingyang Tian, Nufang Fang, Suiji Wang, Xixi Lu, Xiankun Yang, and Frankie Cho
Biogeosciences, 15, 3857–3871, https://doi.org/10.5194/bg-15-3857-2018, https://doi.org/10.5194/bg-15-3857-2018, 2018
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We systematically assessed the transport and fate of riverine carbon in the moderate-sized Wuding catchment on the Chinese Loess Plateau by constructing a riverine carbon budget and further relating it to terrestrial ecosystem productivity. The riverine carbon export accounted for 16 % of the catchment's net ecosystem production (NEP). It seems that a significant fraction of terrestrial NEP in this catchment is laterally transported from the terrestrial biosphere to the drainage network.
Robert O. Hall Jr. and Hilary L. Madinger
Biogeosciences, 15, 3085–3092, https://doi.org/10.5194/bg-15-3085-2018, https://doi.org/10.5194/bg-15-3085-2018, 2018
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Streams exchange oxygen with the atmosphere, but this rate is difficult to measure. We added argon to small mountain streams to estimate gas exchange. We compared these rates with sulfur hexafluoride, an intense greenhouse gas. Argon worked well to measure gas exchange, but had higher-than-predicted rates than sulfur hexafluoride. Argon exchange is more likely to represent that for oxygen because they share similar physical properties. We suggest argon to measure gas exchange in small streams.
Ji-Hyung Park, Omme K. Nayna, Most S. Begum, Eliyan Chea, Jens Hartmann, Richard G. Keil, Sanjeev Kumar, Xixi Lu, Lishan Ran, Jeffrey E. Richey, Vedula V. S. S. Sarma, Shafi M. Tareq, Do Thi Xuan, and Ruihong Yu
Biogeosciences, 15, 3049–3069, https://doi.org/10.5194/bg-15-3049-2018, https://doi.org/10.5194/bg-15-3049-2018, 2018
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Human activities are drastically altering water and material flows in river systems across Asia. This review provides a conceptual framework for assessing the human impacts on Asian river C fluxes and an update on anthropogenic alterations of riverine C fluxes, focusing on the impacts of water pollution and river impoundments on CO2 outgassing from the rivers draining South, Southeast, and East Asian regions that account for the largest fraction of river discharge and C exports from Asia.
Chung-Te Chang, Jr-Chuan Huang, Lixin Wang, Yu-Ting Shih, and Teng-Chiu Lin
Biogeosciences, 15, 2379–2391, https://doi.org/10.5194/bg-15-2379-2018, https://doi.org/10.5194/bg-15-2379-2018, 2018
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Our analysis of ion input–output budget illustrates that hydrochemical responses to typhoon storms are distinctly different from those of regular storms. In addition, even mild land use change may have large impacts on nutrient exports/losses. We propose that hydrological models should separate hydrochemical processes into regular and extreme conditions to better capture the whole spectrum of hydrochemical responses to a variety of climate conditions.
Camille Minaudo, Florence Curie, Yann Jullian, Nathalie Gassama, and Florentina Moatar
Biogeosciences, 15, 2251–2269, https://doi.org/10.5194/bg-15-2251-2018, https://doi.org/10.5194/bg-15-2251-2018, 2018
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We developed the model QUALity-NETwork (QUAL-NET) to simulate water quality variations in large drainage networks. This model is accurate enough to represent processes occurring over short periods of time such as storm events and helps to fully understand water quality variations in stream networks in the context of climate change and varying human pressures. It was tested on the Loire River and provided good performances and a new understanding of the functioning of the river.
Michael P. Schwab, Julian Klaus, Laurent Pfister, and Markus Weiler
Biogeosciences, 15, 2177–2188, https://doi.org/10.5194/bg-15-2177-2018, https://doi.org/10.5194/bg-15-2177-2018, 2018
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We studied the diel fluctuations of dissolved organic carbon (DOC) concentrations in a small stream in Luxembourg. We identified an increased proportion of DOC from terrestrial sources as responsible for the peaks in DOC in the afternoon. Warmer water temperatures in the riparian zone in the afternoon increased the amount of water flowing towards the stream. Consequently, an increased amount of DOC-rich water from the riparian zone was entering the stream.
Trent R. Marwick, Fredrick Tamooh, Bernard Ogwoka, Alberto V. Borges, François Darchambeau, and Steven Bouillon
Biogeosciences, 15, 1683–1700, https://doi.org/10.5194/bg-15-1683-2018, https://doi.org/10.5194/bg-15-1683-2018, 2018
Short summary
Short summary
A 2-year biogeochemical record provides annual sediment and element flux estimates for the non-dammed Sabaki River, Kenya, establishing a baseline for future research in light of impending construction of the first major upstream reservoir. Over 80 % of material fluxes occur across the wet season, with annual yields comparable to the adjacent, and dammed, Tana River. Observations at low-flow periods suggest large mammalian herbivores may be vectors of terrestrial subsidies to the water column.
Cited articles
Aas, W., Eckhardt, S., Fiebig, M., Solberg, S., Platt, S. M., Yttri, K. E.,
and Zwaaftink, C. G.: Monitoring of long-range transported air pollutants in
Norway: NILU report 13/2021, Norwegian Environment Agency, Kjeller, ISBN 978-82-425-3040-0, 2021.
Amiotte Suchet, P., Probst, J.-L., and Ludwig, W.: Worldwide distribution of
continental rock lithology: Implications for the atmospheric/soil CO2
uptake by continental weathering and alkalinity river transport to the
oceans, Global Biogeochem. Cy., 17, 1038, https://doi.org/10.1029/2002GB001891,
2003.
Amundson, R., Stern, L., Baisden, T., and Wang, Y.: The isotopic composition
of soil and soil-respired CO2, Geoderma, 82, 83–114,
https://doi.org/10.1016/S0016-7061(97)00098-0, 1998.
Appelo, C., Verweij, E., and Schäfer, H.: A hydrogeochemical transport
model for an oxidation experiment with pyrite/calcite/exchangers/organic
matter containing sand, Appl. Geochem., 13, 257–268,
https://doi.org/10.1016/S0883-2927(97)00070-X, 1998.
Beel, C. R., Heslop, J. K., Orwin, J. F., Pope, M. A., Schevers, A. J.,
Hung, J. K. Y., Lafrenière, M. J., and Lamoureux, S. F.: Emerging
dominance of summer rainfall driving High Arctic terrestrial-aquatic
connectivity, Nat. Commun., 12, 1448,
https://doi.org/10.1038/s41467-021-21759-3, 2021.
Berger, T. W., Türtscher, S., Berger, P., and Lindebner, L.: A slight
recovery of soils from Acid Rain over the last three decades is not
reflected in the macro nutrition of beech (Fagus sylvatica) at 97 forest
stands of the Vienna Woods, Environ. Pollut.,
216, 624–635, https://doi.org/10.1016/j.envpol.2016.06.024, 2016.
Berner, E. K. and Berner, R. A.: The global water cycle: Geochemistry and
environment, Prentice-Hall, Inc, Englewood Cliffs, 397 pp., ISBN 10 0133571955, 1987.
Berner, R. A., Lasaga, A. C., and Garrels, R. M.: The carbonate-silicate
geochemical cycle and its effect on atmospheric carbon dioxide over the past
100 million years, Am. J. Sci., 283, 641–683,
https://doi.org/10.2475/ajs.283.7.641, 1983.
Blum, J. D., Gazis, C. A., Jacobson, A. D., and Page Chamberlain, C.:
Carbonate versus silicate weathering in the Raikhot watershed within the
High Himalayan Crystalline Series, Geology, 26, 411,
https://doi.org/10.1130/0091-7613(1998)026<0411:CVSWIT>2.3.CO;2, 1998.
Böttcher, M. E.: The Stable Isotopic Geochemistry of the Sulfur and
Carbon Cycles in a Modern Karst Environment, Isot. Environ.
Health S., 35, 39–61, https://doi.org/10.1080/10256019908234078, 1999.
Böttcher, M. E. and Schmiedinger, I.: The impact of temperature on the
water isotope (2H 1H, 17O 16O, 18O 16O) fractionation upon transport through
a low-density polyethylene membrane, Isot. Environ.
Health S., 57, 183–192, https://doi.org/10.1080/10256016.2020.1845668, 2021.
Braathen, A. and Davidsen, B.: Structure and stratigraphy of the
Palaeoproterozoic Karasjok Greenstone Belt, north Norway – regional
implications, Norsk Geol. Tidsskr., 80, 33–50,
https://doi.org/10.1080/002919600750042663, 2000.
Brand, W. A. and Coplen, T. B.: Stable isotope deltas: tiny, yet robust
signatures in nature, Isot. Environ.
Health S., 48,
393–409, https://doi.org/10.1080/10256016.2012.666977, 2012.
Campeau, A., Wallin, M. B., Giesler, R., Löfgren, S., Mörth, C.-M.,
Schiff, S., Venkiteswaran, J. J., and Bishop, K.: Multiple sources and sinks
of dissolved inorganic carbon across Swedish streams, refocusing the lens of
stable C isotopes, Sci. Rep., 7, 9158,
https://doi.org/10.1038/s41598-017-09049-9, 2017.
Camporese, M., Penna, D., Borga, M., and Paniconi, C.: A field and modeling
study of nonlinear storage-discharge dynamics for an Alpine headwater
catchment, Water Resour. Res., 50, 806–822, https://doi.org/10.1002/2013WR013604, 2014.
Cerling, T. E., Solomon, D., Quade, J., and Bowman, J. R.: On the isotopic
composition of carbon in soil carbon dioxide, Geochim. Cosmochim.
Ac., 55, 3403–3405, https://doi.org/10.1016/0016-7037(91)90498-T, 1991.
Chekushin, V. A., Bogatyrev, I. V., Caritat, P. de, Niskavaara, H., and
Reimann, C.: Annual atmospheric deposition of 16 elements in eight
catchments of the central Barents region, Sci. Total Environ.,
220, 95–114, https://doi.org/10.1016/S0048-9697(98)00247-2, 1998.
Conrad, O., Bechtel, B., Bock, M., Dietrich, H., Fischer, E., Gerlitz, L., Wehberg, J., Wichmann, V., and Böhner, J.: System for Automated Geoscientific Analyses (SAGA) v. 2.1.4, Geosci. Model Dev., 8, 1991–2007, https://doi.org/10.5194/gmd-8-1991-2015, 2015.
Davidson, G. R.: The stable isotopic composition and measurement of carbon
in soil CO2, Geochim. Cosmochim. Ac., 59, 2485–2489,
https://doi.org/10.1016/0016-7037(95)00143-3, 1995.
Deines, P., Langmuir, D., and Harmon, R. S.: Stable carbon isotope ratios
and the existence of a gas phase in the evolution of carbonate ground
waters, Geochim. Cosmochim. Ac., 38, 1147–1164,
https://doi.org/10.1016/0016-7037(74)90010-6, 1974.
Didan, K., Munoz, A. B., Solano, R., and Huete, A.: MOD13Q1 v006:
MODIS/Terra Vegetation Indices 16-Day L3 Global 250 m SIN Grid, Land
Processes Distributed Active Archive Center (LP DAAC) [data set], https://doi.org/10.5067/MODIS/MOD13Q1.006,
2015.
Dingman, S. L.: Hydrology of the Glenn Creek watershed, Tanana River Basin,
central Alaska: Res. Rep. 297, Cold Regions Research and Engineering
Laboratory, Hanover, New Hampshire, USA, https://hdl.handle.net/11681/5740 (last access: 15 August 2022), 1971.
Drake, T. W., Tank, S. E., Zhulidov, A. V., Holmes, R. M., Gurtovaya, T.,
and Spencer, R. G. M.: Increasing Alkalinity Export from Large Russian
Arctic Rivers, Environ. Sci. Technol., 52, 8302–8308,
https://doi.org/10.1021/acs.est.8b01051, 2018.
ESRI: Environmental Systems Research Institute (ESRI): ArcGIS pro: Release 2.9, ESRI, Redlands, USA, 2022.
Frey, K. E. and McClelland, J. W.: Impacts of permafrost degradation on
arctic river biogeochemistry, Hydrol. Process., 23, 169–182,
https://doi.org/10.1002/hyp.7196, 2009.
Fritz, P., Drimmie, R. J., Frape, S. K., and O'Shea, K.: The isotopic
composition of precipitation and groundwater in Canada, IAEA, International
Atomic Energy Agency (IAEA), ISBN 92-0-040087-6, 1987.
Gaillardet, J., Dupré, B., Louvat, P., and Allègre, C. J.: Global
silicate weathering and CO2 consumption rates deduced from the chemistry of
large rivers, Chem. Geol., 159, 3–30,
https://doi.org/10.1016/S0009-2541(99)00031-5, 1999.
Garrels, R. M. and Berner, R. A.: The Global Carbonate-Silicate Sedimentary
System – Some Feedback Relations, in: Biomineralization and Biological
Metal Accumulation, edited by: Westbroek, P. and De Jong, E. W., Springer
Netherlands, Dordrecht, 73–87, ISBN 13 978-94-009-7946-8, 1983.
Gislason, S. R., Oelkers, E. H., Eiriksdottir, E. S., Kardjilov, M. I.,
Gisladottir, G., Sigfusson, B., Snorrason, A., Elefsen, S., Hardardottir,
J., Torssander, P., and Oskarsson, N.: Direct evidence of the feedback
between climate and weathering, Earth Planet. Sc. Lett., 277,
213–222, https://doi.org/10.1016/j.epsl.2008.10.018, 2009.
Goll, D. S., Moosdorf, N., Hartmann, J., and Brovkin, V.: Climate-driven
changes in chemical weathering and associated phosphorus release since 1850:
Implications for the land carbon balance, Geophys. Res. Lett., 41,
3553–3558, https://doi.org/10.1002/2014GL059471, 2014.
Hartmann, J.: Bicarbonate-fluxes and CO2-consumption by chemical weathering
on the Japanese Archipelago – Application of a multi-lithological model
framework, Chem. Geol., 265, 237–271,
https://doi.org/10.1016/j.chemgeo.2009.03.024, 2009.
Hartmann, J. and Moosdorf, N.: The new global lithological map database
GLiM: A representation of rock properties at the Earth surface, Geochem.
Geophy. Geosys., 13, 119, https://doi.org/10.1029/2012GC004370, 2012.
Hartmann, J., Jansen, N., Dürr, H. H., Kempe, S., and Köhler, P.:
Global CO2-consumption by chemical weathering: What is the contribution of
highly active weathering regions?, Global Planet. Change, 69,
185–194, https://doi.org/10.1016/j.gloplacha.2009.07.007, 2009.
Hill, T. and Neal, C.: Spatial and temporal variation in pH, alkalinity and conductivity in surface runoff and groundwater for the Upper River Severn catchment, Hydrol. Earth Syst. Sci., 1, 697–715, https://doi.org/10.5194/hess-1-697-1997, 1997.
Hoefs, J.: Ein Beitrag zur Isotopengeochemie des Kohlenstoffs in magmatischen Gesteinen: A contribution on the isotope geochemistry of carbon in igneous rocks, Contrib. Mineral. Petr., 41, 277–300, https://doi.org/10.1007/BF00372168, 1973.
Huete, A., Didan, K., Miura, T., Rodriguez, E., Gao, X., and Ferreira, L.:
Overview of the radiometric and biophysical performance of the MODIS
vegetation indices, Remote Sens. Environ., 83, 195–213,
https://doi.org/10.1016/S0034-4257(02)00096-2, 2002.
International Atomic Energy Agency: Global Network of Isotopes in
Precipitation, The GNIP Database, https://nucleus.iaea.org/wiser (last access: 31 August 2022), 2020.
Jacobson, A. D., Blum, J. D., Chamberlain, C., Poage, M. A., and Sloan, V.
F.: Ca Sr and Sr isotope systematics of a Himalayan glacial chronosequence:
Carbonate versus silicate weathering rates as a function of landscape
surface age, Geochim. Cosmochim. Ac., 66, 13–27,
https://doi.org/10.1016/S0016-7037(01)00755-4, 2002.
Jacobson, A. D., Blum, J. D., Chamberlain, C., Craw, D., and Koons, P. O.:
Climatic and tectonic controls on chemical weathering in the New Zealand
Southern Alps, Geochim. Cosmochim. Ac., 67, 29–46,
https://doi.org/10.1016/S0016-7037(02)01053-0, 2003.
Jacobson, A. D., Grace Andrews, M., Lehn, G. O., and Holmden, C.: Silicate
versus carbonate weathering in Iceland: New insights from Ca isotopes, Earth
Planet. Sc. Lett., 416, 132–142,
https://doi.org/10.1016/j.epsl.2015.01.030, 2015.
Jones, J. B. and Mulholland, P. J.: Influence of drainage basin topography
and elevation on carbon dioxide and methane supersaturation of stream water,
Biogeochemistry, 40, 57–72, https://doi.org/10.1023/A:1005914121280, 1998.
Kempe, S.: Long-term records of CO2 pressure fluctuations in fresh waters,
Mitt. Geol-Paläont. Inst. Univ. Hamburg; SCOPE/UNEP Sonderband, 52,
91–332, https://www.karstwanderweg.de/publika/gpi/52/116-120/index.htm (last access: 15 August 2022), 1982.
Kjellman, S. E., Axelsson, P. E., Etzelmüller, B., Westermann, S., and
Sannel, A. B. K.: Holocene development of subarctic permafrost peatlands in
Finnmark, northern Norway, Holocene, 28, 1855–1869,
https://doi.org/10.1177/0959683618798126, 2018.
Lag, J.: Soil Map Norway – Jordbunnskart, Norges Landbrukshogskole,
https://esdac.jrc.ec.europa.eu/content/soil-map-norway-jordbunnskart (last access: 15 August 2022),
1983.
Land, L. S.: The isotopic and trace element geochemistry of dolomite: the
state of the art, in: Concepts and Models of Dolomitization, edited by: Zenger, D. H.,
Dunham, J. B., and Ethington, R. L., SEPM (Society for Sedimentary
Geology), 87–110, ISBN 10 0918985080, 1980.
Lasaga, A. C.: Chemical kinetics of water-rock interactions, J. Geophys.
Res., 89, 4009–4025, https://doi.org/10.1029/JB089iB06p04009, 1984.
Lehmann, N., Lantuit, H., Böttcher, M. E., Hartmann, J., and Thomas, H.: Alkalinity, DIC, δ13C-DIC, major and trace elements, and stable water isotopes data in water samples from a degrading permafrost landscape at subarctic Iskorasfjellet, northern Norway, PANGAEA [data set], https://doi.org/10.1594/PANGAEA.952905, 2022.
Lehn, G. O., Jacobson, A. D., Douglas, T. A., McClelland, J. W., Barker, A.
J., and Khosh, M. S.: Constraining seasonal active layer dynamics and
chemical weathering reactions occurring in North Slope Alaskan watersheds
with major ion and isotope (δ34S , δ13CDIC, 87Sr 86Sr,
δ44 40Ca, and δ44 / 42Ca) measurements, Geochim. Cosmochim.
Ac., 217, 399–420, https://doi.org/10.1016/j.gca.2017.07.042, 2017.
Li, S., Xia, X., Tan, X., and Zhang, Q.: Effects of catchment and riparian
landscape setting on water chemistry and seasonal evolution of water quality
in the upper Han River basin, China, PloS one, 8, e53163,
https://doi.org/10.1371/journal.pone.0053163, 2013.
Li, S.-L., Calmels, D., Han, G., Gaillardet, J., and Liu, C.-Q.: Sulfuric
acid as an agent of carbonate weathering constrained by δ13CDIC:
Examples from Southwest China, Earth Planet. Sc. Lett., 270,
189–199, https://doi.org/10.1016/j.epsl.2008.02.039, 2008.
Li, S.-L., Liu, C.-Q., Li, J., Lang, Y.-C., Ding, H., and Li, L.:
Geochemistry of dissolved inorganic carbon and carbonate weathering in a
small typical karstic catchment of Southwest China: Isotopic and chemical
constraints, Chem. Geol., 277, 301–309,
https://doi.org/10.1016/j.chemgeo.2010.08.013, 2010.
Liu, J. and Han, G.: Effects of chemical weathering and CO2 outgassing on
δ13CDIC signals in a karst watershed, J. Hydrol., 589, 125192,
https://doi.org/10.1016/j.jhydrol.2020.125192, 2020.
Liu, Z., Macpherson, G. L., Groves, C., Martin, J. B., Yuan, D., and Zeng,
S.: Large and active CO2 uptake by coupled carbonate weathering,
Earth-Sci. Rev., 182, 42–49, https://doi.org/10.1016/j.earscirev.2018.05.007,
2018.
Macpherson, G. L., Sullivan, P. L., Stotler, R. L., Norwood, B. S., Chudaev,
O., Kharaka, Y., Harmon, R., Millot, R., and Shouakar-Stash, O.: Increasing
groundwater CO2 in a mid-continent tallgrass prairie: Controlling factors,
E3S Web Conf., 98, 6008, https://doi.org/10.1051/e3sconf/20199806008, 2019.
Marx, A., Dusek, J., Jankovec, J., Sanda, M., Vogel, T., van Geldern, R.,
Hartmann, J., and Barth, J. A. C.: A review of CO2 and associated carbon
dynamics in headwater streams: A global perspective, Rev. Geophys., 55,
560–585, https://doi.org/10.1002/2016RG000547, 2017a.
Marx, A., Hintze, S., Sanda, M., Jankovec, J., Oulehle, F., Dusek, J.,
Vitvar, T., Vogel, T., van Geldern, R., and Barth, J. A. C.: Acid rain
footprint three decades after peak deposition: Long-term recovery from
pollutant sulphate in the Uhlirska catchment (Czech Republic), Sci.
Total Environ., 598, 1037–1049,
https://doi.org/10.1016/j.scitotenv.2017.04.109, 2017b.
Marx, A., Conrad, M., Aizinger, V., Prechtel, A., van Geldern, R., and Barth, J. A. C.: Groundwater data improve modelling of headwater stream CO2 outgassing with a stable DIC isotope approach, Biogeosciences, 15, 3093–3106, https://doi.org/10.5194/bg-15-3093-2018, 2018.
McGivney, E., Gustafsson, J. P., Belyazid, S., Zetterberg, T., and Löfgren, S.: Assessing the impact of acid rain and forest harvest intensity with the HD-MINTEQ model – soil chemistry of three Swedish conifer sites from 1880 to 2080, SOIL, 5, 63–77, https://doi.org/10.5194/soil-5-63-2019, 2019.
McGlynn, B. L. and McDonnell, J. J.: Quantifying the relative contributions
of riparian and hillslope zones to catchment runoff, Water Resour. Res., 39,
211, https://doi.org/10.1029/2003WR002091, 2003a.
McGlynn, B. L. and McDonnell, J. J.: Role of discrete landscape units in
controlling catchment dissolved organic carbon dynamics, Water Resour. Res.,
39, 251, https://doi.org/10.1029/2002WR001525, 2003b.
McGlynn, B. L. and Seibert, J.: Distributed assessment of contributing area
and riparian buffering along stream networks, Water Resour. Res., 39, 331,
https://doi.org/10.1029/2002WR001521, 2003.
McGuire, K. J. and McDonnell, J. J.: Hydrological connectivity of hillslopes
and streams: Characteristic time scales and nonlinearities, Water Resour.
Res., 46, 400, https://doi.org/10.1029/2010WR009341, 2010.
McNamara, J. P., Kane, D. L., and Hinzman, L. D.: Hydrograph separations in
an arctic watershed using mixing model and graphical techniques, Water
Resour. Res., 33, 1707–1719, https://doi.org/10.1029/97WR01033, 1997.
Meybeck, M.: Composition chimique des ruisseaux non pollués en France.
Chemical composition of headwater streams in France, sgeol, 39, 3–77,
https://doi.org/10.3406/sgeol.1986.1719, 1986.
Meybeck, M.: Global chemical weathering of surficial rocks estimated from
river dissolved loads, Am. J. Sci., 287, 401–428,
https://doi.org/10.2475/ajs.287.5.401, 1987.
Meyboom, P.: Groundwater Studies in the Assiboine River Drainage Basin. Part
II: Hydrolofic Characteristics of Phreatophytic Vegetation in South-Central
Saskatchewan, Geological Survey of Canada, Ottawa, Canada, https://doi.org/10.4095/101495, 1967.
Michaelis, J.: Carbonate rock dissolution under intermediate system
conditions, in: Progress in Hydrogeochemistry: Organics – Carbonate Systems
– Silicate Systems – Microbiology – Models, edited by: Mattheß, G., Frimmel, F.,
Hirsch, P., Schulz, H. D., and Usdowski, E., Springer Berlin Heidelberg,
Berlin, Heidelberg, 167–174, ISBN 13 978-3540540342, 1992.
Michaelis, J., Usdowski, E., and Menschel, G.: Partitioning of 13 C and 12 C
on the degassing of CO2 and the precipitation of calcite; Rayleigh-type
fractionation and a kinetic model, Am. J. Sci., 285,
318–327, https://doi.org/10.2475/ajs.285.4.318, 1985.
Millero, F. J.: The thermodynamics of the carbonate system in seawater,
Geochim. Cosmochim. Ac., 43, 1651–1661,
https://doi.org/10.1016/0016-7037(79)90184-4, 1979.
Millot, R., Gaillardet, J., Dupré, B., and Allègre, C. J.: The
global control of silicate weathering rates and the coupling with physical
erosion: new insights from rivers of the Canadian Shield, Earth
Planet. Sc. Lett., 196, 83–98, https://doi.org/10.1016/S0012-821X(01)00599-4,
2002.
Moore, J., Jacobson, A. D., Holmden, C., and Craw, D.: Tracking the
relationship between mountain uplift, silicate weathering, and long-term CO2
consumption with Ca isotopes: Southern Alps, New Zealand, Chem. Geol.,
341, 110–127, https://doi.org/10.1016/j.chemgeo.2013.01.005, 2013.
Moosdorf, N., Hartmann, J., and Lauerwald, R.: Changes in dissolved silica
mobilization into river systems draining North America until the period
2081–2100, J. Geochem. Explor., 110, 31–39,
https://doi.org/10.1016/j.gexplo.2010.09.001, 2011.
Myrabø, S.: Temporal and spatial scale of response area and groundwater
variation in Till, Hydrol. Process., 11, 1861–1880,
https://doi.org/10.1002/(SICI)1099-1085(199711)11:14<1861::AID-HYP535>3.0.CO;2-P,
1997.
NGU: Berggrunn Data N250, Geological Survey of Norway,
https://www.ngu.no/geologiske-kart/datasett (last access: 18 March 2022), 2022.
Obu, J., Westermann, S., Bartsch, A., Berdnikov, N., Christiansen, H. H.,
Dashtseren, A., Delaloye, R., Elberling, B., Etzelmüller, B., Kholodov,
A., Khomutov, A., Kääb, A., Leibman, M. O., Lewkowicz, A. G., Panda,
S. K., Romanovsky, V., Way, R. G., Westergaard-Nielsen, A., Wu, T., Yamkhin,
J., and Zou, D.: Northern Hemisphere permafrost map based on TTOP modelling
for 2000–2016 at 1 km2 scale, Earth-Sci. Rev., 193, 299–316,
https://doi.org/10.1016/j.earscirev.2019.04.023, 2019.
O'Leary, M. H.: Carbon Isotopes in Photosynthesis, BioScience, 38, 328–336,
https://doi.org/10.2307/1310735, 1988.
Oliva, P., Dupré, B., Martin, F., and Viers, J.: The role of trace
minerals in chemical weathering in a high-elevation granitic watershed
(Estibère, France): Chemical and mineralogical evidence, Geochim.
Cosmochim. Ac., 68, 2223–2243, https://doi.org/10.1016/j.gca.2003.10.043, 2004.
Oliver, L., Harris, N., Bickle, M., Chapman, H., Dise, N., and Horstwood,
M.: Silicate weathering rates decoupled from the 87Sr 86Sr ratio of the
dissolved load during Himalayan erosion, Chem. Geol., 201, 119–139,
https://doi.org/10.1016/S0009-2541(03)00236-5, 2003.
Olsen, L.: Stadials and interstadials during the Weichsel glackiation on
Finnmarksvidda, northern Norway, Boreas, 17, 517–539,
https://doi.org/10.1111/j.1502-3885.1988.tb00566.x, 1988.
Olsen, L., Fredin, O., and Olesen, O.: Quaternary Geology of Norway,
Geological Survey of Norway Special Publication, 13, ISBN 978-82-7385-153-6, 2013.
O'Nions, R. K., Morton, R. D., and Batey, R.: Geological investigations in
the Bamble sector of the Fennoscandian Shield South Norway.: I. The geology
of eastern Bamble, Universitetsforlaget, Oslo, https://hdl.handle.net/11250/2674911 (last access: 15 August 2022), 1970.
Petrone, K. C., Hinzman, L. D., Shibata, H., Jones, J. B., and Boone, R. D.:
The influence of fire and permafrost on sub-arctic stream chemistry during
storms, Hydrol. Process., 21, 423–434, https://doi.org/10.1002/hyp.6247, 2007.
Pierrot, D. E., Wallace, D., and Lewis, E.: CO2SYS: MS Excel Program Developed for
CO2 System Calculations, Carbon Dioxide Information
Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, USA, 2011.
Polsenaere, P. and Abril, G.: Modelling CO2 degassing from small acidic
rivers using water pCO2, DIC and δ13C-DIC data, Geochim.
Cosmochim. Ac., 91, 220–239, https://doi.org/10.1016/j.gca.2012.05.030, 2012.
Porter, C., Morin, P., Howat, I., Noh, M.-J., Bates, B., Peterman, K.,
Keesey, S., Schlenk, M., Gardiner, J., Tomko, K., Willis, M., Kelleher, C.,
Cloutier, M., Husby, E., Foga, S., Nakamura, H., Platson, M., Wethington Jr.,
M., Williamson, C., Bauer, G., Enos, J., Arnold, G., Kramer, W.,
Becker, P., Doshi, A., D'Souza, C., Cummens, P., Laurier, F., and Bojesen,
M.: ArcticDEM, V1, Harvard Dataverse [data set], https://doi.org/10.7910/DVN/OHHUKH, 2018.
Purkamo, L., Ahn, C. M. E. von, Jilbert, T., Muniruzzaman, M., Bange, H. W.,
Jenner, A.-K., Böttcher, M. E., and Virtasalo, J. J.: Impact of
submarine groundwater discharge on biogeochemistry and microbial communities
in pockmarks, Geochim. Cosmochim. Ac., 334, 14–44,
https://doi.org/10.1016/j.gca.2022.06.040, 2022.
QGIS.org: QGIS Geographic Information System, QGIS Association,
http://www.qgis.org (last access: 8 October 2022), 2022.
Rantanen, M., Karpechko, A. Y., Lipponen, A., Nordling, K., Hyvärinen,
O., Ruosteenoja, K., Vihma, T., and Laaksonen, A.: The Arctic has warmed
nearly four times faster than the globe since 1979, Commun. Earth Environ., 3, 168,
https://doi.org/10.1038/s43247-022-00498-3, 2022.
Raymond, P. A. and Hamilton, S. K.: Anthropogenic influences on riverine
fluxes of dissolved inorganic carbon to the oceans, Limnol. Oceanogr. Lett., 3,
143–155, https://doi.org/10.1002/lol2.10069, 2018.
Raymond, P. A., Oh, N.-H., Turner, R. E., and Broussard, W.:
Anthropogenically enhanced fluxes of water and carbon from the Mississippi
River, Nature, 451, 449–452, https://doi.org/10.1038/nature06505, 2008.
Riley, S. J., DeGloria, S. D., and and Elliot, R.: A terrain ruggedness
index that quantifies topographic heterogeneity, Intermountain Journal of
Sciences, 5, 23–27, 1999.
Rouault, E., Warmerdam, F., Schwehr, K., Kiselev, A., Butler, H.,
£oskot, M., Szekeres, T., Tourigny, E., Landa, M., Miara, I.,
Elliston, B., Kumar, C., Plesea, L., Morissette, D., Jolma, A., and Dawson,
N.: GDAL (v3.4.2), Zenodo [code], https://doi.org/10.5281/zenodo.6352176, 2022.
Sandström, B. and Tullborg, E.-L.: Episodic fluid migration in the
Fennoscandian Shield recorded by stable isotopes, rare earth elements and
fluid inclusions in fracture minerals at Forsmark, Sweden, Chem. Geol.,
266, 126–142, https://doi.org/10.1016/j.chemgeo.2009.04.019, 2009.
Schaefer, K. W. and Usdowski, E.: Models for the dissolution of carbonate
rocks and the carbon-13/carbon-12 evolution of carbonate groundwaters,
Zeitschrift fuer Wasser- und Abwasser-Forschung, 20, 69–81, https://eurekamag.com/research/005/910/005910064.php (last access: 15 August 2022), 1987.
Schaefer, K. W. and Usdowski, E.: Application of stable carbon and sulfur
isotope models to the development of ground water in a
limestone-dolomite-anhydrite-gypsum area, in: Progress in Hydrogeochemistry:
Organics – Carbonate Systems – Silicate Systems – Microbiology – Models,
edited by: Mattheß, G., Frimmel, F., Hirsch, P., Schulz, H. D., and Usdowski, E., Springer Berlin Heidelberg, Berlin, Heidelberg, 157–163, ISBN 13 978-3540540342, 1992.
Seibert, J., Grabs, T., Köhler, S., Laudon, H., Winterdahl, M., and Bishop, K.: Linking soil- and stream-water chemistry based on a Riparian Flow-Concentration Integration Model, Hydrol. Earth Syst. Sci., 13, 2287–2297, https://doi.org/10.5194/hess-13-2287-2009, 2009.
Seklima: Observations and weather statistics, Norsk Klimaservicesenter,
https://seklima.met.no/observations/ (last access: 31 August 2022), 2020.
Shadwick, E. H., Thomas, H., Gratton, Y., Leong, D., Moore, S. A.,
Papakyriakou, T., and Prowe, A.: Export of Pacific carbon through the Arctic
Archipelago to the North Atlantic, Cont. Shelf Res., 31, 806–816,
https://doi.org/10.1016/j.csr.2011.01.014, 2011.
Shin, W. J., Chung, G. S., Lee, D., and Lee, K. S.: Dissolved inorganic carbon export from carbonate and silicate catchments estimated from carbonate chemistry and δ13CDIC, Hydrol. Earth Syst. Sci., 15, 2551–2560, https://doi.org/10.5194/hess-15-2551-2011, 2011.
Sollid, J. L., Andersen, S., Hamre, N., Kjeldsen, O., Salvigsen, O.,
Sturød, S., Tveitå, T., and Wilhelmsen, A.: Deglaciation of Finnmark,
North Norway, Norsk Geografisk Tidsskrift – Norwegian Journal of Geography,
27, 233–325, https://doi.org/10.1080/00291951.1973.9728306, 1973.
Stallard, R. F. and Edmond, J. M.: Geochemistry of the Amazon: 3. Weathering
chemistry and limits to dissolved inputs, J. Geophys. Res., 92, 8293,
https://doi.org/10.1029/JC092iC08p08293, 1987.
Stone, L. E., Fang, X., Haynes, K. M., Helbig, M., Pomeroy, J. W.,
Sonnentag, O., and Quinton, W. L.: Modelling the effects of permafrost loss
on discharge from a wetland-dominated, discontinuous permafrost basin,
Hydrol. Process., 33, 2607–2626, https://doi.org/10.1002/hyp.13546, 2019.
Striegl, R. G., Aiken, G. R., Dornblaser, M. M., Raymond, P. A., and
Wickland, K. P.: A decrease in discharge-normalized DOC export by the Yukon
River during summer through autumn, Geophys. Res. Lett., 32, 567,
https://doi.org/10.1029/2005GL024413, 2005.
Stroeven, A. P., Hättestrand, C., Kleman, J., Heyman, J., Fabel, D.,
Fredin, O., Goodfellow, B. W., Harbor, J. M., Jansen, J. D., Olsen, L.,
Caffee, M. W., Fink, D., Lundqvist, J., Rosqvist, G. C., Strömberg, B.,
and Jansson, K. N.: Deglaciation of Fennoscandia, Quaternary Sci.
Rev., 147, 91–121, https://doi.org/10.1016/j.quascirev.2015.09.016, 2016.
Stumm, W. and Morgan, J. J.: Aquatic chemistry an introduction chemical
equilibria in natural water, 2nd ed., A Wiley – Interscience Publication, A
Wiley-Interscience Publication, New York, 780 pp., ISBN 13 978-0471091738, 1981.
Tank, S. E., Frey, K. E., Striegl, R. G., Raymond, P. A., Holmes, R. M.,
McClelland, J. W., and Peterson, B. J.: Landscape-level controls on
dissolved carbon flux from diverse catchments of the circumboreal, Global
Biogeochem. Cy., 26, 323, https://doi.org/10.1029/2012GB004299, 2012.
Tanneberger, F., Tegetmeyer, C., Busse, S., Barthelmes, A., and and 55
others: The peatland map of Europe, Mires Peat, 19, 1–17,
https://doi.org/10.19189/MaP.2016.OMB.264, 2017.
Trolier, M., White, J. W. C., Tans, P. P., Masarie, K. A., and Gemery, P.
A.: Monitoring the isotopic composition of atmospheric CO2: Measurements
from the NOAA Global Air Sampling Network, J. Geophys. Res., 101,
25897–25916, https://doi.org/10.1029/96JD02363, 1996.
Vidon, P.: Towards a better understanding of riparian zone water table
response to precipitation: Surface water infiltration, hillslope
contribution or pressure wave processes?, Hydrol. Process., 26, 3207–3215,
https://doi.org/10.1002/hyp.8258, 2012.
Walker, J. C. G., Hays, P. B., and Kasting, J. F.: A negative feedback
mechanism for the long-term stabilization of Earth's surface temperature, J.
Geophys. Res., 86, 9776, https://doi.org/10.1029/JC086iC10p09776, 1981.
Walvoord, M. A. and Striegl, R. G.: Increased groundwater to stream
discharge from permafrost thawing in the Yukon River basin: Potential
impacts on lateral export of carbon and nitrogen, Geophys. Res. Lett., 34,
L19401, https://doi.org/10.1029/2007GL030216, 2007.
Warner, D. L., Bond-Lamberty, B., Jian, J., Stell, E., and Vargas, R.:
Spatial Predictions and Associated Uncertainty of Annual Soil Respiration at
the Global Scale, Global Biogeochem. Cy., 33, 1733–1745,
https://doi.org/10.1029/2019GB006264, 2019.
Watts, J. D., Natali, S. M., Minions, C., Risk, D., Arndt, K., Zona, D.,
Euskirchen, E. S., Rocha, A. V., Sonnentag, O., Helbig, M., Kalhori, A.,
Oechel, W., Ikawa, H., Ueyama, M., Suzuki, R., Kobayashi, H., Celis, G.,
Schuur, E. A. G., Humphreys, E., Kim, Y., Lee, B.-Y., Goetz, S., Madani, N.,
Schiferl, L. D., Commane, R., Kimball, J. S., Liu, Z., Torn, M. S., Potter,
S., Wang, J. A., Jorgenson, M. T., Xiao, J., Li, X., and Edgar, C.: Soil
respiration strongly offsets carbon uptake in Alaska and Northwest Canada,
Environ. Res. Lett., 16, 84051, https://doi.org/10.1088/1748-9326/ac1222, 2021.
White, A. F., Bullen, T. D., Vivit, D. V., Schulz, M. S., and Clow, D. W.:
The role of disseminated calcite in the chemical weathering of granitoid
rocks, Geochim. Cosmochim. Ac., 63, 1939–1953,
https://doi.org/10.1016/S0016-7037(99)00082-4, 1999.
White, A. F., Schulz, M. S., Lowenstern, J. B., Vivit, D. V., and Bullen, T.
D.: The ubiquitous nature of accessory calcite in granitoid rocks:
Implications for weathering, solute evolution, and petrogenesis, Geochim.
Cosmochim. Ac., 69, 1455–1471, https://doi.org/10.1016/j.gca.2004.09.012, 2005.
Winde, V., Böttcher, M. E., Escher, P., Böning, P., Beck, M.,
Liebezeit, G., and Schneider, B.: Tidal and spatial variations of DI13C and
aquatic chemistry in a temperate tidal basin during winter time, J.
Marine Syst., 129, 396–404, https://doi.org/10.1016/j.jmarsys.2013.08.005, 2014.
Yuanrong, S., Ruihong, Y., Mingyang, T., Xiankun, Y., Lishan, R., Haizhu,
H., Zhuangzhuang, Z., and Xixi, L.: Major ion chemistry in the headwater
region of the Yellow River: Impact of land covers, Environ. Earth Sci., 80,
2637, https://doi.org/10.1007/s12665-021-09692-6, 2021.
Zeebe, R. E. and Westbroek, P.: A simple model for the CaCO 3 saturation
state of the ocean: The “Strangelove,” the “Neritan,” and the “Cretan”
Ocean, Geochem. Geophys. Geosyst., 4, 1104, https://doi.org/10.1029/2003GC000538, 2003.
Zeng, S., Liu, Z., and Kaufmann, G.: Sensitivity of the global carbonate
weathering carbon-sink flux to climate and land-use changes, Nat.
Commun., 10, 5749, https://doi.org/10.1038/s41467-019-13772-4, 2019.
Zeng, S., Kaufmann, G., and Liu, Z.: Natural and Anthropogenic Driving
Forces of Carbonate Weathering and the Related Carbon Sink Flux: A Model
Comparison Study at Global Scale, Global Biogeochem. Cy., 36, e2021GB007096,
https://doi.org/10.1029/2021GB007096, 2022.
Zhang, J., Quay, P. D., and Wilbur, D. O.: Carbon isotope fractionation
during gas-water exchange and dissolution of CO2, Geochim. Cosmochim.
Ac., 59, 107–114, https://doi.org/10.1016/0016-7037(95)91550-D, 1995.
Zolkos, S., Tank, S. E., Striegl, R. G., Kokelj, S. V., Kokoszka, J., Estop-Aragonés, C., and Olefeldt, D.: Thermokarst amplifies fluvial inorganic carbon cycling and export across watershed scales on the Peel Plateau, Canada, Biogeosciences, 17, 5163–5182, https://doi.org/10.5194/bg-17-5163-2020, 2020.
Short summary
Riverine alkalinity in the silicate-dominated headwater catchment at subarctic Iskorasfjellet, northern Norway, was almost entirely derived from weathering of minor carbonate occurrences in the riparian zone. The uphill catchment appeared limited by insufficient contact time of weathering agents and weatherable material. Further, alkalinity increased with decreasing permafrost extent. Thus, with climate change, alkalinity generation is expected to increase in this permafrost-degrading landscape.
Riverine alkalinity in the silicate-dominated headwater catchment at subarctic Iskorasfjellet,...
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