Articles | Volume 14, issue 8
https://doi.org/10.5194/bg-14-2069-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/bg-14-2069-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
24 Apr 2017
Research article |
| 24 Apr 2017
The nitrogen, carbon and greenhouse gas budget of a grazed, cut and fertilised temperate grassland
Stephanie K. Jones
CORRESPONDING AUTHOR
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Scotland's Rural College, King's Buildings, West Mains Road, Edinburgh,
EH9 3JG, UK
Carole Helfter
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Margaret Anderson
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Mhairi Coyle
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Claire Campbell
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Daniela Famulari
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Chiara Di Marco
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Netty van Dijk
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Y. Sim Tang
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Cairistiona F. E. Topp
Scotland's Rural College, King's Buildings, West Mains Road, Edinburgh,
EH9 3JG, UK
Ralf Kiese
Karlsruhe Institute of Technology, Institute for Meteorology and Climate
Research, Atmospheric Environmental Research (IMK-IFU), Kreuzeckbahnstr. 19, 82467
Garmisch-Partenkirchen, Germany
Reimo Kindler
Department of Waste Management and Environmental Research, Technische
Universität Berlin, Franklinstr. 29, 10587 Berlin, Germany
Jan Siemens
Chair of Soil Resources, Institute of Soil Science and Soil Conservation, iFZ Research Centre for BioSystems, Land Use and Nutrition,
Justus Liebig University Giessen, Heinrich-Buff-Ring 26–32, 35392 Giessen, Germany
Marion Schrumpf
Department for Biogeochemical Processes, Max Plank Institute for Biogeochemistry, Hans-Knöll-Str. 10, 07745
Jena, Germany
Klaus Kaiser
Soil Science and Soil Protection, Martin Luther University Halle-Wittenberg, Von-Seckendorff-Platz 3, 06120
Halle (Saale), Germany
Eiko Nemitz
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Peter E. Levy
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Robert M. Rees
Scotland's Rural College, King's Buildings, West Mains Road, Edinburgh,
EH9 3JG, UK
Mark A. Sutton
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
Ute M. Skiba
Centre for Ecology and Hydrology, Edinburgh, Bush Estate, Penicuik,
Midlothian, EH26 QB, UK
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Jasmin Fetzer, Emmanuel Frossard, Klaus Kaiser, and Frank Hagedorn
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Matthias Mauder, Andreas Ibrom, Luise Wanner, Frederik De Roo, Peter Brugger, Ralf Kiese, and Kim Pilegaard
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Turbulent flux measurements suffer from a general systematic underestimation. One reason for this bias is non-local transport by large-scale circulations. A recently developed model for this additional transport of sensible and latent energy is evaluated for three different test sites. Different options on how to apply this correction are presented, and the results are evaluated against independent measurements.
Mark F. Lunt, Alistair J. Manning, Grant Allen, Tim Arnold, Stéphane J.-B. Bauguitte, Hartmut Boesch, Anita L. Ganesan, Aoife Grant, Carole Helfter, Eiko Nemitz, Simon J. O'Doherty, Paul I. Palmer, Joseph R. Pitt, Chris Rennick, Daniel Say, Kieran M. Stanley, Ann R. Stavert, Dickon Young, and Matt Rigby
Atmos. Chem. Phys., 21, 16257–16276, https://doi.org/10.5194/acp-21-16257-2021, https://doi.org/10.5194/acp-21-16257-2021, 2021
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We present an evaluation of the UK's methane emissions between 2013 and 2020 using a network of tall tower measurement sites. We find emissions that are consistent in both magnitude and trend with the UK's reported emissions, with a declining trend driven by a decrease in emissions from England. The impact of various components of the modelling set-up on these findings are explored through a number of sensitivity studies.
Beth S. Nelson, Gareth J. Stewart, Will S. Drysdale, Mike J. Newland, Adam R. Vaughan, Rachel E. Dunmore, Pete M. Edwards, Alastair C. Lewis, Jacqueline F. Hamilton, W. Joe Acton, C. Nicholas Hewitt, Leigh R. Crilley, Mohammed S. Alam, Ülkü A. Şahin, David C. S. Beddows, William J. Bloss, Eloise Slater, Lisa K. Whalley, Dwayne E. Heard, James M. Cash, Ben Langford, Eiko Nemitz, Roberto Sommariva, Sam Cox, Shivani, Ranu Gadi, Bhola R. Gurjar, James R. Hopkins, Andrew R. Rickard, and James D. Lee
Atmos. Chem. Phys., 21, 13609–13630, https://doi.org/10.5194/acp-21-13609-2021, https://doi.org/10.5194/acp-21-13609-2021, 2021
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Ozone production at an urban site in Delhi is sensitive to volatile organic compound (VOC) concentrations, particularly those of the aromatic, monoterpene, and alkene VOC classes. The change in ozone production by varying atmospheric pollutants according to their sources, as defined in an emissions inventory, is investigated. The study suggests that reducing road transport emissions alone does not reduce reactive VOCs in the atmosphere enough to perturb an increase in ozone production.
Ernesto Reyes-Villegas, Upasana Panda, Eoghan Darbyshire, James M. Cash, Rutambhara Joshi, Ben Langford, Chiara F. Di Marco, Neil J. Mullinger, Mohammed S. Alam, Leigh R. Crilley, Daniel J. Rooney, W. Joe F. Acton, Will Drysdale, Eiko Nemitz, Michael Flynn, Aristeidis Voliotis, Gordon McFiggans, Hugh Coe, James Lee, C. Nicholas Hewitt, Mathew R. Heal, Sachin S. Gunthe, Tuhin K. Mandal, Bhola R. Gurjar, Shivani, Ranu Gadi, Siddhartha Singh, Vijay Soni, and James D. Allan
Atmos. Chem. Phys., 21, 11655–11667, https://doi.org/10.5194/acp-21-11655-2021, https://doi.org/10.5194/acp-21-11655-2021, 2021
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This paper shows the first multisite online measurements of PM1 in Delhi, India, with measurements over different seasons in Old Delhi and New Delhi in 2018. Organic aerosol (OA) source apportionment was performed using positive matrix factorisation (PMF). Traffic was the main primary aerosol source for both OAs and black carbon, seen with PMF and Aethalometer model analysis, indicating that control of primary traffic exhaust emissions would make a significant reduction to Delhi air pollution.
Kyle B. Delwiche, Sara Helen Knox, Avni Malhotra, Etienne Fluet-Chouinard, Gavin McNicol, Sarah Feron, Zutao Ouyang, Dario Papale, Carlo Trotta, Eleonora Canfora, You-Wei Cheah, Danielle Christianson, Ma. Carmelita R. Alberto, Pavel Alekseychik, Mika Aurela, Dennis Baldocchi, Sheel Bansal, David P. Billesbach, Gil Bohrer, Rosvel Bracho, Nina Buchmann, David I. Campbell, Gerardo Celis, Jiquan Chen, Weinan Chen, Housen Chu, Higo J. Dalmagro, Sigrid Dengel, Ankur R. Desai, Matteo Detto, Han Dolman, Elke Eichelmann, Eugenie Euskirchen, Daniela Famulari, Kathrin Fuchs, Mathias Goeckede, Sébastien Gogo, Mangaliso J. Gondwe, Jordan P. Goodrich, Pia Gottschalk, Scott L. Graham, Martin Heimann, Manuel Helbig, Carole Helfter, Kyle S. Hemes, Takashi Hirano, David Hollinger, Lukas Hörtnagl, Hiroki Iwata, Adrien Jacotot, Gerald Jurasinski, Minseok Kang, Kuno Kasak, John King, Janina Klatt, Franziska Koebsch, Ken W. Krauss, Derrick Y. F. Lai, Annalea Lohila, Ivan Mammarella, Luca Belelli Marchesini, Giovanni Manca, Jaclyn Hatala Matthes, Trofim Maximov, Lutz Merbold, Bhaskar Mitra, Timothy H. Morin, Eiko Nemitz, Mats B. Nilsson, Shuli Niu, Walter C. Oechel, Patricia Y. Oikawa, Keisuke Ono, Matthias Peichl, Olli Peltola, Michele L. Reba, Andrew D. Richardson, William Riley, Benjamin R. K. Runkle, Youngryel Ryu, Torsten Sachs, Ayaka Sakabe, Camilo Rey Sanchez, Edward A. Schuur, Karina V. R. Schäfer, Oliver Sonnentag, Jed P. Sparks, Ellen Stuart-Haëntjens, Cove Sturtevant, Ryan C. Sullivan, Daphne J. Szutu, Jonathan E. Thom, Margaret S. Torn, Eeva-Stiina Tuittila, Jessica Turner, Masahito Ueyama, Alex C. Valach, Rodrigo Vargas, Andrej Varlagin, Alma Vazquez-Lule, Joseph G. Verfaillie, Timo Vesala, George L. Vourlitis, Eric J. Ward, Christian Wille, Georg Wohlfahrt, Guan Xhuan Wong, Zhen Zhang, Donatella Zona, Lisamarie Windham-Myers, Benjamin Poulter, and Robert B. Jackson
Earth Syst. Sci. Data, 13, 3607–3689, https://doi.org/10.5194/essd-13-3607-2021, https://doi.org/10.5194/essd-13-3607-2021, 2021
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Methane is an important greenhouse gas, yet we lack knowledge about its global emissions and drivers. We present FLUXNET-CH4, a new global collection of methane measurements and a critical resource for the research community. We use FLUXNET-CH4 data to quantify the seasonality of methane emissions from freshwater wetlands, finding that methane seasonality varies strongly with latitude. Our new database and analysis will improve wetland model accuracy and inform greenhouse gas budgets.
Toprak Aslan, Olli Peltola, Andreas Ibrom, Eiko Nemitz, Üllar Rannik, and Ivan Mammarella
Atmos. Meas. Tech., 14, 5089–5106, https://doi.org/10.5194/amt-14-5089-2021, https://doi.org/10.5194/amt-14-5089-2021, 2021
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Vertical turbulent fluxes of gases measured by the eddy covariance (EC) technique are subject to high-frequency losses. There are different methods used to describe this low-pass filtering effect and to correct the measured fluxes. In this study, we analysed the systematic uncertainty related to this correction for various attenuation and signal-to-noise ratios. A new and robust transfer function method is finally proposed.
Olli Peltola, Toprak Aslan, Andreas Ibrom, Eiko Nemitz, Üllar Rannik, and Ivan Mammarella
Atmos. Meas. Tech., 14, 5071–5088, https://doi.org/10.5194/amt-14-5071-2021, https://doi.org/10.5194/amt-14-5071-2021, 2021
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Gas fluxes measured by the eddy covariance (EC) technique are subject to filtering due to non-ideal instrumentation. For linear first-order systems this filtering causes also a time lag between vertical wind speed and gas signal which is additional to the gas travel time in the sampling line. The effect of this additional time lag on EC fluxes is ignored in current EC data processing routines. Here we show that this oversight biases EC fluxes and hence propose an approach to rectify this bias.
James M. Cash, Ben Langford, Chiara Di Marco, Neil J. Mullinger, James Allan, Ernesto Reyes-Villegas, Ruthambara Joshi, Mathew R. Heal, W. Joe F. Acton, C. Nicholas Hewitt, Pawel K. Misztal, Will Drysdale, Tuhin K. Mandal, Shivani, Ranu Gadi, Bhola Ram Gurjar, and Eiko Nemitz
Atmos. Chem. Phys., 21, 10133–10158, https://doi.org/10.5194/acp-21-10133-2021, https://doi.org/10.5194/acp-21-10133-2021, 2021
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We present the first real-time composition of submicron particulate matter (PM1) in Old Delhi using high-resolution aerosol mass spectrometry. Seasonal analysis shows peak concentrations occur during the post-monsoon, and novel-tracers reveal the largest sources are a combination of local open and regional crop residue burning. Strong links between increased chloride aerosol concentrations and burning sources of PM1 suggest burning sources are responsible for the post-monsoon chloride peak.
Robbie Ramsay, Chiara F. Di Marco, Mathew R. Heal, Matthias Sörgel, Paulo Artaxo, Meinrat O. Andreae, and Eiko Nemitz
Biogeosciences, 18, 2809–2825, https://doi.org/10.5194/bg-18-2809-2021, https://doi.org/10.5194/bg-18-2809-2021, 2021
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The exchange of the gas ammonia between the atmosphere and the surface is an important biogeochemical process, but little is known of this exchange for certain ecosystems, such as the Amazon rainforest. This study took measurements of ammonia exchange over an Amazon rainforest site and subsequently modelled the observed deposition and emission patterns. We observed emissions of ammonia from the rainforest, which can be simulated accurately by using a canopy resistance modelling approach.
Julia Drewer, Melissa M. Leduning, Robert I. Griffiths, Tim Goodall, Peter E. Levy, Nicholas Cowan, Edward Comynn-Platt, Garry Hayman, Justin Sentian, Noreen Majalap, and Ute M. Skiba
Biogeosciences, 18, 1559–1575, https://doi.org/10.5194/bg-18-1559-2021, https://doi.org/10.5194/bg-18-1559-2021, 2021
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In Southeast Asia, oil palm plantations have largely replaced tropical forests. The impact of this shift in land use on greenhouse gas fluxes and soil microbial communities remains uncertain. We have found emission rates of the potent greenhouse gas nitrous oxide on mineral soil to be higher from oil palm plantations than logged forest over a 2-year study and concluded that emissions have increased over the last 42 years in Sabah, with the proportion of emissions from plantations increasing.
Gareth J. Stewart, Beth S. Nelson, W. Joe F. Acton, Adam R. Vaughan, Naomi J. Farren, James R. Hopkins, Martyn W. Ward, Stefan J. Swift, Rahul Arya, Arnab Mondal, Ritu Jangirh, Sakshi Ahlawat, Lokesh Yadav, Sudhir K. Sharma, Siti S. M. Yunus, C. Nicholas Hewitt, Eiko Nemitz, Neil Mullinger, Ranu Gadi, Lokesh K. Sahu, Nidhi Tripathi, Andrew R. Rickard, James D. Lee, Tuhin K. Mandal, and Jacqueline F. Hamilton
Atmos. Chem. Phys., 21, 2407–2426, https://doi.org/10.5194/acp-21-2407-2021, https://doi.org/10.5194/acp-21-2407-2021, 2021
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Biomass burning releases many lower-molecular-weight organic species which are difficult to analyse but important for the formation of organic aerosol. This study examined a new high-resolution technique to better characterise these difficult-to-analyse organic components. Some burning sources analysed in this study, such as cow dung cake and municipal solid waste, released extremely complex mixtures containing many thousands of different lower-volatility organic compounds.
Gareth J. Stewart, W. Joe F. Acton, Beth S. Nelson, Adam R. Vaughan, James R. Hopkins, Rahul Arya, Arnab Mondal, Ritu Jangirh, Sakshi Ahlawat, Lokesh Yadav, Sudhir K. Sharma, Rachel E. Dunmore, Siti S. M. Yunus, C. Nicholas Hewitt, Eiko Nemitz, Neil Mullinger, Ranu Gadi, Lokesh K. Sahu, Nidhi Tripathi, Andrew R. Rickard, James D. Lee, Tuhin K. Mandal, and Jacqueline F. Hamilton
Atmos. Chem. Phys., 21, 2383–2406, https://doi.org/10.5194/acp-21-2383-2021, https://doi.org/10.5194/acp-21-2383-2021, 2021
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Biomass burning is a major source of trace gases to the troposphere; however, the composition and quantity of emissions vary greatly between different fuel types. This work provided near-total quantitation of non-methane volatile organic compounds from combustion of biofuels from India. Emissions from cow dung cake combustion were significantly larger than conventional fuelwood combustion, potentially indicating that this source has a disproportionately large impact on regional air quality.
Marion Schrumpf, Klaus Kaiser, Allegra Mayer, Günter Hempel, and Susan Trumbore
Biogeosciences, 18, 1241–1257, https://doi.org/10.5194/bg-18-1241-2021, https://doi.org/10.5194/bg-18-1241-2021, 2021
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A large amount of organic carbon (OC) in soil is protected against decay by bonding to minerals. We studied the release of mineral-bonded OC by NaF–NaOH extraction and H2O2 oxidation. Unexpectedly, extraction and oxidation removed mineral-bonded OC at roughly constant portions and of similar age distributions, irrespective of mineral composition, land use, and soil depth. The results suggest uniform modes of interactions between OC and minerals across soils in quasi-steady state with inputs.
Kirsty C. Paterson, Joanna M. Cloy, Robert M. Rees, Elizabeth M. Baggs, Hugh Martineau, Dario Fornara, Andrew J. Macdonald, and Sarah Buckingham
Biogeosciences, 18, 605–620, https://doi.org/10.5194/bg-18-605-2021, https://doi.org/10.5194/bg-18-605-2021, 2021
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Soil organic carbon sequestration across agroecosystems worldwide can contribute to mitigating the effects of climate change by reducing levels of atmospheric carbon dioxide. The maximum carbon sequestration potential is frequently estimated using the linear regression equation developed by Hassink (1997). This work examines the suitability of this equation for use in grasslands across the United Kingdom. The results highlight the need to ensure the fit of equations to the soils being studied.
Y. Sim Tang, Chris R. Flechard, Ulrich Dämmgen, Sonja Vidic, Vesna Djuricic, Marta Mitosinkova, Hilde T. Uggerud, Maria J. Sanz, Ivan Simmons, Ulrike Dragosits, Eiko Nemitz, Marsailidh Twigg, Netty van Dijk, Yannick Fauvel, Francisco Sanz, Martin Ferm, Cinzia Perrino, Maria Catrambone, David Leaver, Christine F. Braban, J. Neil Cape, Mathew R. Heal, and Mark A. Sutton
Atmos. Chem. Phys., 21, 875–914, https://doi.org/10.5194/acp-21-875-2021, https://doi.org/10.5194/acp-21-875-2021, 2021
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The DELTA® approach provided speciated, monthly data on reactive gases (NH3, HNO3, SO2, HCl) and aerosols (NH4+, NO3−, SO42−, Cl−, Na+) across Europe (2006–2010). Differences in spatial and temporal concentrations and patterns between geographic regions and four ecosystem types were captured. NH3 and NH4NO3 were dominant components, highlighting their growing relative importance in ecosystem impacts (acidification, eutrophication) and human health effects (NH3 as a precursor to PM2.5) in Europe.
Rutambhara Joshi, Dantong Liu, Eiko Nemitz, Ben Langford, Neil Mullinger, Freya Squires, James Lee, Yunfei Wu, Xiaole Pan, Pingqing Fu, Simone Kotthaus, Sue Grimmond, Qiang Zhang, Ruili Wu, Oliver Wild, Michael Flynn, Hugh Coe, and James Allan
Atmos. Chem. Phys., 21, 147–162, https://doi.org/10.5194/acp-21-147-2021, https://doi.org/10.5194/acp-21-147-2021, 2021
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Black carbon (BC) is a component of particulate matter which has significant effects on climate and human health. Sources of BC include biomass burning, transport, industry and domestic cooking and heating. In this study, we measured BC emissions in Beijing, finding a dominance of traffic emissions over all other sources. The quantitative method presented here has benefits for revising widely used emissions inventories and for understanding BC sources with impacts on air quality and climate.
Robbie Ramsay, Chiara F. Di Marco, Matthias Sörgel, Mathew R. Heal, Samara Carbone, Paulo Artaxo, Alessandro C. de Araùjo, Marta Sá, Christopher Pöhlker, Jost Lavric, Meinrat O. Andreae, and Eiko Nemitz
Atmos. Chem. Phys., 20, 15551–15584, https://doi.org/10.5194/acp-20-15551-2020, https://doi.org/10.5194/acp-20-15551-2020, 2020
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The Amazon rainforest is a unique
laboratoryto study the processes which govern the exchange of gases and aerosols to and from the atmosphere. This study investigated these processes by measuring the atmospheric concentrations of trace gases and particles at the Amazon Tall Tower Observatory. We found that the long-range transport of pollutants can affect the atmospheric composition above the Amazon rainforest and that the gases ammonia and nitrous acid can be emitted from the rainforest.
W. Joe F. Acton, Zhonghui Huang, Brian Davison, Will S. Drysdale, Pingqing Fu, Michael Hollaway, Ben Langford, James Lee, Yanhui Liu, Stefan Metzger, Neil Mullinger, Eiko Nemitz, Claire E. Reeves, Freya A. Squires, Adam R. Vaughan, Xinming Wang, Zhaoyi Wang, Oliver Wild, Qiang Zhang, Yanli Zhang, and C. Nicholas Hewitt
Atmos. Chem. Phys., 20, 15101–15125, https://doi.org/10.5194/acp-20-15101-2020, https://doi.org/10.5194/acp-20-15101-2020, 2020
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Air quality in Beijing is of concern to both policy makers and the general public. In order to address concerns about air quality it is vital that the sources of atmospheric pollutants are understood. This work presents the first top-down measurement of volatile organic compound (VOC) emissions in Beijing. These measurements are used to evaluate the emissions inventory and assess the impact of VOC emission from the city centre on atmospheric chemistry.
Benjamin Fersch, Till Francke, Maik Heistermann, Martin Schrön, Veronika Döpper, Jannis Jakobi, Gabriele Baroni, Theresa Blume, Heye Bogena, Christian Budach, Tobias Gränzig, Michael Förster, Andreas Güntner, Harrie-Jan Hendricks Franssen, Mandy Kasner, Markus Köhli, Birgit Kleinschmit, Harald Kunstmann, Amol Patil, Daniel Rasche, Lena Scheiffele, Ulrich Schmidt, Sandra Szulc-Seyfried, Jannis Weimar, Steffen Zacharias, Marek Zreda, Bernd Heber, Ralf Kiese, Vladimir Mares, Hannes Mollenhauer, Ingo Völksch, and Sascha Oswald
Earth Syst. Sci. Data, 12, 2289–2309, https://doi.org/10.5194/essd-12-2289-2020, https://doi.org/10.5194/essd-12-2289-2020, 2020
Freya A. Squires, Eiko Nemitz, Ben Langford, Oliver Wild, Will S. Drysdale, W. Joe F. Acton, Pingqing Fu, C. Sue B. Grimmond, Jacqueline F. Hamilton, C. Nicholas Hewitt, Michael Hollaway, Simone Kotthaus, James Lee, Stefan Metzger, Natchaya Pingintha-Durden, Marvin Shaw, Adam R. Vaughan, Xinming Wang, Ruili Wu, Qiang Zhang, and Yanli Zhang
Atmos. Chem. Phys., 20, 8737–8761, https://doi.org/10.5194/acp-20-8737-2020, https://doi.org/10.5194/acp-20-8737-2020, 2020
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Significant air quality problems exist in megacities like Beijing, China. To manage air pollution, legislators need a clear understanding of pollutant emissions. However, emissions inventories have large uncertainties, and reliable field measurements of pollutant emissions are required to constrain them. This work presents the first measurements of traffic-dominated emissions in Beijing which suggest that inventories overestimate these emissions in the region during both winter and summer.
Hannah L. Walker, Mathew R. Heal, Christine F. Braban, Mhairi Coyle, Sarah R. Leeson, Ivan Simmons, Matthew R. Jones, Richard Kift, and Marsailidh M. Twigg
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2020-219, https://doi.org/10.5194/amt-2020-219, 2020
Revised manuscript not accepted
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Quantifying local photolysis rates are critical to understanding local air quality. We present the first year of a long-term filter radiometer measurement dataset in the UK (Auchencorth Moss, SE Scotland), and demonstrate the potential application of this data to account for variations in local meteorology (e.g. clouds and aerosols) in atmospheric models, which otherwise increase computational cost. The scientific and policy value of these measurements are also emphasised.
Chris R. Flechard, Andreas Ibrom, Ute M. Skiba, Wim de Vries, Marcel van Oijen, David R. Cameron, Nancy B. Dise, Janne F. J. Korhonen, Nina Buchmann, Arnaud Legout, David Simpson, Maria J. Sanz, Marc Aubinet, Denis Loustau, Leonardo Montagnani, Johan Neirynck, Ivan A. Janssens, Mari Pihlatie, Ralf Kiese, Jan Siemens, André-Jean Francez, Jürgen Augustin, Andrej Varlagin, Janusz Olejnik, Radosław Juszczak, Mika Aurela, Daniel Berveiller, Bogdan H. Chojnicki, Ulrich Dämmgen, Nicolas Delpierre, Vesna Djuricic, Julia Drewer, Eric Dufrêne, Werner Eugster, Yannick Fauvel, David Fowler, Arnoud Frumau, André Granier, Patrick Gross, Yannick Hamon, Carole Helfter, Arjan Hensen, László Horváth, Barbara Kitzler, Bart Kruijt, Werner L. Kutsch, Raquel Lobo-do-Vale, Annalea Lohila, Bernard Longdoz, Michal V. Marek, Giorgio Matteucci, Marta Mitosinkova, Virginie Moreaux, Albrecht Neftel, Jean-Marc Ourcival, Kim Pilegaard, Gabriel Pita, Francisco Sanz, Jan K. Schjoerring, Maria-Teresa Sebastià, Y. Sim Tang, Hilde Uggerud, Marek Urbaniak, Netty van Dijk, Timo Vesala, Sonja Vidic, Caroline Vincke, Tamás Weidinger, Sophie Zechmeister-Boltenstern, Klaus Butterbach-Bahl, Eiko Nemitz, and Mark A. Sutton
Biogeosciences, 17, 1583–1620, https://doi.org/10.5194/bg-17-1583-2020, https://doi.org/10.5194/bg-17-1583-2020, 2020
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Experimental evidence from a network of 40 monitoring sites in Europe suggests that atmospheric nitrogen deposition to forests and other semi-natural vegetation impacts the carbon sequestration rates in ecosystems, as well as the net greenhouse gas balance including other greenhouse gases such as nitrous oxide and methane. Excess nitrogen deposition in polluted areas also leads to other environmental impacts such as nitrogen leaching to groundwater and other pollutant gaseous emissions.
Chris R. Flechard, Marcel van Oijen, David R. Cameron, Wim de Vries, Andreas Ibrom, Nina Buchmann, Nancy B. Dise, Ivan A. Janssens, Johan Neirynck, Leonardo Montagnani, Andrej Varlagin, Denis Loustau, Arnaud Legout, Klaudia Ziemblińska, Marc Aubinet, Mika Aurela, Bogdan H. Chojnicki, Julia Drewer, Werner Eugster, André-Jean Francez, Radosław Juszczak, Barbara Kitzler, Werner L. Kutsch, Annalea Lohila, Bernard Longdoz, Giorgio Matteucci, Virginie Moreaux, Albrecht Neftel, Janusz Olejnik, Maria J. Sanz, Jan Siemens, Timo Vesala, Caroline Vincke, Eiko Nemitz, Sophie Zechmeister-Boltenstern, Klaus Butterbach-Bahl, Ute M. Skiba, and Mark A. Sutton
Biogeosciences, 17, 1621–1654, https://doi.org/10.5194/bg-17-1621-2020, https://doi.org/10.5194/bg-17-1621-2020, 2020
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Nitrogen deposition from the atmosphere to unfertilized terrestrial vegetation such as forests can increase carbon dioxide uptake and favour carbon sequestration by ecosystems. However the data from observational networks are difficult to interpret in terms of a carbon-to-nitrogen response, because there are a number of other confounding factors, such as climate, soil physical properties and fertility, and forest age. We propose a model-based method to untangle the different influences.
Lin Yu, Bernhard Ahrens, Thomas Wutzler, Marion Schrumpf, and Sönke Zaehle
Geosci. Model Dev., 13, 783–803, https://doi.org/10.5194/gmd-13-783-2020, https://doi.org/10.5194/gmd-13-783-2020, 2020
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In this paper, we have developed a new soil organic carbon model that describes the formation and turnover of soil organic matter in a more mechanistic manner. With this model, we are able to better represent how microorganisms and nutrient processes influence the below-ground carbon storage and better explain some observed features of soil organic matter. We hope this model can increase our confidence in predictions of future climate change, particularly on how soil can mitigate the process.
Nicholas Cowan, Peter Levy, Andrea Moring, Ivan Simmons, Colin Bache, Amy Stephens, Joana Marinheiro, Jocelyn Brichet, Ling Song, Amy Pickard, Connie McNeill, Roseanne McDonald, Juliette Maire, Benjamin Loubet, Polina Voylokov, Mark Sutton, and Ute Skiba
Biogeosciences, 16, 4731–4745, https://doi.org/10.5194/bg-16-4731-2019, https://doi.org/10.5194/bg-16-4731-2019, 2019
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Commonly used nitrogen fertilisers, ammonium nitrate, urea and urea coated with a urease inhibitor, were applied to experimental plots. Fertilisation with ammonium nitrate supported the largest yields but also resulted in the largest nitrous oxide emissions. Urea was the largest emitter of ammonia. The coated urea did not significantly increase yields; however, ammonia emissions were substantially smaller than urea. The coated urea was the best environmentally but is economically unattractive.
Rupert Holzinger, W. Joe F. Acton, William J. Bloss, Martin Breitenlechner, Leigh R. Crilley, Sébastien Dusanter, Marc Gonin, Valerie Gros, Frank N. Keutsch, Astrid Kiendler-Scharr, Louisa J. Kramer, Jordan E. Krechmer, Baptiste Languille, Nadine Locoge, Felipe Lopez-Hilfiker, Dušan Materić, Sergi Moreno, Eiko Nemitz, Lauriane L. J. Quéléver, Roland Sarda Esteve, Stéphane Sauvage, Simon Schallhart, Roberto Sommariva, Ralf Tillmann, Sergej Wedel, David R. Worton, Kangming Xu, and Alexander Zaytsev
Atmos. Meas. Tech., 12, 6193–6208, https://doi.org/10.5194/amt-12-6193-2019, https://doi.org/10.5194/amt-12-6193-2019, 2019
Erkan Ibraim, Benjamin Wolf, Eliza Harris, Rainer Gasche, Jing Wei, Longfei Yu, Ralf Kiese, Sarah Eggleston, Klaus Butterbach-Bahl, Matthias Zeeman, Béla Tuzson, Lukas Emmenegger, Johan Six, Stephan Henne, and Joachim Mohn
Biogeosciences, 16, 3247–3266, https://doi.org/10.5194/bg-16-3247-2019, https://doi.org/10.5194/bg-16-3247-2019, 2019
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Nitrous oxide (N2O) is an important greenhouse gas and the major stratospheric ozone-depleting substance; therefore, mitigation of anthropogenic N2O emissions is needed. To trace N2O-emitting source processes, in this study, we observed N2O isotopocules above an intensively managed grassland research site with a recently developed laser spectroscopy method. Our results indicate that the domain of denitrification or nitrifier denitrification was the major N2O source.
Zongbo Shi, Tuan Vu, Simone Kotthaus, Roy M. Harrison, Sue Grimmond, Siyao Yue, Tong Zhu, James Lee, Yiqun Han, Matthias Demuzere, Rachel E. Dunmore, Lujie Ren, Di Liu, Yuanlin Wang, Oliver Wild, James Allan, W. Joe Acton, Janet Barlow, Benjamin Barratt, David Beddows, William J. Bloss, Giulia Calzolai, David Carruthers, David C. Carslaw, Queenie Chan, Lia Chatzidiakou, Yang Chen, Leigh Crilley, Hugh Coe, Tie Dai, Ruth Doherty, Fengkui Duan, Pingqing Fu, Baozhu Ge, Maofa Ge, Daobo Guan, Jacqueline F. Hamilton, Kebin He, Mathew Heal, Dwayne Heard, C. Nicholas Hewitt, Michael Hollaway, Min Hu, Dongsheng Ji, Xujiang Jiang, Rod Jones, Markus Kalberer, Frank J. Kelly, Louisa Kramer, Ben Langford, Chun Lin, Alastair C. Lewis, Jie Li, Weijun Li, Huan Liu, Junfeng Liu, Miranda Loh, Keding Lu, Franco Lucarelli, Graham Mann, Gordon McFiggans, Mark R. Miller, Graham Mills, Paul Monk, Eiko Nemitz, Fionna O'Connor, Bin Ouyang, Paul I. Palmer, Carl Percival, Olalekan Popoola, Claire Reeves, Andrew R. Rickard, Longyi Shao, Guangyu Shi, Dominick Spracklen, David Stevenson, Yele Sun, Zhiwei Sun, Shu Tao, Shengrui Tong, Qingqing Wang, Wenhua Wang, Xinming Wang, Xuejun Wang, Zifang Wang, Lianfang Wei, Lisa Whalley, Xuefang Wu, Zhijun Wu, Pinhua Xie, Fumo Yang, Qiang Zhang, Yanli Zhang, Yuanhang Zhang, and Mei Zheng
Atmos. Chem. Phys., 19, 7519–7546, https://doi.org/10.5194/acp-19-7519-2019, https://doi.org/10.5194/acp-19-7519-2019, 2019
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APHH-Beijing is a collaborative international research programme to study the sources, processes and health effects of air pollution in Beijing. This introduction to the special issue provides an overview of (i) the APHH-Beijing programme, (ii) the measurement and modelling activities performed as part of it and (iii) the air quality and meteorological conditions during joint intensive field campaigns as a core activity within APHH-Beijing.
Richard K. F. Nair, Kendalynn A. Morris, Martin Hertel, Yunpeng Luo, Gerardo Moreno, Markus Reichstein, Marion Schrumpf, and Mirco Migliavacca
Biogeosciences, 16, 1883–1901, https://doi.org/10.5194/bg-16-1883-2019, https://doi.org/10.5194/bg-16-1883-2019, 2019
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We investigated how nutrient availability affects seasonal timing of root growth and death in a Spanish savanna, adapted to a long summer drought. We found that nitrogen (N) additions led to more root biomass but number of roots was higher with N and phosphorus together. These effects were strongly affected by the time of year. In autumn root growth occurred after leaf production. This has implications for how we understand biomass production and carbon uptake in these systems.
Vasileios Myrgiotis, Mathew Williams, Robert M. Rees, and Cairistiona F. E. Topp
Biogeosciences, 16, 1641–1655, https://doi.org/10.5194/bg-16-1641-2019, https://doi.org/10.5194/bg-16-1641-2019, 2019
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This study focuses on a northwestern European cropland region and shows that the type of crop growing on a soil has notable effects on the emission of nitrous oxide (N2O – a greenhouse gas) from that soil. It was found that N2O emissions from soils under oilseed cultivation are significantly higher than soils under cereal cultivation. This variation is mostly explained by the fact that oilseeds require more nitrogen (fertiliser) than cereals, especially at early crop growth stages.
Emily D. White, Matthew Rigby, Mark F. Lunt, T. Luke Smallman, Edward Comyn-Platt, Alistair J. Manning, Anita L. Ganesan, Simon O'Doherty, Ann R. Stavert, Kieran Stanley, Mathew Williams, Peter Levy, Michel Ramonet, Grant L. Forster, Andrew C. Manning, and Paul I. Palmer
Atmos. Chem. Phys., 19, 4345–4365, https://doi.org/10.5194/acp-19-4345-2019, https://doi.org/10.5194/acp-19-4345-2019, 2019
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Understanding carbon dioxide (CO2) fluxes from the terrestrial biosphere on a national scale is important for evaluating land use strategies to mitigate climate change. We estimate emissions of CO2 from the UK biosphere using atmospheric data in a top-down approach. Our findings show that bottom-up estimates from models of biospheric fluxes overestimate the amount of CO2 uptake in summer. This suggests these models wrongly estimate or omit key processes, e.g. land disturbance due to harvest.
Carole Helfter, Neil Mullinger, Massimo Vieno, Simon O'Doherty, Michel Ramonet, Paul I. Palmer, and Eiko Nemitz
Atmos. Chem. Phys., 19, 3043–3063, https://doi.org/10.5194/acp-19-3043-2019, https://doi.org/10.5194/acp-19-3043-2019, 2019
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We present a novel approach to estimate the annual budgets of carbon dioxide (881.0 ± 128.5 Tg) and methane (2.55 ± 0.48 Tg) of the British Isles from shipborne measurements taken over a 3-year period (2015–2017). This study brings independent verification of the emission budgets estimated using alternative products and investigates the seasonality of these emissions, which is usually not possible.
Rongting Xu, Hanqin Tian, Shufen Pan, Shree R. S. Dangal, Jian Chen, Jinfeng Chang, Yonglong Lu, Ute Maria Skiba, Francesco N. Tubiello, and Bowen Zhang
Earth Syst. Sci. Data, 11, 175–187, https://doi.org/10.5194/essd-11-175-2019, https://doi.org/10.5194/essd-11-175-2019, 2019
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We provide three gridded datasets of synthetic nitrogen (N) fertilizer and manure N inputs in global pastures and rangelands at a resolution of 0.5° × 0.5° for the period 1860–2016 (i.e., annual manure N deposition (by grazing animals) rate, synthetic N fertilizer use rate and manure N application rate). These three datasets could fill data gaps of N inputs in global and regional grasslands and serve as input drivers for earth system models.
Friederike Gerschlauer, Gustavo Saiz, David Schellenberger Costa, Michael Kleyer, Michael Dannenmann, and Ralf Kiese
Biogeosciences, 16, 409–424, https://doi.org/10.5194/bg-16-409-2019, https://doi.org/10.5194/bg-16-409-2019, 2019
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Mount Kilimanjaro is an iconic environmental asset under serious threat due to increasing human pressures and climate change constraints. We studied variations in the stable isotopic composition of carbon and nitrogen in plant, litter, and soil material sampled along a strong land-use and altitudinal gradient. Our results show that, besides management, increasing temperatures in a changing climate may promote carbon and nitrogen losses, thus altering the stability of Kilimanjaro ecosystems.
Angelo Finco, Mhairi Coyle, Eiko Nemitz, Riccardo Marzuoli, Maria Chiesa, Benjamin Loubet, Silvano Fares, Eugenio Diaz-Pines, Rainer Gasche, and Giacomo Gerosa
Atmos. Chem. Phys., 18, 17945–17961, https://doi.org/10.5194/acp-18-17945-2018, https://doi.org/10.5194/acp-18-17945-2018, 2018
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A 1-month field campaign of ozone (O3) flux measurements along a five-level vertical profile of a mature broadleaf forest highlighted that the biosphere–atmosphere exchange of this pollutant is modulated by complex diel dynamics occurring within and below the canopy. The canopy removed nearly 80 % of the O3 deposited to the forest; only a minor part was removed by the soil and the understorey (2 %), while the remaining 18.2 % was removed by chemical reactions with NO mostly emitted from soil.
Robbie Ramsay, Chiara F. Di Marco, Mathew R. Heal, Marsailidh M. Twigg, Nicholas Cowan, Matthew R. Jones, Sarah R. Leeson, William J. Bloss, Louisa J. Kramer, Leigh Crilley, Matthias Sörgel, Meinrat Andreae, and Eiko Nemitz
Atmos. Chem. Phys., 18, 16953–16978, https://doi.org/10.5194/acp-18-16953-2018, https://doi.org/10.5194/acp-18-16953-2018, 2018
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Understanding the impact of agricultural activities on the atmosphere requires more measurements of inorganic trace gases and associated aerosol counterparts. This research presents 1 month of measurements above agricultural grassland during a period of fertiliser application. It was found that emissions of the important trace gases ammonia and nitrous acid peaked after fertiliser use and that the velocity at which the measured aerosols were deposited was dependent upon their size.
Y. Sim Tang, Christine F. Braban, Ulrike Dragosits, Ivan Simmons, David Leaver, Netty van Dijk, Janet Poskitt, Sarah Thacker, Manisha Patel, Heather Carter, M. Glória Pereira, Patrick O. Keenan, Alan Lawlor, Christopher Conolly, Keith Vincent, Mathew R. Heal, and Mark A. Sutton
Atmos. Chem. Phys., 18, 16293–16324, https://doi.org/10.5194/acp-18-16293-2018, https://doi.org/10.5194/acp-18-16293-2018, 2018
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A unique long-term dataset (1999–2015) of atmospheric gases (HNO3, SO2, HCl, NH3) and aerosol (NO3-, SO42-, Cl-, NH4+, Na+, Ca2+, Mg2+) from two integrated UK networks (>12 sites) was analysed to assess spatial, temporal, and long-term trends. A change in particulate phase from (NH4)2SO4 to NH4NO3 is seen, with indications that a larger fraction of the reduced and oxidized N is remaining in the gas phase. Key pollutant events captured highlight influence of trans-boundary transport into the UK.
Paul I. Palmer, Simon O'Doherty, Grant Allen, Keith Bower, Hartmut Bösch, Martyn P. Chipperfield, Sarah Connors, Sandip Dhomse, Liang Feng, Douglas P. Finch, Martin W. Gallagher, Emanuel Gloor, Siegfried Gonzi, Neil R. P. Harris, Carole Helfter, Neil Humpage, Brian Kerridge, Diane Knappett, Roderic L. Jones, Michael Le Breton, Mark F. Lunt, Alistair J. Manning, Stephan Matthiesen, Jennifer B. A. Muller, Neil Mullinger, Eiko Nemitz, Sebastian O'Shea, Robert J. Parker, Carl J. Percival, Joseph Pitt, Stuart N. Riddick, Matthew Rigby, Harjinder Sembhi, Richard Siddans, Robert L. Skelton, Paul Smith, Hannah Sonderfeld, Kieran Stanley, Ann R. Stavert, Angelina Wenger, Emily White, Christopher Wilson, and Dickon Young
Atmos. Chem. Phys., 18, 11753–11777, https://doi.org/10.5194/acp-18-11753-2018, https://doi.org/10.5194/acp-18-11753-2018, 2018
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This paper provides an overview of the Greenhouse gAs Uk and Global Emissions (GAUGE) experiment. GAUGE was designed to quantify nationwide GHG emissions of the UK, bringing together measurements and atmospheric transport models. This novel experiment is the first of its kind. We anticipate it will inform the blueprint for countries that are building a measurement infrastructure in preparation for global stocktakes, which are a key part of the Paris Agreement.
Antonia Zieger, Klaus Kaiser, Pedro Ríos Guayasamín, and Martin Kaupenjohann
Biogeosciences, 15, 2743–2760, https://doi.org/10.5194/bg-15-2743-2018, https://doi.org/10.5194/bg-15-2743-2018, 2018
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We tested a current theory, which proposes an upper limit for organic carbon (OC) stocks independent of increasing carbon input for a soil with already large OC stocks. The soil received a large additional carbon input as sawdust. In response, only the OC stock in 25–50 cm depth increased significantly. We assume, that due to saturation in 0–25 cm, added OC migrates downwards and becomes retained in 25–50 cm. This indicates the possibility to sustainably increase already large OC stocks further.
Silvia Bucci, Paolo Cristofanelli, Stefano Decesari, Angela Marinoni, Silvia Sandrini, Johannes Größ, Alfred Wiedensohler, Chiara F. Di Marco, Eiko Nemitz, Francesco Cairo, Luca Di Liberto, and Federico Fierli
Atmos. Chem. Phys., 18, 5371–5389, https://doi.org/10.5194/acp-18-5371-2018, https://doi.org/10.5194/acp-18-5371-2018, 2018
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This paper analyses some of the processes affecting PM levels over the Po Valley, one of the most polluted regions of Europe, during the 2012 summer campaigns. Under conditions of air transport from the Sahara, data show that desert dust can rapidly penetrate into the lower atmosphere, directly affecting the PM concentration at the ground. Processes of particles growth in high relative humidity and uplift of local soil particles, potentially affecting PM level, are also analysed.
Riinu Ots, Mathew R. Heal, Dominique E. Young, Leah R. Williams, James D. Allan, Eiko Nemitz, Chiara Di Marco, Anais Detournay, Lu Xu, Nga L. Ng, Hugh Coe, Scott C. Herndon, Ian A. Mackenzie, David C. Green, Jeroen J. P. Kuenen, Stefan Reis, and Massimo Vieno
Atmos. Chem. Phys., 18, 4497–4518, https://doi.org/10.5194/acp-18-4497-2018, https://doi.org/10.5194/acp-18-4497-2018, 2018
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The main hypothesis of this paper is that people who live in large cities in the UK disobey the
smoke control lawas it has not been actively enforced for decades now. However, the use of wood in residential heating has increased, partly due to renewable energy targets, but also for discretionary (i.e. pleasant fireplaces) reasons. Our study is based mainly in London, but similar struggles with urban air quality due to residential wood and coal burning are seen in other major European cities.
Marta Camino-Serrano, Bertrand Guenet, Sebastiaan Luyssaert, Philippe Ciais, Vladislav Bastrikov, Bruno De Vos, Bert Gielen, Gerd Gleixner, Albert Jornet-Puig, Klaus Kaiser, Dolly Kothawala, Ronny Lauerwald, Josep Peñuelas, Marion Schrumpf, Sara Vicca, Nicolas Vuichard, David Walmsley, and Ivan A. Janssens
Geosci. Model Dev., 11, 937–957, https://doi.org/10.5194/gmd-11-937-2018, https://doi.org/10.5194/gmd-11-937-2018, 2018
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Global models generally oversimplify the representation of soil organic carbon (SOC), and thus its response to global warming remains uncertain. We present the new soil module ORCHIDEE-SOM, within the global model ORCHIDEE, that refines the representation of SOC dynamics and includes the dissolved organic carbon (DOC) processes. The model is able to reproduce SOC stocks and DOC concentrations in four different ecosystems, opening an opportunity for improved predictions of SOC in global models.
Peter Levy, Marcel van Oijen, Gwen Buys, and Sam Tomlinson
Biogeosciences, 15, 1497–1513, https://doi.org/10.5194/bg-15-1497-2018, https://doi.org/10.5194/bg-15-1497-2018, 2018
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We present a new method for estimating land-use change using a Bayesian data assimilation approach. This allows us to constrain estimates of gross land-use change with reliable national-scale census data whilst retaining the information available from several other sources. This includes detailed spatial data; further data sources, such as new satellites, could easily be added in future. Uncertainty is propagated appropriately into the output.
Fortune Faith Gomo, Christopher Macleod, John Rowan, Jagadeesh Yeluripati, and Kairsty Topp
Proc. IAHS, 376, 15–23, https://doi.org/10.5194/piahs-376-15-2018, https://doi.org/10.5194/piahs-376-15-2018, 2018
Yuk S. Tang, Christine F. Braban, Ulrike Dragosits, Anthony J. Dore, Ivan Simmons, Netty van Dijk, Janet Poskitt, Gloria Dos Santos Pereira, Patrick O. Keenan, Christopher Conolly, Keith Vincent, Rognvald I. Smith, Mathew R. Heal, and Mark A. Sutton
Atmos. Chem. Phys., 18, 705–733, https://doi.org/10.5194/acp-18-705-2018, https://doi.org/10.5194/acp-18-705-2018, 2018
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A unique long-term dataset of NH3 and NH4+ data from the NAMN is used to assess spatial, seasonal and long-term variability across the UK. NH3 is spatially variable, with distinct temporal profiles according to source types. NH4+ is spatially smoother, with peak concentrations in spring from long-range transport. Decrease in NH3 is smaller than emissions, but NH4+ decreased faster than NH3, due to a shift from stable (NH4)2SO4 to semi-volatile NH4NO3, increasing the atmospheric lifetime of NH3.
Sarah R. Leeson, Peter E. Levy, Netty van Dijk, Julia Drewer, Sophie Robinson, Matthew R. Jones, John Kentisbeer, Ian Washbourne, Mark A. Sutton, and Lucy J. Sheppard
Biogeosciences, 14, 5753–5764, https://doi.org/10.5194/bg-14-5753-2017, https://doi.org/10.5194/bg-14-5753-2017, 2017
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Nitrogen deposition was experimentally increased on a Scottish peat bog over a period of 13 years (2002–2015), simulating pollution from agricultural and fossil-fuel sources. We measured emissions of the greenhouse gas, nitrous oxide (N2O), in response to the increased nitrogen input. In the plots treated with ammonium and nitrate solution, no response was seen. Areas subjected to high ammonia emitted more N2O than expected. Differences were related to impacts on the vegetation.
Ben Langford, James Cash, W. Joe F. Acton, Amy C. Valach, C. Nicholas Hewitt, Silvano Fares, Ignacio Goded, Carsten Gruening, Emily House, Athina-Cerise Kalogridis, Valérie Gros, Richard Schafers, Rick Thomas, Mark Broadmeadow, and Eiko Nemitz
Biogeosciences, 14, 5571–5594, https://doi.org/10.5194/bg-14-5571-2017, https://doi.org/10.5194/bg-14-5571-2017, 2017
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Isoprene flux measurements made above five European oak forests were reviewed to generate new emission potentials. Six variations of the Guenther algorithms were inverted to back out time series of isoprene emission potential, and then an “average” emission potential was determined using one of four commonly used approaches. Our results show that emission potentials can vary by up to a factor of 4 and highlight the need for the community to now harmonize their approach to reduce uncertainty.
Andrea Móring, Massimo Vieno, Ruth M. Doherty, Celia Milford, Eiko Nemitz, Marsailidh M. Twigg, László Horváth, and Mark A. Sutton
Biogeosciences, 14, 4161–4193, https://doi.org/10.5194/bg-14-4161-2017, https://doi.org/10.5194/bg-14-4161-2017, 2017
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This study describes and evaluates a new ammonia (NH3) exchange model for grazed fields (GAG_field). GAG_field is able to simulate the main features of the observed NH3 fluxes. A sensitivity analysis for the non-meteorological model parameters showed that the sensitivity of the NH3 fluxes to a parameter varies among urine patches. Moreover, the fluxes modelled with a dynamic soil pH are similar if a constant pH 7.5 is used, suggesting a useful simplification for regional-scale model application.
Tobias Houska, David Kraus, Ralf Kiese, and Lutz Breuer
Biogeosciences, 14, 3487–3508, https://doi.org/10.5194/bg-14-3487-2017, https://doi.org/10.5194/bg-14-3487-2017, 2017
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CO2 and N2O are two prominent GHGs contributing to global warming. We combined measurement and modelling to quantify GHG emissions from adjacent arable, forest and grassland sites in Germany. Measured emissions reveal seasonal patterns and management effects like fertilizer application, tillage, harvest and grazing. Modelling helps to estimate the magnitude and uncertainty of not measurable C and N fluxes and indicates missing input source, e.g. nitrate uptake from groundwater.
Kerry J. Dinsmore, Julia Drewer, Peter E. Levy, Charles George, Annalea Lohila, Mika Aurela, and Ute M. Skiba
Biogeosciences, 14, 799–815, https://doi.org/10.5194/bg-14-799-2017, https://doi.org/10.5194/bg-14-799-2017, 2017
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Release of greenhouse gases from northern soils contributes significantly to the global atmosphere and plays an important role in regulating climate. This study, based in N. Finland, aimed to measure and understand release of CH4 and N2O, and using satellite imagery, upscale our results to a 2 × 2 km area. Wetlands released large amounts of CH4, with emissions linked to temperature and the presence of Sphagnum; landscape emissions were 2.05 mg C m−2 hr−1. N2O fluxes were consistently near-zero.
Riinu Ots, Massimo Vieno, James D. Allan, Stefan Reis, Eiko Nemitz, Dominique E. Young, Hugh Coe, Chiara Di Marco, Anais Detournay, Ian A. Mackenzie, David C. Green, and Mathew R. Heal
Atmos. Chem. Phys., 16, 13773–13789, https://doi.org/10.5194/acp-16-13773-2016, https://doi.org/10.5194/acp-16-13773-2016, 2016
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Emissions of cooking organic aerosol (COA; from charbroiling, frying, etc.) are currently absent in European emissions inventories yet measurements have pointed to significant COA concentrations. In this study, emissions of COA were developed for the UK by model iteration against year-long measurements at two sites in London. Modelled COA dropped rapidly outside of major urban areas, suggesting that although a notable component in UK urban air, COA does not have a significant effect on rural PM.
Marsailidh M. Twigg, Evgenia Ilyinskaya, Sonya Beccaceci, David C. Green, Matthew R. Jones, Ben Langford, Sarah R. Leeson, Justin J. N. Lingard, Gloria M. Pereira, Heather Carter, Jan Poskitt, Andreas Richter, Stuart Ritchie, Ivan Simmons, Ron I. Smith, Y. Sim Tang, Netty Van Dijk, Keith Vincent, Eiko Nemitz, Massimo Vieno, and Christine F. Braban
Atmos. Chem. Phys., 16, 11415–11431, https://doi.org/10.5194/acp-16-11415-2016, https://doi.org/10.5194/acp-16-11415-2016, 2016
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This study integrates high and low resolution temporal measurements to assess the impact of the Holuhraun effusive eruption in 2014 across the UK. Measurements, modelling and satellite analysis provides details on the transport and chemistry of both gases and particulates during this unique event. The results of the study can be used verify existing atmospheric chemistry models of volcano plumes in order to carry improved risk assessments for future volcanic eruptions.
A. M. Yáñez-Serrano, A. C. Nölscher, E. Bourtsoukidis, B. Derstroff, N. Zannoni, V. Gros, M. Lanza, J. Brito, S. M. Noe, E. House, C. N. Hewitt, B. Langford, E. Nemitz, T. Behrendt, J. Williams, P. Artaxo, M. O. Andreae, and J. Kesselmeier
Atmos. Chem. Phys., 16, 10965–10984, https://doi.org/10.5194/acp-16-10965-2016, https://doi.org/10.5194/acp-16-10965-2016, 2016
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This paper provides a general overview of methyl ethyl ketone (MEK) ambient observations in different ecosystems around the world in order to provide insights into the sources, sink and role of MEK in the atmosphere.
Nicholas J. Cowan, Peter E. Levy, Daniela Famulari, Margaret Anderson, Julia Drewer, Marco Carozzi, David S. Reay, and Ute M. Skiba
Biogeosciences, 13, 4811–4821, https://doi.org/10.5194/bg-13-4811-2016, https://doi.org/10.5194/bg-13-4811-2016, 2016
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Using a quantum cascade laser we measured N2O fluxes before and after a tillage event on a long-term grazed grassland field using the flux chamber and eddy covariance methods. The measurements were gap-filled using a generalised additive model which used meteorological data at the site. Results suggest that tillage of soils containing plant material (crop residues) releases a relatively large amount of N2O-N, similar in magnitude to approximately 0.9 % of the nitrogen in the plant materials.
Carole Helfter, Anja H. Tremper, Christoforos H. Halios, Simone Kotthaus, Alex Bjorkegren, C. Sue B. Grimmond, Janet F. Barlow, and Eiko Nemitz
Atmos. Chem. Phys., 16, 10543–10557, https://doi.org/10.5194/acp-16-10543-2016, https://doi.org/10.5194/acp-16-10543-2016, 2016
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There are relatively few long-term, direct measurements of pollutant emissions in urban settings. We present over 3 years of measurements of fluxes of CO, CO2 and CH4, study their respective temporal and spatial dynamics and offer an independent verification of the London Atmospheric Emissions Inventory. CO and CO2 were strongly controlled by traffic and well characterised by the inventory whilst measured CH4 was two-fold larger and linked to natural gas usage and perhaps biogenic sources.
Giancarlo Ciarelli, Sebnem Aksoyoglu, Monica Crippa, Jose-Luis Jimenez, Eriko Nemitz, Karine Sellegri, Mikko Äijälä, Samara Carbone, Claudia Mohr, Colin O'Dowd, Laurent Poulain, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 16, 10313–10332, https://doi.org/10.5194/acp-16-10313-2016, https://doi.org/10.5194/acp-16-10313-2016, 2016
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Recent studies based on aerosol mass spectrometer measurements revealed that the organic fraction dominates the non-refractory PM1 composition. However its representation in chemical transport models is still very challenging due to uncertainties in emission sources and formation pathways. In this study, a novel organic aerosol scheme was tested in the regional air quality model CAMx and results were compared with ambient measurements at 11 different sites in Europe.
Thimo Klotzbücher, Karsten Kalbitz, Chiara Cerli, Peter J. Hernes, and Klaus Kaiser
SOIL, 2, 325–335, https://doi.org/10.5194/soil-2-325-2016, https://doi.org/10.5194/soil-2-325-2016, 2016
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Uncertainties concerning stabilization of organic compounds in soil limit our basic understanding on soil organic matter (SOM) formation and our ability to model and manage effects of global change on SOM stocks. One controversially debated aspect is the contribution of aromatic litter components, such as lignin and tannins, to stable SOM forms. Here, we summarize and discuss the inconsistencies and propose research options to clear them.
Amy P. Sullivan, Natasha Hodas, Barbara J. Turpin, Kate Skog, Frank N. Keutsch, Stefania Gilardoni, Marco Paglione, Matteo Rinaldi, Stefano Decesari, Maria Cristina Facchini, Laurent Poulain, Hartmut Herrmann, Alfred Wiedensohler, Eiko Nemitz, Marsailidh M. Twigg, and Jeffrey L. Collett Jr.
Atmos. Chem. Phys., 16, 8095–8108, https://doi.org/10.5194/acp-16-8095-2016, https://doi.org/10.5194/acp-16-8095-2016, 2016
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This paper presents the results from our measurements and approach for the investigation of aqueous secondary organic aerosol (aqSOA) formation in the ambient atmosphere. When local aqSOA formation was observed, a correlation of water-soluble organic carbon with organic aerosol, aerosol liquid water, relative humidity, and aerosol nitrate was found. Key factors of local aqSOA production include air mass stagnation, formation of local nitrate overnight, and significant amounts of ammonia.
Simon Schallhart, Pekka Rantala, Eiko Nemitz, Ditte Taipale, Ralf Tillmann, Thomas F. Mentel, Benjamin Loubet, Giacomo Gerosa, Angelo Finco, Janne Rinne, and Taina M. Ruuskanen
Atmos. Chem. Phys., 16, 7171–7194, https://doi.org/10.5194/acp-16-7171-2016, https://doi.org/10.5194/acp-16-7171-2016, 2016
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We present ecosystem exchange fluxes from a mixed oak–hornbeam forest in the Po Valley, Italy. Detectable fluxes were observed for 29 compounds, dominated by isoprene, which comprised over 60 % of the upward flux. Methanol seemed to be deposited to dew, as the deposition happened in the early morning. We estimated that up to 30 % of the upward flux of methyl vinyl ketone and methacrolein originated from atmospheric oxidation of isoprene.
W. Joe F. Acton, Simon Schallhart, Ben Langford, Amy Valach, Pekka Rantala, Silvano Fares, Giulia Carriero, Ralf Tillmann, Sam J. Tomlinson, Ulrike Dragosits, Damiano Gianelle, C. Nicholas Hewitt, and Eiko Nemitz
Atmos. Chem. Phys., 16, 7149–7170, https://doi.org/10.5194/acp-16-7149-2016, https://doi.org/10.5194/acp-16-7149-2016, 2016
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Volatile organic compounds (VOCs) represent a large source of reactive carbon in the atmosphere and hence have a significant impact on air quality. It is therefore important that we can accurately quantify their emission. In this paper we use three methods to determine the fluxes of reactive VOCs from a woodland canopy. We show that two different canopy-scale measurement methods give good agreement, whereas estimates based on leaf-level-based emission underestimate isoprene fluxes.
Riinu Ots, Dominique E. Young, Massimo Vieno, Lu Xu, Rachel E. Dunmore, James D. Allan, Hugh Coe, Leah R. Williams, Scott C. Herndon, Nga L. Ng, Jacqueline F. Hamilton, Robert Bergström, Chiara Di Marco, Eiko Nemitz, Ian A. Mackenzie, Jeroen J. P. Kuenen, David C. Green, Stefan Reis, and Mathew R. Heal
Atmos. Chem. Phys., 16, 6453–6473, https://doi.org/10.5194/acp-16-6453-2016, https://doi.org/10.5194/acp-16-6453-2016, 2016
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This study investigates the contribution of diesel vehicle emissions to organic aerosol formation and particulate matter concentrations in London. Comparisons of simulated pollutant concentrations with observations show good agreement and give confidence in the skill of the model applied. The contribution of diesel vehicle emissions, which are currently not included in official emissions inventories, is demonstrated to be substantial, indicating that more research on this topic is required.
Rebecca M. McKenzie, Mustafa Z. Özel, J. Neil Cape, Julia Drewer, Kerry J. Dinsmore, Eiko Nemitz, Y. Sim Tang, Netty van Dijk, Margaret Anderson, Jacqueline F. Hamilton, Mark A. Sutton, Martin W. Gallagher, and Ute Skiba
Biogeosciences, 13, 2353–2365, https://doi.org/10.5194/bg-13-2353-2016, https://doi.org/10.5194/bg-13-2353-2016, 2016
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Dissolved organic nitrogen (DON) contributes significantly to the overall nitrogen budget and can potentially be biologically available as a source of N. Despite this it is not routinely measured. This study found that DON contributed up to 10 % of the total dissolved nitrogen (TDN) found in precipitation and was the most dominant fraction in soil water (99 %) and stream water (75 %).
Andrea Móring, Massimo Vieno, Ruth M. Doherty, Johannes Laubach, Arezoo Taghizadeh-Toosi, and Mark A. Sutton
Biogeosciences, 13, 1837–1861, https://doi.org/10.5194/bg-13-1837-2016, https://doi.org/10.5194/bg-13-1837-2016, 2016
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A process-based, weather-driven model for ammonia emission from a urine patch has been developed and its sensitivity to various factors assessed. The model can simulate the ammoniacal nitrogen content, pH and the water content of the soil under a urine patch.
The simulated variables were in a good agreement with the measurements. The sensitivity analysis highlighted the vital role of temperature in ammonia exchange. The model is potentially suitable for larger scale application.
Miguel Portillo-Estrada, Mari Pihlatie, Janne F. J. Korhonen, Janne Levula, Arnoud K. F. Frumau, Andreas Ibrom, Jonas J. Lembrechts, Lourdes Morillas, László Horváth, Stephanie K. Jones, and Ülo Niinemets
Biogeosciences, 13, 1621–1633, https://doi.org/10.5194/bg-13-1621-2016, https://doi.org/10.5194/bg-13-1621-2016, 2016
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We studied tree and grass litter decomposition across several climates in Europe. Climatic (air temperature, precipitation and soil water content) controls on litter decomposition were quantitatively more important than species or site of origin. The data were used to generate prediction models of remaining litter mass, and carbon and nitrogen contents during the decomposition period. We also observed a significant drop in remaining litter mass after the first couple of days of decomposition.
D. Fowler, C. E. Steadman, D. Stevenson, M. Coyle, R. M. Rees, U. M. Skiba, M. A. Sutton, J. N. Cape, A. J. Dore, M. Vieno, D. Simpson, S. Zaehle, B. D. Stocker, M. Rinaldi, M. C. Facchini, C. R. Flechard, E. Nemitz, M. Twigg, J. W. Erisman, K. Butterbach-Bahl, and J. N. Galloway
Atmos. Chem. Phys., 15, 13849–13893, https://doi.org/10.5194/acp-15-13849-2015, https://doi.org/10.5194/acp-15-13849-2015, 2015
P. Kountouris, C. Gerbig, K.-U. Totsche, A. J. Dolman, A. G. C. A. Meesters, G. Broquet, F. Maignan, B. Gioli, L. Montagnani, and C. Helfter
Biogeosciences, 12, 7403–7421, https://doi.org/10.5194/bg-12-7403-2015, https://doi.org/10.5194/bg-12-7403-2015, 2015
O. Perez-Priego, J. Guan, M. Rossini, F. Fava, T. Wutzler, G. Moreno, N. Carvalhais, A. Carrara, O. Kolle, T. Julitta, M. Schrumpf, M. Reichstein, and M. Migliavacca
Biogeosciences, 12, 6351–6367, https://doi.org/10.5194/bg-12-6351-2015, https://doi.org/10.5194/bg-12-6351-2015, 2015
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Sun-induced chlorophyll fluorescence and photochemical reflectance index revealed controls of climate and nutrient availability on photosynthesis (gross primary production, GPP). Meteo-driven models (MMs) were unable to describe nutrient-induced effects on GPP. Important implications can be derived from these results, and uncertainties in the prediction of global GPP still remain when MMs do not account for plant nutrient availability.
B. Langford, W. Acton, C. Ammann, A. Valach, and E. Nemitz
Atmos. Meas. Tech., 8, 4197–4213, https://doi.org/10.5194/amt-8-4197-2015, https://doi.org/10.5194/amt-8-4197-2015, 2015
S. Visser, J. G. Slowik, M. Furger, P. Zotter, N. Bukowiecki, F. Canonaco, U. Flechsig, K. Appel, D. C. Green, A. H. Tremper, D. E. Young, P. I. Williams, J. D. Allan, H. Coe, L. R. Williams, C. Mohr, L. Xu, N. L. Ng, E. Nemitz, J. F. Barlow, C. H. Halios, Z. L. Fleming, U. Baltensperger, and A. S. H. Prévôt
Atmos. Chem. Phys., 15, 11291–11309, https://doi.org/10.5194/acp-15-11291-2015, https://doi.org/10.5194/acp-15-11291-2015, 2015
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Trace element measurements in three particle size ranges (PM10-2.5, PM2.5-1.0 and PM1.0-0.3) were performed with 2h time resolution at kerbside, urban background and rural sites during the ClearfLo winter 2012 campaign in London. The environment-dependent variability of emissions was characterized using the Multilinear Engine implementation of the positive matrix factorization model. A total of nine different factors were resolved from local, regional and natural origin.
J. G. Levine, A. R. MacKenzie, O. J. Squire, A. T. Archibald, P. T. Griffiths, N. L. Abraham, J. A. Pyle, D. E. Oram, G. Forster, J. F. Brito, J. D. Lee, J. R. Hopkins, A. C. Lewis, S. J. B. Bauguitte, C. F. Demarco, P. Artaxo, P. Messina, J. Lathière, D. A. Hauglustaine, E. House, C. N. Hewitt, and E. Nemitz
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-24251-2015, https://doi.org/10.5194/acpd-15-24251-2015, 2015
Revised manuscript has not been submitted
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This study explores our ability to simulate atmospheric chemistry stemming from isoprene emissions—a reactive gas emitted from vegetation—in pristine and polluted regions of the Amazon basin. We explore how two contrasting models fare in reproducing recent airborne measurements in the region. Their differing treatments of transport and mixing are found to: profoundly affect their performance; and yield very different pictures of the exposure of the rainforest to harmful ozone concentrations.
M. S. Torn, A. Chabbi, P. Crill, P. J. Hanson, I. A. Janssens, Y. Luo, C. H. Pries, C. Rumpel, M. W. I. Schmidt, J. Six, M. Schrumpf, and B. Zhu
SOIL, 1, 575–582, https://doi.org/10.5194/soil-1-575-2015, https://doi.org/10.5194/soil-1-575-2015, 2015
P. S. Monks, A. T. Archibald, A. Colette, O. Cooper, M. Coyle, R. Derwent, D. Fowler, C. Granier, K. S. Law, G. E. Mills, D. S. Stevenson, O. Tarasova, V. Thouret, E. von Schneidemesser, R. Sommariva, O. Wild, and M. L. Williams
Atmos. Chem. Phys., 15, 8889–8973, https://doi.org/10.5194/acp-15-8889-2015, https://doi.org/10.5194/acp-15-8889-2015, 2015
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Ozone holds a certain fascination in atmospheric science. It is ubiquitous in the atmosphere, central to tropospheric oxidation chemistry, and yet harmful to human and ecosystem health as well as being an important greenhouse gas. It is not emitted into the atmosphere but is a byproduct of the very oxidation chemistry it largely initiates. This review examines current understanding of the processes regulating tropospheric ozone at global to local scales from both measurements and models.
S. Fuzzi, U. Baltensperger, K. Carslaw, S. Decesari, H. Denier van der Gon, M. C. Facchini, D. Fowler, I. Koren, B. Langford, U. Lohmann, E. Nemitz, S. Pandis, I. Riipinen, Y. Rudich, M. Schaap, J. G. Slowik, D. V. Spracklen, E. Vignati, M. Wild, M. Williams, and S. Gilardoni
Atmos. Chem. Phys., 15, 8217–8299, https://doi.org/10.5194/acp-15-8217-2015, https://doi.org/10.5194/acp-15-8217-2015, 2015
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Particulate matter (PM) constitutes one of the most challenging problems both for air quality and climate change policies. This paper reviews the most recent scientific results on the issue and the policy needs that have driven much of the increase in monitoring and mechanistic research over the last 2 decades. The synthesis reveals many new processes and developments in the science underpinning climate-PM interactions and the effects of PM on human health and the environment.
M. M. Twigg, C. F. Di Marco, S. Leeson, N. van Dijk, M. R. Jones, I. D. Leith, E. Morrison, M. Coyle, R. Proost, A. N. M. Peeters, E. Lemon, T. Frelink, C. F. Braban, E. Nemitz, and J. N. Cape
Atmos. Chem. Phys., 15, 8131–8145, https://doi.org/10.5194/acp-15-8131-2015, https://doi.org/10.5194/acp-15-8131-2015, 2015
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Hourly inorganic composition of UK background particulate matter (PM10 and PM2.5) has been studied for a 6.5-year period at Auchencorth Moss, Scotland. Long-range transport of both anthropogenic secondary and natural primary PM is observed, driven primarily by meteorology. The importance of nitrate, sulfate and ammonium during pollution events in the UK is demonstrated.
A. C. Valach, B. Langford, E. Nemitz, A. R. MacKenzie, and C. N. Hewitt
Atmos. Chem. Phys., 15, 7777–7796, https://doi.org/10.5194/acp-15-7777-2015, https://doi.org/10.5194/acp-15-7777-2015, 2015
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Concentrations and fluxes of selected volatile organic compounds were measured over a 5-month period in central London as part of the ClearfLo project using a proton transfer reaction mass spectrometer. Emission sources within the city were inferred from spatio-temporal patterns and showed a detectable biogenic source during warmer months, which was modelled using the Guenther 95 algorithm. Comparisons were made with the local emissions inventories showing mostly underestimated emissions.
C. C. Hoerger, A. Claude, C. Plass-Duelmer, S. Reimann, E. Eckart, R. Steinbrecher, J. Aalto, J. Arduini, N. Bonnaire, J. N. Cape, A. Colomb, R. Connolly, J. Diskova, P. Dumitrean, C. Ehlers, V. Gros, H. Hakola, M. Hill, J. R. Hopkins, J. Jäger, R. Junek, M. K. Kajos, D. Klemp, M. Leuchner, A. C. Lewis, N. Locoge, M. Maione, D. Martin, K. Michl, E. Nemitz, S. O'Doherty, P. Pérez Ballesta, T. M. Ruuskanen, S. Sauvage, N. Schmidbauer, T. G. Spain, E. Straube, M. Vana, M. K. Vollmer, R. Wegener, and A. Wenger
Atmos. Meas. Tech., 8, 2715–2736, https://doi.org/10.5194/amt-8-2715-2015, https://doi.org/10.5194/amt-8-2715-2015, 2015
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The performance of 20 European laboratories involved in long-term non-methane hydrocarbon (NMHC) measurements was assessed with respect to ACTRIS and GAW data quality objectives. The participants were asked to measure both a 30-component NMHC mixture in nitrogen and whole air. The NMHCs were analysed either by GC-FID or GC-MS. Most systems performed well for the NMHC in nitrogen, whereas in air more scatter was observed. Reasons for this are explained in the paper.
C. Helfter, C. Campbell, K. J. Dinsmore, J. Drewer, M. Coyle, M. Anderson, U. Skiba, E. Nemitz, M. F. Billett, and M. A. Sutton
Biogeosciences, 12, 1799–1811, https://doi.org/10.5194/bg-12-1799-2015, https://doi.org/10.5194/bg-12-1799-2015, 2015
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The CO2 sink strength of a temperate peatland in SE Scotland exhibited large inter-annual variability which was well-correlated to the length of the growing season. Mean winter air temperature explained 87% of the inter-annual variability in the sink strength of the following summer, indicating a phenological memory effect. Autotrophic respiration is thought to be dominant, but heterotrophic processes might have been enhanced during dry spells increasing the loss of CO2 to the atmosphere.
N. J. Cowan, P. Norman, D. Famulari, P. E. Levy, D. S. Reay, and U. M. Skiba
Biogeosciences, 12, 1585–1596, https://doi.org/10.5194/bg-12-1585-2015, https://doi.org/10.5194/bg-12-1585-2015, 2015
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The spatial variability of N2O fluxes measured at the field scale were investigated using a high-precision closed loop dynamic chamber. The results highlight the large and often unpredictable variation in N2O flux magnitude measured from agricultural soils at a relatively small scale. Available nitrogen content of the soils accounts for some of the variability in N2O emissions. The study suggests animal waste is an important source of N2O emissions released from livestock farms.
S. Sitch, P. Friedlingstein, N. Gruber, S. D. Jones, G. Murray-Tortarolo, A. Ahlström, S. C. Doney, H. Graven, C. Heinze, C. Huntingford, S. Levis, P. E. Levy, M. Lomas, B. Poulter, N. Viovy, S. Zaehle, N. Zeng, A. Arneth, G. Bonan, L. Bopp, J. G. Canadell, F. Chevallier, P. Ciais, R. Ellis, M. Gloor, P. Peylin, S. L. Piao, C. Le Quéré, B. Smith, Z. Zhu, and R. Myneni
Biogeosciences, 12, 653–679, https://doi.org/10.5194/bg-12-653-2015, https://doi.org/10.5194/bg-12-653-2015, 2015
N. J. Cowan, D. Famulari, P. E. Levy, M. Anderson, D. S. Reay, and U. M. Skiba
Atmos. Meas. Tech., 7, 4455–4462, https://doi.org/10.5194/amt-7-4455-2014, https://doi.org/10.5194/amt-7-4455-2014, 2014
S. J. O'Shea, G. Allen, M. W. Gallagher, K. Bower, S. M. Illingworth, J. B. A. Muller, B. T. Jones, C. J. Percival, S. J-B. Bauguitte, M. Cain, N. Warwick, A. Quiquet, U. Skiba, J. Drewer, K. Dinsmore, E. G. Nisbet, D. Lowry, R. E. Fisher, J. L. France, M. Aurela, A. Lohila, G. Hayman, C. George, D. B. Clark, A. J. Manning, A. D. Friend, and J. Pyle
Atmos. Chem. Phys., 14, 13159–13174, https://doi.org/10.5194/acp-14-13159-2014, https://doi.org/10.5194/acp-14-13159-2014, 2014
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This paper presents airborne measurements of greenhouse gases collected in the European Arctic. Regional scale flux estimates for the northern Scandinavian wetlands are derived. These fluxes are found to be in excellent agreement with coincident surface measurements within the aircraft's sampling domain. This has allowed a significant low bias to be identified in two commonly used process-based land surface models.
C. Kalogridis, V. Gros, R. Sarda-Esteve, B. Langford, B. Loubet, B. Bonsang, N. Bonnaire, E. Nemitz, A.-C. Genard, C. Boissard, C. Fernandez, E. Ormeño, D. Baisnée, I. Reiter, and J. Lathière
Atmos. Chem. Phys., 14, 10085–10102, https://doi.org/10.5194/acp-14-10085-2014, https://doi.org/10.5194/acp-14-10085-2014, 2014
C. Fountoukis, A. G. Megaritis, K. Skyllakou, P. E. Charalampidis, C. Pilinis, H. A. C. Denier van der Gon, M. Crippa, F. Canonaco, C. Mohr, A. S. H. Prévôt, J. D. Allan, L. Poulain, T. Petäjä, P. Tiitta, S. Carbone, A. Kiendler-Scharr, E. Nemitz, C. O'Dowd, E. Swietlicki, and S. N. Pandis
Atmos. Chem. Phys., 14, 9061–9076, https://doi.org/10.5194/acp-14-9061-2014, https://doi.org/10.5194/acp-14-9061-2014, 2014
M. Vieno, M. R. Heal, S. Hallsworth, D. Famulari, R. M. Doherty, A. J. Dore, Y. S. Tang, C. F. Braban, D. Leaver, M. A. Sutton, and S. Reis
Atmos. Chem. Phys., 14, 8435–8447, https://doi.org/10.5194/acp-14-8435-2014, https://doi.org/10.5194/acp-14-8435-2014, 2014
J. B. Fisher, M. Sikka, W. C. Oechel, D. N. Huntzinger, J. R. Melton, C. D. Koven, A. Ahlström, M. A. Arain, I. Baker, J. M. Chen, P. Ciais, C. Davidson, M. Dietze, B. El-Masri, D. Hayes, C. Huntingford, A. K. Jain, P. E. Levy, M. R. Lomas, B. Poulter, D. Price, A. K. Sahoo, K. Schaefer, H. Tian, E. Tomelleri, H. Verbeeck, N. Viovy, R. Wania, N. Zeng, and C. E. Miller
Biogeosciences, 11, 4271–4288, https://doi.org/10.5194/bg-11-4271-2014, https://doi.org/10.5194/bg-11-4271-2014, 2014
M. Crippa, F. Canonaco, V. A. Lanz, M. Äijälä, J. D. Allan, S. Carbone, G. Capes, D. Ceburnis, M. Dall'Osto, D. A. Day, P. F. DeCarlo, M. Ehn, A. Eriksson, E. Freney, L. Hildebrandt Ruiz, R. Hillamo, J. L. Jimenez, H. Junninen, A. Kiendler-Scharr, A.-M. Kortelainen, M. Kulmala, A. Laaksonen, A. A. Mensah, C. Mohr, E. Nemitz, C. O'Dowd, J. Ovadnevaite, S. N. Pandis, T. Petäjä, L. Poulain, S. Saarikoski, K. Sellegri, E. Swietlicki, P. Tiitta, D. R. Worsnop, U. Baltensperger, and A. S. H. Prévôt
Atmos. Chem. Phys., 14, 6159–6176, https://doi.org/10.5194/acp-14-6159-2014, https://doi.org/10.5194/acp-14-6159-2014, 2014
O. Peltola, A. Hensen, C. Helfter, L. Belelli Marchesini, F. C. Bosveld, W. C. M. van den Bulk, J. A. Elbers, S. Haapanala, J. Holst, T. Laurila, A. Lindroth, E. Nemitz, T. Röckmann, A. T. Vermeulen, and I. Mammarella
Biogeosciences, 11, 3163–3186, https://doi.org/10.5194/bg-11-3163-2014, https://doi.org/10.5194/bg-11-3163-2014, 2014
E. Boegh, R. Houborg, J. Bienkowski, C. F. Braban, T. Dalgaard, N. van Dijk, U. Dragosits, E. Holmes, V. Magliulo, K. Schelde, P. Di Tommasi, L. Vitale, M. R. Theobald, P. Cellier, and M. A. Sutton
Biogeosciences, 10, 6279–6307, https://doi.org/10.5194/bg-10-6279-2013, https://doi.org/10.5194/bg-10-6279-2013, 2013
J. Schmale, J. Schneider, E. Nemitz, Y. S. Tang, U. Dragosits, T. D. Blackall, P. N. Trathan, G. J. Phillips, M. Sutton, and C. F. Braban
Atmos. Chem. Phys., 13, 8669–8694, https://doi.org/10.5194/acp-13-8669-2013, https://doi.org/10.5194/acp-13-8669-2013, 2013
C. R. Flechard, R.-S. Massad, B. Loubet, E. Personne, D. Simpson, J. O. Bash, E. J. Cooter, E. Nemitz, and M. A. Sutton
Biogeosciences, 10, 5183–5225, https://doi.org/10.5194/bg-10-5183-2013, https://doi.org/10.5194/bg-10-5183-2013, 2013
E. Solly, I. Schöning, S. Boch, J. Müller, S. A. Socher, S. E. Trumbore, and M. Schrumpf
Biogeosciences, 10, 4833–4843, https://doi.org/10.5194/bg-10-4833-2013, https://doi.org/10.5194/bg-10-4833-2013, 2013
C. Le Quéré, R. J. Andres, T. Boden, T. Conway, R. A. Houghton, J. I. House, G. Marland, G. P. Peters, G. R. van der Werf, A. Ahlström, R. M. Andrew, L. Bopp, J. G. Canadell, P. Ciais, S. C. Doney, C. Enright, P. Friedlingstein, C. Huntingford, A. K. Jain, C. Jourdain, E. Kato, R. F. Keeling, K. Klein Goldewijk, S. Levis, P. Levy, M. Lomas, B. Poulter, M. R. Raupach, J. Schwinger, S. Sitch, B. D. Stocker, N. Viovy, S. Zaehle, and N. Zeng
Earth Syst. Sci. Data, 5, 165–185, https://doi.org/10.5194/essd-5-165-2013, https://doi.org/10.5194/essd-5-165-2013, 2013
M. Schrumpf, K. Kaiser, G. Guggenberger, T. Persson, I. Kögel-Knabner, and E.-D. Schulze
Biogeosciences, 10, 1675–1691, https://doi.org/10.5194/bg-10-1675-2013, https://doi.org/10.5194/bg-10-1675-2013, 2013
U. Skiba, S. K. Jones, J. Drewer, C. Helfter, M. Anderson, K. Dinsmore, R. McKenzie, E. Nemitz, and M. A. Sutton
Biogeosciences, 10, 1231–1241, https://doi.org/10.5194/bg-10-1231-2013, https://doi.org/10.5194/bg-10-1231-2013, 2013
J. T. Walker, M. R. Jones, J. O. Bash, L. Myles, T. Meyers, D. Schwede, J. Herrick, E. Nemitz, and W. Robarge
Biogeosciences, 10, 981–998, https://doi.org/10.5194/bg-10-981-2013, https://doi.org/10.5194/bg-10-981-2013, 2013
M. C. Braakhekke, T. Wutzler, C. Beer, J. Kattge, M. Schrumpf, B. Ahrens, I. Schöning, M. R. Hoosbeek, B. Kruijt, P. Kabat, and M. Reichstein
Biogeosciences, 10, 399–420, https://doi.org/10.5194/bg-10-399-2013, https://doi.org/10.5194/bg-10-399-2013, 2013
M. Crippa, P. F. DeCarlo, J. G. Slowik, C. Mohr, M. F. Heringa, R. Chirico, L. Poulain, F. Freutel, J. Sciare, J. Cozic, C. F. Di Marco, M. Elsasser, J. B. Nicolas, N. Marchand, E. Abidi, A. Wiedensohler, F. Drewnick, J. Schneider, S. Borrmann, E. Nemitz, R. Zimmermann, J.-L. Jaffrezo, A. S. H. Prévôt, and U. Baltensperger
Atmos. Chem. Phys., 13, 961–981, https://doi.org/10.5194/acp-13-961-2013, https://doi.org/10.5194/acp-13-961-2013, 2013
L. J. Sheppard, I. D. Leith, S. R. Leeson, N. van Dijk, C. Field, and P. Levy
Biogeosciences, 10, 149–160, https://doi.org/10.5194/bg-10-149-2013, https://doi.org/10.5194/bg-10-149-2013, 2013
E. Vogt, C. F. Braban, U. Dragosits, M. R. Theobald, M. F. Billett, A. J. Dore, Y. S. Tang, N. van Dijk, R. M. Rees, C. McDonald, S. Murray, U. M. Skiba, and M. A. Sutton
Biogeosciences, 10, 119–133, https://doi.org/10.5194/bg-10-119-2013, https://doi.org/10.5194/bg-10-119-2013, 2013
O. Hertel, C. A. Skjøth, S. Reis, A. Bleeker, R. M. Harrison, J. N. Cape, D. Fowler, U. Skiba, D. Simpson, T. Jickells, M. Kulmala, S. Gyldenkærne, L. L. Sørensen, J. W. Erisman, and M. A. Sutton
Biogeosciences, 9, 4921–4954, https://doi.org/10.5194/bg-9-4921-2012, https://doi.org/10.5194/bg-9-4921-2012, 2012
Related subject area
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A differentiable, physics-informed ecosystem modeling and learning framework for large-scale inverse problems: demonstration with photosynthesis simulations
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Using atmospheric observations to quantify annual biogenic carbon dioxide fluxes on the Alaska North Slope
Forest–atmosphere exchange of reactive nitrogen in a remote region – Part II: Modeling annual budgets
Growth and actual leaf temperature modulate CO2 responsiveness of monoterpene emissions from holm oak in opposite ways
Multi-year observations reveal a larger than expected autumn respiration signal across northeast Eurasia
Reviews and syntheses: VOC emissions from soil cover in boreal and temperate natural ecosystems of the Northern Hemisphere
Internal tree cycling and atmospheric archiving of mercury: examination with concentration and stable isotope analyses
Contrasting drought legacy effects on gross primary productivity in a mixed versus pure beech forest
CO2 and CH4 exchanges between moist moss tundra and atmosphere on Kapp Linné, Svalbard
Recent extreme drought events in the Amazon rainforest: assessment of different precipitation and evapotranspiration datasets and drought indicators
Variability and uncertainty in flux-site-scale net ecosystem exchange simulations based on machine learning and remote sensing: a systematic evaluation
Update of a biogeochemical model with process-based algorithms to predict ammonia volatilization from fertilized cultivated uplands and rice paddy fields
Massive warming-induced carbon loss from subalpine grassland soils in an altitudinal transplantation experiment
Climatic variation drives loss and restructuring of carbon and nitrogen in boreal forest wildfire
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Technical note: Incorporating expert domain knowledge into causal structure discovery workflows
Sensitivity of biomass burning emissions estimates to land surface information
Rosemary J. Eufemio, Galit Renzer, Mariah Rojas, Jolanta Miadlikowska, Todd L. Sformo, François Lutzoni, Boris A. Vinatzer, and Konrad Meister
Biogeosciences, 22, 2087–2096, https://doi.org/10.5194/bg-22-2087-2025, https://doi.org/10.5194/bg-22-2087-2025, 2025
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Biological ice nucleation plays key roles in organism survival and in shaping Earth’s atmospheric patterns. Our pan-American screening of Peltigera lichens reveals that the lichen thalli produce highly active ice nucleators (INs) resistant to freeze–thaw cycles. Notably, a pure fungal culture from Peltigera britannica released the most potent INs reported to date. Given the global abundance of these lichens, the INs may be important contributors to atmospheric processes.
Archana Dayalu, Marikate Mountain, Bharat Rastogi, John B. Miller, and Luciana Gatti
Biogeosciences, 22, 1509–1528, https://doi.org/10.5194/bg-22-1509-2025, https://doi.org/10.5194/bg-22-1509-2025, 2025
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The Amazon is facing unprecedented disturbance. Determining trends in Amazonia's carbon balance and its sensitivity to disturbance requires reliable vegetation models that adequately capture how its ecosystems exchange carbon with the atmosphere. Using ground- and satellite-based ecosystem products, we present an improved model of land–atmosphere vegetation carbon exchange across the Amazon. Our model agrees with independent aircraft observations from different locations.
Andrew S. Kowalski
Biogeosciences, 22, 785–789, https://doi.org/10.5194/bg-22-785-2025, https://doi.org/10.5194/bg-22-785-2025, 2025
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The laws of physics show that leaf oxygen is not photosynthetically enriched but extremely dilute due to the overwhelming effects of humidification. This challenges the prevailing diffusion-only paradigm regarding leaf gas exchanges because non-diffusive transport is required. Such transport also explains why fluxes of carbon dioxide and water vapour become decoupled at very high temperatures, as has been observed but not explained by plant physiologists.
Florian Wieland, Nadine Bothen, Ralph Schwidetzky, Teresa M. Seifried, Paul Bieber, Ulrich Pöschl, Konrad Meister, Mischa Bonn, Janine Fröhlich-Nowoisky, and Hinrich Grothe
Biogeosciences, 22, 103–115, https://doi.org/10.5194/bg-22-103-2025, https://doi.org/10.5194/bg-22-103-2025, 2025
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Betula pendula is a widespread birch tree species containing ice nucleation agents that can trigger the freezing of cloud droplets and thereby alter the evolution of clouds. Our study identifies three distinct ice-nucleating macromolecule (INM) aggregates of varying size that can nucleate ice at temperatures up to –5.4°C. Our findings suggest that these vegetation-derived particles may influence atmospheric processes, weather, and climate more strongly than previously thought.
Nicholas Cowan, Toby Roberts, Mark Hanlon, Aurelia Bezanger, Galina Toteva, Alex Tweedie, Karen Yeung, Ajinkya Deshpande, Peter Levy, Ute Skiba, Eiko Nemitz, and Julia Drewer
EGUsphere, https://doi.org/10.5194/egusphere-2024-3654, https://doi.org/10.5194/egusphere-2024-3654, 2024
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We measured soil hydrogen (H2) fluxes from two field sites, a managed grassland and a planted deciduous woodland, with flux measurements of H2 covering full seasonal cycles. We estimate annual H2 uptake of -3.1 ± 0.1 and -12.0 ± 0.4 kg H2 ha-1 yr-1 for the grassland and woodland sites, respectively. Soil moisture was found to be the primary driver of H2 uptake, with the clay content of the soils providing a physical barrier which limited H2 uptake.
Matthew G. Davis, Kevin Yan, and Jennifer G. Murphy
Biogeosciences, 21, 5381–5392, https://doi.org/10.5194/bg-21-5381-2024, https://doi.org/10.5194/bg-21-5381-2024, 2024
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Ammonia applied as fertilizer can volatilize into the atmosphere. This can threaten vulnerable ecosystems and human health. We investigated the partitioning of ammonia between an immobile adsorbed phase and mobile aqueous phase using several adsorption models. Using the Temkin model we determined that previous approaches to this issue may overestimate the quantity available for exchange by a factor of 5–20, suggesting that ammonia emissions from soil may be overestimated.
Annika Einbock and Franz Conen
Biogeosciences, 21, 5219–5231, https://doi.org/10.5194/bg-21-5219-2024, https://doi.org/10.5194/bg-21-5219-2024, 2024
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A small fraction of particles found at great heights in the atmosphere can freeze cloud droplets at temperatures of ≥ −10 °C and thus influence cloud properties. We provide a novel type of evidence that plant canopies are a major source of such biological ice-nucleating particles in the air above the Alps, potentially affecting mixed-phase cloud development.
Stephen E. Schwartz
Biogeosciences, 21, 5045–5057, https://doi.org/10.5194/bg-21-5045-2024, https://doi.org/10.5194/bg-21-5045-2024, 2024
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Anticorrelation in uptake of atmospheric CO2 following pulse emission or abrupt cessation of emissions is examined in two key model intercomparison studies. In both studies net transfer coefficients from the atmosphere to the world ocean and the terrestrial biosphere are anticorrelated across models, reducing inter-model diversity in decrease of atmospheric CO2 following the perturbation, increasing uncertainties of global warming potentials and consequences of prospective emission reductions.
Laura Dénise Nadolski, Tarek Sebastian El Madany, Jacob Allen Nelson, Arnaud Carrara, Gerardo Moreno, Richard K. F. Nair, Yunpeng Luo, Anke Hildebrandt, Victor Rolo, Markus Reichstein, and Sung-Ching Lee
EGUsphere, https://doi.org/10.5194/egusphere-2024-3190, https://doi.org/10.5194/egusphere-2024-3190, 2024
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Semi-arid ecosystems are crucial for Earth's carbon balance and are sensitive to changes in nitrogen (N) and phosphorus (P) levels. Their carbon dynamics are complex and not fully understood. We studied how long-term nutrient changes affect carbon exchange. In summer, N+P changed plant composition and productivity. In transitional seasons, carbon exchange was less weather-dependent with N. Adding N and N+P are increasing carbon exchange variability, driven by grass greenness.
Qian Li, Gil Lerner, Einat Bar, Efraim Lewinsohn, and Eran Tas
Biogeosciences, 21, 4133–4147, https://doi.org/10.5194/bg-21-4133-2024, https://doi.org/10.5194/bg-21-4133-2024, 2024
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Our research indicates that instantaneous changes in meteorological parameters better reflect drought-induced changes in the emission rates of biogenic volatile organic compounds (BVOCs) from natural vegetation than their absolute values. However, following a small amount of irrigation, this trend became more moderate or reversed, accompanied by a dramatic increase in BVOC emission rates. These findings advance our understanding of BVOC emissions under climate change.
Pia Gottschalk, Aram Kalhori, Zhan Li, Christian Wille, and Torsten Sachs
Biogeosciences, 21, 3593–3616, https://doi.org/10.5194/bg-21-3593-2024, https://doi.org/10.5194/bg-21-3593-2024, 2024
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To improve the accuracy of spatial carbon exchange estimates, we evaluated simple linear models for net ecosystem exchange (NEE) and gross primary productivity (GPP) and how they can be used to upscale the CO2 exchange of agricultural fields. The models are solely driven by Sentinel-2-derived vegetation indices (VIs). Evaluations show that different VIs have variable power to estimate NEE and GPP of crops in different years. The overall performance is as good as results from complex crop models.
Liliana Scapucci, Ankit Shekhar, Sergio Aranda-Barranco, Anastasiia Bolshakova, Lukas Hörtnagl, Mana Gharun, and Nina Buchmann
Biogeosciences, 21, 3571–3592, https://doi.org/10.5194/bg-21-3571-2024, https://doi.org/10.5194/bg-21-3571-2024, 2024
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Forests face increased exposure to “compound soil and atmospheric drought” (CSAD) events due to global warming. We examined the impacts and drivers of CO2 fluxes during CSAD events at multiple layers of a deciduous forest over 18 years. Results showed reduced net ecosystem productivity and forest-floor respiration during CSAD events, mainly driven by soil and atmospheric drought. This unpredictability in forest CO2 fluxes jeopardises reforestation projects aimed at mitigating CO2 emissions.
Piaopiao Ke, Anna Lintunen, Pasi Kolari, Annalea Lohila, Santeri Tuovinen, Janne Lampilahti, Roseline Thakur, Maija Peltola, Otso Peräkylä, Tuomo Nieminen, Ekaterina Ezhova, Mari Pihlatie, Asta Laasonen, Markku Koskinen, Helena Rautakoski, Laura Heimsch, Tom Kokkonen, Aki Vähä, Ivan Mammarella, Steffen Noe, Jaana Bäck, Veli-Matti Kerminen, and Markku Kulmala
EGUsphere, https://doi.org/10.5194/egusphere-2024-1967, https://doi.org/10.5194/egusphere-2024-1967, 2024
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Our research explores diverse ecosystems’ role in climate cooling via the concept of CarbonSink+ Potential. We measured CO2 uptake and loaal aerosol production in forests, farms, peatlands, urban gardens, and coastal areas across Finland and Estonia. The long-term data reveal that while forests are vital regarding CarbonSink+ Potential, farms and urban gardens also play significant roles. These insights can help optimize management policy of natural resource to mitigate global warming.
Tamara Emmerichs, Yen-Sen Lu, and Domenico Taraborrelli
Biogeosciences, 21, 3251–3269, https://doi.org/10.5194/bg-21-3251-2024, https://doi.org/10.5194/bg-21-3251-2024, 2024
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We assess the representation of the plant response to surface water in a global atmospheric chemistry model. This sensitivity is crucial for the return of precipitation back into the atmosphere and thus significantly impacts the representation of weather as well as air quality. The newly implemented response function reduces this process and has a better comparison with satellite observations. This yields a higher intensity of unusual warm periods and higher production of air pollutants.
Nina L. H. Kinney, Charles A. Hepburn, Matthew I. Gibson, Daniel Ballesteros, and Thomas F. Whale
Biogeosciences, 21, 3201–3214, https://doi.org/10.5194/bg-21-3201-2024, https://doi.org/10.5194/bg-21-3201-2024, 2024
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Molecules released from plant pollen induce the formation of ice from supercooled water at temperatures warm enough to suggest an underlying function for this activity. In this study we show that ice nucleators are ubiquitous in pollen. We suggest the molecules responsible fulfil some unrelated biological function and nucleate ice incidentally. The ubiquity of ice-nucleating molecules in pollen and particularly active examples reveal a greater potential for pollen to impact weather and climate.
Max Gaber, Yanghui Kang, Guy Schurgers, and Trevor Keenan
Biogeosciences, 21, 2447–2472, https://doi.org/10.5194/bg-21-2447-2024, https://doi.org/10.5194/bg-21-2447-2024, 2024
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Gross primary productivity (GPP) describes the photosynthetic carbon assimilation, which plays a vital role in the carbon cycle. We can measure GPP locally, but producing larger and continuous estimates is challenging. Here, we present an approach to extrapolate GPP to a global scale using satellite imagery and automated machine learning. We benchmark different models and predictor variables and achieve an estimate that can capture 75 % of the variation in GPP.
Sinikka J. Paulus, Rene Orth, Sung-Ching Lee, Anke Hildebrandt, Martin Jung, Jacob A. Nelson, Tarek Sebastian El-Madany, Arnaud Carrara, Gerardo Moreno, Matthias Mauder, Jannis Groh, Alexander Graf, Markus Reichstein, and Mirco Migliavacca
Biogeosciences, 21, 2051–2085, https://doi.org/10.5194/bg-21-2051-2024, https://doi.org/10.5194/bg-21-2051-2024, 2024
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Porous materials are known to reversibly trap water from the air, even at low humidity. However, this behavior is poorly understood for soils. In this analysis, we test whether eddy covariance is able to measure the so-called adsorption of atmospheric water vapor by soils. We find that this flux occurs frequently during dry nights in a Mediterranean ecosystem, while EC detects downwardly directed vapor fluxes. These results can help to map moisture uptake globally.
Luana Krebs, Susanne Burri, Iris Feigenwinter, Mana Gharun, Philip Meier, and Nina Buchmann
Biogeosciences, 21, 2005–2028, https://doi.org/10.5194/bg-21-2005-2024, https://doi.org/10.5194/bg-21-2005-2024, 2024
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This study explores year-round forest-floor greenhouse gas (GHG) fluxes in a Swiss spruce forest. Soil temperature and snow depth affected forest-floor respiration, while CH4 uptake was linked to snow cover. Negligible N2O fluxes were observed. In 2022, a warm year, CO2 emissions notably increased. The study suggests rising forest-floor GHG emissions due to climate change, impacting carbon sink behavior. Thus, for future forest management, continuous year-round GHG flux measurements are crucial.
Simone Rodrigues, Glauber Cirino, Demerval Moreira, Andrea Pozzer, Rafael Palácios, Sung-Ching Lee, Breno Imbiriba, José Nogueira, Maria Isabel Vitorino, and George Vourlitis
Biogeosciences, 21, 843–868, https://doi.org/10.5194/bg-21-843-2024, https://doi.org/10.5194/bg-21-843-2024, 2024
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The radiative effects of atmospheric particles are still unknown for a wide variety of species and types of vegetation present in Amazonian biomes. We examined the effects of aerosols on solar radiation and their impacts on photosynthesis in an area of semideciduous forest in the southern Amazon Basin. Under highly smoky-sky conditions, our results show substantial photosynthetic interruption (20–70 %), attributed specifically to the decrease in solar radiation and leaf canopy temperature.
Ruben B. Schulte, Jordi Vilà-Guerau de Arellano, Susanna Rutledge-Jonker, Shelley van der Graaf, Jun Zhang, and Margreet C. van Zanten
Biogeosciences, 21, 557–574, https://doi.org/10.5194/bg-21-557-2024, https://doi.org/10.5194/bg-21-557-2024, 2024
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We analyzed measurements with the aim of finding relations between the surface atmosphere exchange of NH3 and the CO2 uptake and transpiration by vegetation. We found a high correlation of daytime NH3 emissions with both latent heat flux and photosynthetically active radiation. Very few simultaneous measurements of NH3, CO2 fluxes and meteorological variables exist at sub-diurnal timescales. This study paves the way to finding more robust relations between the NH3 exchange flux and CO2 uptake.
Alex Mavrovic, Oliver Sonnentag, Juha Lemmetyinen, Carolina Voigt, Nick Rutter, Paul Mann, Jean-Daniel Sylvain, and Alexandre Roy
Biogeosciences, 20, 5087–5108, https://doi.org/10.5194/bg-20-5087-2023, https://doi.org/10.5194/bg-20-5087-2023, 2023
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We present an analysis of soil CO2 emissions in boreal and tundra regions during the non-growing season. We show that when the soil is completely frozen, soil temperature is the main control on CO2 emissions. When the soil is around the freezing point, with a mix of liquid water and ice, the liquid water content is the main control on CO2 emissions. This study highlights that the vegetation–snow–soil interactions must be considered to understand soil CO2 emissions during the non-growing season.
Yuhao Cui, Eri Tachibana, Kimitaka Kawamura, and Yuzo Miyazaki
Biogeosciences, 20, 4969–4980, https://doi.org/10.5194/bg-20-4969-2023, https://doi.org/10.5194/bg-20-4969-2023, 2023
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Fatty alcohols (FAs) are major components of surface lipids in plant leaves and serve as surface-active aerosols. Our study on the aerosol size distributions in a forest suggests that secondary FAs (SFAs) originated from plant waxes and that leaf senescence status is likely an important factor controlling the size distribution of SFAs. This study provides new insights into the sources of primary biological aerosol particles (PBAPs) and their effects on the aerosol ice nucleation activity.
Joyson Ahongshangbam, Liisa Kulmala, Jesse Soininen, Yasmin Frühauf, Esko Karvinen, Yann Salmon, Anna Lintunen, Anni Karvonen, and Leena Järvi
Biogeosciences, 20, 4455–4475, https://doi.org/10.5194/bg-20-4455-2023, https://doi.org/10.5194/bg-20-4455-2023, 2023
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Urban vegetation is important for removing urban CO2 emissions and cooling. We studied the response of urban trees' functions (photosynthesis and transpiration) to a heatwave and drought at four urban green areas in the city of Helsinki. We found that tree water use was increased during heatwave and drought periods, but there was no change in the photosynthesis rates. The heat and drought conditions were severe at the local scale but were not excessive enough to restrict urban trees' functions.
Ryan Vella, Andrea Pozzer, Matthew Forrest, Jos Lelieveld, Thomas Hickler, and Holger Tost
Biogeosciences, 20, 4391–4412, https://doi.org/10.5194/bg-20-4391-2023, https://doi.org/10.5194/bg-20-4391-2023, 2023
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We investigated the effect of the El Niño–Southern Oscillation (ENSO) on biogenic volatile organic compound (BVOC) emissions from plants. ENSO events can cause a significant increase in these emissions, which have a long-term impact on the Earth's atmosphere. Persistent ENSO conditions can cause long-term changes in vegetation, resulting in even higher BVOC emissions. We link ENSO-induced emission anomalies with driving atmospheric and vegetational variables.
Nadav Bekin and Nurit Agam
Biogeosciences, 20, 3791–3802, https://doi.org/10.5194/bg-20-3791-2023, https://doi.org/10.5194/bg-20-3791-2023, 2023
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The mechanisms of soil CO2 flux in dry desert soils are not fully understood. Yet studies conducted in desert ecosystems rarely discuss potential errors related to using the commonly used flux chambers in dry and bare soils. In our study, the conventional deployment practice of the chambers underestimated the instantaneous CO2 flux by up to 50 % and the total daily CO2 uptake by 35 %. This suggests that desert soils are a larger carbon sink than previously reported.
Rosemary J. Eufemio, Ingrid de Almeida Ribeiro, Todd L. Sformo, Gary A. Laursen, Valeria Molinero, Janine Fröhlich-Nowoisky, Mischa Bonn, and Konrad Meister
Biogeosciences, 20, 2805–2812, https://doi.org/10.5194/bg-20-2805-2023, https://doi.org/10.5194/bg-20-2805-2023, 2023
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Lichens, the dominant vegetation in the Arctic, contain ice nucleators (INs) that enable freezing close to 0°C. Yet the abundance, diversity, and function of lichen INs is unknown. Our screening of lichens across Alaska reveal that most species have potent INs. We find that lichens contain two IN populations which retain activity under environmentally relevant conditions. The ubiquity and stability of lichen INs suggest that they may have considerable impacts on local atmospheric patterns.
Doaa Aboelyazeed, Chonggang Xu, Forrest M. Hoffman, Jiangtao Liu, Alex W. Jones, Chris Rackauckas, Kathryn Lawson, and Chaopeng Shen
Biogeosciences, 20, 2671–2692, https://doi.org/10.5194/bg-20-2671-2023, https://doi.org/10.5194/bg-20-2671-2023, 2023
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Photosynthesis is critical for life and has been affected by the changing climate. Many parameters come into play while modeling, but traditional calibration approaches face many issues. Our framework trains coupled neural networks to provide parameters to a photosynthesis model. Using big data, we independently found parameter values that were correlated with those in the literature while giving higher correlation and reduced biases in photosynthesis rates.
Norbert Pirk, Kristoffer Aalstad, Yeliz A. Yilmaz, Astrid Vatne, Andrea L. Popp, Peter Horvath, Anders Bryn, Ane Victoria Vollsnes, Sebastian Westermann, Terje Koren Berntsen, Frode Stordal, and Lena Merete Tallaksen
Biogeosciences, 20, 2031–2047, https://doi.org/10.5194/bg-20-2031-2023, https://doi.org/10.5194/bg-20-2031-2023, 2023
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We measured the land–atmosphere exchange of CO2 and water vapor in alpine Norway over 3 years. The extremely snow-rich conditions in 2020 reduced the total annual evapotranspiration to 50 % and reduced the growing-season carbon assimilation to turn the ecosystem from a moderate annual carbon sink to an even stronger source. Our analysis suggests that snow cover anomalies are driving the most consequential short-term responses in this ecosystem’s functioning.
Hamadou Balde, Gabriel Hmimina, Yves Goulas, Gwendal Latouche, and Kamel Soudani
Biogeosciences, 20, 1473–1490, https://doi.org/10.5194/bg-20-1473-2023, https://doi.org/10.5194/bg-20-1473-2023, 2023
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This study focuses on the relationship between sun-induced chlorophyll fluorescence (SIF) and ecosystem gross primary productivity (GPP) across the ICOS European flux tower network. It shows that SIF, coupled with reflectance observations, explains over 80 % of the GPP variability across diverse ecosystems but fails to bring new information compared to reflectance alone at coarse spatial scales (~5 km). These findings have applications in agriculture and ecophysiological studies.
John T. Walker, Xi Chen, Zhiyong Wu, Donna Schwede, Ryan Daly, Aleksandra Djurkovic, A. Christopher Oishi, Eric Edgerton, Jesse Bash, Jennifer Knoepp, Melissa Puchalski, John Iiames, and Chelcy F. Miniat
Biogeosciences, 20, 971–995, https://doi.org/10.5194/bg-20-971-2023, https://doi.org/10.5194/bg-20-971-2023, 2023
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Better estimates of atmospheric nitrogen (N) deposition are needed to accurately assess ecosystem risk and impacts from deposition of nutrients and acidity. Using measurements and modeling, we estimate total N deposition of 6.7 kg N ha−1 yr−1 at a forest site in the southern Appalachian Mountains, a region sensitive to atmospheric deposition. Reductions in deposition of reduced forms of N (ammonia and ammonium) will be needed to meet the lowest estimates of N critical loads for the region.
Yi-Ying Chen and Sebastiaan Luyssaert
Biogeosciences, 20, 349–363, https://doi.org/10.5194/bg-20-349-2023, https://doi.org/10.5194/bg-20-349-2023, 2023
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Tropical cyclones are typically assumed to be associated with ecosystem damage. This study challenges this assumption and suggests that instead of reducing leaf area, cyclones in East Asia may increase leaf area by alleviating water stress.
Deborah F. McGlynn, Graham Frazier, Laura E. R. Barry, Manuel T. Lerdau, Sally E. Pusede, and Gabriel Isaacman-VanWertz
Biogeosciences, 20, 45–55, https://doi.org/10.5194/bg-20-45-2023, https://doi.org/10.5194/bg-20-45-2023, 2023
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Using a custom-made gas chromatography flame ionization detector, 2 years of speciated hourly biogenic volatile organic compound data were collected in a forest in central Virginia. We identify diurnal and seasonal variability in the data, which is shown to impact atmospheric oxidant budgets. A comparison with emission models identified discrepancies with implications for model outcomes. We suggest increased monitoring of speciated biogenic volatile organic compounds to improve modeled results.
Luke D. Schiferl, Jennifer D. Watts, Erik J. L. Larson, Kyle A. Arndt, Sébastien C. Biraud, Eugénie S. Euskirchen, Jordan P. Goodrich, John M. Henderson, Aram Kalhori, Kathryn McKain, Marikate E. Mountain, J. William Munger, Walter C. Oechel, Colm Sweeney, Yonghong Yi, Donatella Zona, and Róisín Commane
Biogeosciences, 19, 5953–5972, https://doi.org/10.5194/bg-19-5953-2022, https://doi.org/10.5194/bg-19-5953-2022, 2022
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As the Arctic rapidly warms, vast stores of thawing permafrost could release carbon dioxide (CO2) into the atmosphere. We combined observations of atmospheric CO2 concentrations from aircraft and a tower with observed CO2 fluxes from tundra ecosystems and found that the Alaskan North Slope in not a consistent source nor sink of CO2. Our study shows the importance of using both site-level and atmospheric measurements to constrain regional net CO2 fluxes and improve biogenic processes in models.
Pascal Wintjen, Frederik Schrader, Martijn Schaap, Burkhard Beudert, Richard Kranenburg, and Christian Brümmer
Biogeosciences, 19, 5287–5311, https://doi.org/10.5194/bg-19-5287-2022, https://doi.org/10.5194/bg-19-5287-2022, 2022
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For the first time, we compared four methods for estimating the annual dry deposition of total reactive nitrogen into a low-polluted forest ecosystem. In our analysis, we used 2.5 years of flux measurements, an in situ modeling approach, a large-scale chemical transport model (CTM), and canopy budget models. Annual nitrogen dry deposition budgets ranged between 4.3 and 6.7 kg N ha−1 a−1, depending on the applied method.
Michael Staudt, Juliane Daussy, Joseph Ingabire, and Nafissa Dehimeche
Biogeosciences, 19, 4945–4963, https://doi.org/10.5194/bg-19-4945-2022, https://doi.org/10.5194/bg-19-4945-2022, 2022
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We studied the short- and long-term effects of CO2 as a function of temperature on monoterpene emissions from holm oak. Similarly to isoprene, emissions decreased non-linearly with increasing CO2, with no differences among compounds and chemotypes. The CO2 response was modulated by actual leaf and growth temperature but not by growth CO2. Estimates of annual monoterpene release under double CO2 suggest that CO2 inhibition does not offset the increase in emissions due to expected warming.
Brendan Byrne, Junjie Liu, Yonghong Yi, Abhishek Chatterjee, Sourish Basu, Rui Cheng, Russell Doughty, Frédéric Chevallier, Kevin W. Bowman, Nicholas C. Parazoo, David Crisp, Xing Li, Jingfeng Xiao, Stephen Sitch, Bertrand Guenet, Feng Deng, Matthew S. Johnson, Sajeev Philip, Patrick C. McGuire, and Charles E. Miller
Biogeosciences, 19, 4779–4799, https://doi.org/10.5194/bg-19-4779-2022, https://doi.org/10.5194/bg-19-4779-2022, 2022
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Plants draw CO2 from the atmosphere during the growing season, while respiration releases CO2 to the atmosphere throughout the year, driving seasonal variations in atmospheric CO2 that can be observed by satellites, such as the Orbiting Carbon Observatory 2 (OCO-2). Using OCO-2 XCO2 data and space-based constraints on plant growth, we show that permafrost-rich northeast Eurasia has a strong seasonal release of CO2 during the autumn, hinting at an unexpectedly large respiration signal from soils.
Valery A. Isidorov and Andrej A. Zaitsev
Biogeosciences, 19, 4715–4746, https://doi.org/10.5194/bg-19-4715-2022, https://doi.org/10.5194/bg-19-4715-2022, 2022
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Biogenic volatile organic compounds (VOCs) play a critical role in earth-system processes: they are
main playersin the formation of tropospheric O3 and secondary aerosols, which have a significant impact on climate, human health and crops. A complex mixture of VOCs, formed as a result of physicochemical and biological processes, is released into the atmosphere from the forest floor. This review presents data on the composition of VOCs and contribution of various processes to their emissions.
David S. McLagan, Harald Biester, Tomas Navrátil, Stephan M. Kraemer, and Lorenz Schwab
Biogeosciences, 19, 4415–4429, https://doi.org/10.5194/bg-19-4415-2022, https://doi.org/10.5194/bg-19-4415-2022, 2022
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Spruce and larch trees are effective archiving species for historical atmospheric mercury using growth rings of bole wood. Mercury stable isotope analysis proved an effective tool to characterise industrial mercury signals and assess mercury uptake pathways (leaf uptake for both wood and bark) and mercury cycling within the trees. These data detail important information for understanding the mercury biogeochemical cycle particularly in forest systems.
Xin Yu, René Orth, Markus Reichstein, Michael Bahn, Anne Klosterhalfen, Alexander Knohl, Franziska Koebsch, Mirco Migliavacca, Martina Mund, Jacob A. Nelson, Benjamin D. Stocker, Sophia Walther, and Ana Bastos
Biogeosciences, 19, 4315–4329, https://doi.org/10.5194/bg-19-4315-2022, https://doi.org/10.5194/bg-19-4315-2022, 2022
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Identifying drought legacy effects is challenging because they are superimposed on variability driven by climate conditions in the recovery period. We develop a residual-based approach to quantify legacies on gross primary productivity (GPP) from eddy covariance data. The GPP reduction due to legacy effects is comparable to the concurrent effects at two sites in Germany, which reveals the importance of legacy effects. Our novel methodology can be used to quantify drought legacies elsewhere.
Anders Lindroth, Norbert Pirk, Ingibjörg S. Jónsdóttir, Christian Stiegler, Leif Klemedtsson, and Mats B. Nilsson
Biogeosciences, 19, 3921–3934, https://doi.org/10.5194/bg-19-3921-2022, https://doi.org/10.5194/bg-19-3921-2022, 2022
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We measured the fluxes of carbon dioxide and methane between a moist moss tundra and the atmosphere on Svalbard in order to better understand how such ecosystems are affecting the climate and vice versa. We found that the system was a small sink of carbon dioxide and a small source of methane. These fluxes are small in comparison with other tundra ecosystems in the high Arctic. Analysis of temperature sensitivity showed that respiration was more sensitive than photosynthesis above about 6 ℃.
Phillip Papastefanou, Christian S. Zang, Zlatan Angelov, Aline Anderson de Castro, Juan Carlos Jimenez, Luiz Felipe Campos De Rezende, Romina C. Ruscica, Boris Sakschewski, Anna A. Sörensson, Kirsten Thonicke, Carolina Vera, Nicolas Viovy, Celso Von Randow, and Anja Rammig
Biogeosciences, 19, 3843–3861, https://doi.org/10.5194/bg-19-3843-2022, https://doi.org/10.5194/bg-19-3843-2022, 2022
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The Amazon rainforest has been hit by multiple severe drought events. In this study, we assess the severity and spatial extent of the extreme drought years 2005, 2010 and 2015/16 in the Amazon. Using nine different precipitation datasets and three drought indicators we find large differences in drought stress across the Amazon region. We conclude that future studies should use multiple rainfall datasets and drought indicators when estimating the impact of drought stress in the Amazon region.
Haiyang Shi, Geping Luo, Olaf Hellwich, Mingjuan Xie, Chen Zhang, Yu Zhang, Yuangang Wang, Xiuliang Yuan, Xiaofei Ma, Wenqiang Zhang, Alishir Kurban, Philippe De Maeyer, and Tim Van de Voorde
Biogeosciences, 19, 3739–3756, https://doi.org/10.5194/bg-19-3739-2022, https://doi.org/10.5194/bg-19-3739-2022, 2022
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A number of studies have been conducted by using machine learning approaches to simulate carbon fluxes. We performed a meta-analysis of these net ecosystem exchange (NEE) simulations. Random forests and support vector machines performed better than other algorithms. Models with larger timescales had a lower accuracy. For different plant functional types (PFTs), there were significant differences in the predictors used and their effects on model accuracy.
Siqi Li, Wei Zhang, Xunhua Zheng, Yong Li, Shenghui Han, Rui Wang, Kai Wang, Zhisheng Yao, Chunyan Liu, and Chong Zhang
Biogeosciences, 19, 3001–3019, https://doi.org/10.5194/bg-19-3001-2022, https://doi.org/10.5194/bg-19-3001-2022, 2022
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The CNMM–DNDC model was modified to simulate ammonia volatilization (AV) from croplands. AV from cultivated uplands followed the first-order kinetics, which was jointly regulated by the factors of soil properties and meteorological conditions. AV simulation from rice paddy fields was improved by incorporating Jayaweera–Mikkelsen mechanisms. The modified model performed well in simulating the observed cumulative AV measured from 63 fertilization events in China.
Matthias Volk, Matthias Suter, Anne-Lena Wahl, and Seraina Bassin
Biogeosciences, 19, 2921–2937, https://doi.org/10.5194/bg-19-2921-2022, https://doi.org/10.5194/bg-19-2921-2022, 2022
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Because soils are an important sink for greenhouse gasses, we subjected sub-alpine grassland to a six-level climate change treatment.
Two independent methods showed that at warming > 1.5 °C the grassland ecosystem lost ca. 14 % or ca. 1 kg C m−2 in 5 years.
This shrinking of the terrestrial C sink implies a substantial positive feedback to the atmospheric greenhouse effect.
It is likely that this dramatic C loss is a transient effect before a new, climate-adjusted steady state is reached.
Johan A. Eckdahl, Jeppe A. Kristensen, and Daniel B. Metcalfe
Biogeosciences, 19, 2487–2506, https://doi.org/10.5194/bg-19-2487-2022, https://doi.org/10.5194/bg-19-2487-2022, 2022
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This study found climate to be a driving force for increasing per area emissions of greenhouse gases and removal of important nutrients from high-latitude forests due to wildfire. It used detailed direct measurements over a large area to uncover patterns and mechanisms of restructuring of forest carbon and nitrogen pools that are extrapolatable to larger regions. It also takes a step forward in filling gaps in global knowledge of northern forest response to climate-change-strengthened wildfires.
Sparkle L. Malone, Youmi Oh, Kyle A. Arndt, George Burba, Roisin Commane, Alexandra R. Contosta, Jordan P. Goodrich, Henry W. Loescher, Gregory Starr, and Ruth K. Varner
Biogeosciences, 19, 2507–2522, https://doi.org/10.5194/bg-19-2507-2022, https://doi.org/10.5194/bg-19-2507-2022, 2022
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To understand the CH4 flux potential of natural ecosystems and agricultural lands in the United States of America, a multi-scale CH4 observation network focused on CH4 flux rates, processes, and scaling methods is required. This can be achieved with a network of ground-based observations that are distributed based on climatic regions and land cover.
Bruna R. F. Oliveira, Jan J. Keizer, and Thomas Foken
Biogeosciences, 19, 2235–2243, https://doi.org/10.5194/bg-19-2235-2022, https://doi.org/10.5194/bg-19-2235-2022, 2022
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This study analyzes the impacts of this windthrow on the aerodynamic characteristics of zero-plane displacement and roughness length and, ultimately, their implications for the turbulent fluxes. The turbulent fluxes were only affected to a minor degree by the windthrow, but the footprint area of the flux tower changed markedly so that the target area of the measurements had to be redetermined.
Minttu Havu, Liisa Kulmala, Pasi Kolari, Timo Vesala, Anu Riikonen, and Leena Järvi
Biogeosciences, 19, 2121–2143, https://doi.org/10.5194/bg-19-2121-2022, https://doi.org/10.5194/bg-19-2121-2022, 2022
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The carbon sequestration potential of two street tree species and the soil beneath them was quantified with the urban land surface model SUEWS and the soil carbon model Yasso. The street tree plantings turned into a modest sink of carbon from the atmosphere after 14 years. Overall, the results indicate the importance of soil in urban carbon sequestration estimations, as soil respiration exceeded the carbon uptake in the early phase, due to the high initial carbon loss from the soil.
Jarmo Mäkelä, Laila Melkas, Ivan Mammarella, Tuomo Nieminen, Suyog Chandramouli, Rafael Savvides, and Kai Puolamäki
Biogeosciences, 19, 2095–2099, https://doi.org/10.5194/bg-19-2095-2022, https://doi.org/10.5194/bg-19-2095-2022, 2022
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Causal structure discovery algorithms have been making headway into Earth system sciences, and they can be used to increase our understanding on biosphere–atmosphere interactions. In this paper we present a procedure on how to utilize prior knowledge of the domain experts together with these algorithms in order to find more robust causal structure models. We also demonstrate how to avoid pitfalls such as over-fitting and concept drift during this process.
Makoto Saito, Tomohiro Shiraishi, Ryuichi Hirata, Yosuke Niwa, Kazuyuki Saito, Martin Steinbacher, Doug Worthy, and Tsuneo Matsunaga
Biogeosciences, 19, 2059–2078, https://doi.org/10.5194/bg-19-2059-2022, https://doi.org/10.5194/bg-19-2059-2022, 2022
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This study tested combinations of two sources of AGB data and two sources of LCC data and used the same burned area satellite data to estimate BB CO emissions. Our analysis showed large discrepancies in annual mean CO emissions and explicit differences in the simulated CO concentrations among the BB emissions estimates. This study has confirmed that BB emissions estimates are sensitive to the land surface information on which they are based.
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Short summary
We assessed the nitrogen (N), carbon (C) and greenhouse gas (GHG) budget from an intensively managed grassland in southern Scotland using flux budget calculations as well as changes in soil N and C pools over time. Estimates from flux budget calculations indicated that N and C were sequestered, whereas soil stock measurements indicated a smaller N storage and a loss of C from the ecosystem. The GHG sink strength of the net CO2 ecosystem exchange was strongly affected by CH4 and N2O emissions.
We assessed the nitrogen (N), carbon (C) and greenhouse gas (GHG) budget from an intensively...
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